Atmospheric Sciences Commons^™

A Simple Model To Estimate Atmospheric Concentrations Of Aerosol Chemical Species Based On Snow Core Chemistry At Summit, Greenland, M H. Bergin, C Davidson, Jack E. Dibb, J L. Jaffrezo, H D. Kuhns, S N. Pandis

Earth Sciences

A simple model is presented to estimate atmospheric concentrations of chemical species that exist primarily as aerosols based on snow core/ice core chemistry at Summit, Greenland. The model considers the processes of snow, fog, and dry deposition. The deposition parameters for each of the processes are estimated for SO₄²⁻ and Ca²⁺ and are based on experiments conducted during the 1993 and 1994 summer field seasons. The seasonal mean atmospheric concentrations are estimated based on the deposition parameters and snow cores obtained during the field seasons. The ratios of the estimated seasonal mean airborne concentration divided by the …

The Effects Of Vegetative Canopies On Atmospheric Dispersion, John R. Lindell

Theses and Dissertations

This research was conducted to improve our understanding of the effects of vegetative canopy-induced turbulence on the dispersion of air pollution. The computer model most often used to calculate atmospheric dispersion is the Gaussian plume model, which requires some method to compute the downwind dispersions coefficients. These coefficients are a parameterization of the atmospheric stability or the level of turbulence in the atmosphere. The Environmental Protection Agency's recommended parameterization scheme is the Pasquill-Gifford method. By comparing the Pasquill-Gifford method to the Modified Mitchell method using sigma theta, the standard deviation of the horizontal wind fluctuations, the relative precision of each …

The Role Of Frame Selection And Bispectrum Phase Reconstruction For Speckle Imaging Through Atmospheric Turbulence, Elizabeth A. Harpold

Theses and Dissertations

Frame selection using quality sharpness metrics have been shown in previous AFIT theses, to be effective in improving the final product of images obtained using adaptive optics. This thesis extends this idea to noncompensated speckle image data. Speckle image reconstruction is simulated with and without frame selection. Speckle images require the processing of hundreds of data frames. Frame selection is a method of reducing the amount of data required to reconstruct the image. A collection of short exposure image data frames of a single object are sorted based on sharpness metrics. Only the highest quality frames are retained and processed …

A Comparison Of Methods For Estimating Rms Error: A `Brute Force" Approach Versus A Mathematically-Elegant Approach, As Applied To The Calculation Of A Specific Retrieval Error For A Limb-Scanning Microwave Radiometer-Spectrometer, Larry L. Johnson

Theses and Dissertations

The Millimeter-wave Atmospheric Sounder (MAS) is a high resolution limb- scanning microwave radiometer-spectrometer which has been flown aboard the Space Shuttle. The instrument was designed to sense the microwave emission from several upper atmospheric constituents, including water vapor and ozone. The resonant frequencies of water vapor and ozone are extremely close (183 and 184 GHz, respectively), so that the high-frequency wing of the water vapor spectrum overlaps the low frequency wing of the ozone spectrum. Consequently, the measured ozone spectrum incorporates a slight water vapor contribution; therefore, the retrieved ozone profile is dependent on the true water vapor profile. The …

Characterization Of Atmospheric Turbulence Over Long Horizontal Paths Using Optical Slope Measurements, Eric E. Silbaugh

Theses and Dissertations

Atmospheric turbulence has long been recognized as one of the fundamental factors affecting optical systems operating through the atmosphere. Turbulence over vertical paths has been well characterized, both theoretically and experimentally. Much less is known about turbulence over long, horizontal paths. Perturbations of the wave front phase can be measured using a Hartmann wave front sensor (H-WFS). Theoretical expressions for the tilt removed structure function of the H-WFS slope measurements were derived and evaluated using quadrature. These slope structure functions are functions of the phase structure function. The Kolmogorov turbulence model was assumed. Simulated H-WFS slope measurements were generated using …

The Effect Of Meteorological Data Averaging Times On Plume Concentrations From Explosive Ordnance Disposal Open Burning Operations, Ida L. Widmann

Theses and Dissertations

Explosive Ordnance Disposal (EOD) Open Burning (OB) operations are performed to treat and dispose of unserviceable munitions in the Department of Defense (DOD) inventory. Air pollution modeling of OB operations is an Environmental Protection Agency requirement for permit issuance at OB sites. Specific OB regulation is still in its infancy; therefore, establishment of OB modeling techniques is still in the early stages. This thesis effort sought to develop a computer model, based upon the Gaussian Puff Equation. The model varies from standard plume modeling practices by not making the assumption that the wind direction, wind speed and turbulence are uniform …

Analysis And Interpretation Of Ion Data Associated With Neutral Gas Releases In The Earth's Ionosphere, Timothy M. Shadid

Theses and Dissertations

Barium and strontium release experiments were conducted throughout 1991 from the Combined Release and Radiation Effects Satellite (CRRES) to study both natural and man-made disturbances in the earth's ionosphere. A mass spectrometer on the spacecraft counted the Ba and Sr ions as the cloud expanded. In this study, data from the G-1 (in sunlight) and G-11b (in darkness) releases were modeled to understand the source of the ion signals. The model reproduced the Ba⁺ sun data well assuming photoionization (τ = 28 s) was the primary ionization mechanism. However, it was not able to account for the remaining ion …

A Chemical-Dynamical Model Of Wave-Driven Sodium Fluctuations, Michael P. Hickey Ph.D., John M.C. Plane

Publications

A comprehensive chemical-dynamical model is used to investigate the interaction of gravity waves with twenty minor species involved in the atomic sodium chemistry in the mesopause region. We find that chemistry becomes important on the underside of the sodium layer, primarily below 85 km altitude, where the relative importance of chemistry in wave-driven sodium fluctuations increases with increasing wave period and increasing horizontal wavelength. We also find that for altitudes below 80 km an adequate determination of the effects of chemistry in these fluctuations requires the inclusion of several reactions related to ozone chemistry. However, the atomic Na density is …

Diel Variations Of H2o2 In Greenland: A Discussion Of The Cause And Effect Relationship, R Bales, Joe Mcconnell, Mark V. Losleben, Martha H. Conklin, Katrin Fuhrer, Albrecht Neftel, Jack E. Dibb, D W. Kahl, C Stearns

Earth Sciences

Atmospheric hydrogen peroxide (H₂O₂) measurements at Summit, Greenland, in May–June, 1993 exhibited a diel variation, with afternoon highs typically 1–2 parts per billion by volume (ppbv) and nighttime lows about 0.5 ppbv lower. This variation closely followed that for temperature; specific humidity exhibited the same general trend. During a 17-day snowfall-free period, surface snow was accumulating H₂O₂, apparently from nighttime cocondensation of H₂O and H₂O₂. Previous photochemical modeling (Neftel et al., 1995) suggests that daytime H₂O₂ should be about 1 ppbv, significantly lower …

New Sources For The Hot Oxygen Geocorona: Solar Cycle, Seasonal, Latitudinal, And Diurnal Variations, Michael P. Hickey Ph.D., P. G. Richards, D. G. Torr

Publications

This paper demonstrates the variability of thermospheric sources of hot oxygen atoms. Numerical calculations were performed for day and night, high and low solar activity, summer and winter, and low- and middle-latitude conditions. Under most conditions, reactions involving metastable species are more important hot O sources than previously considered dissociative recombination of O2+ and NO+. All the hot O sources are an order of magnitude lower at midnight than at noon. At night, dissociative recombination of O2+and NO+ are the most important sources. Quenching of vibrationally excited N2 (N2*) by O is the most important metastable source at night. Above …

The Contributions Of Snow, Fog, And Dry Deposition To The Summer Flux Of Anions And Cations At Summit, Greenland, M H. Bergin, J L. Jaffrezo, C Davidson, Jack E. Dibb, S N. Pandis, R Hillamo, W Maenhaut, H D. Kuhns, T Makela

Earth Sciences

Experiments were performed during the period May–July of 1993 at Summit, Greenland. Aerosol mass size distributions as well as daily average concentrations of several anionic and cationic species were measured. Dry deposition velocities for SO₄²⁻ were estimated using surrogate surfaces (symmetric airfoils) as well as impactor data. Real-time concentrations of particles greater than 0.5 μm and greater than 0.01 μm were measured. Snow and fog samples from nearly all of the events occurring during the field season were collected. Filter sampler results indicate that SO₄²⁻ is the dominant aerosol anion species, with Na⁺, NH …

Ocena I Weryfikacja Lokalizacji Stanowisk Pomiarowych Imisji Zanieczyszczeń Powietrza W Województwie Kieleckim, Marian Mazur, Robert Oleniacz

Robert Oleniacz

The paper presents the implementation of air pollution monitoring in the province of Kielce (Poland), associated with verification of the location and the measuring range of points to measure the concentrations of air pollutants. For this purpose were used calculations of the pollutants dispersion and statistical analysis of measurement results obtained on existing measuring stations. In the statistical calculations were used analysis of variance homogeneity, based on Cochran, Bartlett and Hartley tests. As a result of analysis and calculations, it was found that the original location is not always correct and does not reflect the spatial differentiation of pollutant concentrations. …

Dynamics Of Dipoles In The Middle Atlantic Bight, Bruce L. Lipphardt Jr.

OES Theses and Dissertations

Beginning with the observations made by the Warm-Core Rings program in the early 1980's, several Gulf Stream warm-core rings (WCR's) in the Middle Atlantic Bight (MAB) have been observed with one or more cyclones around their periphery. These ring systems are observed in the slope water between the Gulf Stream's western boundary and the shelf break. Observations of ring systems have motivated a reanalysis of existing satellite surface temperature imagery, which revealed that multipole structure is common for both warm and cold core rings. This suggests that rings are better characterized as one part of multipole systems rather than as …

A Feasibility Study Of Dynamical Assimilation Of Tide Gauge Data In The Chesapeake Bay, Yvette H. Spitz

OES Theses and Dissertations

The feasibility of dynamical assimilation of surface elevation from tide gauges is investigated to estimate the bottom drag coefficient and surface stress as a first step in improving modeled tidal and wind-driven circulation in the Chesapeake Bay. A two-dimensional shallow water model and an adjoint variational method with a limited memory quasi-Newton optimization algorithm are used to achieve this goal.

Assimilation of tide gauge observations from ten permanent stations in the Bay and use of a two-dimensional model adequately estimate the bottom drag coefficient, wind stress and surface elevation at the Bay mouth. Subsequent use of these estimates in the …

Global Perspective Of Nitrate Flux In Ice Cores, Qinzhao Yang, Paul A. Mayewski, Sallie I. Whitlow, Mark S. Twickler, Michael Morrison, R. Talbot, Jack E. Dibb, Ernst Linder

Earth Sciences

The relationships between the concentration and the flux of chemical species (Cl-, NO3 - , SO42-, Na +, K + , NH4 + , Mg 2+ , Ca 2+) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly (a = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally distributed. Therefore we suggest that nitrate concentration …

Global Perspective Of Nitrate Flux In Ice Cores, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Michael Morrison, Robert Talbot, Jack Dibb, Ernst Linder

Earth Science Faculty Scholarship

The relationships between the concentration and the flux of chemical species(Cl^-, NO₃^-, SO₄^2-, Na⁺, K⁺, NH₄⁺, Mg²⁺, Ca²⁺) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly(α = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally …

Changes In Continental And Sea-Salt Atmospheric Loadings In Central Greenland During The Most Recent Deglaciation: Model-Based Estimates, R. B. Alley, R. C. Finkel, K. Nishizumi, A. Anandakrishnan, C. A. Shuman, G. Mershon, G. A. Zielinski, Paul Andrew Mayewski

Earth Science Faculty Scholarship

By fitting a very simple atmospheric impurity model to high-resolution data on ice accumulation and contaminant f1uxes in the GISP2 ice core, we have estimated changes in the atmospheric concentrations of soluble major ions, insoluble particulates and ¹⁰Be during the transition from glacial to Holocene conditions. For many species, changes in concentration in the ice typically overestimate atmospheric changes, and changes in flux to the ice typically underestimate atmospheric changes, because times of increased atmospheric contaminant loading are also times of reduced snowfall. The model interpolates between the flux and concentration records by explicitly allowing [or wet- and dry- …

Fisheries And Oceanography Off Galicia, Nw Spain: Mesoscale Spatial And Temporal Changes In Physical Processes And Resultant Patterns Of Biological Productivity, K. R. Tenore, M. Alonsonval, L. P. Atkinson, J. M. Cabanas, R. M. Cal, H. J. Campos, F. Castillejo, E. J, Chesney, N. Gonzalez, R. B. Hanson, C. R. Mcclain, A. Miranda, M. R. Roman, J. Sanchez, G. Santiago, L. Valdes, M. Varela, J. Yoder

CCPO Publications

The Galician shelf off NW Spain (43N degrees 9W degrees) exhibits mesoscale spatial and temporal changes in biological productivity associated with upwelling. Spatial heterogeneity results from local geomorphic and land-sea interactions superimposed on the large scale atmospheric processes that produce upwelling. Wind-induced upwelling events, commonly of short (i.e., week) duration, are more common in the summer than in the winter. A Series of cruises, including some time series sampling, and satellite imagery analysis showed that surface upwelling was more common and persistent on the northern coast compared with the western coast off the coastal embayments, the Rias Bajas. Nearshore off …

A Numerical Model Of The Global Carbon Cycle To Predict Atmospheric Carbon Dioxide Concentrations, Alexis Demitrios Kambis

Dissertations, Theses, and Masters Projects

A numerical model of the global carbon cycle is presented which includes the effects of anthropogenic &CO\sb2& emissions &(CO\sb2& produced from fossil fuel combustion, biomass burning, and deforestation) on the global carbon cycle. The model is validated against measured atmospheric &CO\sb2& concentrations. Future levels of atmospheric &CO\sb2& are then predicted for the following scenarios: (1) Business as Usual (BaU) for the period 1990-2000; (2) Same as (1), but with no biomass burning; (3) Same as (1), but with no fossil fuel combustion; (4) Same as (1), but with a doubled atmospheric &CO\sb2& concentration and a 2 K warmer surface temperature …