Oceanography and Atmospheric Sciences and Meteorology Commons^™

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Review Of Harmful Algal Bloom Effects On Birds With Implications For Avian Wildlife In The Chesapeake Bay Region, Barnett A. Rattner, Catherine E. Wazniak, Julia S. Lankton, Peter C. Mcgowan, Serguei V. Drovetski, Todd A. Egerton

United States Geological Survey: Staff Publications

The Chesapeake Bay, along the mid-Atlantic coast of North America, is the largest estuary in the United States and provides critical habitat for wildlife. In contrast to point and non-point source release of pesticides, metals, and industrial, personal care and household use chemicals on biota in this watershed, there has only been scant attention to potential exposure and effects of algal toxins on wildlife in the Chesapeake Bay region. As background, we first review the scientific literature on algal toxins and harmful algal bloom (HAB) events in various regions of the world that principally affected birds, and to a lesser …

Characterization Of Environmental Levels Of Pesticide Residues In Household Air And Dust Samples Near A Bioenergy Plant Using Treated Seed As Feedstock, Jabeen Taiba, Eleanor G. Rogan, Daniel D. Snow, Chandran Achutan, Muhammad Zahid

Nebraska Water Center: Faculty Publications

Exposure to neonicotinoid insecticides is associated with adverse human health outcomes. There is environmental contamination in Saunders County, Nebraska, due to the accumulation of fungicides and insecticides from a now-closed ethanol plant using seed corn as stock. A pilot study quantified environmental contamination in nearby houses from residual pesticides by measuring dust and air (indoor/outdoor) concentrations of neonicotinoids and fungicides at the study site (households within two miles of the plant) and control towns (20–30 miles away). Air (SASS^® 2300 Wetted-Wall Air Sampler) and surface dust (GHOST wipes with 4 × 4-inch template) samples were collected from eleven study …

Leaching Performance Of Nanotechnology-Induced High-Arsenic-Bearing Tooeleite-Like Mineral Nanowaste, Arindam Malakar, Sanjit Das, Samirul Islam, Rajneesh Singh, Sugata Ray

Nebraska Water Center: Faculty Publications

For arsenic decontamination from groundwater, arsenic crystallization is becoming adopted due to its sustainability and economic benefits. However, arsenic crystallization technology is a two-step process, which makes it complex and generates hazardous waste. Successful efforts toward making it a single-step process are presented here. The addition of nanorods and ball-milled zinc sulfide nanoparticles to arsenic-contaminated water result in highly monodispersed and higharsenic- containing mineralized nanowaste with a crystalline structure similar to the mineral Tooeleite ((Fe³⁺₆(As³⁺O₃)₄SO₄(OH)₄•4H₂O)). This study reports the results of a short-term stability test …

Reducing Uncertainty In Sea-Level Rise Prediction: A Spatial-Variability-Aware Approach, Subhankar Ghosh, Shuai An, Arun Sharma, Jayant Gupta, Shashi Shekhar, Aneesh Subramanian

I-GUIDE Forum

Given multi-model ensemble climate projections, the goal is to accurately and reliably predict future sea-level rise while lowering the uncertainty. This problem is important because sea-level rise affects millions of people in coastal communities and beyond due to climate change's impacts on polar ice sheets and the ocean. This problem is challenging due to spatial variability and unknowns such as possible tipping points (e.g., collapse of Greenland or West Antarctic ice-shelf), climate feedback loops (e.g., clouds, permafrost thawing), future policy decisions, and human actions. Most existing climate modeling approaches use the same set of weights globally, during either regression or …

How Sensitive Are Catchment Runoff Estimates To On-Farm Storages Under Current And Future Climates?, David E. Robertson, Hongxing Zheng, Jorge L. Pena-Arancibia, Francis H S Chiew, Santosh Aryal, Martino E. Malerba, Nicholas J. Wright

Climate Science Research Articles

Storage of water in farm dams is important to support irrigation, stock requirements and domestic uses when reticulated water is unavailable. Farm dams that fill by intercepting landscape runoff change the total volume and seasonality of catchment streamflow, potentially impacting water policy outcomes. While numerous studies have quantified how climate change and farm dams independently change streamflow characteristics, few studies have investigated their interactions. This study investigates the interactions between farm dams and climate change in the Murray-Darling Basin of southern and eastern Australia. We use hydrological modelling that explicitly represent farm dams and remotely sensed data describing historical farm …

Causes And Effects Of Shisper Glacial Lake Outburst Flood Event In Karakoram In 2022, Sandeep Kumar Mondal, Vatsal D. Patel, Rishikesh Bharti, Ramesh P. Singh

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Karakoram Himalayas are vulnerable to glacial lake outburst floods (GLOFs), which cause catastrophic floods in the surrounding areas. The increasing natural and anthropogenic activities, especially in the Indo-Gangetic Plains at the southern flank of the towering Himalayas, could be the cause of climate change affecting the frequency of the natural hazards in the Himalayas. In the present study, a detailed analysis of the Shisper Lake breach of 7 May 2022 is carried out using satellite remote sensing. A decreasing trend in the glacial mass balance is observed between 2017 and 2021; in this period, frequent GLOF episodes occurred. A pronounced …

The Influence Of Effluent: Exploring How Wastewater Effluent Impacts Ísafjörður, Iceland, Madi Bennett-Wells

Iceland: Climate Change and The Arctic

Wastewater effluent is of growing concern in communities without proper wastewater treatment plans in place. This study examines the effects that wastewater discharge has on water quality in various communities through field research and an accompanying literature review. Water quality parameters (pH and temperature) were used to determine the impact effluent has on the local harbor, Pollurinn, in Ísafjörður, Iceland. Results showed that there was a statistical significance between pH and the area of study, while temperature was more varied; these results signify that effluent has the biggest impact on the area immediately surrounding the effluent pipe. The literature review …

Assessing The Performance Of Agricultural Systems In The Inland And Coastal Regions Of Northern Portugal Using Indicators: Establishing The Foundation Towards Better Agricultural Practices, Genevieve Gehlken

Independent Study Project (ISP) Collection

This study conducts a comprehensive evaluation of agricultural systems in the distinct coastal and inland regions of Northern Portugal. Employing key indicators, including soil erosion, nitrogen surplus, irrigation practices, Agricultural Gross Domestic Product (GDP), and crop yield, the analysis reveals statistically significant disparities and unique challenges in each region. The coastal areas, marked by higher agricultural GDP, exhibit distinct economic dependencies on agriculture, while the inland regions face challenges related to water scarcity, soil erosion, and rural isolation. The looming threat of climate change adds complexity to these dynamics, further highlighting the need for region-specific, sustainable agricultural practices. In the …

A New View Of Chlorophyll Dynamics In The Southern Mid-Atlantic Bight From A Two-Year High-Resolution Spray Glider Survey, Francesco Lane

OES Theses and Dissertations

The southern Mid-Atlantic Bight (MAB) near Cape Hatteras, NC, USA, is likely a hotspot for the episodic export of carbon-rich shelf waters to the open ocean. Over a 2 year period, from March 2017 to May 2019, Spray gliders repeatedly occupied transects, along the slope and across the shelf, generating high-resolution chlorophyll fluorescence (fChl) data in the southern MAB. This study implements an fChl calibration method utilizing remotely sensing ocean color as a standard. We validate the method’s utility by demonstrating a reduction in post-calibration cross-mission fChl variability and demonstrating close correspondence between the calibrated fChl data and an in …

Understanding The Role Of The Jet Streams And Gulf Stream Eddies On The Northwest Atlantic Marine Heatwaves, Lydia Rose Duncan Sims

Theses and Dissertations

The Northwest (NW) Atlantic is one of the fastest warming regions in the global ocean and in the recent decade has experienced several extreme temperature events. These extreme anomalous temperature events are known as Marine Heatwaves (MHWs), which are forced by a variety of physical processes that affect the heat source and sink of the water column. These MHWs have been increasing globally in duration and frequency due to anthropogenic warming, and have increased ecological damage seen in mass mortality events of economically viable species. Within the NW Atlantic, several key processes encourage the formation of MHWs, such as the …

Wind Speed Forecasting Using Wavelet Analysis And Recurrent Artificial Neural Networks Based On Local Measurements In Singida Region, Tanzania, Rajabu J. Mangara, Mwingereza J. Kumwenda

Tanzania Journal of Science

High accuracy wind speed forecasting is essential for wind energy harvest and plays a significant role in wind farm management and grid integration. Wind speed is intermittent in nature, which makes the forecasting to be a big challenge. In the present study, three hybrid single-step wind speed forecasting techniques are proposed and tested by local measurement data in Singida region, Tanzania. The three techniques are based on Wavelet Analysis (WA), Back Propagation (BP) optimization algorithm, and Recurrent Neural Network (RNN). They are referred to as WA-RNN, BP-RNN, and WA-BP-RNN. The model results showed that WA-BP-RNN outperforms the other two proposed …

Microplastics Distribution Within Western Arctic Seawater And Sea Ice, Alessandra D’Angelo, Nicole Trenholm, Brice Loose, Laura Glastra, Jacob Strock, Jongsun Kim

School of Earth, Environmental, & Marine Sciences Faculty Publications

Microplastic pollution has emerged as a global environmental concern, exhibiting wide distribution within marine ecosystems, including the Arctic Ocean. Limited Arctic microplastic data exist from beached plastics, seabed sediments, floating plastics, and sea ice. However, no studies have examined microplastics in the sea ice of the Canadian Arctic Archipelago and Tallurutiup Imanga National Marine Conservation Area, and few have explored Arctic marginal seas’ water column. The majority of the microplastic data originates from the Eurasian Arctic, with limited data available from other regions of the Arctic Ocean. This study presents data from two distinct campaigns in the Canadian Arctic Archipelago …

Approaches To Assessing Nutrient Coupling In Open Ocean Datasets, James M. Moore, Claire P. Till

IdeaFest: Interdisciplinary Journal of Creative Works and Research from Cal Poly Humboldt

Nutrient coupling describes a process where the biogeochemical cycles of two elements are linked by being incorporated similarly into biomass. This paper uses data from the GEOTRACES GP16 cruise (Eastern Pacific Zonal Transect) to investigate the relationship between certain macronutrients generally coupled to trace elements in terms of their oceanic distributions with the notable exception of in an oxygen minimum zone: cadmium-phosphate and zinc-silicate. There are many methods applied to oceanographic data to correlate analyte concentrations; while they are often presented independently in literature, here we attempt to use them in conjunction for a more thorough interpretation. By compiling 1) …

Reaction Steps In Heterogeneous Photocatalytic Oxidation Of Toluene In Gas Phase—A Review, Yerzhigit Tulebekov, Zhandos Orazov, Bagdat Satybaldiyev, Daniel D. Snow, Raphaël Schneider, Bolat Uralbekov

Nebraska Water Center: Faculty Publications

A review of the current literature shows there is no clear consensus regarding the reaction mechanisms of air-borne aromatic compounds such as toluene by photocatalytic oxidation. Potential oxidation reactions over TiO₂ or TiO₂-based catalysts under ultraviolet and visible (UV/VIS) illumination are most commonly considered for removal of these pollutants. Along the pathways from a model pollutant, toluene, to final mineralization products (CO₂ and H₂O), the formation of several intermediates via specific reactions include parallel oxidation reactions and formation of less-reactive intermediates on the TiO₂ surface. The latter may occupy active adsorption sites and …

How Is Flash Drought Understood?—Experts’ Definitions And Decision-Makers’ Perceptions, Caily Schwartz, Tonya Haigh, Mark D. Svoboda, Madeline Goebel

National Drought Mitigation Center: Faculty Publications

Because flash drought is a relatively new phenomenon in drought research, defining the concept is critical for scientists and decision-makers. Having detrimental impacts on many sectors, it is important to have a consistent definition and understanding of flash drought, between experts and stakeholders, to provide early warning to the community. This study focuses on onset and progression of conditions and demonstrates the difference in flash drought identification for 15 events across six quantitative definitions of flash drought that use the U.S. Drought Monitor (USDM). Five flash drought events have been studied in the literature while 10 additional events have been …

Evaluation And Description Of Nature-Based Engineering Stream Restoration Through Dutton Shadyside Park, Julie Wildschut, Andrea Lubberts, David P. Warners, Haley Weesies

Faculty and Professional Research

As land uses change over time, from wetlands and forests to agricultural fields, suburban neighborhoods, and commercial areas, stormwater runoff increases in volume and moves more rapidly into nearby streams. This altered hydrology conveys pollutants directly to local waterways and increases erosion, resulting in deeply entrenched channels with steep banks lacking vegetation. Plaster Creek, located near Grand Rapids, MI, is an example of such an impaired stream, having become channelized and separated from adjacent floodplain habitat along much of its 26-mile length. As part of a Michigan EGLE 319 grant, Plaster Creek Stewards, an initiative of Calvin University, used nature-based …

The Irrigation Efficiency Trap: Rational Farm-Scale Decisions Can Lead To Poor Hydrologic Outcomes At The Basin Scale, Christina N. Morrisett, Robert W. Van Kirk, London O. Bernier, Andrea L. Holt, Chloe B. Perel, Sarah E. Null

Watershed Sciences Faculty Publications

Agricultural irrigation practices have changed through time as technology has enabled more efficient conveyance and application. In some agricultural regions, irrigation can contribute to incidental aquifer recharge important for groundwater return flows to streams. The Henrys Fork Snake River, Idaho (United States) overlies a portion of the Eastern Snake Plain Aquifer, where irrigated agriculture has occurred for over a century. Using irrigator interviews, aerial and satellite imagery, and statistical streamflow analysis, we document the impact of farm-scale decisions on basin-scale hydrology. Motivated to improve economic efficiency, irrigators began converting from surface to center-pivot sprinkler irrigation in the 1950s, with rapid …

The Patchwork Governance Of Ecologically Available Water: A Case Study In The Upper Missouri Headwaters, Montana, United States, Amanda E. Cravens, Julia B. Goolsby, Theresa Jedd, Deborah J. Bathke, Shelley Crausbay, Ashley E. Cooper, Jason Dunham, Tonya Haigh, Kimberly R. Hall, Michael J. Hayes, Jamie Mcevoy, Rebecca L. Nelson, Markéta Poděbradská, Aaron Ramirez, Elliot Wickham, Dionne Zoanni

National Drought Mitigation Center: Faculty Publications

Institutional authority and responsibility for allocating water to ecosystems (“ecologically available water” [EAW]) is spread across local, state, and federal agencies, which operate under a range of statutes, mandates, and planning processes. We use a case study of the Upper Missouri Headwaters Basin in southwestern Montana, United States, to illustrate this fragmented institutional landscape. Our goals are to (a) describe the patchwork of agencies and institutional actors whose intersecting authorities and actions influence the EAW in the study basin; (b) describe the range of governance mechanisms these agencies use, including laws, policies, administrative programs, and planning processes; and (c) assess …

Insar Time Series Analysis To Evaluate Subsidence Risk Of Monumental Chandigarh City (India) And Surroundings, Jungrack Kim, Shih-Yuan Lin, Tejpal Singh, Ramesh P. Singh

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Groundwater depletion is one of the serious geo-environmental issues causing ground subsidence, which damage buildings, infrastructures and causes loss of life. The quantitative and qualitative evaluation of groundwater variability requires multiple approaches to measure hydraulic head level and geodetic deformation. In this study, we have made efforts to integrate multiple hierarchical space-borne data, including Gravity Recovery and Climate Experiment (GRACE), Sentinel-1 Interferometric Synthetic Aperture Radar (InSAR), geological and hydrological data, to quantify subsidence in Chandigarh city and its surroundings. First, we conducted New-Small BAseline Subsets (NSBAS) and pointwise persistent scatterer (PS) InSAR techniques in parallel, using three-years Sentinel-1 data showing …

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …

History Of Ice-Rafting In The Arctic Ocean During Glacial Maxima Through Marine Isotope Stage 6, Shannon M. Cofield

OES Theses and Dissertations

Numerous studies attempted to reconstruct Arctic paleoclimate, specifically ice mass timing and locations, during glacial maxima. While some regions, like the Barents-Svalbard Ice Sheet (BSIS) are well-studied, they may benefit from a high-resolution paleo proxy. Other regions are highly contested, such as the East Siberian Sea or the presence of a central Arctic Ocean ice mass.

This research uses an Fe-grain provenance method to (1) define how the BSIS behaved during Marine Isotope Stage (MIS) 2, 4, and 6, and when it retreated; (2) determine the presence and ages of Shelf Ice Masses (SIMs) in the Beaufort Sea and East …

Nitrogen Cycling In The Lower Chesapeake Bay And Mid- And South Atlantic Bight, Yifan Zhu

OES Theses and Dissertations

Nitrogen (N) is central to marine primary production; its availability often limits the capacity and rates of primary productivity in most of the world’s oceans. Contrastingly, estuaries frequently receive anthropogenic N loading, oftentimes resulting in eutrophication, harmful algal blooms (HABs), and substantially degraded water quality. Nutrient variability in both estuaries and oceanic regimes results from meteorological forcing and physical processes, including wind-induced, tidal, and mesoscale mixing and upwelling. In this dissertation, a comprehensive investigation of N variability and cycling and its links to physical-biogeochemical processes was conducted using time-series monitoring approaches, flux estimations, satellite imaging, biogeochemical measurements, and molecular analyses. …

Crustal Structures Of Diebold Knoll And Adjacent Juan De Fuca Oceanic Crust From Integration Of Seismic, Gravity And Magnetic Data, Md Ariful Islam

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Cascadia Subduction Zone (CSZ) has a long history of devastating earthquakes as the Juan de Fuca plate subducts beneath North America, where an imminent megathrust earthquake is expected. Compared to other subduction zones, CSZ exhibits unusually low seismic activity, particularly in the central region with respect to relatively high seismicity zones to the north and south. Some researchers attribute this behavior to subducted seamounts, although their impact on seismicity remains poorly understood and highly debated in the literature. Examining subducted seamounts is challenging due to complexity of the overburden strata. That is why this study focuses on an isolated not-yet-subducted …

Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort

Nebraska Water Center: Faculty Publications

The amount of antibiotics and personal care products entering local sewage systems and ultimately natural waters is increasing and raising concerns about long-term human health effects. We developed an adsorptive photocatalyst, Cu_0.5Mn_0.5Fe₂O₄ nanoparticles, utilizing co-precipitation and calcination with melamine, and quantified its efficacy in removing paraben and oxytetracycline (OTC). During melamine calcination, Cu_0.5Mn_0.5Fe₂O₄ recrystallized, improving material crystallinity and purity for the adsorptive–photocatalytic reaction. Kinetic experiments showed that all four parabens and OTC were removed within 120 and 45 min. We found that contaminant adsorption and reaction …

Droughtscape, Summer 2023, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

DroughtScape, Summer 2023

Nitrous Oxide Cycling In The Eastern Tropical North Pacific Oxygen Deficient Zone From Concentrations, Stable Isotopes And Isotopomers, Margaret Ann Gaspar

Theses and Dissertations

Nitrous oxide (N₂O) is a potent greenhouse gas and ozone depleting substance. It is estimated that the ocean accounts for about one third of total atmospheric emissions, which mostly occur in Oxygen Deficient Zones (ODZs) connected to coastal upwelling regions. Modeling efforts and high-resolution datasets are starting to provide a clearer picture of global marine N₂O fluxes, spatiotemporal variability, and the impacts of submesoscale processes on N₂O distributions. We measured nitrous oxide concentrations, stable isotope ratios and isotopomers at 7 open ocean stations along a transect crossing the Eastern Tropical North Pacific ODZ as …

Incorporation Of Carbon Dioxide Production And Transport Module Into A Soil-Plant-Atmosphere Continuum Model, Sahila Beegum, Wenguang Sun, Dennis Timlin, Zhuangji Wang, David Fleisher, Vangimalla R. Reddy, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

Carbon dioxide release from agricultural soils is influenced by multiple factors, including soil (soil properties, soil-microbial respiration, water content, temperature, soil diffusivity), plant (carbon assimilation, rhizosphere respiration), atmosphere (climate, atmospheric carbon dioxide), etc. Accurate estimation of the carbon dioxide (CO₂) fluxes in the soil and soil respiration (CO₂ flux between soil and atmosphere) requires a process-based modeling approach that accounts for the influence of all these factors. In this study, a module for CO₂ production via root and microbial respiration and diffusion-based carbon dioxide transport is developed and integrated with MAIZSIM (a process-based maize crop growth …

Wildlife Ecological Risk Assessment In The 21st Century: Promising Technologies To Assess Toxicological Effects, Barnett A. Rattner, Thomas G. Bean, Val R. Beasley, Philippe Berny, Karen M. Eisenreich, John E. Elliott, Margaret L. Eng, Phyllis C. Fuchsman, Mason D. King, Rafael Mateo, Carolyn B. Meyer, Jason M. O'Brien, Christopher J. Salice

United States Geological Survey: Staff Publications

Despite advances in toxicity testing and the development of new approach methodologies (NAMs) for hazard assessment, the ecological risk assessment (ERA) framework for terrestrial wildlife (i.e., air‐breathing amphibians, reptiles, birds, and mammals) has remained unchanged for decades. While survival, growth, and reproductive endpoints derived from whole-animal toxicity tests are central to hazard assessment, nonstandard measures of biological effects at multiple levels of biological organization (e.g., molecular, cellular, tissue, organ, organism, population, community, ecosystem) have the potential to enhance the relevance of prospective and retrospective wildlife ERAs. Other factors (e.g., indirect effects of contaminants on food supplies and infectious disease processes) …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …