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Full-Text Articles in Meteorology
Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, A. S. Wozniak, J. E. Bauer, R. L. Sleighter, R. M. Dickhut, Patrick Hatcher
Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, A. S. Wozniak, J. E. Bauer, R. L. Sleighter, R. M. Dickhut, Patrick Hatcher
Chemistry & Biochemistry Faculty Publications
Despite the acknowledged relevance of aerosol-derived water-soluble organic carbon (WSOC) to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) was utilized in this study to provide detailed molecular level characterization of the hi(,h molecular weight (HMW; m/z>223) component of aerosol-derived WSOC collected from rural sites in Virginia and New York, USA. More than 3000 peaks were detected by ESI FT-ICR MS within a m/z range of 223-600 for each sample. Approximately 86% (Virginia) and 78% (New York) of these peaks were assigned molecular formulas …
A 200 Year Record Of Carbon-13 And Carbon-14 Variations In A Bermuda Coral, Y. Nozaki, D. M. Rye, K. K. Turekian, Richard E. Dodge
A 200 Year Record Of Carbon-13 And Carbon-14 Variations In A Bermuda Coral, Y. Nozaki, D. M. Rye, K. K. Turekian, Richard E. Dodge
Marine & Environmental Sciences Faculty Articles
A 200 year old brain coral, captured in Bermuda in 1976 was slabbed and x-rayed. Using the annual growth bands sequential, dated samples were taken over the entire growth period of the coral and analyzed for Δ14C, δ13C and δ18O. During the past 80 years atmospheric variations in Δ14C and δ13C due to human effects, such as release of bomb C-14 and dilution of both C-14 and C-13 by fossil fuel burning, are closely tracked by the coral. Prior to 1900 divergences between the coral and tree Δ14C …