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Full-Text Articles in Physics

Synthesis, Characterization And Ferroelectric Properties Of Ln-Type Znsno3 Nanostructures, Corisa Kons Nov 2015

Synthesis, Characterization And Ferroelectric Properties Of Ln-Type Znsno3 Nanostructures, Corisa Kons

USF Tampa Graduate Theses and Dissertations

With increasing focus on the ill health and environmental effects of lead there is a greater push to develop Pb-free devices and materials. To this extent, ecofriendly and earth abundant LiNbO3-type ZnSnO3, a derivative of the ABO3 perovskite structure, has a high theoretically predicted polarization making it an excellent choice as a suitable alternative to lead based material such as PZT. In this work we present a novel synthesis procedure for the growth of various ZnSnO3 nanostructures by combined physical/chemical processes. Various ZnSnO3 nanostructures of different dimensions were grown from a ZnO:Al template …


Strong Resistance To Bending Observed For Nanoparticle Membranes, Yifan Wang, Jianhui Liao, Sean P. Mcbride, Efi Efrati, Xiao-Min Lin, Heinrich M. Jaeger Aug 2015

Strong Resistance To Bending Observed For Nanoparticle Membranes, Yifan Wang, Jianhui Liao, Sean P. Mcbride, Efi Efrati, Xiao-Min Lin, Heinrich M. Jaeger

Physics Faculty Research

We demonstrate how gold nanoparticle monolayers can be curled up into hollow scrolls that make it possible to extract both bending and stretching moduli from indentation by atomic force microscopy. We find a bending modulus that is 2 orders of magnitude larger than predicted by standard continuum elasticity, an enhancement we associate with nonlocal microstructural constraints. This finding opens up new opportunities for independent control of resistance to bending and stretching at the nanoscale.


Characterization Of Order-Disorder Phase Transition Temperature For Select Nanoparticles, Gregory J. Sutherland Jun 2015

Characterization Of Order-Disorder Phase Transition Temperature For Select Nanoparticles, Gregory J. Sutherland

Theses and Dissertations

A method was found for creating ordered nanoparticles whose size and theoretical order-disorder temperature are ideal for study in the TEM. Specifically FePt, NiPt, FeNiPt and AuCu nanoparticles were studied. We were able to show how a nanoparticle's size affects its order-disorder temperature (Tod). When the particles were around 6 nm in diameter there was a shift downward of the Tod of 10-15 percent compared to the bulk. While particles around 10 nm in diameter experienced a downward shift of 0-6 percent compared to the bulk. One can approximate that particles less than 10-15 nm in diameter would show significant …


Density-Functional Theory+Dynamical Mean-Field Theory Study Of The Magnetic Properties Of Transition-Metal Nanostructures, Alamgir Kabir Jan 2015

Density-Functional Theory+Dynamical Mean-Field Theory Study Of The Magnetic Properties Of Transition-Metal Nanostructures, Alamgir Kabir

Electronic Theses and Dissertations

In this thesis, Density Functional Theory (DFT) and Dynamical Mean-Field Theory (DMFT) approaches are applied to study the magnetic properties of transition metal nanosystems of different sizes and compositions. In particular, in order to take into account dynamical electron correlation effects (time-resolved local charge interactions), we have adopted the DFT+DMFT formalism and made it suitable for application to nanostructures. Preliminary application of this DFT+DMFT approach, using available codes, to study the magnetic properties of small (2 to 5-atom) Fe and FePt clusters provide meaningful results: dynamical effects lead to a reduction of the cluster magnetic moment as compared to that …