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Full-Text Articles in Physics

Fabrication Of Nd3+ And Yb3+ Doped Nir Emitting Nano Fluorescent Probe: A Candidate For Bioimaging Applications, D. Karthickraja, G. A. Kumar, D. K. Sardar, S. Karthi, Gamage C. Dannangoda, Karen S. Martirosyan, M. Prasath, M. Gowri, E. L. Girija Jun 2021

Fabrication Of Nd3+ And Yb3+ Doped Nir Emitting Nano Fluorescent Probe: A Candidate For Bioimaging Applications, D. Karthickraja, G. A. Kumar, D. K. Sardar, S. Karthi, Gamage C. Dannangoda, Karen S. Martirosyan, M. Prasath, M. Gowri, E. L. Girija

Physics and Astronomy Faculty Publications and Presentations

The intentional design of rare earth doped luminescent architecture exhibits unique optical properties and it can be considered as a promising and potential probe for optical imaging applications. Calcium fluoride (CaF2) nanoparticles doped with optimum concentration of Nd3+ and Yb3+ as sensitizer and activator, respectively, were synthesized by wet precipitation method and characterized by x-ray diffraction (XRD) and photoluminescence. In spite of the fact that the energy transfer takes place from Nd3+ to Yb3+, the luminescence intensity was found to be weak due to the lattice defects generated from the doping of trivalent cations (Nd3+ and Yb3+) for divalent host …


Characterization Of Order-Disorder Phase Transition Temperature For Select Nanoparticles, Gregory J. Sutherland Jun 2015

Characterization Of Order-Disorder Phase Transition Temperature For Select Nanoparticles, Gregory J. Sutherland

Theses and Dissertations

A method was found for creating ordered nanoparticles whose size and theoretical order-disorder temperature are ideal for study in the TEM. Specifically FePt, NiPt, FeNiPt and AuCu nanoparticles were studied. We were able to show how a nanoparticle's size affects its order-disorder temperature (Tod). When the particles were around 6 nm in diameter there was a shift downward of the Tod of 10-15 percent compared to the bulk. While particles around 10 nm in diameter experienced a downward shift of 0-6 percent compared to the bulk. One can approximate that particles less than 10-15 nm in diameter would show significant …


Nanoscale Surface Patterning And Applications: Using Top-Down Patterning Methods To Aid Bottom-Up Fabrication, Anthony Craig Pearson Aug 2012

Nanoscale Surface Patterning And Applications: Using Top-Down Patterning Methods To Aid Bottom-Up Fabrication, Anthony Craig Pearson

Theses and Dissertations

Bottom-up self-assembly can be used to create structures with sub-20 nm feature sizes or materials with advanced electrical properties. Here I demonstrate processes to enable such self-assembling systems including block copolymers and DNA origami, to be integrated into nanoelectronic devices. Additionally, I present a method which utilizes the high stability and electrical conductivity of graphene, which is a material formed using a bottom-up growth process, to create archival data storage devices. Specifically, I show a technique using block copolymer micelle lithography to fabricate arrays of 5 nm gold nanoparticles, which are chemically modified with a single-stranded DNA molecule and used …


Simulation And Analysis Of Cadmium Sulfide Nanoparticles, Chad Everett Junkermeier Dec 2008

Simulation And Analysis Of Cadmium Sulfide Nanoparticles, Chad Everett Junkermeier

Theses and Dissertations

I used ab initio molecular dynamics calculations to model cadmium sulfide nanoparticles. The nanoparticles were originaly spherical, bulk-like zinc-blende structures. Constant temperature molecular dynamics calculations reveals that CdS nanoparticles that are about 2 nm in diameter and have unpassivated surfaces are in an amorphous structure with short range order. The nearest neighbor distance on the surface of the nanoparticles being near the wurtzite nearest neighbor distance. I wrote the program xyzSTATS and used its results in justifying the amorphous nanoparticles claim. I also estimated the band gap of the CdS nanoparticles with unpassivated dangling bonds.