Physics Commons^™

Optical Detection And Classification Of Phytoplankton Taxa Through Spectral Analysis, Daniel Tyler Sensi

USF Tampa Graduate Theses and Dissertations

Phytoplankton serve as the bottom of the marine food web and therefore play an essential role in marine ecosystems. On the other hand, coastal phytoplankton communities can adversely affect the marine ecosystem and humans. A variety of techniques have been developed to measure and study phytoplankton, including in situ methods (e.g., flow cytometry) and laboratory methods (e.g., microscopic taxonomy). These provide accurate measurements of phytoplankton taxa and concentrations, yet they are limited in space and time, and synoptic information is difficult to obtain with these techniques.

Optical remote sensing may provide complementary information for its synoptic nature, as demonstrated by …

The Characterization Of Volatiles Associated With Young Stellar Objects, Kari Anne Wojtkowski

Doctoral Dissertations

In the first portion of this work, we searched for differences in volatiles within a single star forming region, Rho Ophiuchi. We determined the amount, temperature, and composition of two ice features, the bending modes of CO₂ and H₂O at 15 µm and 6 µm, respectively, toward 28 Young Stellar Objects (YSOs). We found that more than 50% of the YSOs studied contained a portion of crystalline CO₂ ice. We also found that some sources with Flat or borderline Class II Spectral Energy Distributions (SEDs) have a larger abundance of CO₂ ice with respect to H₂O ice. In addition to …

Two-Photon Direct Frequency Comb Spectroscopy Of Rubidium, Sophia Lee Chen

Honors Papers

Precision spectroscopy measurements have contributed significantly to our understanding of the fundamental structure of atoms. Here we present an experiment involving a new precision spectroscopic technique using a femtosecond optical frequency comb to excite two-photon transitions in rubidium. A femtosecond optical frequency comb is an ultrashort, pulsed laser with tens of thousands of frequencies, equally spaced in frequency-space. These frequencies can be used to excite atoms to specific transitions. The frequency comb is a versatile instrument that can avoid many of the experimental uncertainties that are associated with other spectroscopic techniques. The specific technique we use is called velocity selective …

Standoff Laser Interferometric Photoacoustic Spectroscopy For The Detection Of Explosives, Logan Marcus

Electronic Theses and Dissertations

There will unfortunately always be a pressing need to detect and identify explosive materials. Performing detection at a standoff distance is much safer and this is the impetus for this work. Photoacoustic spectroscopy is well suited to the task of explosive detection at a standoff distance. A detailed theory of the standoff measurement of the physical response of a system to photoacoustic excitation with an interferometric sensor has been constructed and tested. The use of this methodology to measure the standoff photoacoustic spectrum of TNT with an interferometric sensor has clearly been demonstrated. This methodology and the tested theory can …

Identification Of Clay Minerals Of The Eastern Southern Region Of Lake Victoria By Ethylene Glycol And Heat: X-Ray Diffraction And Infrared Spectroscopy Studies, E. H. J. Lugwisha

Tanzania Journal of Science

The effect of glycol and heat on some clay minerals of the eastern southern region of Lake Victoria in Tanzania has been studied. First, Whole Rock Powder mount XRD analysis was carried out at the measuring range 2 # ranging between 2o – 65o. Four non-clay minerals found in samples were Na-feldspar, K-feldspar, pyrope and quartz. Oriented clay mineral XRD analysis diffractograms were developed when the air-dried samples were diffracted in measuring range 2# between 2oo – 32o. Main clay mineral groups found in the samples were kaolinite, illite and montmorillonite. After glycolating the samples, it was evident that kaolinite …

The Role Of Llnl's Fast Calibration Facility In Diagnosing Nif Fusion Plasmas, Joshua G. Thompson, Carey Scott, Greg V. Brown

STAR Program Research Presentations

The Fusion and Astrophysics (FAST) Calibration and Diagnostic Facility uses the original Electron Beam Ion Trap (EBIT-I) to profile x-ray filters that are used in the Dante Soft X-Ray Diagnostic at the National Ignition Facility (NIF). FAST has an advantage over any other facility not only for its high accuracy, but also for its proximity to NIF in the Lawrence Livermore National Laboratory (LLNL). This makes for highly accurate and near-instantaneous filter calibration turnover.

EBIT-I was first constructed to create, trap, and observe static highly charged ions (HCIs) and conduct experimental astrophysics (creating an x-ray spectroscopy catalogue of ions). To …

Laboratory Astrophysics: Using Ebit Measurements To Interpret High Resolution Spectra From Celestial Sources, Carey Scott, Joshua Thompson, N. Hell, Greg V. Brown

STAR Program Research Presentations

Astrophysicists use radiation to investigate the physics controlling a variety of celestial sources, including stellar atmospheres, black holes, and binary systems. By measuring the spectrum of the emitted radiation, astrophysicists can determine a source’s temperature and composition. Accurate atomic data are needed for reliably interpreting these spectra. Here we present an overview of how LLNL’s EBIT facility is used to put the atomic data on sound footing for use by the high energy astrophysics community.

Laser-Induced Breakdown Spectroscopy, Connor Drake

Physics

The goal of this work is to use a Neodymium-Doped Yttrium Aluminum Garnet (Nd:YAG) Laser, spectrometer, and computer to create a Laser Induced Breakdown Spectroscopy (LIBS) system. LIBS utilizes a focused, high-powered, pulsed laser whose peak electric field ionizes materials at the beam focal point, creating localized plasma.  The plasma state includes broken molecular bonds, atom/electron-ionization, and excited electrons, which on the macroscopic level is a loud “snap” and a bright spark. In this project, a fiber optic cable is used to capture light emitted from the spark, and direct it into a spectrometer which tallies the number of photons …

Directional Pair-Production Spectrometer Design For Airborne Stand-Off Detection Of Special Nuclear Material, William L. Harrell

Theses and Dissertations

The purposes of this research are to experimentally and theoretically prove the concept of a directional pair-production spectrometer to detect and locate the tailings that are created when making Special Nuclear Material (SNM) at stand-off distances from a remotely piloted vehicle (RPV). A directional pair-production spectrometer uses the information garnered from the high energy gamma rays emitted by these SNM manufacturing tailings to perform pair-production spectroscopy and identify the isotope of interest. Through simultaneous operation as a Compton camera, the detection system will be able to measure rudimentary directional information from the medium energy gamma decays. The detector used for …

Improving The Efficiency Of Photon Collection By Compton Rescue, Alexander W. Stevenson

Theses and Dissertations

A method to improve the efficiency of photon collection in thin planar HPGe detectors was investigated. The method involved implementing a second HPGe detector to collect Compton scattered photons from the primary detector and incorporating coincident interactions in the two detectors that sum to the full energy event into the energy spectrum. This method is termed Compton rescue because the Compton scattered photons make a partial energy deposition in the primary detector and are added back to the spectrum after being detected by the second detector. This research has implications on improving the efficiency of positron annihilation spectroscopy (PAS) techniques …

Remote Quantification Of Smokestack Total Effluent Mass Flow Rates Using Imaging Fourier-Transform Spectroscopy, Jacob L. Harley

Theses and Dissertations

A Telops Hyper-Cam midwave infrared (1.5 − 5.5μm) imaging Fourier-transform spectrometer (IFTS) was used to estimate industrial smokestack total effluent mass flow rates by combining spectrally-determined species concentrations with flow rates estimated via analysis of sequential images in the raw interferogram cube. Strong emissions from H₂O, CO₂, CO, SO₂, and NO were observed in the spectrum. A previously established plume radiative transfer model was used to estimate gas concentrations, and a simple temporal cross-correlation analysis of sequential imagery enabled an estimation of the flow velocity. Final effluent mass flow rates for CO₂ and …

Poincare Recurrence And Spectral Cascades In Three-Dimensional Quantum Turbulence, George Vahala, Jeffrey Yepez, Linda L. Vahala, Min Soe, Bo Zhang, Sean Ziegeler

Electrical & Computer Engineering Faculty Publications

The time evolution of the ground state wave function of a zero-temperature Bose-Einstein condensate (BEC) gas is well described by the Hamiltonian Gross-Pitaevskii (GP) equation. Using a set of appropriately interleaved unitary collision-stream operators, a qubit lattice gas algorithm is devised, which on taking moments, recovers the Gross-Pitaevskii (GP) equation under diffusion ordering (time scales as length²). Unexpectedly, there is a class of initial states whose Poincaré recurrence time is extremely short and which, as the grid resolution is increased, scales with diffusion ordering (and not as length³). The spectral results of J. Yepez et al. …

Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation explores the use of UV-Visible spectroscopy and Time Resolved Laser Induced Fluorescence spectroscopy as near real time process monitors of uranium and plutonium concentrations in aqueous reprocessing trains. The molar absorptivities and linear ranges of these metals were investigated under total nitrate and acid concentrations similar to those found in current reprocessing systems. Concurrent to this, a new multiple wavelength monitor was derived that is capable of determining the total nitrate concentration spectroscopically. This method uses the uranium absorbance spectrum to calculate the nitrate concentration in solution. When used as part of an Advanced Safeguard suite, this technique …

Vibrational Spectroscopic Monitoring Of Co2-O Energy Transfer: Cooling Processes In Atmospheres Of Venus & Mars, Jakob Aaron Schaeffer

Honors Theses

The vibrational excitation of CO2 by a fast-moving O atom followed by infrared emission from the vibrationally excited CO2 has been shown to be an important cooling mechanism in the upper atmospheresof Venus, Earth and Mars. We are trying to determine more precisely the efficiency (rate coefficient) of the CO2-O vibrational energy transfer. For experimental ease the reverse reaction is used, i.e. collision of a vibrationally excited CO2 with atomic O, where we are able to convert to the atmospherically relevant reaction via a known equilibrium constant. The goal of this experiment was to measure the magnitudes of rate coefficients …

Spectroscopic Analysis Of Tungsten Oxide Thin Films For Sensor Applications, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

The objective of this study is targeted toward improving the quality of pure tungsten oxide (WO3) for application to the detection of poisoning gases, especially of H2S. While pure WO3 is a recognized candidate for gas sensing, its characteristics are strongly dependent on the conditions and methods used in its deposition.

Samples of WO3 thin films analyzed in this work were grown on silicon and sapphire substrates using RF magnetron sputtering at a number of different substrate temperatures and Ar:O2 pressure ratios. The properties of the samples were investigated spectroscopically with the goal of determining how variations in the above …

Spectroscopic Study Of The Inhibition Of Calcium Oxalate Calculi By Larrea Tridentata, Luis Alonso Pinales

Open Access Theses & Dissertations

The causes of urolithiasis include such influences as diet, metabolic disorders, and genetic factors which have been documented as sources that aggravate urinary calculi depositions and aggregations, and, implicitly, as causes of urolithiasis. This study endeavors to detail the scientific mechanisms involved in calcium oxalate calculi formation, and, more importantly, their inhibition under growth conditions imposed by the traditional medicinal approach using the herbal extract, Larrea tridentata. The calculi were synthesized without and with Larrea tridentata infusion by employing the single diffusion gel technique. A visible decrease in calcium oxalate crystal growth with increasing amounts of Larrea tridentata herbal infusion …

Core-Level Spectroscopy Of The Pd/W(110) Interface: Evidence Of Long-Range Pd-Island—Winteractions At Submonolayer Coverages, D. Mark Riffe, N. D. Shinn, B. Kim, K. J. Kim, T. H. Kang

All Physics Faculty Publications

We have measured W 4f_7/2 core-level photoemission spectra from W(1 1 0) in the presence of Pd overlayers for coverages up to ∼1 pseudomorphic monolayer (ML). At coverages close to 0.05 ML a striking change in the W core-level spectrum is observed, which we interpret as indicating a long-range lateral effect of 2D Pd islands upon the W electronic structure in both the first and second W layers. As the coverage increases the long-range effect weakens and finally vanishes near 0.85 ML. Above this coverage the W spectra are typical for a W-based bimetallic interface, with the first-layer …

Measurement Of Direct Ƒ0(980) Photoproduction On The Proton, M. Battaglieri, Gerard P. Gilfoyle, Et. Al.

Physics Faculty Publications

We report on the results of the first measurement of exclusive ƒ₀(980) meson photoproduction on protons for E_γ = 3.0–3.8 GeV and -t = 0.4–1.0 GeV^2. Data were collected with the CLAS detector at the Thomas Jefferson National Accelerator Facility. The resonance was detected via its decay in the π⁺ π^- channel by performing a partial wave analysis of the reaction γ p → pπ⁺π^-. Clear evidence of the ƒ₀(980) meson was found in the interference between P and S waves at M_{π⁺π …}

Measurement Of Direct Fₒ(980) Photoproduction On The Proton, K. P. Adhikari, H. Bagdasaryan, S. Bültmann, S. L. Careccia, K. V. Dharmawardane, G. E. Dodge, N. Kalantarians, A. Klein, A.V. Klimenko, S. E. Kuhn, J. Lanchiet, M. R. Niroula, J. Zhang

Physics Faculty Publications

We report on the results of the first measurement of exclusive f₀(980) meson photoproduction on protons for E_γ = 3.0–3.8  GeV and −t = 0.4–1.0  GeV² . Data were collected with the CLAS detector at the Thomas Jefferson National Accelerator Facility. The resonance was detected via its decay in the π⁺π⁻ channel by performing a partial wave analysis of the reaction γp→pπ⁺π⁻ . Clear evidence of the f₀(980) meson was found in the interference between P and S waves at M _π+π− ∼1  GeV. The S -wave differential …

Superfluid Turbulence From Quantum Kelvin Wave To Classical Kolmogorov Cascades, Jeffrey Yepez, George Vahala, Linda L. Vahala, Min Soe

Electrical & Computer Engineering Faculty Publications

The main topological feature of a superfluid is a quantum vortex with an identifiable inner and outer radius. A novel unitary quantum lattice gas algorithm is used to simulate quantum turbulence of a Bose-Einstein condensate superfluid described by the Gross-Pitaevskii equation on grids up to 5760³. For the first time, an accurate power-law scaling for the quantum Kelvin wave cascade is determined: k^-3. The incompressible kinetic energy spectrum exhibits very distinct power-law spectra in 3 ranges of k space: a classical Kolmogorov k^-(5/3) spectrum at scales greater than the outer radius of individual quantum vortex …

Spectroscopic Study Of The Dimerisation Process Of Iron Protoporphyrin Ix, K. Dziedzic-Kocurek, Hugh Byrne, A. Swiderski, J. Stanek

Articles

The commercial protoporphyrin IX, iron-ferriprotoporphyrin IX-chloride and synthesized iron porphyrin μ-oxo-dimers were examined by UV/vis absorption and fluorescence, Fourier transformed infrared spectroscopy, resonance Raman, X-ray absorption, Mössbauer spectroscopy and SQUID. The evidence of Fe-O-Fe antiferromagnetic coupling concluded from SQUID and Mössbauer in the case of samples containing dimerized forms confirmed the presence of the oxo-bridges. In this paper the results of UV/vis, fluorescence, Fourier transform infrared FTIR and Raman spectroscopies are reported and discussed. The study is based on the comparison of the free-base protoporphyrin IX, Fe-PPIX-Cl and the synthesized dimerized specimen. The vibrational modes in two energy regions i.e. …

Core-Level Spectroscopy Of The Ni/W(110) Interface: Correlation Of W Interfacial Core Levelshifts With First-Layer Ni Phases, D. Mark Riffe, R. T. Franckowiak, N. D. Shinn, B. Kim, K. J. Kim, T. H. Kang

All Physics Faculty Publications

We have measured W 4f_7/2 core-level photoemission spectra from W(1 1 0) in the presence of Ni overlayers, from ∼0.2 to ∼3 monolayers. Interfacial core-level shifts associated with first-layer Ni phases have been identified: −230 ± 15 meV for the 1 × 1 pseudomorphic phase and −70 ± 7 meV for the 7 × 1 close-packed commensurate phase. At higher Ni coverages the interfacial core-level shift is −100 ± 10 meV. These shifts are analyzed using the partial-shift model of Nilsson et al. [Phys. Rev. B 38 (1988) 10357]; the analysis indicates that the difference in binding energies between …

Evanescent Field Absorption Sensing Using Sapphire Fibers, Michael Grossman

USF Tampa Graduate Theses and Dissertations

This thesis explores the application of coiled sapphire multimode optical fibers for evanescent wave chemical sensing in both the visible spectrum and the near infrared. As has been suggested in the literature pertaining to silica fibers, bending converts low-order modes to high order ones, which leads to more evanescent absorption and thus a more sensitive chemical detector. By coiling the fiber many times, it was expected that even greater sensitivity would be attained.

Experiments were performed to investigate the sensor response to different solutions and to characterize this response. In the first of three experiments, the large absorption peak of …

Raman Scattering In Gan And Zno, Shinobu Nagata

Theses and Dissertations

The Micro-Raman scattering technique has been used for the study of GaN and ZnO. Capabilities of the Raman technique and existing literature on Raman spectroscopy in GaN and ZnO are reviewed. About 50 GaN and ZnO samples with a wide range of properties are studied. From the analysis of positions of the E2H and A1(LO) phonon modes, biaxial stress and plasmon coupling of the Al(LO) mode are observed and compared to a bulk GaN sample. The stress-related shift rate for the AI(LO) mode in hexagonal GaN is established to be 2.7 ± 0.4 cm-1/GPa through series of GaN with low …

Study Of Propagation And Detection Methods Of Terahertz Radiation For Spectroscopy And Imaging, Aparajita Bandyopadhyay

Dissertations

The applications of terahertz (THz, 1 THz is 1012 cycles per second or 300 pm in wavelength) radiation are rapidly expanding. In particular, THz imaging is emerging as a powerful technique to spatially map a wide variety of objects with spectral features which are present for many materials in THz region. Objects buried within dielectric structures can also be imaged due to the transparency of most dielectrics in this regime. Unfortunately, the image quality in such applications is inherently influenced by the scattering introduced by the sample inhomogeneities and by the presence of barriers that reduces both the transmitted power …

Molecular Structure-Nonlinear Optical Property Relationships For A Series Of Polymethine And Squaraine Molecules, Jie Fu

Electronic Theses and Dissertations

This dissertation reports on the investigation of the relationships between molecular structure and two-photon absorption (2PA) properties for a series of polymethine and squaraine molecules. Current and emerging applications exploiting the quadratic dependence upon laser intensity, such as two-photon fluorescence imaging, three-dimensional microfabrication, optical data storage and optical limiting, have motivated researchers to find novel materials exhibiting strong 2PA. Organic materials are promising candidates because their linear and nonlinear optical properties can be optimized for applications by changing their structures through molecular engineering. Polymethine and squaraine dyes are particularly interesting because they are fluorescent and showing large 2PA. We used …

Potential Of Vibrational Spectroscopy In The Diagnosis Of Human Tumours., Eoghan O'Faolain

Doctoral

Just fewer than 20,000 people are annually diagnosed with some form of cancer in Ireland and one in three people are likely to contract some form of cancer by age 74. With the number of cases increasing at an annual rate of 2%, the early detection and treatment of cancer is becoming increasingly important. Both IR and Raman spectroscopy offer the potential for real time, quantitative detection of cancer and even precancer. This study investigates the potential of Raman and Fourier transform infrared, both benchtop and synchrotron spectroscopies for the detection of cervical cancer. The tissue was classified and its …

High-Temperature Calcium Vapor Cell For Spectroscopy On The 4s2 1s0-4s4p 3p1 Intercombination Line, Christopher J. Erickson, Brian Neyenhuis, Dallin S. Durfee

Faculty Publications

We have demonstrated a high-temperature vapor cell for absorption spectroscopy on the Ca intercombination line. The cell uses a dual-chamber design to achieve the high temperatures necessary for an optically dense vapor while avoiding the necessity of high-temperature vacuum valves and glass-to-metal seals. We have observed over 50% absorption in a single pass through the cell. Although pressure broadening in the cell prevented us from performing saturated-absorption spectroscopy, the broadening resulted in higher signal-to-noise ratios by allowing us to probe the atoms with intensities much greater than the 0.2µW/cm2 saturation intensity of the unbroadened transition. The techniques presented in this …

Interaction Of Single Walled Carbon Nanotubes With Starch-Based Systems, Alan Casey, Gerald Farrell, Mary Mcnamara, Hugh Byrne, Gordon Chambers

Conference papers

The interaction of carbon nanotubes with soft organic molecules such as cyclodextrins and other saccharides has recently been shown to produce water-soluble composites. Such systems offer considerable advantages over polymer based composites due to their biocompatibility and noncovalent coupling which can potentially preserve the unique properties of the tubes. The mechanism of interaction of such systems has been proposed to be dominated by hydrophobic and hydrophilic interactions along the surface of the tube. In this study a number of composite systems have been formed with HiPco carbon nanotubes using starch and starch based polymers. The first composite formed with starch …

Relativistic And Radiative Corrections To The Mollow Spectrum, Jorg Evers, Ulrich D. Jentschura, Christoph H. Keitel

Physics Faculty Research & Creative Works

The incoherent inelastic part of the resonance fluorescence spectrum of a laser-driven atom is known as the Mollow spectrum [B. R. Mollow, Phys. Rev. 188, 1969 (1969)]. Starting from this level of description, we discuss theoretical foundations of high-precision spectroscopy using the resonance fluorescence light of strongly laser-driven atoms. Specifically, we evaluate the leading relativistic and radiative corrections to the Mollow spectrum, up to the relative orders of ( Z α )² and α ( Z α )² , respectively, and Bloch-Siegert shifts as well as stimulated radiative corrections involving off-resonant virtual states. Complete results are provided for …