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Study Of The Photoinduced Surface Relief Modulation In Photopolymers Caused By Illumination With A Gaussian Beam Of Light, Tzvetanka Babeva, Dana Mackey, Suzanne Martin, Izabela Naydenova, Vincent Toal
Study Of The Photoinduced Surface Relief Modulation In Photopolymers Caused By Illumination With A Gaussian Beam Of Light, Tzvetanka Babeva, Dana Mackey, Suzanne Martin, Izabela Naydenova, Vincent Toal
Articles
The formation of surface relief profile in photopolymerisable systems when illuminated with a focused beam of light is simulated numerically using a two-way diffusion model that takes account both for monomer and short polymer chains diffusion. The concentration and spatial distribution dynamics of monomer and short and long polymer chains are calculated. The surface profile is obtained from calculated components concentrations considering different densities of monomer and polymer. The influence of the illumination time, intensity and spot diameter on the surface profiles dynamics is discussed. A good agreement between the calculated and the experimentally measured profiles is observed thus demonstrating …
Investigation Of The Diffusion Processes In Self-Processing Acrylamide-Based Photopolymer System, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Suzanne Martin, Vincent Toal
Investigation Of The Diffusion Processes In Self-Processing Acrylamide-Based Photopolymer System, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Suzanne Martin, Vincent Toal
Articles
Results from the investigation of the diffusion processes in a dry acrylamide-based photopolymer system are presented. The investigation is carried out in the context of experimental work on optimization of the high spatial frequency response of the photopolymer. Tracing the transmission holographic grating dynamics at short times of exposure is utilized to measure diffusion coefficients. The results reveal that two different diffusion processes contribute with opposite sign to the refractive index modulation responsible for the diffraction grating build up. Monomer diffusion from dark to bright fringe areas increases the refractive index modulation. It is characterized with diffusion constant D0=1.6E-7 cm2/s. …