Geochemistry Commons^™

Assessment Of Coal Geology, Resources, And Reserves In The Montana Powder River Basin, Jon E. Haacke, David C. Scott, Lee M. Osmonson, James A. Luppens, Paul E. Pierce, Jay A. Gunderson

United States Geological Survey: Publications

The purpose of this report is to summarize geology, coal resources, and coal reserves in the Montana Powder River Basin (MTPRB) assessment area in southeastern Montana. This report represents the fourth assessment area within the Powder River Basin to be evaluated in the continuing U.S. Geological Survey regional coal assessment program.

There are four active coal mines in the MTPRB assessment area: the Spring Creek and Decker Mines, both near Decker; the Rosebud Mine, near Colstrip; and the Absaloka Mine, west of Colstrip. During 2011, coal production from these four mines totaled approximately 36 million short tons (MST). A fifth …

Environmental History Of A Closed-Basin Lake In The Us Great Plains: Diatom Response To Variations In Groundwater Flow Regimes Over The Last 8500 Cal. Yr Bp, William O. Hobbs, Sherilyn C. Fritz, Jeffery R. Stone, Joseph J. Donovan, Eric C. Grimm, James E. Almendinger

Department of Earth and Atmospheric Sciences: Faculty Publications

Sediment records from closed-basin lakes in the Northern Great Plains (NGP) of North America have contributed significantly to our understanding of regional paleoclimatology. A high-resolution (near decadal) fossil diatom record from Kettle Lake, ND, USA that spans the last 8500 cal. yr BP is interpreted in concert with percent abundance of aragonite in the sediment as an independent proxy of groundwater flow to the lake (and thus lake water level). Kettle Lake has been relatively fresh for the majority of the Holocene, likely because of the coarse substrata and a strong connection to the underlying aquifer. Interpretation of diatom assemblages …

Evaluation Of The Sensitivity Of Inventory And Monitoring National Parks To Acidification Effects From Atmospheric Sulfur And Nitrogen Deposition, Northern Great Plains Network (Ngpn), T. J. Sullivan, T. C. Mcdonnell, G. T. Mcpherson, S. D. Mackey, D. Moore

United States National Park Service: Publications

Northern Great Plains Network (NGPN)

National maps of atmospheric sulfur (S) and nitrogen (N) emissions and deposition are provided in Maps A through D as context for subsequent network data presentations. Maps A and B show county level emissions of total S and total N for the year 2002. Maps C and D show total S and total N deposition, again for the year 2002.

There are three parks in the Northern Great Plains Network that are larger than 100 square miles: Badlands (BADL), Missouri (MNRR), and Theodore Roosevelt (THRO). In addition, there are 10 smaller parks.

Total annual S …

Evaluation Of The Sensitivity Of Inventory And Monitoring National Parks To Nutrient Enrichment Effects From Atmospheric Nitrogen Deposition Northern Great Plains Network (Ngpn), T. J. Sullivan, T. C. Mcdonnell, G. T. Mcpherson, S. D. Mackey, D. Moore

United States National Park Service: Publications

Northern Great Plains Network (NGPN)

National maps of atmospheric N emissions and deposition are provided in Maps A and B as context for subsequent network data presentations. Map A shows county level emissions of total N for the year 2002. Map B shows total N deposition, again for the year 2002.

There are three parks in the Northern Great Plains Network that are larger than 100 square miles: Badlands (BADL), Missouri (MNRR), and Theodore Roosevelt (THRO). In addition, there are 10 other smaller parks.

Total annual N emissions, by county, are shown in Map C for lands in and surrounding …

Demographic Responses Of Least Terns And Piping Plovers To The 2011 Missouri River Flood—A Large-Scale Case Study, Michael J. Anteau, Mark H. Sherfy, Terry L. Shaffer, Rose J. Swift, Dustin L. Toy, Colin M. Dovichin

United States Geological Survey: Publications

2011 led to substantial changes in abundance and distribution of unvegetated sand habitat. This river system is a major component of the breeding range for interior Least terns (Sternula antillarum; “terns”) and piping plovers (Charadrius melodus; “plovers”), both of which are Federally listed ground-nesting birds that prefer open, unvegetated sand and gravel nesting substrates on sandbars and shorelines. The 2011 flood inundated essentially all tern and plover nesting habitat during 2011, but it had potential to generate post-flood habitat conditions that favored use by terns and plovers in subsequent years. We compared several tern and plover demographic parameters during the …

Policy And Science Of Geothermal Heat Use At Mcmurdo Station, Antarctica, Joe Alvine

Department of Environmental Studies: Undergraduate Student Theses

My thesis research project deals with the use of geothermal heat in Antarctica. Currently it is not allowed due to article 7 of the 1991 Protocol on Environmental Protection that placed a 50 moratorium on the exploitation of mineral resources. The US main base in Antarctica, McMurdo Station is currently powered by diesel generators that are inefficient, cause environmental damage, and is expensive to run. By exploring alternative energy options, McMurdo Station can reduce its dependence on non-renewable energy sources. By determining the geothermal potential of McMurdo Station, this project explores the possibilities and benefits that would occur with the …

A Sequence Stratigraphic And Isotopic Study Of Uppermost Pennsylvanian–Lower Permian Carbonate Strata, Orogrande Basin, New Mexico, Jesse Koch

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Determining how the tropics respond to glaciation is important for improving our global understanding of icehouse worlds. The impetus behind this study is to identify the far-field impacts of Gondwanan glaciation during the Early Permian. Impacts including climate and sea-level change should be evident in sensitive carbonate systems, such as the upper Paleozoic paleotropical strata in the Orogrande Basin. A sequence stratigraphic and stable isotopic approach is used to examine the effects of late Paleozoic climate change in the Orogrande Basin during the acme and subsequent demise of the late Paleozoic ice age.

Sequence stratigraphic analysis suggests the occurrence of …

Riparian And Associated Habitat Characteristics Related To Nutrient Concentrations And Biological Responses Of Small Streams In Selected Agricultural Areas, United States, 2003–04, Ronald B. Zelt, Mark D. Munn

United States Geological Survey: Publications

Physical factors, including both in-stream and riparian habitat characteristics that limit biomass or otherwise regulate aquatic biological condition, have been identified by previous studies. However, linking the ecological significance of nutrient enrichment to habitat or landscape factors that could allow for improved management of streams has proved to be a challenge in many regions, including agricultural landscapes, where many ecological stressors are strong and the variability among watersheds typically is large. Riparian and associated habitat characteristics were sampled once during 2003–04 for an intensive ecological and nutrients study of small perennial streams in five contrasting agricultural landscapes across the United …

Soil Chemistry Northwest New Mexico, Larry V. Benson

United States Geological Survey: Datasets

These data result from soil chemistry samples extracted from several regions in northwest New Mexico and were used in the following publications:

Larry V. Benson, J. Stein, H. Taylor, R. Friedman, and T. C. Windes. 2006. The agricultural productivity of Chaco Canyon and the source(s) of pre-Hispanic maize found in the Pueblo Bonito Great House. In: J. E. Staller, R. H. Tykot, and B. F. Benz, eds. Histories of Maize: Multidisciplinary Approaches to the Prehistory, Linguistics, Biogeography, Domestication, and Evolution of Maize, 289–314. Elsevier/Academic Press.

Larry V. Benson. 2017. The Chuska Slope as an agricultural alternative to Chaco …

Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton

United States Geological Survey: Staff Publications

Loess is one of the most extensive surficial geologic deposits in mid-continental North America, particularly in the central Great Plains region of Nebraska. Last-glacial-age loess (Peoria Loess) reaches its greatest known thickness in the world in this area. New stratigraphic, geochronologic, mineralogic, and geochemical data yield information about the age and provenance of Peoria Loess, as well as evaluation of recent climate models.

Comparison Of Total Mercury And Methylmercury Cycling At Five Sites Using The Small Watershed Approach, James B. Shanley, M. Alisa Mast, Donald H. Campbell, George R. Aiken, David P. Krabbenhoft, Randall J. Hunt, John F. Walker, Paul F. Schuster, Ann Chalmers, Brent T. Aulenbach, Norman E. Peters, Mark Marvin-Dipasquale, David W. Clow, Martin M. Shafer

United States Geological Survey: Staff Publications

The small watershed approach is well-suited but underutilized in mercury research. We applied the small watershed approach to investigate total mercury (THg) and methylmercury (MeHg) dynamics in streamwater at the five diverse forested headwater catchments of the US Geological Survey Water, Energy, and Biogeochemical Budgets (WEBB) program. At all sites, baseflow THg was generally less than 1 ng L^-1 and MeHg was less than 0.2 ng L^-1. THg and MeHg concentrations increased with streamflow, so export was primarily episodic. At three sites, THg and MeHg concentration and export were dominated by the particulate fraction in association with …

Concentrations Of Metals In Aquatic Invertebrates From The Ozark National Scenic Riverways, Missouri, Christopher J. Schmitt, William G. Brumbaugh, John M. Besser, Thomas W. May

United States Geological Survey: Publications

This report summarizes the findings of a study conducted as a pilot for part of a park-wide monitoring program being developed for the Ozark National Scenic Riverways (ONSR) of southeastern Missouri. The objective was to evaluate using crayfish (Orconectes spp.) and Asian clam (Corbicula fluminea) for monitoring concentrations of metals associated with lead-zinc mining. Lead-zinc mining presently (2007) occurs near the ONSR and additional mining has been proposed. Three composite samples of each type (crayfish and Asian clam), each comprising ten animals of approximately the same size, were collected during late summer and early fall of 2005 …

Guide To Participation For The Andrill Mcmurdo Ice Shelf Project, Andrill Science Management Office, Mcmurdo-Andrill Science Implementation Committee

ANDRILL Project Information

Purpose of This Document

This document is a guide to participation for science team members involved in the McMurdo Ice Shelf (MIS) Project of the ANDRILL Program. The document provides the following information: 1) An overview of the ANtarctic geologic DRILLing (ANDRILL) Program; 2) An overview of expected individual involvement in and commitment to the MIS Project; and 3) Logistical information most relevant to on-ice participants. Information provided in this document will be supplemented by the publication of the MIS Science and Logistics Implementation Plan (SLIP).The SLIP will be available to all MIS ANDRILL participants prior to commencement of drilling. …

Scientific Logistics Implementation Plan For The Andrill Mcmurdo Ice Shelf Project, Timothy R. Naish, Richard H. Levy, Ross D. Powell, Mis Science And Operations Team Members

ANDRILL Project Information

Summary

Response of Antarctic ice sheets to projected greenhouse warming of up to 5.8°C by the end of the century is unknown. Models on which predictions are based need to be constrained by geological proxy data from the ancient ice sheets during times when Earth is known to have been warmer than today. The marine-based West Antarctic Ice Sheet (WAIS) and its fringing ice shelves are hypothesized (Clark et al., 2002; Weaver et al., 2003; Stocker, 2003) and documented (Scherer et al., 1998) to have collapsed during past “super-interglacial” warm extremes when global sea-level was more than 5m higher than …

The Sparrow Surface Water-Quality Model: Theory, Application And User Documentation, G. E. Schwarz, A. B. Hoos, R. B. Alexander, R. A. Smith

United States Geological Survey: Publications

SPARROW (SPAtially Referenced Regressions On Watershed attributes) is a watershed modeling technique for relating water-quality measurements made at a network of monitoring stations to attributes of the watersheds containing the stations. The core of the model consists of a nonlinear regression equation describing the non-conservative transport of contaminants from point and diffuse sources on land to rivers and through the stream and river network. The model predicts contaminant flux, concentration, and yield in streams and has been used to evaluate alternative hypotheses about the important contaminant sources and watershed properties that control transport over large spatial scales.

This report provides …

The Earth All Around Us: Selected Building Stone In Lincoln, Nebraska. A Walking Tour, William J. Wayne

Department of Earth and Atmospheric Sciences: Faculty Publications

Stone has been a primary building material for millennia. Cities, therefore, are treasure troves of earth materials. A wide variety of stones from many places are used for walls, as foundations to support entire buildings, as trim, and more recently as cladding (facing, an overlay). The Earth science teacher can find, in the limited space of an urban environment, a superb collection of stones with which to introduce students to these materials. The surfaces of stones on the outsides of buildings illustrate the durability and the vulnerability of each kind of stone to the local climate. And the history of …

Andrill Mcmurdo Ice Shelf Project Scientific Prospectus, Timothy R. Naish, Ross D. Powell, Peter J. Barrett, Huw Horgan, Gavin B. Dunbar, Gary S. Wilson, Richard Levy, Natalie Robinson, L. Carter, Alex R. Pyne, Frank Niessen, Stephen Bannister, Natalie Balfour, Detlef Damaske, Stuart Henrys, Phil Kyke, Terry Wilson

ANDRILL Project Information

Response of Antarctic ice sheets to projected greenhouse warming of up to 5.8!C by the end of the century is not known. Models on which predictions are based need to be constrained by geological data of the ancient ice sheets during times when Earth is known to have been warmer than today. The marine-based West Antarctic Ice Sheet (WAIS) and its fringing ice shelves are hypothesized (Clark et al., 2002; Weaver et al., 2003; Stocker, 2003) and documented (Scherer et al., 1998) to have collapsed during past “super-interglacial” warm extremes when global sea-level was more than 5m higher than today. …

Andrill Southern Mcmurdo Sound Project Scientific Prospectus, David M. Harwood, Fabio Florindo, Richard H. Levy, Christopher R. Fielding, Stephen F. Pekar, M. A. Speece, Sms Science Team, Andrill Science Management Office

ANDRILL Project Information

During the austral summer of 2007 the ANtarctic DRILLing program (ANDRILL) will drill from a sea-ice platform in southern McMurdo Sound to obtain new information about the Neogene Antarctic cryosphere and evolution of Antarctic rift basins.

Contaminant Concentrations And Biomarker Responses Of Fish From The Mobile, Apalachicola, Savannah, And Pee Dee River Basins, Jo Ellen Hinck, V. S. Blazer, N. D. Denslow, T. S. Gross, T. W. May, C. E. Orazio, J. J. Coyle, P. J. Anderson, D. E. Tillitt

United States Geological Survey: Publications

No abstract provided.

Major And Trace Element Composition Of Copiapite-Group Minerals And Coexisting Water From The Richmond Mine, Iron Mountain, California, Heather E. Jamieson, Clare Robinson, Charles N. Alpers, R. Blaine Mccleskey, D. Kirk Nordstrom, Ronald C. Peterson

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Copiapite-group minerals of the general formula AR₄(SO₄)₆(OH)₂• nH₂O, where A is predominantly Mg, Fe²⁺, or 0.67Al³⁺, R is predominantly Fe³⁺, and n is typically 20, are among several secondary hydrous Fe sulfates occurring in the inactive mine workings of the massive sulfide deposit at Iron Mountain, CA, a USEPA Superfund site that produces extremely acidic drainage. Samples of copiapite-group minerals, some with coexisting water, were collected from the Richmond mine. Approximately 200 mL of brownish pore water with a pH of ‒0.9 were …

Evaluation Of Argon Ages And Integrity Of Fluid-Inclusion Compositions: Stepwise Noble Gas Heating Experiments On 1.87 Ga Alunite From Tapajo´ S Province, Brazil, G.P. Landis, L.W. Snee, C. Juliani

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Quantitative analyses are reported for active (N₂, CH₄, CO, CO₂, H₂, O₂, HF, HCl, H₂S, SO₂) and noble (He, Ar, Ne) gases released by crushing and step heating of magmatic-hydrothermal alunite from the Tapajo´ s gold province in Brazil. This is the oldest known alunite (⁴⁰Ar/³⁹Ar age of 1.87 Ga), and because it has undergone minimal postdepositional thermal or tectonic strain, it is excellent material to test the retention of gas species in fluid inclusions and within the crystal structure over geological …

Alunite And The Role Of Magmatic Fluids In The Tambo High-Sulfidation Deposit, El Indio–Pascua Belt, Chile, C.L. Deyell, R.O. Rye, G.P. Landis, T. Bissig

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Tambo high-sulfidation deposit, located within the El Indio–Pascua belt in Chile, produced almost 25 t (0.8 M oz) of gold from altered Tertiary rhyodacitic volcanic rocks. Episodic magmatic-hydrothermal activity in the district occurred over at least 4 my and is characterized by several stages of acid-sulfate alteration, including magmatic-hydrothermal, magmatic steam, steam-heated, and apparent supergene assemblages. Two stages of Au±Ag mineralization are recognized and are hosted in barite and alunite within hydrothermal breccias and veins. Isotopic compositions of fluid in alunite show a dominant magmatic signature, with only a variable ¹⁸O-enriched meteoric water component throughout the entire hydrothermal …

Secondary Sulfate Minerals Associated With Acid Drainage In The Eastern Us: Recycling Of Metals And Acidity In Surficial Environments, J. M. Hammarstrom, R. R. Seal Ii, A. L. Meier, J. M. Kornfeld

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Weathering of metal-sulfide minerals produces suites of variably soluble efflorescent sulfate salts at a number of localities in the eastern United States. The salts, which are present on mine wastes, tailings piles, and outcrops, include minerals that incorporate heavy metals in solid solution, primarily the highly soluble members of the melanterite, rozenite, epsomite, halotrichite, and copiapite groups. The minerals were identified by a combination of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron-microprobe. Base-metal salts are rare at these localities, and Cu, Zn, and Co are commonly sequestered as solid solutions within Fe- and Fe–Al sulfate minerals. Salt …

Characterization Of Gas Chemistry And Noble-Gas Isotope Ratios Of Inclusion Fluids In Magmatic-Hydrothermal And Magmatic-Steam Alunite, Robert O. Rye, G.P. Landis

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Chemical and isotope data were obtained for the active gas and noble gas of inclusion fluids in coarse-grained samples of magmatic-hydrothermal and magmatic-steam alunite from well-studied deposits (Marysvale, Utah; Tambo, Chile; Tapajo´s, Brazil; Cactus, California; Pierina, Peru), most of which are discussed in this Volume. Primary fluid inclusions in the alunite typically are less than 0.2 µm but range up to several micrometers. Analyses of the active-gas composition of these alunitehosted inclusion fluids released in vacuo by both crushing and heating indicate consistent differences in the compositions of magmatic-hydrothermal and magmatic-steam fluids. The compositions of fluids released by crushing were …

Evolution Of The Magmatic-Hydrothermal Acid-Sulfate System At Summitville, Colorado: Integration Of Geological, Stable-Isotope, And Fluid-Inclusion Evidence, Philip M. Bethke, Robert O. Rye, Roger E. Stoffregen, Peter G. Vikre

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Summitville Au–Ag–Cu deposit is a classic volcanic dome-hosted high-sulfidation deposit. It occurs in the Quartz Latite of South Mountain, a composite volcanic dome that was emplaced along the coincident margins of the Platoro and Summitville calderas at 22.5±0.5 Ma, penecontemporaneous with alteration and mineralization. A penecontemporaneous quartz monzonite porphyry intrusion underlies the district and is cut and overlain by pyrite–quartz stockwork veins with traces of chalcopyrite and molybdenite. Alteration and mineralization proceeded through three hypogene stages and a supergene stage, punctuated by at least three periods of hydrothermal brecciation. Intense acid leaching along fractures in the quartz latite produced …

Paleoproterozoic High-Sulfidation Mineralization In The Tapajo´S Gold Province, Amazonian Craton, Brazil: Geology, Mineralogy, Alunite Argon Age, And Stable-Isotope Constraints, Caetano Juliani, Robert O. Rye, Carmen M.D. Nunes, Lawrence W. Snee, Rafael H. Corrêa Silva, Lena V.S. Monteiro, Jorge S. Bettencourt, Rainer Neumann, Arnaldo Alcover Neto

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Brazilian Tapajós gold province contains the first evidence of high-sulfidation gold mineralization in the Amazonian Craton. The mineralization appears to be in large nested calderas. The Tapajós–Parima (or Ventuari–Tapajo´ s) geological province consists of a metamorphic, igneous, and sedimentary sequence formed during a 2.10 to 1.87 Ga ocean ̶ continent orogeny. The high-sulfidation mineralization with magmatic-hydrothermal alunite is related to hydrothermal breccias hosted in a rhyolitic volcanic ring complex that contains granitic stocks ranging in age from 1.89 to 1.87 Ga. Cone-shaped hydrothermal breccias, which flare upward, contain vuggy silica and have an overlying brecciated cap of massive silica; …

A Review Of The Stable-Isotope Geochemistry Of Sulfate Minerals In Selected Igneous Environments And Related Hydrothermal Systems, Robert O. Rye

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The stable-isotope geochemistry of sulfate minerals that form principally in I-type igneous rocks and in the various related hydrothermal systems that develop from their magmas and evolved fluids is reviewed with respect to the degree of approach to isotope equilibrium between minerals and their parental aqueous species. Examples illustrate classical stable-isotope systematics and principles of interpretation in terms of fundamental processes that occur in these systems to produce (1) sulfate in igneous apatite, (2) igneous anhydrite, (3) anhydrite in porphyry-type deposits, (4) magmatic-hydrothermal alunite and closely related barites in high-sulfidation mineral deposits, (5) coarse-banded alunite in magmatic-steam systems, (6) …

"Sour Gas" Hydrothermal Jarosite: Ancient To Modern Acid-Sulfate Mineralization In The Southern Rio Grande Rift, Virgil W. Lueth, Robert O. Rye, Lisa Peters

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite–barite±sulfide–jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite–bariteFsulfide and late hematite– gypsum. These deposits range in age from ~10 to …

Stable-Isotope Geochemistry Of The Pierina High-Sulfidation Au–Ag Deposit, Peru: Influence Of Hydrodynamics On So42-–H2S Sulfur Isotopic Exchange In Magmatic-Steam And Steam-Heated Environments, Richard H. Fifarek, Robert O. Rye

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Pierina high-sulfidation Au–Ag deposit formed 14.5 my ago in rhyolite ash flow tuffs that overlie porphyritic andesite and dacite lavas and are adjacent to a crosscutting and interfingering dacite flow dome complex. The distribution of alteration zones indicates that fluid flow in the lavas was largely confined to structures but was dispersed laterally in the tuffs because of a high primary and alteration-induced permeability. The lithologically controlled hydrodynamics created unusual fluid, temperature, and pH conditions that led to complete SO₄ ^2‒–H₂S isotopic equilibration during the formation of some magmatic-steam and steam-heated alunite, a phenomenon not …

Supergene Destruction Of A Hydrothermal Replacement Alunite Deposit At Big Rock Candy Mountain, Utah: Mineralogy, Spectroscopic Remote Sensing, Stable-Isotope, And Argon-Age Evidences, Charles G. Cunningham, Robert O. Rye, Barnaby W. Rockwell, Michael J. Kunk, Terry B. Councell

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Big Rock Candy Mountain is a prominent center of variegated altered volcanic rocks in west-central Utah. It consists of the eroded remnants of a hypogene alunite deposit that, at ~21 Ma, replaced intermediate-composition lava flows. The alunite formed in steam-heated conditions above the upwelling limb of a convection cell that was one of at least six spaced at 3- to 4- km intervals around the margin of a monzonite stock. Big Rock Candy Mountain is horizontally zoned outward from an alunite core to respective kaolinite, dickite, and propylite envelopes. The altered rocks are also vertically zoned from a lower pyrite– …