Atmospheric Sciences Commons^™

Variability In Accumulation Rates From Gpr Profiling On The West Antarctic Plateau, Vandy B. Spikes, Gordon S. Hamilton, Steven A. Arcone, Susan Kaspari, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Isochronal layers in firn detected with ground-penetrating radar (GPR) and dated using results from ice-core analyses are used to calculate accumulation rates along a 100 km across-flow profile in West Antarctica. Accumulation rates are shown to be highly variable over short distances. Elevation measurements from global positioning system surveys show that accumulation rates derived from shallow horizons correlate well with surface undulations, which implies that wind redistribution of snow is the leading cause of this variability. Temporal changes in accumulation rate over 25-185 year intervals are smoothed to along-track length scales comparable to surface undulations in order to identify trends …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Limited Migration Of Soluble Ionic Species In A Siple Dome, Antarctica, Ice Core, Karl J. Kreutz, Paul Andrew Mayewski, Sallie I. Whitlow, Mark S. Twickler

Earth Science Faculty Scholarship

High-resolution (>10 samples a ^-1) glaciochemical analyses covering the last 110 years from a Siple Dome, Antarctica, ice core reveal limited migration of certain soluble ionic species (methane sulfonic acid, NO₃ and Mg²⁺). Th e observed chemical migration m ay be due in part to seasonal alternation between less acidic winter (from high sea-salt concentrations) and m ore acidic summer (from high marine biogenic acid concentrations) layers, common at coastal sites such as Siple Dome. Exact mechanisms to explain the migration are unclear, although simple diffusion and gravitational movement are unlikely since new peaks are …

Spatial Variability Of Snow Chemistry In Western Dronning Maud Land, Antarctica, Malin Stenberg, Elisabeth Isaksson, Margareta Hansson, Wibjörn Karlén, Paul Andrew Mayewski, Mark S. Twickler, Sallie I. Whitlow, Niels Gundestrup

Earth Science Faculty Scholarship

During the austral summer of 1993-94 a number of 1-2 m deep snow pits were sampled in connection with firn-coring in western Dronning Maud Land, Antarctica. The traverse went from 800 to about 3000 m a.s.l. upon the high-altitude plateau. Profiles of cations (Na⁺, K⁺, Mg²⁺, Ca²⁺), anions (CI^-, NO^3-, SO₄^2-, CH₃SO₃^-) and stable oxygen isotopes (δ¹⁸O) from II snow pits are presented here. Close to the coast 2 m of snow accumulates in about 2-3 years, whilst …

Assessment Of The Record Of The 1982 El Chichón Eruption As Preserved In Greenland Snow, Gregory A. Zielinski, Jack E. Dibb, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Mark S. Twickler, Mark S. Germani

Earth Science Faculty Scholarship

Variability in the SO 4 2 - and Cl⁻ time series for the 1980s from 12 shallow snow pits across the Greenland ice sheet is used to evaluate the record of the 1982 El Chichón eruption and the potential for recording a moderate northern equatorial eruption in a single Greenland ice core. Composition of volcanic glass found in spring 1983 snow in one of the pits in the Summit region matches that from El Chichón glass, thereby verifying the deposition of material from the eruption. High Na⁺ and Cl⁻ concentrations in this same layer probably represent deposition …

Historical Biomass Burning: Late 19th Century Pioneer Agriculture Revolution In Northern Hemisphere Ice Core Data And Its Atmospheric Interpretation, G. Holdsworth, K. Hiuchi, G. A. Zielinski, Paul Andrew Mayewski, M. Wahlen, B. Deck, P. Chylek, B. Johnson, P. Damiano

Earth Science Faculty Scholarship

Ice core data from Yukon and Greenland spanning from ∼1750 to 1950 indicate that between ∼1850 and ≤1910 a clear atmospheric signal exists of an episodic biomass burning event that is referred to as the Pioneer Agriculture Revolution. This is best seen in NH₄⁺ ion and particulate concentrations but also in some limited black carbon concentration data, where for all three quantities maximum levels reach about 3 times the prerevolution background concentrations. Tree cellulose δ¹³C data and some early, controversial, French, air CO₂ data, occurring within the same time interval, are interpreted as providing other …

Chemical Species Spatial Distribution And Relationship To Elevation And Snow Accumulation Rate Over The Greenland Ice Sheet, Q. Yang, Paul Andrew Mayewski, E. Linder, S. Whitlow, M. Twickler

Earth Science Faculty Scholarship

Major chemical species (Cl⁻, NO⁻₃, SO²⁻₄, Na⁺, K⁺, Mg²⁺, Ca²⁺) from 24 snowpits (sampled at a resolution of 3 cm, total 2995 samples) collected from northern, central, and southern Greenland were used for this investigation. The annual and seasonal (winter and summer) concentration of each chemical species was calculated and used to study the spatial distribution of chemical species over the central portion of the Greenland Ice Sheet. A two-sided t-distribution test (α=0.05) suggests that concentrations of major chemical species in snow do …

Global Perspective Of Nitrate Flux In Ice Cores, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Michael Morrison, Robert Talbot, Jack Dibb, Ernst Linder

Earth Science Faculty Scholarship

The relationships between the concentration and the flux of chemical species(Cl^-, NO₃^-, SO₄^2-, Na⁺, K⁺, NH₄⁺, Mg²⁺, Ca²⁺) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly(α = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally …

Two-Hundred-Year Record Of Biogenic Sulfur In A South Greenland Ice Core (20d), P. Y. Whung, E. S. Saltzman, M. J. Spencer, Paul Andrew Mayewski, N. Gundestrup

Earth Science Faculty Scholarship

The concentration of methanesulfonic acid (MSA) was determined in a shallow south central Greenland ice core(20D). This study provides a high-resolution record of the DMS-derived biogenic sulfur in Greenland precipitation over the past 200 years. The mean concentration of MSA is 3.30 ppb(σ = 2.38 ppb,n = 1134). The general trend of MSA is an increase from 3.01 to 4.10 ppb between 1767 and 1900, followed by a steady decrease to 2.34 ppb at the present time. This trend is in marked contrast to that of non-sea-salt sulfate (nss SO₄^2-), which increases dramatically after 1900 due to …

Greenland Ice Core Greenland Ice Core "Signal" Characteristics: An Expanded View Of Climate Change, Paul Andrew Mayewski, L. D. Meeker, M. C. Morrison, M. S. Twickler, S. I. Whitlow, K. K. Ferland, D. A. Meese, M. R. Legrand, J. P. Steffensen

Earth Science Faculty Scholarship

The last millenium of Earth history is of particular interest because it documents the environmental complexities of both natural variability and anthropogenic activity. We have analyzed the major ions contained in the Greenland Ice Sheet Project 2 (GISP 2) ice core from the present to ∼674 A.D. to yield an environmental reconstruction for this period that includes a description of nitrogen and sulfur cycling, volcanic emissions, sea salt and terrestrial influences. We have adapted and extended mathematical procedures for extracting sporadic (e.g., volcanic) events, secular trends, and periodicities found in the data sets. Finally, by not assuming that periodic components …

Anthropogenic Sulfate And Asian Dust Signals In Snow From Tien Shan, Northwest China, Cameron P. Wake, Paul Andrew Mayewski, Wang Ping, Yang Qinzhao, Han Jiankang, Xie Zichu

Earth Science Faculty Scholarship

Snow samples were collected from a 0.5 m snowpack at Glacier No. 1 and near Bogda Feng, eastern Tien Shan, northwest China. Samples that were melted in the field were analyzed for chloride, nitrate, sulfate, sodium, potassium, magnesium, calcium, and microparticles. Eight samples were returned frozen and were analyzed for the above ions plus ammonium, acetate, formate, methylsulfonate, and hydrogen peroxide. There was no significant difference in measured major ion concentrations between the melted and frozen samples. Measured cations in both sets of samples were two to three times greater than measured anions. Calcium and sodium are the dominant cations …

Detailed Glaciochemical Investigations In Southern Victoria Land, Antarctica — A Proxy Climate Record, Paul Andrew Mayewski

Earth Science Faculty Scholarship

The production of environmental change records using time-series data retrieved from ice cores has seen minimal application in the Transantarctic Mountains despite the existence of a well-developed lower resolution glacial geologic record for this area which forms the primary basis for understanding the glacial history of East Antarctica. In addition, records derived from marine and lake cores, glacier margin fluctuation studies, measures of volcanic activity, and meteorological data sets from within or close to the Transantarctic Mountains are available for comparison. This emerging environmental data-base provides the tools needed to define the change characteristics, over a period of thousands of …

A Glaciochemical Survey Of The Summit Region, Greenland, Paul Andrew Mayewski, M. J. Spencer, M. S. Twickler, S. Whitlow

Earth Science Faculty Scholarship

Spatial representativeness and an understanding of controls on chemical species distribution are essential requirements of any significant ice core investigation. Snowpit studies provide an essential tool in this process. In preparation for the central Greenland deep drilling effort a series of snowpits was sampled in detail for oxygen isotopes, major anions, major cations, total acidity and radionuclides. The results of this sampling program are used to define: (I) the chemical composition of the snow in the region, (2) the input timing and spatial distribution of major chemical species, (3) the potential dependence of species concentration on accumulation rate, and (4) …