Geology Commons^™

Quantifying Crustal Assimilation In Historical To Recent (1329-2005) Lavas At Mt. Etna, Italy: Insights From Thermodynamic Modeling, Marie Takach

All Master's Theses

The nearly continuous volcanic eruption record at Mt. Etna dating back approximately 700 years provides an excellent opportunity to investigate the geochemical evolution of a highly active volcano. Of particular interest is elucidating the cause of a selective enrichment in alkali elements (K, Rb, Cs) and ⁸⁷Sr/⁸⁶Sr. This alkali enrichment trend, which began in the 17^th century and accelerated after 1971, was accompanied by an increase in the volume, frequency, and explosivity of eruptions. To explain this enrichment, two major arguments are invoked: (1) crustal contributions (e.g., assimilation of the sedimentary basement), and (2) changes in …

Trace Metal And Metalloid Behavior In The Submicron Scale Components Of Coal Fly Ashes: Insights From Combined Microscopic And Microbiological Studies, Matthew Costa

Open Access Theses & Dissertations

For over a century, coal has been used worldwide to meet ever-growing energy demands. Coal combustion accounts for over 30% of electricity generation in the United States. In the U.S., coal combustion produces annually over 100 million tons of coal combustion products (CCPs) of which only 30% are used in beneficial and economic ways. One of the primary CCPs from coal-burning power plants is fly ash, typically fine-sized and enriched in many trace elements (e.g., arsenic, chromium, lead, and vanadium). When disposed in the environment, fly ash may release significant concentrations of trace elements into surrounding ecosystems and induce toxicity …

Occupational Seasonality And Paleoenvironmental Reconstruction At Quebrada Jaguay 280, Stephanie Melissa Gruver

Graduate Research Theses & Dissertations

Quebrada Jaguay 280 (QJ-280) is one of the oldest maritime archaeological sites in the New World. Previous excavations of the southern Peruvian coastal site have dated occupation from ~13,000-8,000 cal yr BP. These excavations also determined that the occupants of the site used preferential maritime resource procurement strategies and had an interzonal connection to the highlands. In 2017 a new excavation was conducted at QJ-280 and the remains of the marine mollusk Mesodesma donacium were recovered. Geochemical examinations on the shell remains informed on the occupational seasonality of the site and reconstructed sea surface temperatures experienced off the coast of …

Tuhualite In A Peralkaline Rhyolitic Ignimbrite From Pantelleria, Italy, Boguslaw Baginski, Ray Macdonald, John C. White, Lidia Jezak

EKU Faculty and Staff Scholarship

An occurrence of the rare mineral tuhualite (NaFe3+Fe2+Si6O15) is reported in a peralkaline rhyolitic ignimbrite from the 11 island of Pantelleria, Italy. The mineral formed during devitrification of glassy fiamme and varies in form from anhedral plates to 12 perfect euhedral in open vesicles. There is significant replacement of Fe2+ by Mn (FMQ in the presence of a 14 hydrous fluid.

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Provenance Analysis Of The Grover Gravel Using Detrital Zircon Geochronology, Petrology And Heavy Mineral Analysis, Grant Spoering

Graduate Theses/Dissertations

The Grover Gravel in the St. Louis, Missouri area contains a mix of chert, quartzite, jasper, and ironstone in clast sizes ranging up to 60 cm. The gravel varies in thickness from a veneer to over 30 feet and rests on upland surfaces at elevations sometimes exceeding 300 feet above the floors of major valleys. A pre-Pleistocene age generally has been proposed or assumed for the gravel, which classically has been interpreted to be a meandering-stream deposit atop an extensive flat upland surface, which was subsequently eroded and dissected by rejuvenated streams. However, large quartzite boulders in the gravel also …

A Geochemical Investigation And Comparison Between Organic-Rich Black Shales And Mississippi Valley-Type Pb-Zn Ores In The Southern Ozarks Region, Bryan Michael Bottoms

Graduate Theses and Dissertations

Mississippi Valley-type (MVT) deposits are base metal sulfide deposits that are important economic sources of both Pb and Zn, accounting for 24% of the global Pb and Zn reserves. They are found all over the world, often hosted in platform carbonates on the flanks of sedimentary basins, and often in proximity to hydrocarbons. They are epigenetic, not related to igneous activity, and thought to be sourced from low temperature, highly saline basinal brines that are expelled from sedimentary basins during compaction and/or in conjunction with an orogenic event. The basinal lithologies responsible for providing the metals for the ores are …

U–Pb Dating Of Cave Spar: A New Shallow Crust Landscape Evolution Tool, D. D. Decker, V. J. Ployak, Y. Asmeron, Matthew Lachniet

Geoscience Faculty Research

In carbonate terranes, rocks types that provide apatite are not available to effectively use apatite fission track (AFT) or (U/Th)‐He chronometry (AHe). Here we suggest that calcite cave spar can be an effective chronometer and complimentary to AFT and AHe thermochronometers in carbonate regions such as our study area, the Guadalupe Mountains of southeastern New Mexico, and west Texas. Our measured depth of cave spar deposition is 500 ± 250 m beneath the regional water table, formed at temperatures of 40° to 80°C, indicating that these caves and their spar crystals form near the supercritical CO2‐subcritical CO2 boundary where we …

Resolving Chronological And Temperature Constraints On Antarctic Deglacial Evolution Through Improved Dating Methodology, Cristina Subt

USF Tampa Graduate Theses and Dissertations

In order to determine the timing of Antarctic ice sheet retreat and advance during the Late Quaternary, various tools are used to measure the age of marginal marine sediments. Carbonate 14C dating is a well-established approach, but requires foraminiferal microfossils, shells or other carbonate materials that are rare in most Antarctic regions, and may also suffer from vital effects, which can result in variability of up to 500 years in living organisms. Bulk acid insoluble organic (AIO) 14C dates are frequently as an alternative, but this approach works best where high productivity and sedimentation rates reign, and not too well …

Paleoenvironmental Variation And Provenance Records From Neogene Deep Sea Sediment Of The South China Sea, Chang Liu

LSU Doctoral Dissertations

I employed several paleoenvironmental proxies by utilizing deep sea sediment from the largest marginal basin in east Asia, namely the South China Sea (SCS), to reconstruct the long term paleoenvironmental variation in SE Asia since the Neogene. Sediments deposited within the SCS were mainly delivered by several major fluvial systems whose catchment basins cover several geological blocks in SE Asia. By analyzing the sediment’s geochemical and mineralogical characteristics, several indices which are affected by the source of the sedimentary influx, as well as the weathering state could be built and applied to constrain my paleoenvironmental reconstructions

Two deep sea drilling …

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …

A Geochemical And Petrological Analysis Of The San Rafael Volcanic Field, Utah, Danielle Koebli

USF Tampa Graduate Theses and Dissertations

The San Rafael Volcanic Field, Utah, is a 4.6 Ma extinct monogenetic field that is found in the Northern Transition Zone of the Colorado Plateau. The field has been eroded, leaving the dikes, conduits, and sills visible. Within the sills we see evidences of immiscibility in the form of an intermediate syenite (~50 wt% SiO₂) enclosed in a mafic shonkinite (~48 wt % SiO₂). Field relations indicate that sills were formed due to single events (Richardson et al., 2015), which makes in-situ differentiation the process at the origin of both rock types. Geochemical data supports differentiation …

Further Study Of Garnet Xenocrysts In New York City Migmatites, Stanley Schleifer, Nazrul I. Khandaker

Publications and Research

The authors have previously published an article at the 2004 Geological Society of America Annual Meeting, Petrogenetic Significance of Garnets in the Bedrock of New York City, in which they suggested that the garnet xenocrysts observed in the quartzofeldspathic zones of the migmatites, so frequently seen both at the surface, and below the surface pursuant to the construction of the Manhattan portion of New york City Water Tunnel #3, were a refractory residue of the anatectic melting of the immediately surrounding schistose bedrock. Although the relatively high melting point temperature of garnet compared to other minerals in the surrounding …

Diurnal And Seasonal Variation In Groundwater Nitrate -N Concentration In A Saturated Buffer Zone, Joseph Miller

Theses and Dissertations

Surface water pollution by nitrate (NO3-) is identified as a critical problem in agricultural land-use areas. Excess NO3- loading causes eutrophication and hypoxia in near-shore marine waters such as the Gulf of Mexico. Diversion of agricultural runoff into saturated buffer zones reduces NO3- loading. Although the mechanisms responsible for NO3- reduction in saturated buffer zones are well characterized, little is known about how NO3- concentrations vary temporally and what factors control those changes. The objective of this study is to understand NO3- concentration and environmental factor variability in a saturated buffer zone on a diurnal scale within and among the …

40ar/39ar Ages And Zircon Petrochronology For The Rear Arc Of The Izu-Bonin-Marianas Intra-Oceanic Subduction Zone, Graham Dm Andrews

Faculty & Staff Scholarship

Long-lived intra-oceanic arcs of Izu-Bonin-Marianas (IBM)-type are built on thick, granodioritic crust formed in the absence of pre-existing continental crust. International Ocean Discovery Program Expedition 350, Site U1437, explored the IBM rear arc to better understand continental crust formation in arcs. Detailed petrochronological (U–Pb geochronology combined with trace elements, oxygen and hafnium isotopes) characterizations of zircon from Site U1437 were carried out, taking care to exclude potential contaminants by (1) comparison of zircon ages with ship-board palaeomagnetic and biostratigraphic ages and 40Ar/39Ar geochronology, (2) analysing zircon from drill muds for comparison, (3) selectively carrying out in situ analysis in petrographic …

Conduction Plus Convection Heat Flow Modeling For The Linga Complex, Peruvian Coastal Batholith, Luciano Uriel González Olivares

Loma Linda University Electronic Theses, Dissertations & Projects

Factors affecting the thermal evolution of the Linga magmatic intrusion in the Ica-Pisco area of the Peruvian Coastal Batholith were studied using field work, petrography, geochemistry data, and computer modeling. Field work and petrography involved collecting samples for geochemical analysis and documenting widespread propylitic and potassic hydrothermal alteration. Major element geochemistry was used to estimate rock density, viscosity, liquidus temperature, and water content. The δ18O values of seven fresh samples showed a slightly increasing west-east and old-young trend of approximately 7-8‰, indicating an increasing crustal component. The δ18O and δD values for eleven altered samples indicated that alteration came mostly …

Investigating Core Shale Depositional Environments Of Late Pennsylvanian Cyclothems Utilizing Geochemical Proxies To Test The Superestuarine Model, Bryce A. Mathis

LSU Master's Theses

The Late Paleozoic Midcontinent Sea (LPMS) inundated vast areas of the North American interior during glacio-eustatic transgressions, depositing widespread black shales facies within the core shale intervals of major cyclothems. These black shale deposits are unique because no modern analogs can adequately explain the depositional environments and model for organic matter preservation across such vast ancient epicontinental settings. One possible explanation is that a superestuarine circulation system developed across the LPMS during humid interglacial phases, which promoted strong water column stratification and benthic anoxia.

The goal of this research was to test the validity of the superestuarine estuarine model and …

Sedimentary Characteristics And Nutrient Sequestration Of Embanked Floodplains Along The Lower Mississippi River, Mississippi And Louisiana, R M Malitha Rathnayake

Master's Theses

The Mississippi River Basin is the largest river basin in North America and the third largest river basin in the world. Most of the corn, soybeans, wheat, cattle, and hogs harvested in the United States come from the Mississippi River Basin and about 58% of the entire drainage basin is croplands. Runoff from these lands carries sediments and nutrients, and the Mississippi River transports these downstream and ultimately deposits them in the Gulf of Mexico. The northern Gulf of Mexico is one of largest human-caused hypoxic zones in the world. Hypoxia is the phenomena where the dissolved oxygen level decreases …

The Dynamic Relationship Between The Bear River, Quaternary Basaltic Center, Normal Faults, And The Resulting Rearrangement Of Rivers In The Northeast Edge Of The Great Basin, Southeast Idaho, Brady Utley

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The objective of this research project in Gem Valley graben, southeast Idaho is to identify the location, age and history of the Quaternary diversion of the Bear River into paleo-Lake Thatcher, and then into the Lake Bonneville basin from the Columbia River basin. Mapping, geochemical analysis, cross-cutting relationships, and five new age determinations, together with prior published research, shed new light on the complex history of interaction between the volcanic rocks, rivers, lakes, and faults in Gem Valley. Research goals were to test the hypothesis that local faulting and volcanism drove the diversion of the Bear River and controlled the …

Geochemistry Of Volatiles Released By Incipient Continental Rifting And Subduction Processes, Hyunwoo Lee

Earth and Planetary Sciences ETDs

Volatiles (N2, CO2, and He) are released by volcanism and hydrothermal activity during continental rifting and subduction processes. Analyses of volatile components have been conducted to obtain gas contents (CO2, SO2, H2S, N2, Ar, He, and so on), stable isotope compositions (δ13C, δ15N, and so on), and noble gas isotopes (3He/4He, 40Ar/36Ar, and so on). This dissertation includes four chapters to report new nitrogen isotope fractionation factors of bubbling gases during gas-water transfer at various water temperatures (Chapter 1), first measurements of massive amounts of CO2 released by incipient continental rifting in the Magadi and Natron Basin, East African Rift …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Mineral Evidence For Generating Compositionally Zoned Rhyolites Of The Devine Canyon Tuff, High Lava Plains, Oregon, Erik Paul Shafer

Dissertations and Theses

Large-volume silicic eruptions are often evacuated from magma reservoirs which display gradients in composition, temperature, crystallinity, and volatile content. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon represents such an eruption, with >300 km³ of compositionally zoned pyroclastic material deposited as a variably-welded ignimbrite. The ignimbrite displays homogenous bulk tuff major element compositions with a wide range of trace element compositions, allowing for the investigation of how these magmas were generated, stored, and modified in the magma reservoir by studying pumices which represent the primary magmas composing the DCT. Five pumices ranging from dacite to rhyolite bulk compositions …

Magmatic Hydrothermal Alteration And Secondary Post-Shock Features In Martian Olivine-Phyric Basalt Northwest Africa 10416; Petrology And Geochemistry Of Primitive Achondrite Northwest Africa 11042, Zoltan Vaci

Earth and Planetary Sciences ETDs

The Martian olivine-phyric basalt Northwest Africa (NWA) 10416 contains large olivine xenocrysts whose cores have been stained brown by hydrothermal alteration and whose rims are composed of pristine olivine overgrowths. Microanalysis of these olivine cores reveals various degrees of amorphization, some of which have been overprinted by terrestrial weathering, evident as part of a weathering rind along the exposed surface of the meteorite. Studies of a completely unweathered terrestrial analogue basalt from southern Colorado reveal similar features and indicate that both basalts were altered in a supersolidus magma chamber setting. The alteration features in NWA 10416 thus imply the presence …

Depositional Dynamics Of The Upper Eagle Ford (Upper Cretaceous): Karnes And Gonzales Counties, South Texas, Josie Brunick

Graduate Theses and Dissertations

The mixed siliciclastic/carbonate late Cretaceous Eagle Ford Formation is commonly divided into the lower Eagle Ford and the upper Eagle Ford. The lower Eagle Ford is arguably the most obvious organic rich interval highlighted with wireline log data; however, the upper Eagle Ford may have just as much potential for hydrocarbon production success as the lower Eagle Ford has had. A better understanding of the upper Eagle Ford will allow a more thorough and educated assessment into its full potential as an unconventional reservoir, and allow its sweet spots for oil or gas to be found and exploited.

This study …

Hydrocarbon And Co2 Emissions From Oil And Gas Production Well Pad Soils Comparative To Background Soil Emissions In Eastern Utah, Cody S. Watkins

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

What effect does the development of oil and gas have on the observed air quality (i.e., increased ozone, carbon dioxide (CO₂), volatile organic compounds (VOCs), and/or methane emissions) in northeastern Utah? What percentage of these gases is natural background emissions, and what percentage is due to the recent oil and gas development in the region? Emissions in this text refer to gases released from the earth’s surface to the atmosphere. Methane is the primary compound in natural gas. Natural gas is a naturally occurring hydrocarbon gas mixture. Emissions of methane, non-methane hydrocarbons (NMHC), and CO₂ at 27 …

An Elemental Highway: Investigation Of A High Nickel Anomaly In Olivine From The Island Of Niihau, Hawaii, Alexander James Valentine

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of volcanic geochemistry is one of the main gateways for investigating the Earth’s mantle. One important topic in the field is that of nickel (Ni) in the mineral olivine. While Ni is a compatible element in olivine, its high concentration at a given MgO content is not well understood. A variety of hypotheses have been proposed, including attributing presence of Ni to pyroxenite source melting, contribution from the core, or variation in peridotite source melting. In addition to the other hypotheses, chemical diffusion may also be a mechanism for enriching olivine Ni concentration. Magnesium-iron (Mg-Fe) isotopic measurements have …

Mineralogy And Geochemistry Of The Heddleston Porphyry Cu-Mo Deposit, Montana, Ben Schubert

Graduate Theses & Non-Theses

The Heddleston porphyry Cu-Mo deposit is located in Lewis and Clark County, Montana, near the headwaters of the Blackfoot River. It is immediately west of the historic Mike Horse mine, an important producer of Pb-Zn from polymetallic veins and lodes. The Heddleston property was explored extensively by the Anaconda Company in the 1960s and 1970s, but was never mined. Specimens of polished drill core from the deposit are archived in the Anaconda Research Collection at Montana Tech campus. The purpose of this research project was to use the archived samples to examine the geochemistry and mineralogy of the Heddleston and …

Supergene Mineralization Of The Continental Pit, Butte, Silver Bow County, Montana, Kyle Eastman

Graduate Theses & Non-Theses

The Butte porphyry Cu-Mo-Ag deposit has been considerably altered by supergene processes that enriched Cu and Ag, and mobilized other metals. Supergene enrichment provided early miners with excellent ore grades, and contributes significantly to current mining operations in Butte. The Continental Pit exhibits the classic leached and enriched vertical zonation that is common in near-surface porphyry systems around the world. Although studied by the Anaconda Copper Mining Company during the mid-20th century, significant and economically relevant questions remain regarding this deposit’s supergene heavy metal geochemistry and its relationship to the local hydrology and tectonic history.

This thesis investigates the paragenesis …

Quantity Trumps Quality: Bayesian Statistical Accumulation Modeling Guides Radiocarbon Measurements To Construct A Chronology In Real-Time, Devon Robert Firesinger

USF Tampa Graduate Theses and Dissertations

The development of an accurate and precise geochronology is imperative to understanding archives containing information about Earth’s past. Unable to date all intervals of an archive, researchers use methods of interpolation to approximate age between dates. Sections of the radiocarbon calibration curve can induce larger chronological uncertainty independent of instrumental precision, meaning even a precise date may carry inflated error in its calibration to a calendar age. Methods of interpolation range from step-wise linear regression to, most recently, Bayesian statistical models. These employ prior knowledge of accumulation rate to provide a more informed interpolation between neighboring dates. This study uses …

Characterizing The Evolution Of Slab Inputs In The Earliest Stages Of Subduction: Preliminary Evidence From The Fluid-Mobile Element (B, Cs, As, Li) Systematics Of Izu-Bonin Boninitic Glasses Recovered During Iodp Expedition 352, Keir Aavon Sanatan

USF Tampa Graduate Theses and Dissertations

Fluid-mobile elements (FMEs) such as B, Cs, As, Li and Tl can mobilize readily under low P-T conditions (0.2-0.5 GPa). This makes them effective geochemical tracers that can be used as a way of tracking fluid-rock exchanges at the shallow depths encountered in the earliest stages of subduction.

The Izu-Bonin-Mariana (IBM) subduction system is unique in that it preserves a record of the sequences produced from the onset of subduction through the development of arc magmatism. International Ocean Discovery Program (IODP) Expedition 352 recovered >800m of boninite core material from the earliest IBM magmatic events.

Select boninitic glasses from these …