Physics Commons^™

Dielectric Analysis Of Aqueous Poly(L-Glutamic Acid) And Poly-L-(Glutamic Acid4, Tyrosine1) Solutions At High Frequencies From Capacitance Measurements, Jorge Monreal, Tatiana Eggers, Manh-Huong Phan

Physics Faculty Publications

A new parallel-plate capacitor fixture has been designed and successfully used to measure dielectric loss of polyelectrolyte solutions with volumes as low as droplets of 13–26 μL. It is particularly useful when studying polypeptides that are either high-cost or can be synthesized only in limited quantities. The ease with which the fixture can be used to obtain preliminary dielectric loss data yields savings in time and cost. In this study capacitance measurements were performed in a wide range of frequencies between 1 and 800 MHz using an Agilent 4191RF Impedance Analyzer. Accuracy of measurements was carefully examined through a comparison …

Polymer Characteristics Of Polyelectrolyte Polypeptides, Jorge Monreal

USF Tampa Graduate Theses and Dissertations

Polypeptides are polymerized chains of amino acids linked covalently through peptide bonds. Polyelectrolyte polypeptides are polypeptides with electrolyte repeating groups. Several amino acids contain ionizable side chains which result in charge distributions when dissolved in aqueous solutions. This dissertation is motivated by a desire to gain knowledge of polyelectrolyte polypeptides as recent advances in chemical synthesis of polypeptides have made possible the fabrication of designed polypeptides that do not naturally occur in nature. Potential applications of newly designed polypeptides span the range from medical to clothing and energy even to robotics.

In this dissertation we compare the characteristic behavior of …