Geochemistry Commons^™

Isotope Geochemistry And Geochronology Of Lavas From The Line Islands Chain, Central Pacific Basin: Insight Into The Origin Of The Line Islands, Lauren Storm

Open Access Theses & Dissertations

Geochemical compositions of melts produced in the Earth's mantle provide key data for understanding Earth's internal structure. Particularly, the compositions of unusually large outpourings of basaltic lavas in large igneous provinces involve substantial source volumes, thereby contributing to our understanding of mantle structure and dynamics. Although the origin of such lavas remains enigmatic, geochemically they may originate from Earth's oldest and deepest mantle reservoir, transported by a mantle plume or by entrainment in passive upwelling beneath a fast spreading center. The Pacific Ocean basin hosts several large igneous provinces that formed near a triple junction of three oceanic plates, and …

Geochemical Systematics Among Amphibolitic Rocks In The Central Blue Ridge Province Of Southwestern North Carolina, Nathan Collins

USF Tampa Graduate Theses and Dissertations

The Central Blue Ridge sub-province of the southern Appalachian Mountains preserves an unique and complex geologic history. The Cartoogechaye terrane is the westernmost terrane of the Central Blue Ridge sub-province, and is characterized by extensive olistostromal sequences, including mafic-ultramafic massifs, isolated mafic units, and block-in-matrix structures of varying scales. This study investigates the genetic and tectonic relationships, and regional chemical and metamorphic trends of the amphibolitic rocks entrained within units of the Cartoogechaye and nearby terranes, toward constraining the origins of these regional sequences, and examining the rationale for the current Blue Ridge terrane designations.

A distinct compositional variation exists …

Geochemical And Geochronological Constraints On The Tectonothermal History Of The Central And Eastern Nepal Himalaya: Implications For Thermal-Mechanical Models, Stacey Lynn Corrie

Boise State University Theses and Dissertations

Syntheses of Himalayan tectonics imply an average shortening rate of ~2 cm/yr across the Himalaya over the last 20-25 Myr. However, despite decades of research, basic questions still remain about how strain was partitioned. Fluctuations in the timing and rate of thrusting could have significant implications for strain partitioning across the Himalaya, and for partitioning during collisional orogenesis as a whole.

Due to the observed chronology and thermobarometry of Greater Himalayan Sequence (GHS) rock units in the Annapurna region of central Nepal, we revise the original interpretation of the Bhanuwa Fault from a normal fault to a thrust, and identify …

Petrogenesis Of The Greenwater Range: Comparison To The Crater Flat Volcanic Field And Implications For Hazard Assessment, Ashley Kaye Tibbetts

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pliocene basalts of the Greenwater Range, California erupted from 24 volcanic vents now represented by volcanic plugs, craters and scoria mounds. Basaltic magmas originated in the asthenospheric mantle, but show evidence of a lithospheric component. Depths and temperatures of melting calculated using a silica activity geobarometer are 54.3–89.6 km and 1367-1435oC, placing melting in the asthenosphere. The preferred petrogenetic model involves melting of lithospheric mantle thermally and mechanically, but not chemically, converted to asthenospheric mantle. Melting depths correspond to low velocity zones in the mantle as revealed in seismic profiles. Chemical and lithologic similarities between basalt in the Greenwater Range …

Paleogene Mirelands Of The Upper Mississippi Embayment, Western Kentucky, Jennifer Marie Klein O'Keefe

University of Kentucky Doctoral Dissertations

Detailed petrography, geochemistry, and palynology together describe the depositional environments and paleoecology of an abandoned meander-fill system in western Kentucky. Oriented block petrography reveals alternating clay-rich and attrinite-rich zones of variable thickness. Woody tissues, where present, do not show dessication features and deflation layers could not be identified. Overall, petrography is indicative of a topogenous mire. Mire palyno-assemblages are less diverse than assemblages reported from clays in the region. Castanea-Cupuliferoidaepollenites assemblages dominate the entire system and other tree pollen are common; fungal spores are relatively uncommon. Weighted statistical analyses reveal ecological groupings beyond this dominance and define botanical succession within …

Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton

United States Geological Survey: Staff Publications

Loess is one of the most extensive surficial geologic deposits in mid-continental North America, particularly in the central Great Plains region of Nebraska. Last-glacial-age loess (Peoria Loess) reaches its greatest known thickness in the world in this area. New stratigraphic, geochronologic, mineralogic, and geochemical data yield information about the age and provenance of Peoria Loess, as well as evaluation of recent climate models.

Shallow Slab Fluid Release Across And Along The Mariana Arc-Basin System: Insights From Geochemistry Of Serpentinized Peridotites From The Mariana Fore Arc, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Patricia Fryer

Geology Faculty Publications

Shallow slab devolatilization is not only witnessed through fluid expulsion at accretionary prisms, but is also evidenced by active serpentinite seamounts in the shallow fore-arc region of the Mariana convergent margin. Ocean Drilling Program (ODP) Leg 195 recovered serpentinized peridotites that present a unique opportunity to study the products of shallow level exchanges between the upper mantle and slab-derived fluids. Similar to samples recovered during ODP Leg 125, the protoliths of these fore-arc serpentinized peridotites are mantle harzburgites that have suffered large volume melt extraction (up to 25%) prior to interactions with fluids released from the downgoing Pacific Plate. Samples …

Outcrop Analog For Lower Paleozoic Hydrothermal Dolomite Reservoirs, Mohawk Valley, Ny, Brian E. Slater

Geology Theses and Dissertations

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that they have undergone significant fault-related hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally an early Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A 3D ground penetrating radar survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or “sags” flanked by anticlines. The dolomite structures …

Origin Of Gabbroic Xenoliths Within The Lone Mountain Dacite Intrusion, Big Sky, Montana: A Field And Petrographic Analysis, Emily Clement

Undergraduate Review

No abstract provided.

Thermochronology And Provenance Of The Yakutat Terrane, Southern Alaska Based On Fission-Track And U/Pb Analysis Of Detrital Zircon, Stephanie Ellen Perry

Geology Theses and Dissertations

Northward transport of the Yakutat terrane along the Transition and Queen Charlotte-Fairweather transform faults led to Neogene collision of the Yakutat terrane with the southern continental Alaska margin. Northward translation resulted in a stratigraphy that records the erosion of thermotectonic terranes along its path. The strata of the Yakutat terrane includes the Lower Oligocene to Lower Eocene Kulthieth Formation, the Upper Eocene to Lower Miocene Poul Creek Formation and the Miocene-Pleistocene Yakataga Formation. Detrital zircon fission-track (DZFT) ages from stratigraphically coordinated samples collected in the Northern Robinson Mountains yield provenance information of the units that can shed light on their …

Geochemistry Of Serpentinized Peridotites From The Mariana Forearc Conical Seamount, Odp Leg 125: Implications For The Elemental Recycling At Subduction Zones, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Katherine Kelley, Patrick Mattie

Geology Faculty Publications

Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These …

Support For The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This final report details the activities completed for Task 8 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). Task 8, titled "Support for the Nye County Early Warning Drilling Program" provided for a variety of hydrochemical analyses. The requirements of the University and Community College System of Nevada (UCCSN) Quality Assurance (QA) Program were followed for all work performed on this task. The primary activity performed by the Harry Reid Center for Environmental Studies (HRC) for Task 8 was to provide hydrochemical analyses of the groundwater samples collected from …

Thermochronological Evolution Of Calcite Formation At The Proposed Yucca Mountain Repository Site, Nevada: Part 1, Secondary Mineral Paragenesis And Geochemistry, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

In the near future a decision will be made as to whether or not Yucca Mountain, 90 miles northwest of Las Vegas, Nevada is a suitable site for a permanent, underground, high level nuclear waste repository. A major factor in determining the suitability of Yucca Mountain as a repository is the potential for the site to be flooded by water during the regulatory lifetime. The current study was undertaken to examine the past fluid history at the site, to gain a better understanding of the possibility of flooding in the near geologic future. To estimate the past fluid flux into …

The Use Of A Synthetic Binary Solid Solution To Model Igneous Textural Evolution, Elizabeth Scott

Geology Theses and Dissertations

Crystallization experiments using a synthetic igneous analog have shown that grain boundary migration can take place in melt-present environments (Means and Park, 1994). In order to evaluate the importance of metamorphic processes during the textural evolution of a crystal mush, microstructural evidence is needed to link them with final igneous textures. In natural magmatic systems, plagioclase may provide a microstructural link; plagioclase solid solution enables the process of chemical zoning and preserves a record of crystal morphology (and chemistry) during growth. If metamorphic processes are common, they should affect the zoning patterns of plagioclase crystals.
A petrographic stage heater apparatus …

The Geochronology And Geochemistry Of The Bearhead Rhyolite, Jemez Volcanic Field, New Mexico, Leigh Justet

UNLV Theses, Dissertations, Professional Papers, and Capstones

Around 82% of mapped Bearhead Rhyolite (Main Cluster) and Peralta Tuff appears to have been derived from a relatively long-lived (~680 ka), large, shallow (Earth's surface) magma chamber that did not produce a caldera-forming eruption. Although volatile contents were great enough (~ wt.% H₂O), no large-scale explosive eruptions occurred because magma may have been tectonically vented. The lack of systematic chemical variation within the Main Cluster with time during this ~680 ka interval may imply that erupted magmas were physically separated from each other by fault-formed cupolas in the roof of the magma chamber. These results are significant …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …

Identification Of Past Climate Variability Of The Eastern Pacific Ocean Using Both D13c And D18o Records In Corals From Clipperton Atoll (1994-1906), Lei Ren

Geology Theses and Dissertations

The ENSO (El Nino and the Southern Oscillation) is a fundamental ocean-atmosphere phenomenon that dominates interannual global climate variability. Reconstructing past ENSO events is therefore important for documenting and understanding the past behavior of the global climate system and enabling us to predict future climate change. However, the present understanding of ENSO events has been mainly based on the instrumental record of Pacific climate which provides detailed data only for the past few decades. Recent studies have shown that the stable isotope record in coral skeletons can be used as a valuable indicator of paleoclimatic changes in tropical regions, and …

Geochemical Evolution Of A Mid-Miocene Synextensional Volcanic Complex: The Dolan Springs Volcanic Field, Northwestern Arizona, Scott Michael Mcdaniel

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Dolan Springs volcanic field (DSV), of northwestern Arizona, is dominated by andesite and basaltic-andesite flows and breccias, with minor amounts of basalt, rhyolite, and ash-flow tuff. Geochemistry is used here as a tool to evaluate the roles and contributions of the lithospheric and asthenospheric mantles to magmatism related to Miocene extension in the Colorado River extension corridor (CREC). The majority of synextensional volcanic rocks in the DSV are geochemically similar to regional trends, but rare tholeiitic basalts erupted near the end of extension. The tholeiites have trace element signatures similar to ocean island basalt (OIB), but have isotopic values …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

Trace-Element Modelling Of Melting In Spinel Peridotites, Susanne Petra Vogel

Geology Theses and Dissertations

This study addresses three independent topics related to trace element modeling of spinel peridotites that are suggested by the pioneering work of Johnson et al. (1990) on abyssal harzburgites.
First, the fractional non-modal melting equation derived by Johnson and coworkers (1990) is algebraically modified to present a "one-element/two-phase" model. This model suggests a simple test for estimating mantle heterogeneity in the source rock of spinel lherzolites. This model is applied to data from the literature for samples from Dreiser Weiher, Germany; San Luis Potosi, Mexico; and Western Victoria, Australia.
Second, trace elements in clinopyroxenes of abyssal peridotites and continental spinel …

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

Mineral Paragenesis Of The Granulite Facies In The Lake George Area, New York, Boknam Ree

Geology Theses and Dissertations

The Lake George Area belongs to the southeastern part of the Adirondack Highlands. The rocks of this area show variations in mineral assemblages which are caused by differences in bulk chemical composition. This makes it unsuccessful to use a subdivision of the granulite facies which is suggested by de Waard (1965).
The CFM diagram (Abbott, 1982) is used to show the relationship between composition and paragenesis of the Lake George Area. In this study, a different result has been found in the order of partitioning of Fe between coexisting minerals, namely, garnet>hornblende>biotite>orthopyroxene>clinopyroxene. The hornblende granitic gneiss …

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

Identification Of Endmembers For Magma Mixing In Little Sitkin Volcano, Alaska, Douglas A. Wolf

Geology Theses and Dissertations

Little Sitkin island is an Aleutian calc-alkalic volcanic center that has erupted a suite of lavas ranging from andesite through rhyodacite. Whole-rock chemistry of these lavas indicates contrasting evolutionary processes; major-oxide silica variation diagrams exhibit linear trends that are suggestive of magma-mixing while trace-element trends are largely controlled by accessory-phase fractionation.
Plagioclase, the dominant phenocryst phase in all lavas, commonly occurs in two distinct populations with markedly different compositions and textures. Both normal and reverse zonation is noted in the plagioclase and clinopyroxene of several samples. In addition, clinopyroxene is found as rims on orthopyroxene grains and as cores with …

The Continental Crust: Its Composition And Evolution, Stuart Ross Taylor, Scott M. Mclennan

Department of Geosciences Faculty Publications

Graduates in geology, geochemistry and geophysics will find this book a valuable reference text. The book begins by describing the known composition of the present upper crust, then deals with possible compositions for the total crust and the inferred composition of the lower crust. The question of the uniformity of crustal composition throughout geological time is discussed, the rate of growth of the crust and the effects of extraction of the crust on mantle compositions are considered. Finally, the question of early pre-geological crusts on Earth is debated and comparisons are given with crusts on the Moon, Mercury, Mars, Venus …

Some Chemical And Mineralogical Aspects Of Plutonic Rocks From The North Arm Mountain Massif, Bay Of Islands Ophiolite, Newfoundland, Jerry W. Sullivan

Geology Theses and Dissertations

Whole-rock major and trace element compositions of one basalt, one diabase, and 21 rocks from the magmatic-plutonic units of the North Arm Mountain massif, Bay of Islands ophiolite, Newfoundland, were determined. Mineral compositions of a subset of the plutonic rocks were also determined.
The major and trace element compositions of the basalt and diabase are similar to abyssal tholeiites, and this is consistent with the REE data of Malpas (1978) and Suen, et. al. (1979) that suggest the lavas and dikes formed from a depleted or slightly enriched abyssal tholeiitic magma. The alkaline nature of the magma proposed by several …

Saratoga: The Bubbles Of Reputation And Their Implications For An Embryonic Rift System In The Upper Hudson River Valley, James R. Young

Geology Theses and Dissertations

Carbonated, alkaline, saline waters occur over a wide area in the upper Hudson River Valley approaching 1,000 square miles. Through the sampling (spring and fall) of 39 locations, half of which were hitherto unsampled, the waters are shown to be a complexly mixed system with at least five major components.
They are:
1) a gaseous phase consisting primarily of CO2;
2) a fluid (containing the dissolved CO2) possibly analogous to a metamorphic brine whose major chemistry is HCO3>Na>Cl;
3) formational waters of variably low salinities which may be the end products of progressive dilution of Paleozoic connate brines …

"Energy Resources", Harrison Scott Brown

Special Collections: Oregon Public Speakers

With: Salter, C. L. The urban enigma.

Petrology Of The Oceanographer Fracture Zone (35ºn35ºw), Tsugio Shibata

Geology Theses and Dissertations

During a geological and geophysical survey of the Oceanographer Fracture Zone (35°N, 35°W), seventeen dredge hauls containing a variety of rocks were obtained. Petrographic study shows that these rock samples can be classified into six main rock types: fresh basalt, weathered basalt, metabasalt, gabbro, metagabbro, and serpentinite. Most of the dredge hauls were positioned on the steep, southern wall of the fracture zone, and an inference from the dredging results suggests that basalt is the most abundant rock type which outcrops at the junction between the rift valley and the fracture zone; however, as we move away from the junction, …

A Geochemical Study Of A Marsh Environment, Thomas F. Lytle, Julia Sever Lytle, Patrick L. Parker

Gulf and Caribbean Research

The goal of this study was twofold: 1) chemically to characterize a specific salt marsh, the sediments and associated biota and 2) to establish clear relationships between the chemical substances residing in the sediments and similar or identical substances occurring in the biological specimens. In this particular study it was felt that the hydrocarbons would yield the most significant organic geochemical information. These compounds are ubiquitous but minor components of all organisms. Though their function is not entirely understood, it is known that they are concentrated in the waxy coatings of plants and most likely aid in the protective mechanisms …