Geochemistry Commons^™

Stable Isotope And Geochemical Characterization Of Nutrient Sources In The Big Creek Watershed Of Northwest Arkansas, Kelly Robin Sokolosky

Graduate Theses and Dissertations

The establishment of a concentrated animal-feeding operation (CAFO) in Newton County, Arkansas near Big Creek, a tributary of the Buffalo National River, has raised concern over potential degradation of water-quality in the watershed. In this study, isotopic tools were combined with standard geochemical approaches to characterize nutrient sources and dynamics in Big Creek. An isotopic and geochemical reference library of potential nutrient sources in the Big Creek watershed was established by direct sampling of representative potential sources, including septic-system effluent, poultry litter, swine and cattle manure, and CAFO waste lagoons. Representative nutrient sources and Big Creek stream samples were analyzed …

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …

Use Of Pre-Industrial Baselines To Assess Sources And Pathways Of Metals In Surface Sediment Of Floodplain Lakes In The Peace-Athabasca Delta (Alberta, Canada), Tanner Owca

Theses and Dissertations (Comprehensive)

The effects of natural resources exploitation in northern Canada on downstream aquatic ecosystems is a concern. Assessing these effects requires comprehensive monitoring practices to better inform stakeholders and environmental stewardship decisions. Here, a monitoring approach is developed and applied to assess metals concentrations in lake surface sediments of the Peace-Athabasca Delta (PAD), northern Alberta, Canada. Since the ecological integrity of the PAD is strongly tied to river floodwaters that are critical for replenishing the delta, and the PAD is located downstream of the Alberta oil sands, concerns have been raised over the potential transport of metal contaminants to the PAD …

Groundwater Hydrogeolgy And Hydrochemistry Of Karst Springs In The Eastern Peninsula Of Fort Hood Military Installation, William Scribner Welles

Electronic Theses and Dissertations

The eastern peninsula of Fort Hood Military Installation is underlain by a complex karst spring network. These springs are a primary water source in a protected habitat for endangered songbirds, which has only recently begun to be fully investigated. These Fredericksburg Group springs express both epigenetic and hypogenetic karst signatures. The study area is part of a paleo reef trend, a hydraulically disconnected segment of the northern section of the Edwards Aquifer. This study utilized standard ion index values, repeated measures, and principal component analyses on the chemical profiles of six perennial springs to classify spring water sources and their …

Relating Cyanobacteria And Physicochemical Water-Quality Properties In Willow Creek Lake, Nebraska, 2012–14, David L. Rus, Brent M. Hall, Steven A. Thomas

United States Geological Survey: Water Reports and Publications

Document abstract

Cyanobacteria (also referred to as blue-green algae) are naturally present members of phytoplankton assemblages that may detract from beneficial uses of water because some strains produce cyanotoxins that pose health hazards to people and animals. Cyanobacteria populations observed in Willow Creek Lake during 2012 through 2014 were compared to external nutrient loading from the Willow Creek drainage basin and several other physicochemical properties within the lake, including internal nutrient loading. This report is part of a cooperative study between the United States Geological Survey, the Lower Elkhorn Natural Resources District, the Nebraska Department of Environmental Quality, the Nebraska …

Groundwater Contamination At Coal Ash Deposit Sites In Kentucky, Brandon Rose

Scholars Week

No abstract provided.

Regulation Of Dissolved Arsenic Using Zero-Valent Iron With Gypsum And Sulfate Reducing Bacteria: Laboratory Microcosm And Column Studies, Ying Liu

Dissertations, Theses, and Capstone Projects

Bench scale microcosm incubation was first conducted in two stages to examine the removal of arsenic (As) by zero-valent iron (ZVI) in the presence of sulfate reducing bacteria, gypsum as well as organic substrates under anaerobic condition. About 98% of dissolved As was removed from solution within 20 days with concurrent decrease of dissolved sulfate and growth of bacterial population. Mineralogy analysis using SEM-EDS found the formation of iron sulfide and Fourier-transformed infrared (FTIR) spectroscopy analysis indicates that some As is associated with pyrite. The main iron corrosion product was found as ferrihydrite with traces of lepidocrocite. Sequential leaching shows …

Spatial And Temporal Trends Of Mining-Related Lead-Zinc Sediment Contamination, Galena River Watershed, Sw Wisconsin-Nw Illinois, Dylan Alexander King

Graduate Theses/Dissertations

Alluvial sediments within the Galena River Watershed were severely contaminated with heavy metals by historical zinc (Zn) and lead (Pb) mining operations during the early 1800s until 1979. Since the mines closed, there have been efforts to remediate on-site mine waste. However, the effectiveness of these efforts to reduce metal concentrations in stream sediments is unknown. This study compares present-day (2017) contamination trends in the Galena River Watershed to trends reported 25 years ago. A total of 415 sediment/soil samples were collected and analyzed using X-ray florescence spectrometry to determine sediment metal concentrations. The highest concentrations of zinc measured were …

Predicting Spatial Patterns In Precipitation Isotope (Δ2h And Δ18o) Seasonality Using Sinusoidal Isoscapes, Scott T. Allen, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding how precipitation isotopes vary spatially and temporally is important for tracer applications. We tested how well month‐to‐month variations in precipitation δ18O and δ2H were captured by sinusoidal cycles, and how well spatial variations in these seasonal cycles could be predicted, across Switzerland. Sine functions representing seasonal cycles in precipitation isotopes explained between 47% and 94% of the variance in monthly δ18O and δ2H values at each monitoring site. A significant sinusoidal cycle was also observed in line‐conditioned excess. We interpolated the amplitudes, phases, and offsets of these sine functions across the landscape, using multiple linear …

Abandoned Mine Land Impacts On Tributaries In The Upper Yakima River Watershed, Eastern Cascades, Washington, Scott Kugel

All Master's Theses

Effluent from abandoned mine lands (AMLs) in several drainages in Washington’s Eastern Cascades flows into the Yakima River. Similar sites in Idaho and Colorado are known producers of heavy metals and acid mine drainage. I determined the effects of nine AMLs on water quality in four tributaries to the Yakima River. Archival work was conducted to determine sites that were mined and contained a mill. Each site was characterized by physical features. Water and sediment samples were collected above, at, and below each AML. Samples were analyzed for pH and heavy metal content, and evaluated to determine if the AMLs …

The Role Of High-Elevation Headwater Runoff In Streamflow Generation And Water Supply In The Northern Andes, Colombia, Laura Lotero Lozano

USF Tampa Graduate Theses and Dissertations

Water security requires that sufficient quantities of water be available at critical times. This is particularly challenging for high-intensity urban and agricultural settings. In underdeveloped nations, streamflow is commonly the preferred water source, as it is readily available and delivered cost-free to users. Yet, the sources of these critical streamflows are often unknown. This issue is salient in the Northern Andes, where basic knowledge of controlling factors for the quantity, quality, and timing of runoff is lacking. High-elevation headwaters are the primary catchment areas in the Northern Andes, but the extent of water providing to municipalities in the Northern Andes …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …

Dam Removal In The Usa: Effects On River Water Quality, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Dam removal decisions should ideally be made after a thorough cost-benefit analysis. If dam obsolescence, structural safety, harm to fisheries, maintenance costs, and reservoir eutrophication are among the primary concerns, decommissioning would likely be favored. On the other hand, dams provide considerable benefits including water storage for agricultural and urban consumption, renewable electricity generation, support of navigational canal systems, flood control, and lakes for recreation. Because of these competing factors and interests, dam removal decision-making in the United States is often a slow process fraught with controversy, as in the case of the Klamath River.

Dams provided mechanical water power …

Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis

All Master's Theses

The complex bedrock lithologies in the Upper Kittitas County provide an ideal setting for developing isotopic methodology to identify groundwater sources and track flow paths through water-rock interaction. A wide range of 87Sr/86Sr (0.7040 to 0.7068) in surface waters, springs, and groundwater from wells was found, allowing for identification of the individual signatures of lithologic units. Rock leachates from different lithology were compared to water samples to determine a general 87Sr/86Sr signature of the water-rock interaction for that lithology. The signatures identified were systematically lower than their associated waters, but similar enough to identify the expected 87Sr/86Sr of water-rock interaction …

Chlorine Demand Shows Thresholds And Hierarchy With Source Water Quality At Beaver Lake, Arkansas, Jaime M. Gile

Graduate Theses and Dissertations

This study investigated the effects of source water quality in Beaver Lake on the amount of chlorine (Cl) needed to develop decision support system to help guide chlorination practices in pre-treatment of source water. Chlorine demand assays were performed on water samples from Beaver Lake collected from the intake structure at Beaver Water District from March 2014 through August 2015, and using data from these assays, the two points of interest in this study were the Cl dose at which Cl residuals began to accumulate and the mean Cl demand occurring after that dose. Three methods of analysis were used …

Proportions Of Convective And Stratiform Precipitation Revealed In Water Isotope Ratios, Pradeep K. Aggarwal, Ulrike Romatschke, Luis Araguas-Araguas, Dagnachew Belachew, Fred J. Longstaffe, Peter Berg, Courtney Schumacher, Aaron Funk

Earth Sciences Publications

Tropical and midlatitude precipitation is fundamentally of two types, spatially-limited and high-intensity convective or widespread and lower-intensity stratiform, owing to differences in vertical air motions and microphysical processes governing rain formation. These processes are difficult to observe or model and precipitation partitioning into rain types is critical for understanding how the water cycle responds to climate changes. Here, we combine two independent data sets – convective and stratiform precipitation fractions, derived from the Tropical Rainfall Measuring Mission satellite or synoptic cloud observations, and stable isotope and tritium compositions of surface precipitation, derived from a global network – to show that …

Geochemical Processes And Controls Affecting Water Quality Of The Karst Area Of Big Creek Near Mt. Judea, Arkansas, V. Brahana, J. Nix, C. Kuyper, T. Turk, F. Usrey, S. Hodges, C. Bitting, K. Ficco, E. Pollock, R. Quick, B. Thompson, J. Murdoch

Journal of the Arkansas Academy of Science

Karst regions typically are considered to be vulnerable with respect to various land-use activities, owing to the intimate association of surface and groundwater and lack of contaminant attenuation provided by most karst aquifers. Inasmuch as the soluble rocks of the karst landscape can be dissolved to create large, rapid-flow zones that compete successfully with surface streams, groundwater and subsurface flow represent a much larger component of the hydrologic budget in karst regions than in areas where non-soluble rocks predominate. Karst areas typically are distinguished by being unique, but some general approaches can be applied to characterize the hydrology of the …

Using Nitrate, Chloride, Sodium, And Sulfate To Calculate Groundwater Age, Kimm Crawford, Terry Lee

Sinkhole Conference 2015

Regression analysis is used to identify monotonic trends to assign water age using ion data from two large well water databases from southeast Minnesota (SE MN). Nitrate (NO3-N), chloride (Cl), sodium (Na), and sulfate (SO4) ions in the commonly used aquifers in SE MN can be used as groundwater tracers since they are either entirely or partly anthropogenic in their sources, their loading occurs on a regional scale, and they are almost entirely conserved. Ion concentrations over time are used to establish six trend patterns. Two patterns are unchanging (background and stable above background), and four are changing (linear up, …

Stable Isotopes As A Tool To Characterize Carbon Cycling And Develop Hydrologic Budgets In Mantled Karst Settings, Katherine Knierim

Graduate Theses and Dissertations

Isotopes of water (δ2H/δ18O), carbon dioxide (δ13C-CO2), and dissolved inorganic carbon (δ13C-DIC) were used to explore water quality, trace carbon cycling, and quantify recharge sources through mantled karst and into Blowing Spring Cave (BSC). Of the possible sources of contamination in the BSC recharge area, septic-tank effluent was hypothesized to degrade water quality at the spring outlet of BSC because of the dominance of septic tanks for waste treatment, unsuitable topography and soil for septic-tank absorption fields, increased nitrate and chloride concentrations concomitant with increased urbanization, and increased Escherichia coli with discharge. Carbon cycling between the soil and BSC was …

Using Kriging, Cokriging, And Gis To Visualize Fe And Mn In Groundwater, Crystal Johnson

Electronic Theses and Dissertations

For aesthetic, economic, and health-related reasons, allowable concentrations of iron (Fe) and manganese (Mn) found present in drinking water are 0.3 mg/L and 0.05 mg/L, respectively. Water samples taken from private drinking wells in the rural communities within Buncombe County, North Carolina contain amounts of these metals in concentrations higher than the suggested limits. This study focused on bedrock geology, elevation, saprolite thickness, and well depth to determine factors affecting Fe and Mn. Using ArcGIS 10.2, spatial trends in Fe and Mn concentrations ranges were visualized, and estimates of the metal concentrations were interpolated to unmonitored areas. Results from this …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …

Pore Water Extraction For Unsaturated Zone Isotope Research: An Investigation Using An Immiscible Displacement Fluid And A Centrifuge, Caitlin Burnett Weaver

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Accurate and reliable pore water extraction techniques are important to an array of scientific fields including, but not limited to, hydrogeology, soil science, and paleoenvironmental research. The aim of the current project is to test the applicability of an immiscible displacement extraction technique for stable isotopes of water under a range of textural, hydrologic, and chemical conditions. In this study, laboratory experiments were conducted to establish the extent to which the proposed method 1) achieves sufficient yield for laboratory isotopic analyses, 2) results in isotopic exchange between water and the displacement fluid, 3) conserves initial isotopic compositions of spike test …

Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott

Publications and Research

Test boring associated with the recently accomplished City Water Tunnel # 3 in Manhattan, New York City revealed moderately to highly weathered marble with insoluble silicate residues composed mostly of phlogopite, chlorite, and tremolite. Apparent control on the weatherability of the marble was in response to original mineral constituents dominating this lithology. Encountered marble samples ranged between pure calcitic to mixed dolomitic/siliceous types. Fresh marble samples collected from adjacent boring locations revealed characteristic geochemical data: Lime (25-45%), Silica (4-7%), Alumina (1-3%), MgO (5-20%), and LOI (35-42%); compressive strength of unweathered marble varied between 2000-3000 Kg/cm². Relict foliations with …

Assessing Ageing At Beaver Reservoir, Northwest Arkansas: Limnological, Geochemical & Paleolimnological Approach, Byron Anthony Winston

Graduate Theses and Dissertations

Access to potable water has been arguably one of the most important requisites for the advancement of human civilization on earth. As a result, man in his infinite wisdom devised the dam and formed reservoirs, (man- made lakes), to exploit water resources at will. In all natural lakes and reservoirs changes occur in the water quality parameters as it relates to chemical nutrients, temperature and turbidity over time. These changes are collectively referred to as "Reservoir Ageing", of which sedimentation and eutrophication are primary. Reservoir Ageing has consequences which adversely affect and defeat many of the intended uses of the …

Identification Of Geochemical Facies Through Major Ion Data And Additional Parameters From Shallow Groundwater Utilizing A Comparison Of Geomathematics And Traditional Methods In Las Vegas Valley, Nevada, Eric Dano

UNLV Theses, Dissertations, Professional Papers, and Capstones

There has been little exploration to identify geochemical facies in shallow groundwater in the Las Vegas Valley in Clark County, Nevada. Identification of hydrochemical facies in Las Vegas Valley is important for assessing the extent and nature of a potential groundwater resource. The identification of facies could be complicated by the possibility that secondary recharge constitutes a hydrochemical facies of its own. To identify geochemical facies, groundwater samples for major ions, stable isotopes and some municipal tracers were collected from 35 wells in an established network of monitor wells. Wells were purged with a bailer or 12V pump and EC, …

Hydrogeochemistry Of Caves Drip Water At Selected Caves In Peninsular Malaysia., Nor Bakhiah Baharim

Student Works (2010-2019)

This preliminary study represents the study on hydrogeochemical of caves drip water throughout Peninsular Malaysia. All samples were analysed for pH, Total Dissolved Solid (TDS), Dissolved Oxygen (DO), Conductivity, cation and anion. Despite local hydrological and geological differences among sampling sites, the monitoring revealed significant synchronous intersite variations that related to rainfall variation and control the volume of water input. The constant hydraulic pressure is expected in karst system as a result of moist condition of tropical region and rainfall throughout the year. Drip sites were classified into to two classifications which are seepages flow and seasonal flow. A simplified …

Comparison Of Total Mercury And Methylmercury Cycling At Five Sites Using The Small Watershed Approach, James B. Shanley, M. Alisa Mast, Donald H. Campbell, George R. Aiken, David P. Krabbenhoft, Randall J. Hunt, John F. Walker, Paul F. Schuster, Ann Chalmers, Brent T. Aulenbach, Norman E. Peters, Mark Marvin-Dipasquale, David W. Clow, Martin M. Shafer

United States Geological Survey: Staff Publications

The small watershed approach is well-suited but underutilized in mercury research. We applied the small watershed approach to investigate total mercury (THg) and methylmercury (MeHg) dynamics in streamwater at the five diverse forested headwater catchments of the US Geological Survey Water, Energy, and Biogeochemical Budgets (WEBB) program. At all sites, baseflow THg was generally less than 1 ng L^-1 and MeHg was less than 0.2 ng L^-1. THg and MeHg concentrations increased with streamflow, so export was primarily episodic. At three sites, THg and MeHg concentration and export were dominated by the particulate fraction in association with …

The Impact Of Acid Mine Drainage On West Little Sugar Creek, Vigo Co., In, Jodie L. Gibson

All-Inclusive List of Electronic Theses and Dissertations

This study evaluates the degree and extent of contamination in West Little Sugar Creek by analyzing water chemistry in the stream during low and moderate flow conditions. West Little Sugar Creek is located in Vigo County, Indiana and has been severely impacted by AMD discharging from the abandoned Green Valley Mine site. Stream water is commonly acidic (as low as pH 2.4) with elevated concentrations of Fe and Al and elevated trace elements including Ni, Zn, Cu, Cd, Cr, Co, and others, many of which exceed local and/or national surface water quality standards. Amorphous Fe and Al precipitates also form …

Tunnel Geology As Seen By Geologists: Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Alan R. Slaughter, Belal A. Sayeed, Dorean J. Flores, Mario Jo-Ramirez

Publications and Research

Current exploratory boring operations in and around Manhattan, New York City are providing geologists and geotechnical engineers with a plethora of new and interesting geological information, which has not been previously reported. The rocks encountered, mostly medium to high-grade metamorphic rocks, with both mafic and felsic intrusives, are highly variable in competency and mechanical durability. One of the most frequently encountered rock types is a garnetiferous-muscovite-biotite schist which grades into schistose gneiss and displays a wide variety of structural, compositional, and textural attributes. Metamorphic minerals showing the variable degree of metamorphism include graphite, talc, garnet, kyanite, tourmaline, emory, and occasionally …