Geology Commons^™

The Dynamics And Speciation Of Arsenic In Drinking Water Wells In Eastern Wisconsin, Evvan Plank

Theses and Dissertations

Arsenic typically develops in Eastern Wisconsin groundwater as a result of oxidation of sulfide bearing minerals in the limestone bedrock (Schreiber et al. 2000). Naturally occurring arsenic exists in groundwater as oxyanions which have two oxidation states, As(III) and As(V). Under ambient pH conditions As(V) is primarily present as an anion (i.e., H2AsO4-) while As(III) tends to be uncharged (i.e., H3AsO3), making it much more difficult to remove through the existing treatment techniques such as adsorption and reverse osmosis (RO). Although many studies exist establishing arsenic concentrations across Wisconsin, there is a lack of investigations into the concentrations of each …

A Granger Causality Analysis Of Groundwater Patterns Over A Half-Century, Nitin K. Singh, David M. Borrok

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Groundwater depletion in many areas of the world has been broadly attributed to irrigation. However, more formal, data-driven, causal mechanisms of long-term groundwater patterns have not been assessed. Here, we conducted the first Granger causality analysis to identify the "causes" of groundwater patterns using the rice-producing parishes of Louisiana, USA, as an example. Trend analysis showed a decline of up to 6 m in groundwater level over 51 years. We found that no single cause explained groundwater patterns for all parishes. Causal linkages were noted between groundwater and area harvested, number of irrigation wells, summer precipitation totals, and drought. Bi-directional …

Characterizing Hydrothermal System Groundwater Dynamics Using Conservative And Non-Conservative Tracers: Insights And Implications Drawn From Study At The Taupo Volcanic Zone (New Zealand) And Valles Caldera (Usa), Joshua Michael Blackstock

Graduate Theses and Dissertations

Hydrothermal systems constitute an important component of heat and mass transport within Earth’s crust having direct and indirect impacts to society. Investigating contemporary hydrochemical differences and change are critical to evaluating and deconvolving factors that influence geothermal systems through time. In this dissertation, groundwater mixing approaches were used to study hydrochemical differences in two globally significant hydrothermal areas, which included fabrication of a low-cost dissolved CO2 monitoring for dissolved inorganic carbon (DIC). In the Taupo Volcanic Zone (New Zealand), empirical spatial relations were used to derive low-temperature groundwater end-members of Cl and Cl/Br for end-member mixing analysis (EMMA). Using EMMA, …

Groundwater Investigations To Support Irrigated Agriculture At La Grange, Western Australia: 2013–18 Results, Robert J. Paul, Gregory Paul Raper, Richard J. George Dr, Nicholas J. Wright, Adam M. Lillicrap, Peter S. Gardiner

Resource management technical reports

The Broome Sandstone aquifer is the main aquifer and groundwater resource in the La Grange area, near Broome in the West Kimberley, Western Australia. Land use is dominated by cattle grazing on pastoral stations, dispersed mining and tourism. Irrigated agriculture has developed at a small scale, with about 470 hectares under cultivation in 2014. Groundwater abstraction is licensed under the La Grange groundwater allocation plan (Department of Water 2010) and managed by the Department of Water and Environmental Regulation. The La Grange groundwater allocation area is split into the La Grange North subarea and La Grange South subarea, with groundwater …

Evidence Of Variable Climate And Resources During The Late Pleistocene And Holocene At Gona, Ethiopia, Marie White

Steeplechase: An ORCA Student Journal

The African Humid Period (AHP) spanned a period of approximately 15 to 5 thousand years ago (ka) and resulted in Northern and Eastern Africa being wetter than today. This climate change event impacted flora, fauna, and humans to an unknown extent. Much of the work on the AHP across Eastern Africa utilizes lacustrine and marine proxies rather than river-based (fluvial). Gona, located in the Afar region of Ethiopia, is known for its extensive archaeological and fossil records in fluvial deposits. However, the paleoenvironment of the AHP at Gona has not been investigated. This study uses stratigraphy, geochronology, and paleopedology to …

Petrogenesis Of Basaltic Lavas In Iceland And The Springerville Volcanic Field, U.S.A.: The Influence Of Tectonic Setting, Depth Of Melting And Volatiles, Marissa Mnich

Doctoral Dissertations

Icelandic basalts were long thought to be low in water (e.g. Gunnarsson et al., 1998), but more recent studies suggest that hotspots, like the Iceland mantle plume, may be a source of hydrous basaltic melts (Nichols et al., 2002). To explore a possible link between location, volatile concentration and resulting petrogenetic implications, samples were collected from eleven volcanic centers throughout Iceland. Water concentrations were measured in melt inclusions and phenocrysts using Fourier transform infrared (FTIR) spectroscopy. Results for a subset of samples indicate variable water in melt inclusions ranging from approximately 50 ppm to over 3000 ppm. Samples from southwestern …

Reinterpreting The Tectonic Model Of The Southern Part Of The Taconic Orogeny Through A Provenance Study Of Late Ordovician Sandstones, Juan Carlos Guerrero

LSU Master's Theses

A provenance study of quartz arenites that stratigraphically are closely associated with major Ordovician K-bentonites has been conducted in order to further our understanding of the tectonic setting of eastern Laurentia during the Late Ordovician. Using laser ablation ICP-MS, detrital zircons separated from Ordovician sandstone samples in the southeastern Appalachian Mountains (Virginia to Alabama) were dated using U-Pb geochronology. Analytical results show three dominate age ranges for the zircons from these sandstones: ~440-490 Ma, ~900-1300 Ma, and ~1300-1500 Ma. In addition, some zircon ages grouped into older ranges of ~1600-1800 Ma, ~1800-1900 Ma, and ~2600-2800 Ma. Zircon ages from ~900-2800 …

Boron Variation And The Subducted Sediment Component In The Volcanics From The Bifurcated Portion Of The Lesser Antilles Island Arc (Laia), Ami Margret Ngo Ward

USF Tampa Graduate Theses and Dissertations

North of Martinique island the Lesser Antilles volcanic arc bifurcates, creating a double arc. Here volcanic activity has migrated up to 50 km westward with time, resulting in two volcanic lines that are distinct in age. The eastern line, commonly referred to as the old arc, was active from Early Eocene to Mid-Miocene (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., 1988). The western line, commonly referred to as the recent arc, has been active since the late Pliocene, ~6 Ma ago (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., …

Neogene Chemical Weathering And Provenance Records Of The Western Himalaya Preserved In The Arabian Sea, Peng Zhou

LSU Doctoral Dissertations

Some tectonic models for the Himalaya emphasize the importance of surface processes in controlling the structural evolution. To investigate this tectonic–climatic interactions, and the weathering and erosion of the western Himalaya, International Ocean Discovery Program (IODP) Expedition 355 drilled two sites (site U1456 and U1457) in Laxmi Basin, which located in the Eastern Arabian Sea. In my research project, I plan to use a series of geochemical and geochronological methods on the sediment samples from the cores of these two sites, and sediments from an industrial borehole Indus Marine A-1, which near the Indus river mouth, to reconstruct a climatic …

A Terrestrial Reconstruction Of Gona, Ethiopia Before And During The African Humid Period, Marie N. White, Gary E. Stinchcomb

Posters-at-the-Capitol

The African Humid Period (AHP) resulted in more humid conditions across Northern and Eastern Africa from 15 to 5 thousand years ago (ka). This wetter climate affected flora, fauna and the Homo sapiens living in East Africa. The lack of terrestrial paleoenvironmental reconstructions is a problem in East Africa, especially during the AHP, where most are done utilizing lacustrine or marine proxies. In the case of Gona, Ethiopia, terrestrial proxies are desired due to the rich archaeological and fossil concentrations that occur in the area. Paleosols provide more direct, localized reconstructions that provide context for these finds. This study utilizes …

On The Ablation Of Meteors And The Implications On Organic Delivery To Earth, Christopher Alan Mehta

USF Tampa Graduate Theses and Dissertations

The synthesis of prebiotic organic compounds is a key step in the origin of life. Sources of these materials are divided into endogenous and exogenous sources. Endogenous synthesis—occurring potentially on the surface of the Earth—includes such historic experiments as the Miller spark discharge and formose chemistry. However, one avenue for exogenous synthesis to occur is when meteors enters an atmosphere. Using principles of orbital mechanics, geology, physics, and chemistry, we study meteor ablation and the transport of organic matter to the surface of Earth. To do so, I create numerical models that simulates meteors traveling through the atmosphere of Earth …

Influence Of Spring Flow Reversals On Cave Dissolution In A Telogenetic Karst Aquifer, Mammoth Cave, Ky, Chelsey Kipper

Masters Theses & Specialist Projects

An often overlooked connection between karst groundwater systems and surface water is spring flow reversal, the flow of river water into karst springs caused by changes in hydraulic gradient. Karst aquifers are subject to the intrusion of river water when the hydraulic head of a base level river is higher than the hydraulic head of a base level spring. When this occurs, the flow out of the spring reverses, allowing river water to enter base level conduits. River water thus becomes a source of recharge into karst basins, transporting both valuable nutrients and harmful contaminants into karst aquifers. The rapid …

Shock Effects Recorded By The U-Pb Radiometric System In Zircons Of Apollo 17 Impact Breccias And By Raman Spectroscopy In Enstatite Meteorites, Bidong Zhang

Electronic Thesis and Dissertation Repository

Impact cratering processes and formations are ubiquitous on the rocky planets within the Solar System. The Earth-Moon system was formed by a massive planetary impact, and numerous impacts afterwards significantly reshaped the topography and lithology of the Moon surface. This dissertation focuses on studying some specific geochemical, geochronological, and geophysical signatures of impact processes preserved in lunar rocks and asteroidal meteorites.

The zircon U-Pb radiometric system is one of the most reliable geochronometers in measuring geological time. Recently, unsupported radiogenic Pb enrichment has been reported to compromise the accuracy and precision of zircon U-Pb geochronometer in terrestrial rocks. In Chapter …

Ni And Fe Isotope Fractionation During Weathering And The Formation Of Ni Laterite Ore Deposits In The Philippines, Congxi Zhu

Electronic Thesis and Dissertation Repository

Weathering processes on Ni-rich ultramafic rocks in tropical areas produce laterites that become exploitable for Ni mining. To better understand these processes, samples were collected stratigraphically with water samples from several Ni mines in the Philippines and studied for Ni and Fe isotope compositions. This study found that Ni isotope fractionation takes place during the formation of Ni-enriched minerals (goethite), when light Ni isotopes are preferentially incorporated into new minerals formed, leaving heavy Ni isotopes in groundwater. The Δ⁶⁰Ni_{Limonite-Bedrock} is up to -0.19 ± 0.32‰. Even though Fe is partitioned with redox state change during these reactions, …

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …

Oldowan Tool Behaviors Through Time On The Homa Peninsula, Kenya, Emma M. Finestone

Dissertations, Theses, and Capstone Projects

The adaptive significance of tool use to genus Homo is a central theme in human origins. However, what we know from the early Oldowan sites suggests that persistent technology may have begun as an opportunistic behavior with minimal investment, rather than a habitual and widespread adaptive revolution. This dissertation seeks to investigate investment in Oldowan tool production on the Homa Peninsula, Kenya, considering raw material selection, transport, and lithic production at two newly discovered Oldowan localities: Nyayanga (ca. 2.6 Ma) and Sare River (ca. 1.7 Ma).

The first section of this dissertation outlines a method that enables the comparison of …

Environmental Assessment Of Arsenic And Mercury Levels At The Garfield Mill Site, Calico, California, Steven Gregory Thorp

Electronic Theses, Projects, and Dissertations

Environmental impacts of mining at Calico, California, are poorly understood in comparison to the details of its history of silver production. Human health risks associated with arsenic from the lode rock, as well as mercury from the silver milling process, include central nervous system damage, organ failure, and death. To quantify the potential human health risk and manage remediation of this site, tailings from the Garfield Mill site were digitally mapped and chemically analyzed by portable x-ray fluorescence, which permitted volumetric estimates of total mill tailings and the arsenic and mercury budget, as well as identification of anomalies in the …

Fractures, Fluids, And Metamorphism: Shear Zone Initiation In The Marcy Anorthosite Massif, Adirondacks, New York, Usa, James Hodge

Electronic Theses and Dissertations

Localized shear zones are important rheological features that influence deformation behavior throughout the Earth’s middle-to-lower crust. Therefore, the processes through which shear zones initiate and localize remains an important geologic question. The study of strain localization and shear zone initiation is made difficult due to continued deformation overprinting the microstructures which lead to initiation and obfuscating the context in which localization occurred. The Marcy anorthosite in the Adirondack Highlands, New York, is a nominally granulite-facies, plagioclase-rich massif cut by centimeter-to-meter scale shear zones which provides a natural example of shear zone localization within the middle-to-lower crust. My work focuses on …

Fluid-Mobile Trace Element Variability Of Serpentinites And Entrained Crustal Rocks Across The Mariana Forearc System, Raymond M. Johnston

USF Tampa Graduate Theses and Dissertations

In the Mariana subduction system, active serpentinite mud volcanoes are associated with the subduction of the Pacific plate beneath the Philippine plate in a non-accretionary convergent plate margin. This location offers a unique opportunity to study the subduction zone interface with little crustal contamination. The systematics of fluid-mobile trace elements (FME) (As, Cs, Rb, Sb, Tl, Pb, and Sr) in erupted serpentinite muds and entrained serpentinized ultramafic and mafic clasts can place constraints on the release of slab-derived fluids from the downgoing plate, and ultimately the pressure/temperature (P/TC°) conditions at which these fluids are mobilized.

The samples analyzed in this …

Sedimentological And Geochemical Analysis Of Deep-Water Deposits In The Mojón De Hierro Formation At Arroyo Garrido, Tepuel-Genoa Basin, Patagonia, Argentina, Natalie Beatrice Mcnall

Theses and Dissertations

The Earth has had multiple Phanerozoic glacial intervals but the Late Paleozoic Ice Age (LPIA) was its longest and most extensive, lasting from the Late Devonian (~372 Ma) until the Late Permian (~254 Ma). The LPIA is the last complete climate shift from a greenhouse to icehouse and back to a greenhouse state and the only one to occur on a biologically complex Earth. Therefore, it provides perspectives on deep-time climatic transitions, the parameters controlling them, and the Earth’s physical, chemical and biological responses to such climate changes. Research on mid to high-latitude deposits in Gondwana provides evidence that the …

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …

Provenance And Maximum Depositional Age Analysis Of The Moenave Formation Using Detrital Zircon U-Pb Geochronology And Sandstone Petrography, Asher Rea Boudreaux

Graduate Theses and Dissertations

In southwestern Utah and northeastern Arizona, Moenave Formation (latest Triassic(?)-Jurassic) is bracketed by well-studied Mesozoic units extensively sampled for detrital zircon geochronology and is poorly documented in regard to provenance, representing an important gap in knowledge. The Moenave Formation provides a unique opportunity to employ detrital zircon U-Pb geochronology and sandstone petrography relevant to completing the paleogeographic, evolutionary, and climatic story of the region. This study aims to characterize the sedimentary provenance of the Moenave Formation and to identify, or at least improve constraints on, the stratigraphic position of the Triassic-Jurassic boundary (TJB) and placement of the end-Triassic extinction (ETE), …

A Metasomatized Lithospheric Mantle Control On The Metallogenic Signature Of Post-Subduction Magmatism, David A. Holwell, Marco Fiorentini, Iain Mcdonald, Yongjun Lu, Andrea Giuliani, Daniel J. Smith, Manuel Keith, Marek Locmelis

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Ore deposits are loci on Earth where energy and mass flux are greatly enhanced and focussed, acting as magnifying lenses into metal transport, fractionation and concentration mechanisms through the lithosphere. Here we show that the metallogenic architecture of the lithosphere is illuminated by the geochemical signatures of metasomatised mantle rocks and post-subduction magmatic-hydrothermal mineral systems. Our data reveal that anomalously gold and tellurium rich magmatic sulfides in mantle-derived magmas emplaced in the lower crust share a common metallogenic signature with upper crustal porphyry-epithermal ore systems. We propose that a trans-lithospheric continuum exists whereby post-subduction magmas transporting metal-rich sulfide cargoes play …

Assessing Bioavailability, Metal Fractionation, Magnetic Susceptibility, And Organic Matter Interactivity In Mine-Waste Contaminated Sediments In Turkey Creek, Joplin, Missouri, Zachary Joseph Collette

MSU Graduate Theses

Joplin, Missouri, part of the Tri-State Mining District (TSMD), has a long history of mining that resulted in mine waste piles proximal to the mines throughout the area. A local lead smelter also resulted in smelter fallout in Joplin. Mine waste pile runoff and local smelter fallout resulted in contamination of sediments, soils, and waterways. In the 1990s, remediation of residential soils and play areas began after blood lead levels in children were much higher than the national average. Soon afterwards, the chat piles were removed and used for beneficial reuse purposes. In May of 2011, an EF5 tornado devastated …

Constraining The Oxygen Values Of The Late Cretaceous Western Interior Seaway Using Marine Bivalves, Camille H. Dwyer

Earth and Planetary Sciences ETDs

The Western Interior Seaway (WIS) remains an oceanographic enigma, including its circulation, similarity to the open ocean, and the fidelity of geochemical proxies to reconstruct paleoenvironments. Across the late Campanian and early Maastrichtian I test whether: 1) the WIS had unique δ¹⁸O_VPDB compared to other marine settings, 2) increasing oceanographic restriction changed the stable isotope composition, and 3) biases, e.g., taxonomy or diagenesis, influenced stable isotope compositions. Results indicate distinct δ¹⁸O_VPDB in the WIS compared to other marine settings. δ¹⁸O_VPDB values were stable through time, suggesting insignificant oceanographic restriction and a …

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …

Identifying Characteristics Of Actionable Science For Drought Planning And Adaptation, Adam Wilke, Amanda Cravens

Publications of the US Geological Survey

Changing climate conditions can make water management planning and drought preparedness decisions more complicated than ever before. Federal and State natural resource managers can no longer rely solely on historical trends as a baseline and thus are in need of science that is relevant to their specific needs to inform important planning decisions. Questions remain, however, regarding the most effective and efficient methods for extending scientific knowledge and products into management and decision-making. This project analyzed two unique cases of water management to better understand how science can be translated into resource management actions and decision-making, focusing particularly on how …

Calcium Isotopes In The Saint Agatha Kettle Lake Deposits Of Southern Ontario, Emma-Dawn Ferguson

Electronic Thesis and Dissertation Repository

The St. Agatha kettle lake deposits, ON, Canada, contain a thick section of endogenic marl and coeval shelly fauna. Marl accumulation occurred from ~13,500 to ~8,200 cal yrs BP. This study examines controls on marl and shell δ^44/42Ca, element ratios (Mg, Fe, and Ba), δ¹⁸O, δ¹³C, and ⁸⁷Sr/⁸⁶Sr ratios of marl calcite, shell aragonite, groundwater, and bedrock as proxies for paleolacustrine conditions. Results for Interval A (532.0 to 475.0cm) indicates a cooler, wetter climate, lower primary lake productivity and higher lake levels. Interval B (475.0 to 345.0cm) marks the onset of …

Stable Isotope Geochemistry Of Shelled Marine Invertebrates: Wide-Ranging Applications, Nasser M. Al-Qattan

USF Tampa Graduate Theses and Dissertations

Mollusks grow by adding discrete growth layers throughout their lifetime (i.e., accretion). More specifically, most marine mollusks precipitate their shells in oxygen isotopic equilibrium with seawater or with a constant offset from equilibrium. The stable oxygen isotope values (δ¹⁸O) of their shells are determined by the temperature and δ¹⁸O values of the surrounding water during calcification without significant vital effects. In comparison, the stable carbon isotope values (δ¹³C) of their shells reflect those of the dissolved inorganic carbon (δ¹³C- DIC) and respired carbon dioxide. Therefore, variations in the oxygen and carbon isotope …

Geothermometry Of H6 And L6 Chondrites And The Relationship Between Impact Processing And Retrograde Metamorphism, Michael Tyler Ream

Dissertations and Theses

Ordinary chondrites are the most common type of meteorite to fall to Earth and are composed of lithified primitive nebular materials which have experienced variable extents of thermal metamorphism and shock processing. They were subjected to radiogenic heating by incorporation of unstable short lived radionuclides such as ²⁶Al in the early solar system.

The relationship between metamorphism and impact processing in ordinary chondrites is not fully understood. An unresolved issue in the study of ordinary chondrites is whether their original parent bodies were fragmented by impacts into rubble-pile bodies while they were still hot, or whether they retained their …