Open Access. Powered by Scholars. Published by Universities.®

Physics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 31 - 60 of 150

Full-Text Articles in Physics

Third-Order Optical Nonlinearity Properties Of Cdcl2-Modifed Ge–Sb–S Chalcogenide Glasses, Xiaosong Lu, Jianhui Li, Lu Yang, Runan Zhang, Yindong Zhang, Jing Ren, Aurelian Catalin Galca, Mihail Secu, Gerald Farrell, Pengfei Wang Jan 2019

Third-Order Optical Nonlinearity Properties Of Cdcl2-Modifed Ge–Sb–S Chalcogenide Glasses, Xiaosong Lu, Jianhui Li, Lu Yang, Runan Zhang, Yindong Zhang, Jing Ren, Aurelian Catalin Galca, Mihail Secu, Gerald Farrell, Pengfei Wang

Articles

We developed a new type of chalcohalide glasses with physicochemical and nonlinear optical properties that are tunable by composition. It is found that more than 60 mol.% CdCl2 heavy metal halide can be dissolved into the ternary Ge–Sb–S system and forming stable glasses. The visible-light transparency range is extended to shorter wavelengths with the addition of CdCl2, which is beneficial for the optical quality control and infra-red (IR) system alignment. The third-order optical nonlinearity (TONL) is studied using the femtosecond Z-scan method. The results show that both the nonlinear refractive index and two photon absorption co-efficient decrease with CdCl2. Benefiting …


A Twelve-Wavelength Thulium-Doped Fibre Laser Based On A Microfibre Coil Resonator Incorporating Black Phosphorus, Shi Li, Yu Yin, Elfed Lewis, Gerald Farrell, Pengfei Wang Jan 2019

A Twelve-Wavelength Thulium-Doped Fibre Laser Based On A Microfibre Coil Resonator Incorporating Black Phosphorus, Shi Li, Yu Yin, Elfed Lewis, Gerald Farrell, Pengfei Wang

Articles

A novel multi-wavelength continuous Thulium-doped fibre laser incorporating a microfibre coil resonator based on black phosphorus (MCR-BP) material has been successfully fabricated and demonstrated. A twelve-wavelength spectrum with 0.54 nm channel spacing has been achieved by simply adjusting the pump source power. A single peak extinction ratio of more than 40 dB was observed. The superior performance of the MCR-BP described in this article compared to conventional MCR based fibre lasers can be attributed the inclusion of the Black Phosphorous Material. The enhanced lasing is primarily due to the twin properties of the MCR-BP device combining a comb-like filter effect …


All Fibre Q-Switched Thulium-Doped Fibre Laser Incorporating Thulium–Holmium Co-Doped Fibre As A Saturable Absorber, Shi Li, Elfed Lewis, Gerald Farrell, Ahmad Haziq Aiman Rosol, A.A. Latiff, Sulaiman Wadi Harun, Bingang Guo, Pengfei Wang Jan 2019

All Fibre Q-Switched Thulium-Doped Fibre Laser Incorporating Thulium–Holmium Co-Doped Fibre As A Saturable Absorber, Shi Li, Elfed Lewis, Gerald Farrell, Ahmad Haziq Aiman Rosol, A.A. Latiff, Sulaiman Wadi Harun, Bingang Guo, Pengfei Wang

Articles

A novel all fibre Q-switched Thulium-doped fibre laser (TDFL) is reported which includes a short length of a Thulium–Holmiumco-doped fibre (THDF) as a saturable absorber. A high repetition rate (27.26 kHz) coupled with a low pulse width (19.06μs) is obtained for single wavelength Q-switched pulse operation at an output wavelength of 1911.5 nm using a pump power of 200 mW. Increasing the pump power from 200 mW to 700 mW results in the repetition rate increasing from 27.26 kHz to 99.67 kHz and the pulse width decreasing from 19.06μs to 920 ns. The centre wavelength of the single Q-switched pulse …


Distribution Of Tm 3+ And Ni 2+ In Chalcogenide Glass Ceramics Containing Ga2s3 Nanocrystals: Influence On Photoluminescence Properties, Xiaosong Lu, Zhiqiang Lai, Jing Ren, Lukas Strizik, Tomas Wagner, Yanqiu Du, Gerald Farrell, Pengfei Wang Jan 2019

Distribution Of Tm 3+ And Ni 2+ In Chalcogenide Glass Ceramics Containing Ga2s3 Nanocrystals: Influence On Photoluminescence Properties, Xiaosong Lu, Zhiqiang Lai, Jing Ren, Lukas Strizik, Tomas Wagner, Yanqiu Du, Gerald Farrell, Pengfei Wang

Articles

The distribution of Tm3+ and Ni2+ ions is unambiguously exhibited in 80GeS2-20Ga2S3 chalcogenide glass ceramics (GCs) containing Ga2S3 nanocrystals (NCs) by using advanced analytical transmission electron microscopy. Distinctively different distribution patterns of Tm3+ and Ni2+ ions are observed in the GCs obtained by controlled crystallization. The distribution of the dopants imposes strong influence on their optical properties which are revealed by absorption and photoluminescence (PL) spectra. Detailed discussions are given of the mechanisms of the crystallization-induced PL enhancement and quenching of the Tm3+ mid-infrared and Ni2+ near-infrared emissions, respectively.


In-Fiber Temperature Sensor Based On Green Up-Conversion Luminescence In An Er3+-Yb3+ Co-Doped Tellurite Glass Microsphere, Meng Zhang, Angzhen Li, Jibo Yu, Xiaosong Lu, Shunbin Wang, Elfed Lewis, Gerald Farrell, Libo Yuan, Pengfei Wang Jan 2019

In-Fiber Temperature Sensor Based On Green Up-Conversion Luminescence In An Er3+-Yb3+ Co-Doped Tellurite Glass Microsphere, Meng Zhang, Angzhen Li, Jibo Yu, Xiaosong Lu, Shunbin Wang, Elfed Lewis, Gerald Farrell, Libo Yuan, Pengfei Wang

Articles

A novel, to the best of our knowledge, in-fiber temperature sensor based on green up-conversion (UC) luminescence in an Er3+-Yb3+" role="presentation" style="box-sizing: border-box; display: inline; font-size: 12.88px; line-height: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">Er3+-Yb3+Er3+-Yb3+ co-doped tellurite glass microsphere is described. The tellurite glass microsphere is located firmly inside a suspended tri-core hollow-fiber (STCHF) structure. The pump light launched via a single-mode fiber (SMF) is passed through a section of multimode fiber, which is fusion spliced between the SMF …


Ultrabroadband Mid-Infrared Emission From Cr 2+ -Doped Infrared Transparent Chalcogenide Glass Ceramics Embedded With Thermally Grown Zns Nanorods, Xiaosong Lu, Zhiqiang Lai, Runan Zhang, Haitao Guo, Jing Ren, Lukas Strizik, Tomas Wagner, Gerald Farrell, Pengfei Wang Jan 2019

Ultrabroadband Mid-Infrared Emission From Cr 2+ -Doped Infrared Transparent Chalcogenide Glass Ceramics Embedded With Thermally Grown Zns Nanorods, Xiaosong Lu, Zhiqiang Lai, Runan Zhang, Haitao Guo, Jing Ren, Lukas Strizik, Tomas Wagner, Gerald Farrell, Pengfei Wang

Articles

We report, for the first time to our knowledge, an ultrabroadband mid-infrared (MIR) emission in the range of 1800–2800 nm at room temperature from a Cr2+-doped chalcogenide glass ceramic embedded with pure hexagonal (wurtzite) β-ZnS nanorods and study the emission-dependent properties on the doping concentration of Cr2+. A new family of chalcogenide glasses based on (100 − x) Ge1.5As2S6.5 – x ZnSe (in mol.%) was prepared by melt-quenching method. The Cr2+: β-ZnS nanorods of ˜150 nm in diameter and ˜1 μm in length were grown in the Cr2+-doped glass after thermal annealing. The compositional variations of glass structures and optical …


Mode Transition In Conventional Step-Index Optical Fibers, Xiaokang Lian, Gerald Farrell, Qiang Wu, Wei Han, Fangfang Wei, Yuliya Semenova Jan 2019

Mode Transition In Conventional Step-Index Optical Fibers, Xiaokang Lian, Gerald Farrell, Qiang Wu, Wei Han, Fangfang Wei, Yuliya Semenova

Conference Papers

The discrete self-imaging effect reveals the distinct properties of cladding modes with core modes in step-index optical fibers, as was shown in our previous work [1], where only the linearly polarized LP0n modes were studied. In this paper, the dispersion diagram of the first 17 vector modes (TE0n, TM0n, HEmn and EHmn) and the related first 9 LPmn modes are calculated by both the full-vector finite element method and the graphical method with a three-layer step-index optical fiber model. The cladding modes distributions and the transitions between the core and cladding modes are analyzed. The results of this work are …


Sensing Of Multiple Parameters With Whispering Gallery Mode Optical Fiber Micro-Resonators, Arun Kumar Mallik Dr, Vishnan Kavungal, Gerald Farrell, Yuliya Semenova Jan 2019

Sensing Of Multiple Parameters With Whispering Gallery Mode Optical Fiber Micro-Resonators, Arun Kumar Mallik Dr, Vishnan Kavungal, Gerald Farrell, Yuliya Semenova

Conference Papers

Monitoring of multiple physical parameters, such as humidity, temperature, strain, concentrations of certain chemicals or gases in various environments is of great importance in many industrial applications both for minimizing adverse effects on human health as well as for maintaining production levels and quality of products. In this paper we demonstrate two different approaches to the design of multi-parametric sensors using coupled whispering gallery mode (WGM) optical fiber micro-resonators. In the first approach, a small array of micro-resonators is coupled to a single fiber taper, while in the second approach each of the micro-resonators within an array is coupled to …


Theoretical Analysis Of A Volume Holographic Lens Using Matlab, Sanjay Keshri, Kevin Murphy, Izabela Naydenova, Suzanne Martin Jan 2019

Theoretical Analysis Of A Volume Holographic Lens Using Matlab, Sanjay Keshri, Kevin Murphy, Izabela Naydenova, Suzanne Martin

Conference Papers

Volume holographic lenses have great potential for different types of applications requiring light redirection and beam shaping such as solar light collection and LED light management. For lighting applications using LEDs, it is essential to make a highly efficient optical element to be placed in front of the LED in order to decrease energy losses. For that reason, a careful theoretical analysis of the properties and operation regime of the lens must be carried out at the design stage. The characteristics of focusing Holographic Optical Elements (HOE) depend on many factors including their thickness, spatial frequency, the angular range of …


Sns Optical Fiber Structure Sensor For Direct Detection Of The Phase Transition In C18h38 N-Alkane Material, Wei Han, Marek Rebow, Xiaokang Lian, Dejun Liu, Gerald Farrell, Qiang Wu, Yuliya Semenova Jan 2019

Sns Optical Fiber Structure Sensor For Direct Detection Of The Phase Transition In C18h38 N-Alkane Material, Wei Han, Marek Rebow, Xiaokang Lian, Dejun Liu, Gerald Farrell, Qiang Wu, Yuliya Semenova

Articles

A singlemode-no-core-singlemode (SNS) fiber structure optical sensor for detecting the solid-liquid phase change in a phase change material: C18H38 n-alkane material (n-octadecane) is proposed and demonstrated. The transmission-type sensor probe consists of a short section of no-core fiber sandwiched between two sections of a singlemode fiber. Phase changes in n-octadecane are accompanied by large step-like variations of its refractive index (RI). Such a large discontinuous change of the n-octadecane’s RI during its phase transition, leads to the corresponding step-like change in the transmitted optical power that can reliably indicate the phase change of the sample in the vicinity of the …


Magnetic Field Sensor Based On A Tri-Microfiber Coupler Ring In Magnetic Fluid And A Fiber Bragg Grating, Fangfang Wei, Dejun Liu, Arun Kumar Mallik, Gerald Farrell, Qiang Wu, Gang-Ding Peng, Yuliya Semenova Jan 2019

Magnetic Field Sensor Based On A Tri-Microfiber Coupler Ring In Magnetic Fluid And A Fiber Bragg Grating, Fangfang Wei, Dejun Liu, Arun Kumar Mallik, Gerald Farrell, Qiang Wu, Gang-Ding Peng, Yuliya Semenova

Articles

In this paper we propose and investigate a novel magnetic field sensor based on a Tri-microfiber coupler combined with magnetic fluid and a fiber Bragg grating (FBG) in a ring. A sensitivity of 1306 pm/mT was experimentally demonstrated in the range of magnetic fields from 0 to 15 mT. The reflection peak in the output spectrum associated with the FBG serves as a reference point allowing to avoid ambiguity in determining the spectral shift induced by the magnetic field. Due to its high sensitivity at low magnetic fields, the proposed structure could be of high interest in low field biosensing …


Significance Of A Non-Thermal Plasma Treatment On Ldpe Biodegradation With Pseudomonas Aeruginosa, Laurence Scally, Miroslav Gulan, Lars Weigang, Patrick Cullen, Vladimir Milosavljevic Oct 2018

Significance Of A Non-Thermal Plasma Treatment On Ldpe Biodegradation With Pseudomonas Aeruginosa, Laurence Scally, Miroslav Gulan, Lars Weigang, Patrick Cullen, Vladimir Milosavljevic

Articles

The use of plastics has spanned across almost all aspects of day to day life. Although their uses are invaluable, they contribute to the generation of a lot of waste products that end up in the environment and end up polluting natural habitats such as forests and the ocean. By treating low-density polyethylene (LDPE) samples with non-thermal plasma in ambient air and with an addition of 4% CO2, the biodegradation of the samples can be increased due to an increase in oxidative species causing better cell adhesion and acceptance on the polymer sample surface. It was, however, found that the …


Holographic Beam-Shaping Diffractive Diffusers Fabricated By Using Controlled Laser Speckle, Kevin Murphy, Vincent Toal, Izabela Naydenova, Suzanne Martin Apr 2018

Holographic Beam-Shaping Diffractive Diffusers Fabricated By Using Controlled Laser Speckle, Kevin Murphy, Vincent Toal, Izabela Naydenova, Suzanne Martin

Articles

A method for fabricating diffractive holographic optical diffusers is reported, allowing a high degree of control of the resulting diffuser characteristics. The method consists of recording a laser speckle pattern using a single carrier beam, with controlled speckle size and shape, in an acrylamide-based volume photopolymer. The multiple interferences that create the speckle pattern form the hologram. Results are presented verifying the diffusers are volume holographic in nature and the speckle pattern is recorded accurately in the photopolymer. Diffusers recorded by this method are analysed to characterise the optical performance of the diffusers and to illustrate their beam-shaping capabilities, particularly …


Investigation Of Temperature Response Of Photopolymer Material Used For Holographic Sensor, Muhammad Irfan, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova Mar 2018

Investigation Of Temperature Response Of Photopolymer Material Used For Holographic Sensor, Muhammad Irfan, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova

Conference Papers

Recently, functionalised photopolymer has emerged as a versatile recording material in the field of optical holography due to its novel characteristics and potential use in the development of holographic based sensors, and optical elements. This work describes the temperature response of a newly developed photopolymer, containing of a monomer Nisopropylacrylamide (NIPA) which under photopolymerisation forms a temperature sensitive polymer - Poly(Nisopropylacrylamide) (PNIPA). The photonic sensor was developed by holographic recording of volume phase transmission gratings in a self-processing NIPA-based polymer with a 532 nm laser beam. A 633 nm probe beam was used to monitor real time diffraction efficiency (DE) …


Studies Of Geometrical Profiling In Fabricated Tapered Optical Fbers Using Whispering Gallery Modes Spectroscopy, Vishnu Kavungal, Gerald Farrell, Qiang Wu, Arun Kumar Mallik, Yuliya Semenova Mar 2018

Studies Of Geometrical Profiling In Fabricated Tapered Optical Fbers Using Whispering Gallery Modes Spectroscopy, Vishnu Kavungal, Gerald Farrell, Qiang Wu, Arun Kumar Mallik, Yuliya Semenova

Articles

This paper experimentally demonstrates a method for geometrical profiling of asymmetries in fabricated thin microfiber tapers with waist diameters ranging from ∼10 to ∼50µm with submicron accuracy. The method is based on the analysis of whispering gallery mode resonances excited in cylindrical fiber resonators as a result of evanescent coupling of light propagating through the fiber taper. The submicron accuracy of the proposed method has been verified by SEM studies. The method can be applied as a quality control tool in fabrication of microfiber based devices and sensors or for fine-tuning of microfiber fabrication set-ups.


Self-Processing Photopolymer Materials For Versatile Design And Fabrication Of Holographic Sensors And Interactive Holograms, Dervil Cody, Sabad-E Gul, Tatsiana Mikulchyk, Muhammad Irfan, Anastasia Kharchenko, Kamila Goldyn, Suzanne Martin, Svetlana Mintova, John Cassidy, Izabela Naydenova Jan 2018

Self-Processing Photopolymer Materials For Versatile Design And Fabrication Of Holographic Sensors And Interactive Holograms, Dervil Cody, Sabad-E Gul, Tatsiana Mikulchyk, Muhammad Irfan, Anastasia Kharchenko, Kamila Goldyn, Suzanne Martin, Svetlana Mintova, John Cassidy, Izabela Naydenova

Articles

The aim of this paper is to discuss the benefits as well as the limitations of utilizing photopolymer materials in the design of holograms that are responsive to changes in their environment, such as changes in the concentration of a specific substance, temperature, and pressure. Three different case studies are presented, including both surface and volume phase holograms, in order to demonstrate the flexibility in the approach of utilizing holographic photopolymers for the design of sensors and interactive optical devices. First, a functionalized surface relief hologram is demonstrated to operate as an optical sensor for the detection of metal ions …


Theoretical Modeling And Design Of Photonic Structures In Zeolite Nanocomposites For Gas Sensing. Part Ii: Volume Gratings, Dervil Cody, Izabela Naydenova Jan 2018

Theoretical Modeling And Design Of Photonic Structures In Zeolite Nanocomposites For Gas Sensing. Part Ii: Volume Gratings, Dervil Cody, Izabela Naydenova

Articles

The suitability of holographic structures fabricated in zeolite nanoparticle-polymer composite materials for gas sensing applications has been investigated. Theoretical modelling of the sensor response (i.e. change in hologram readout due to a change in refractive index modulation or thickness as a result of gas adsorption) of different sensor designs was carried out using Raman-Nath theory and Kogelnik’s Coupled Wave Theory. The influence of a range of parameters on the sensitivity of holographically-recorded surface and volume photonic structures has been studied, namely hologram geometry, hologram thickness and spatial frequency, reconstruction wavelength, and zeolite nanoparticle refractive index. From this, the optimum fabrication …


Strain-Induced Spectral Tuning Of The Whispering Gallery Modes In A Cylindrical Micro-Resonator Formed By A Polymer Optical Fiber, Vishnu Kavungal, Arun Mallik, Gerald Farrell, Qiang Wu, Yuliya Semenova Feb 2017

Strain-Induced Spectral Tuning Of The Whispering Gallery Modes In A Cylindrical Micro-Resonator Formed By A Polymer Optical Fiber, Vishnu Kavungal, Arun Mallik, Gerald Farrell, Qiang Wu, Yuliya Semenova

Articles

A mechanical strain assisted technique for spectral tuning of whispering gallery modes (WGM) in a cylindrical micro-resonator formed by a polymer optical fiber (POF) is investigated. WGMs in the POF based micro-cylinder are excited by evanescent light coupling using a tapered single mode silica fiber. WGMs observed in the transmission spectrum of the silica fiber taper have a high extinction ratio of up to 19 dB and a Q-factor of up to 2.64 × 104. The application of tensile axial strain (μɛ) in the range from 0 to 1746 μɛ (0.17 %) to the POF micro-resonator results in …


Application Of Phase Shifting Electronic Speckle Pattern Interferometry In Studies Of Photoinduced Shrinkage Of Photopolymer Layers, Mohesh Moothanchery, Viswanath Bavigadda, Manojit Pramanik, Vincent Toal, Izabela Naydenova Jan 2017

Application Of Phase Shifting Electronic Speckle Pattern Interferometry In Studies Of Photoinduced Shrinkage Of Photopolymer Layers, Mohesh Moothanchery, Viswanath Bavigadda, Manojit Pramanik, Vincent Toal, Izabela Naydenova

Articles

Photoinduced shrinkage occurring in photopolymer layers during holographic recording was determined by Phase Shifting Electronic Speckle Pattern Interferometry. Phase maps were calculated from the changes in intensity at each pixel due to the phase differences introduced between object and reference beams. Shrinkage was then obtained from the changes in phase as recording proceeded. The technique allows for whole field measurement of the dimensional changes in photopolymers during holographic recording.


N-Isopropylacrylamide-Based Photopolymer For Holographic Recording Of Thermosensitive Transmission And Reflection Grating, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova Jan 2017

N-Isopropylacrylamide-Based Photopolymer For Holographic Recording Of Thermosensitive Transmission And Reflection Grating, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova

Articles

In recent years, functionalized photopolymer systems capable of holographic recording are in great demand due to their potential use in the development of holographic sensors. This work presents a newly developed Nisopropylacrylamide(NIPA)-based photopolymer for holographic recording in reflection and transmission modes. The optimized composition of the material is found to reach refractive index modulation of up to 5  10-3 and 1.6  10-3 after recording in transmission and reflection mode, respectively. In addition to fulfilling the requirements for holographic recording materials, the NIPA-based photopolymer is sensitive to temperature and has lower toxicity than acrylamide-based photopolymers. Possible application of the …


Humidity And Temperature Induced Changes In The Diffraction Efficiency And The Bragg Angle Of Slanted Photopolymer-Based Holographic Gratings, Tatsiana Mikulchyk, James Walshe, Dervil Cody, Suzanne Martin, Izabela Naydenova Jan 2017

Humidity And Temperature Induced Changes In The Diffraction Efficiency And The Bragg Angle Of Slanted Photopolymer-Based Holographic Gratings, Tatsiana Mikulchyk, James Walshe, Dervil Cody, Suzanne Martin, Izabela Naydenova

Articles

This work explores the humidity and temperature response of volume phase slanted gratings recorded in photopolymers with varied chemical composition. Acrylamide and diacetone acrylamide were used as monomers and triethanolamine and N-phenylglycine were used as photoinitiators. The study demonstrates that the response of photopolymer-based holographic gratings to relative humidity (RH) and temperature (T) can be tuned by alteration of the photopolymer composition.Humidity and temperature response of the holograms has been characterized by recording Bragg selectivity curves of transmission gratings and by monitoring the position of the maximum intensity in the spectral response of reflection gratings. Investigation of the humidity response …


Compact Holographic Optical Element-Based Electronic Speckle Pattern Interferometer For Rotation And Vibration Measurements, Viswanath Bavigadda, Mohesh Moothanchery, Manojit Pramanik, Emilia Mihaylova, Vincent Toal Jan 2017

Compact Holographic Optical Element-Based Electronic Speckle Pattern Interferometer For Rotation And Vibration Measurements, Viswanath Bavigadda, Mohesh Moothanchery, Manojit Pramanik, Emilia Mihaylova, Vincent Toal

Conference Papers

An out-of-plane sensitive electronic speckle pattern interferometer (ESPI) using holographic optical elements (HOEs) for studying rotations and vibrations is presented. Phase stepping is implemented by modulating the wavelength of the laser diode in a path length imbalanced interferometer. The time average ESPI method is used for vibration measurements. Some factors influencing the measurements accuracy are reported. Some advantages and limitations of the system are discussed.


Advancing Vibrational Spectroscopy For Cellular And Sub Cellular Analysis: Raman Spectroscopy As An In Vitro Chemotherapeutic Screeening And Assessment Protocol, Zeineb Farhane Jan 2017

Advancing Vibrational Spectroscopy For Cellular And Sub Cellular Analysis: Raman Spectroscopy As An In Vitro Chemotherapeutic Screeening And Assessment Protocol, Zeineb Farhane

Doctoral

Vibrational spectroscopy, including Raman micro-spectroscopy, has attracted considerable attention over the last few years, as a powerful, non-invasive tool for clinical applications, especially in cancer diagnosis, in vivo and ex vivo. As a molecular fingerprinting technique with optical resolution, Raman micro-spectroscopy is able to monitor biochemical processes, drug uptake, efficacy and mode of action and mechanisms of interaction of chemotherapeutic drugs at a subcellular level. In vitro applications may be more strategically achievable, and can help guide drug design and discovery, and eventually evaluate To this end, different lung cell lines were used and Raman micro-spectroscopy was coupled to valuable …


Development And Characterisation Of A Bath-Based Vertical Blackbody Cavity Calibration Source For The Range −30 °C To 150 °C, Sam Boles, Igor Pušnik, Dubhaltach Mac Lochlainn, David Fleming, Izabela Naydenova, Suzanne Martin Jan 2017

Development And Characterisation Of A Bath-Based Vertical Blackbody Cavity Calibration Source For The Range −30 °C To 150 °C, Sam Boles, Igor Pušnik, Dubhaltach Mac Lochlainn, David Fleming, Izabela Naydenova, Suzanne Martin

Articles

Industrial use of Radiation Thermometers (RTs) is becoming increasingly common due to the perceived advantages and wide market availability. Blackbody Cavity Radiation Sources (BCRSs) are typically used for calibration of these instruments, and these cavities are oriented horizontally in most cases. For BCRSs based in thermal baths, this necessitates the use of custom-built baths with side openings. This paper presents a unique design of vertical bath-based BCRS that may be immersed in conventional calibration baths without modifications to the baths. The method, results, and analysis of an international comparison comparing this vertical BCRS, standard horizontal BCRSs, and a previous iteration …


Effect Of Monomer Diffusion On Photoinduced Shrinkage In Photopolymer Layers Determined By Electronic Speckle Pattern Interferometry, Mohesh Moothanchery, Manojit Pramanik, Vincent Toal, Izabela Naydenova Jan 2017

Effect Of Monomer Diffusion On Photoinduced Shrinkage In Photopolymer Layers Determined By Electronic Speckle Pattern Interferometry, Mohesh Moothanchery, Manojit Pramanik, Vincent Toal, Izabela Naydenova

Conference Papers

The aim of this study is to determine the effect of monomer diffusion on the photoinduced shrinkage profile in acrylamide based photopolymer layers during holographic recording. Using phase shifting electronic speckle pattern interferometry the displacement at each pixel in the image of the layer is measured. The complete displacement profile of the layer was obtained using phase shifting technique. We observed a reduction in shrinkage as a result of monomer diffusion from unexposed regions of holographic exposure. As a result of diffusion the maximum shrinkage was reduced by 26 % from 7.18μm to 5.28μm in a photopolymer layer of thickness160 …


Theoretical Modeling Of The Effect Of Polymer Chain Immobilization Rates On Holographic Recording In Photopolymers, Dana Mackey, Paul O'Reilly, Izabela Naydenova Apr 2016

Theoretical Modeling Of The Effect Of Polymer Chain Immobilization Rates On Holographic Recording In Photopolymers, Dana Mackey, Paul O'Reilly, Izabela Naydenova

Articles

This paper introduces an improved mathematical model for holographic grating formation in an acrylamide-based photopolymer, which consists of partial differential equations derived from physical laws. The model is based on the two-way diffusion theory of \cite{izabela}, which assumes short polymer chains are free to diffuse, and generalizes a similar model presented in \cite{josab} by introducing an immobilization rate governed by chain growth and cross-linking. Numerical simulations were carried out in order to investigate the behaviour of the photopolymer system for short and long exposures, with particular emphasis on the effect of recording parameters (such as illumination frequency and intensity), as …


Quantitative Measurement Of Displacement In Photopolymer Layers During Holographic Recording Using Phase Shifting Electronic Speckle Pattern Interferometry, Mohesh Moothanchery, Viswanath Bavigadda, Paul Kumar Upputturi, Manojit Pramanik, Vincent Toal, Izabela Naydenova Jan 2016

Quantitative Measurement Of Displacement In Photopolymer Layers During Holographic Recording Using Phase Shifting Electronic Speckle Pattern Interferometry, Mohesh Moothanchery, Viswanath Bavigadda, Paul Kumar Upputturi, Manojit Pramanik, Vincent Toal, Izabela Naydenova

Conference Papers

The aim of this study is to determine the displacement profile due to shrinkage in acrylamide-based photopolymer layer during holographic recording. Using phase shifting electronic speckle pattern interferometry the displacement at each pixel in the image of the object is measured by phase shifting technique so that a complete displacement profile of the object can be obtained. It was observed that the displacement profile is Gaussian and resembles to the profile of the recording beam. We observed an increase in shrinkage from 2 μm at 20 seconds of recording to 7.5 μm after 120 seconds of recording. The technique allows …


Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova Oct 2015

Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova

Articles

The polymerisation rate of a low-toxicity Diacetone Acrylamide (DA)-based photopolymer has been measured for the first time using Raman spectroscopy. A value for the polymerisation rate of 0.020 s−1 has been obtained for the DA photopolymer by modelling the polymerisation reaction dynamics as a stretched exponential or Kohlrausch decay function. This is significantly lower than the polymerisation rate of 0.100 s−1 measured for the well known Acrylamide (AA)-based photopolymer composition. The effect of the additive glycerol on the polymerisation rate of the DA-based photopolymer has also been investigated. The inclusion of glycerol is observed to increase the rate …


Spectroscopic Characterization Of A Radio-Frequency Argon Plasma Jet Discharge In Ambient Air, Patrick Cullen, Vladimir Milosavljevic Jun 2015

Spectroscopic Characterization Of A Radio-Frequency Argon Plasma Jet Discharge In Ambient Air, Patrick Cullen, Vladimir Milosavljevic

Articles

This study includes a detailed experimental investigation of the spatial and temporal spectroscopic emission of an argon plasma jet discharge. The study is carried out in ambient air and quenching by inflowing air species is considered. The optical emission spectroscopy of neutral atomic spectral lines and molecular bands, over a range of plasma process parameters, is investigated. Wavelength-resolved argon optical emission profiles are used to monitor the electron energy distribution function and the density of argon metastable atoms. The experimental data indicates that the argon flow rate, in a confined open-air plasma discharge, limits the impact of molecular oxygen in …


Multivariate Statistical Methodologies Applied In Biomedical Raman Spectroscopy: Assessing The Validity Of Partial Least Squares Regression Using Simulated Model Datasets., Mark Keating Apr 2015

Multivariate Statistical Methodologies Applied In Biomedical Raman Spectroscopy: Assessing The Validity Of Partial Least Squares Regression Using Simulated Model Datasets., Mark Keating

Articles

Raman spectroscopy is fast becoming a valuable analytical tool in a number of biomedical scenarios, most notably disease diagnostics. Importantly, the technique has also shown increasing promise in the assessment of drug interactions on a cellular and subcellular level, particularly when coupled with multivariate statistical analysis. However, an important consideration, both with Raman spectroscopy and the associated statistical methodologies, is the accuracy of these techniques and more specifically the sensitivities which can be achieved and ultimately the limits of detection of the various methods. The purpose of this study is thus the construction of a model simulated data set with …