Geochemistry Commons^™

Regional Geochemical Mapping Of The Superior Upland Province; Ichnology Of The Cretaceous Mesilla Valley Formation, Cerro De Cristo Rey; A New Ichnospecies Of Cardioichnus From The Cretaceous (Albian) Of New Mexico; A Pedagogy For The Cerro De Cristo Rey Tracksite; Walking In The Footprints Of Dino, Eric J. Kappus

Open Access Theses & Dissertations

This is a multi-disciplinary study that covers a variety of geoscience topics on both international borders of the continental United States. This Dissertation is the product of several separate investigations. First is a report on the landscape geochemistry of the Superior Upland Province of Minnesota, Wisconsin, and Michigan, with regional maps of 37 chemical elements interpreted in terms of bedrock, glacial reworking, and anthropogenic influence. The next 2 sections are reports on the invertebrate ichnology of the Cretaceous Mesilla Valley Formation at Cerro de Cristo Rey, including the proposal of a new ichnospecies of echinoid resting trace, Cardioichnus biloba nov. …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …

Trace Element Behavior During Coal Combustion: Insights From Cadmium And Zinc Isotope Analysis, Fotios Fouskas

Open Access Theses & Dissertations

Due to its low cost and abundance, coal has been pervasively used in recent decades to meet large energy demands worldwide. Coal combustion provides the dominant electrical source in the U.S and produces over 100 million tons of coal combustion products (CCPs) per year domestically. The disposal/beneficial use of CCPs has the potential to release toxic trace elements, including cadmium (Cd) and zinc (Zn), into the environment. High temperature combustion of coal changes both physical states and chemical properties of Cd and Zn compounds in CCPs. Related processes such as evaporation and condensation, can lead to mass-dependent fractionation of Cd …

Quantifying Weathering Rates On Tropical Volcanic Basse-Terre Island, French Guadeloupe: Insights From U-Series Isotopes In Weathering Rinds, Jacqueline Engel

Open Access Theses & Dissertations

Weathering of volcanic rocks plays many important roles at Earth’s surface such as modifying landscapes, providing nutrients to soil, and regulating atmospheric CO2. U-series isotopes (e.g. 238U-234U-230Th and 232Th) have been established as a chronometer used to constrain the formation rates of weathering rinds in tropical island environments. Here, U-series isotopes and major element concentrations were analyzed in two basaltic-andesite weathering rinds collected from the Deshaies watershed located in the northern, relatively dry (mean annual precipitation (MAP) = 1800 mm) region of tropical Basse-Terre Island, Guadeloupe. The two clasts are referred to as clasts AN-14-7.5 and AN-14-7.6. Elemental mobility trends …

Geochemical Studies Of Backfill Aggregates, Lake Sediment Cores And The Hueco Bolson Aquifer, Anita Thapalia

Open Access Theses & Dissertations

This Dissertation comprises of three different researches that focuses on the application of geochemistry from aggregates, lake sediment cores and Hueco Bolson Aquifer. Each study is independent and presented in the publication format. The first chapter is already published and the second chapter is in revision phase. Overall, three studies measure the large scale (field) as well as bench scale (lab) water-rock interactions influenced by the climatic and anthropogenic factors spans from the field of environmental geology to civil engineering.

The first chapter of this Dissertation addresses the chemical evaluation of coarse aggregates from six different quarries in Texas. The …

Exploring The Hydrogeologic Controls On Brackish Water And Its Suitability For Use In Hydraulic Fracturing: The Dockum Aquifer, Midland Basin Texas, Francisco Ruben Reyes

Open Access Theses & Dissertations

Water scarcity in arid regions can limit or impede certain hydrocarbon production activities, such as hydraulic fracturing and well drilling. The Midland Basin, a major oil-producing area in semi-arid far west Texas and the eastern sub-basin of the Permian Basin, is already impacted by limited freshwater availability. A typical tight oil well in the Midland Basin requires ~3.8-11.4 x 103 m3 of water per fracture treatment (Nicot et al., 2012). Despite draught conditions and limited resources, data for 2011 indicate freshwater comprises ~70% of the water used in hydraulic fracturing in the Midland basin. Thus, the Midland Basin represents an …

In-Situ, Integrated U-Pb, Hf And O Isotopic Study Of Igneous, Metamorphic And Detrital Zircons. Implications To Crustal Evolution And Geodynamics, Munazzam Ali Mahar

Open Access Theses & Dissertations

Zircon data from South Karakoram gneiss dome provide evidence for Proterozoic inherited cores (1.8-1.9 Ga and 2.3-.2.5 Ga) surrounded by migmatitic overgrowth with ages ranging from ~6 to ~20Ma. Oxygen isotopic data of Neogene migmatite and inherited core is similar and indistinguishable ranging from 7.5 to 9.5 /. However, Neogene overgrowth is significantly less evolved than the inherited core in terms of Hf composition. This implies that the Hf composition of the migmatitic zircons is not controlled exclusively by the dissolution of the inherited cores and that contamination by external melts is likely. Isotopic data from the Baltoro plutonic unit …

Rare Earth Element Geochemistry Of The Sierra Blanca Laccoliths, Texas, Amed Gomez

Open Access Theses & Dissertations

No abstract provided.

Isotope Geochemistry And Geochronology Of Lavas From The Line Islands Chain, Central Pacific Basin: Insight Into The Origin Of The Line Islands, Lauren Storm

Open Access Theses & Dissertations

Geochemical compositions of melts produced in the Earth's mantle provide key data for understanding Earth's internal structure. Particularly, the compositions of unusually large outpourings of basaltic lavas in large igneous provinces involve substantial source volumes, thereby contributing to our understanding of mantle structure and dynamics. Although the origin of such lavas remains enigmatic, geochemically they may originate from Earth's oldest and deepest mantle reservoir, transported by a mantle plume or by entrainment in passive upwelling beneath a fast spreading center. The Pacific Ocean basin hosts several large igneous provinces that formed near a triple junction of three oceanic plates, and …

The Impact Of Sulfide Mineral Weathering On The Isotopic Signatures Of Fe And Cu In Metal-Rich Streams, Ana Lourdes Gutierrez

Open Access Theses & Dissertations

The oxidative weathering of sulfide minerals, like pyrite, at the Earth's surface controls the formation of acid mine drainage sites as well as the Fe isotope composition of these areas and the main processes taken place. In this study, water and rock samples were collected from acidic drainages (most from abandoned mining sites) from the St. Juan Mountains in Colorado. The water samples were measured in-situ for dissolved oxygen, dissolved Fe(II), pH, and conductivity. Filtered acidified, unfiltered acidified, and Fe-oxide samples were analyzed for their metal concentrations. Ion-exchange chromatography was applied to both water and digested oxide fractions in order …

Dispersion Geochemistry At Different Scales At The Nopal I Deposit, Peña Blanca Uranium District, Chihuahua, Mexico, Katrina Pekar-Carpenter

Open Access Theses & Dissertations

The Nopal I mine in the Peña Blanca Uranium District, Chihuahua, Mexico is a natural analog for the geologic storage of nuclear waste. This dissertation presents data from two sites within Nopal I: 1) the PB-1 core, which was drilled along the extent of uranium mineralization in the Nopal I mine; and 2) a high-grade stockpile boulder from the mineralized Nopal tuff.

The PB-1 core allowed an investigation into the mineralogical and geochemical changes that are important to research on a nuclear waste repository. Five zones were determined to control these changes: 1) Zone 1, the primary uranium mineralization (quartz-uraninite-pyrite-kaolinite-ilmenite); …

Mineralization In The San Juan Mountains, Colorado, William M. Sheriff

Open Access Theses & Dissertations

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Characterization Of Mantle/Crust Interactions Using Pb Isotope Analyses Of Lavas In The Southern Rio Grande Rift, New Mexico, Lynnette Crocker

Open Access Theses & Dissertations

The Pb isotope composition of volcanic rocks in the Rio Grande Rift (RGR) can be used to investigate the interaction of mantle melts with continental lithosphere, and has important implications for the composition of the lithosphere. We suggest some compositional signatures may pre-date current tectonic processes. Existing data from several volcanic fields in New Mexico show a converging pattern on a very limited Pb isotope range, corresponding to lower crustal xenolith compositions from Kilbourne Hole. The different volcanic fields show Pb isotope trends diverging from this lower crustal composition, likely depicting mixing with different upper crustal reservoirs. These very common, …

Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna

Open Access Theses & Dissertations

Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …

Copper Isotope Fractionation During Surface Adsorption And Intracellular Incorporation By Bacteria, Jesica Urbina Navarrete

Open Access Theses & Dissertations

Copper isotopes may prove to be a useful tool for investigating bacteria-metal interactions recorded in natural waters, soils, and rocks. However, experimental data that constrain Cu isotope fractionation in biologic systems are limited and unclear. In this study we utilized Cu isotopes (65Cu) as a tool to investigate Cu-bacteria interactions, including surface adsorption and intracellular incorporation. Experiments were conducted with individual Gram-positive (Bacillus subtilis) and Gram-negative (Escherichia coli) bacterial species as well as with bacterial consortia from several natural environments. Adsorption experiments were conducted with live or dead cells over the pH range 2.5 to 6. Surface adsorption of Cu …

Granulometry And Geochemistry Of Dust Emission From Owens (Dry) Lake, California, Analila Rojo

Open Access Theses & Dissertations

Owens (dry) Lake, the terminus of Owens River, is located in the Basin and Range physiographic province in east–central California. The transformation of Owens Lake into a desiccated desert playa (approximately 280 km2) via diversion of the river into the Los Angeles Aqueduct (in 1913) led to extensive wind erosion, making the playa one of the most intense sources of airborne dust in the Western Hemisphere. The processes that direct the chemical and mineralogical composition of surface sediments at Owens (dry) Lake and the physical mechanisms of wind erosion, saltation and dust emission at Owens (dry) Lake are well–understood. However, …

Suswa Volcano, Kenya Rift: Evidence Of Magma Mixing, Na-F Complexing And Eruptions Triggered By Recharge, Vanessa Veronica Espejel Garcia

Open Access Theses & Dissertations

The Cenozoic East African rift system (EARS) is a sequence of grabens, intraplate transforms, accommodation zones, and abundant magmatism. The Central Kenya Peralkaline Province (CKPP) includes a variety of volcanic rocks -trachyte, pantellerite, comendite, phonolite, trachy-basalt, basaltic trachy-andesite, and basalt- which erupted from volcanoes including: Mount Kenya; Eburru and the Greater Olkaria volcanic complexes; Longonot, Menengai, and Suswa volcanoes; and Ndabibi, Elmenteita, and Tandamara mafic volcanic fields. Only two of the volcanoes, Mount Kenya (on the flank of the central graben) and Suswa (the southernmost of the CKPP volcanoes), have phonolites as part of their assemblage.

The evolution of Suswa …

Estimating Variation In Stiffness And Volume Change Of Clays From Geochemical And Index Properties, Cynthia Roxanna Zuniga

Open Access Theses & Dissertations

Clayey soils from six different locations in Texas were analyzed and evaluated with respect to their expansion and shrinkage and change in stiffness associated with moisture content variation. These soils consist of five high plasticity-index (PI) clays (PI greater than 25) and one low-PI clay (PI = 17). The behavior of the clays changes dramatically with moisture content fluctuation, thus causing stiffness and volume changes throughout the year. Total or differential volume movements caused by swell or shrinkage strains of expansive soils and reduction in modulus can exert enough pressure to damage the pavements and cause maintenance problems.

The intent …

Zinc And Copper Isotopes As Tracers Of Anthropogenic Contamination In A Sediment Core From An Urban Lake, Anita Thapalia

Open Access Theses & Dissertations

Concentration data alone are often insufficient to resolve metal sources. This study applies stable Zn and Cu isotopes to fingerprint and track the sources of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core pre-dates settlement in the region, while the upper sections record the impact of atmospheric emissions from the nearby Tacoma smelter, as well as Cu and Zn inputs from urban sources. δ⁶⁶Zn and δ⁶⁵Cu varied by 0.42 / and 0.29 /, respectively, over the >300 year core record. Isotopic changes were correlated …

Using Chromium Stable Isotopes To Monitor Chromium Reactive Transport: Oxidation Experiments And Field Studies, Alejandro Villalobos Aragon

Open Access Theses & Dissertations

Chromium (Cr) is a common contaminant found at a number of sites globally. Cr sources can be either anthropogenic or natural. Cr occurs in nature in two valences, with Cr(VI) being carcinogenic, more toxic and mobile than Cr(III). Reduction of Cr(VI) to Cr(III) is a common remediation strategy, but monitoring Cr reduction using only concentration and speciation analyses is a difficult endeavor because concentrations can be affected by dilution and advection in addition to reduction. Cr isotopes are fractionated during reduction processes, so monitoring isotopic changes in Cr may be a faster and more effective way to monitor reduction. This …

A Multi-Tracer Study Of Saltwater Origin, Cross-Formational Flow, And The Geochemical Evolution Of Groundwater In The Southern High Plains Aquifer Along The Western Caprock Escarpment, East-Central New Mexico, Jeff Langman

Open Access Theses & Dissertations

Sustainable management of groundwater resources requires sufficient knowledge of the distribution of fresh and saline groundwater and the processes affecting saltwater intrusion that may influence the beneficial use of groundwater. A hydrogeologic investigation that coupled various chemical and isotopic tracers, including 3H/3He, 14C, δD, δ18O, 87Sr/86Sr, and δ11B, with the physical characteristics of the aquifer was conducted to determine source waters, the origin of saltwater and its influence through cross-formational flow, and water-rock interactions in the Southern High Plains aquifer along the Western Caprock Escarpment. Sub-aquifers or local flow systems are present along the Western Caprock Escarpment, and the study …