Geochemistry Commons^™

Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott

Publications and Research

Test boring associated with the recently accomplished City Water Tunnel # 3 in Manhattan, New York City revealed moderately to highly weathered marble with insoluble silicate residues composed mostly of phlogopite, chlorite, and tremolite. Apparent control on the weatherability of the marble was in response to original mineral constituents dominating this lithology. Encountered marble samples ranged between pure calcitic to mixed dolomitic/siliceous types. Fresh marble samples collected from adjacent boring locations revealed characteristic geochemical data: Lime (25-45%), Silica (4-7%), Alumina (1-3%), MgO (5-20%), and LOI (35-42%); compressive strength of unweathered marble varied between 2000-3000 Kg/cm². Relict foliations with …

Geochemistry, Geothermobarometry And Geochronology Of High-Pressure Granulites And Implications For The Exhumation History Of Ultrahigh-Pressure Terranes: Dulan, Western China, Benjamin David Joseph Christensen

All Master's Theses

The Dulan ultrahigh-pressure (UHP) rocks of the North Qaidam terrane, Western China, represent continental crust that has been subducted ~100 km during continental collision. Adjacent granulites representing burial to ~50 km could either be overprinted eclogites or a separate high-pressure-high-temperature (HP-HT) granulite unit. Overprinted eclogites and HP-HT granulites imply different P-T-t paths for UHP rocks. Metamorphic conditions for the granulites are 750–880 °C and 14–17 kbar. Zircon U-Pb geochronology, REE patterns and Ti-in-zircon thermometry indicate an increase in temperature from ~800 °C (449 Ma) to ~900 °C (418 Ma). This temperature increase could explain the presence of granulite leucosomes and …

Petrologic, Geochemical, And Geochronologic Constraints On The Tectonic Evolution Of The Southern Appalachian Orogen, Blue Ridge Province Of Western North Carolina, Eric Douglas Anderson

University of Kentucky Doctoral Dissertations

The Blue Ridge Province of western North Carolina contains a wide variety of metamorphosed igneous and sedimentary rocks that record the tectonic effects of Precambrian and Paleozoic orogenic cycles. Tectonic interpretations of the events that led to the present configuration are varied and often conflicting. This investigation examines metamorphosed mafic rocks that are widely interpreted to have formed during the closure of ocean basins. Metabasites, and specifically eclogites, have a tendency to mark tectonic sutures and frequently preserve pressure (P), temperature (T), and age data (t) that can be gleaned from mineral equilibria and U-Pb isotopic compositions. As such, the …

Upper Cretaceous Peay Bentonites (North-Central Wyoming): Provenance And Tectonics Interpretation From Ash Composition, Nazrul I. Khandaker, Carl F. Vondra, Karl E. Seifert, Malek Shami, Rochelle Cardinale, Thakur Chaturgan

Publications and Research

The Peay bentonites belong to the basal Frontier Formation (Bighorn Basin, north-central Wyoming), primarily outcrop in the Bighorn Basin, rest on an extensively bioturbated sandstone unit, the Peay Sandstone, and are generally the thinner bentonitic unit. Beds of very light gray to greenish gray bentonite are also abundant in the lower Frontier units between Kaycee and Mayoworth (Powder River Basin) and are very rarely as much as 3 m thick. Bentonite occurs within the interstratified shale, sandstone, and siltstone sequences of the lower Frontier unit throughout much of the southwestern Powder River Basin. The purpose of this study is to …

Detrital Zircon Geochronology For Neoproterozoic To Cambrian Sediment Sources Of The Deep Creek Range And The Pilot Range In The Southwestern United States, Kaysea Perry

Earth and Soil Sciences

Detrital zircon studies of miogeoclinal sediments can help provide a deeper look into the mechanisms leading to continental breakup by studying the evolution of the continental margin of North America. Few detrital zircon studies have been conducted to support previous research and theories about the sedimentation of the Miogeocline from the Neoproterozoic to the Cambrian. Studies targeted at the Basin and Range province of the western United States show a trend of increasing local sediment sources. We analyzed detrital zircons from the Pilot and Deep Creek Ranges in Nevada and Utah via LA-MC-ICP-MS at the University of Arizona LaserChron Center …

Paragneiss Zircon Geochronology And Trace Element Geochemistry, North Qaidam Hp/Uhp Terrane, Western China, Chris G. Mattinson, Joseph L. Wooden, Jian-Xin Zhang, D. K. Bird

All Faculty Scholarship for the College of the Sciences

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ∼3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ± 5 Ma …

Exhumation Of The Inyo Mountains, California: Implications For The Timing Of Extension Along The Western Boundary Of The Basin And Range Province And Distribution Of Dextral Fault Slip Rates Across The Eastern California Shear Zone, Jeffrey Lee, Daniel F. Stockli, Lewis A. Owen, Robert C. Finkel, Roman Kislitsyn

All Faculty Scholarship for the College of the Sciences

New geologic mapping, tectonic geomorphologic, ¹⁰Be terrestrial cosmogenic nuclide, and (U-Th)/He zircon and apatite thermochronometric data provide the first numerical constraints on late Cretaceous to late Quaternary exhumation of the Inyo Mountains and vertical slip and horizontal extension rates across the eastern Inyo fault zone, California. The east-dipping eastern Inyo fault zone bounds the eastern flank of the Inyo Mountains, a prominent geomorphic feature within the western Basin and Range Province and eastern California shear zone. (U-Th)/He zircon and apatite thermochronometry yield age patterns across the range that are interpreted as indicating: (1) two episodes of moderate to rapid …

In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttrium is used in geochemical investigations of arc volcanics and metamorphic geothermometers. The ability to use Y as a geochemical tool is predicated on an understanding of the mobility of Y during fluid-saturated conditions attending metamorphic and igneous processes. The goal of this work was to use the hydrothermal diamond anvil cell (HDAC) and synchrotron radiation X-ray fluorescence to quantify, in situ, the concentration of Y in aqueous fluids at 2-5 GPa and 650 - 800 °C; conditions likely at the oceanic lithosphere - mantle wedge interface in subduction zones. Previous studies have used modified diamond anvils which limits their …

Outcrop Analog For Lower Paleozoic Hydrothermal Dolomite Reservoirs, Mohawk Valley, Ny, Brian E. Slater

Geology Theses and Dissertations

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that they have undergone significant fault-related hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally an early Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A 3D ground penetrating radar survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or “sags” flanked by anticlines. The dolomite structures …

Late Cretaceous To Paleocene Metamorphism And Magmatism In The Funeral Mountains Metamorphic Core Complex, Death Valley, California, Chris G. Mattinson, Joseph P. Colgan, James R. Metcalf, Elizabeth L. Miller, Joseph L. Wooden

All Faculty Scholarship for the College of the Sciences

Amphibolite-facies Proterozoic metasedimentary rocks below the low-angle Cenozoic Boundary Canyon Detachment record deep crustal processes related to Mesozoic crustal thickening and subsequent extension. A 91.5 ± 1.4 Ma Th-Pb SHRIMP-RG (sensitive high-resolution ion microprobe–reverse geometry) monazite age from garnet-kyanite-staurolite schist constrains the age of prograde metamorphism in the lower plate. Between the Boundary Canyon Detachment and the structurally deeper, subparallel Monarch Spring fault, prograde metamorphic fabrics are overprinted by a pervasive greenschist-facies retrogression, high-strain subhorizontal mylonitic foliation, and a prominent WNW-ESE stretching lineation parallel to corrugations on the Boundary Canyon Detachment. Granitic pegmatite dikes are deformed, rotated into parallelism, and …

Tunnel Geology As Seen By Geologists: Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Alan R. Slaughter, Belal A. Sayeed, Dorean J. Flores, Mario Jo-Ramirez

Publications and Research

Current exploratory boring operations in and around Manhattan, New York City are providing geologists and geotechnical engineers with a plethora of new and interesting geological information, which has not been previously reported. The rocks encountered, mostly medium to high-grade metamorphic rocks, with both mafic and felsic intrusives, are highly variable in competency and mechanical durability. One of the most frequently encountered rock types is a garnetiferous-muscovite-biotite schist which grades into schistose gneiss and displays a wide variety of structural, compositional, and textural attributes. Metamorphic minerals showing the variable degree of metamorphism include graphite, talc, garnet, kyanite, tourmaline, emory, and occasionally …

Evolution Of The Kangmar Dome, Southern Tibet: Structural, Petrologic, And Thermochronologic Constraints, Jeffrey Lee, Bradley R. Hacker, William S. Dinklage, Yu Wang, Phillip Gans, Andrew Calvert, Jinglin Wan, Wenji Chen, Ann E. Blythe, William Mcclelland

All Faculty Scholarship for the College of the Sciences

Structural, thermobarometric, and thermochronologic investigations of the Kangmar Dome, southern Tibet, suggest that both extensional and contractional deformational histories are preserved within the dome. The dome is cored by an orthogneiss which is mantled by staurolite + kyanite zone metasedimentary rocks; metamorphic grade dies out up section and is defined by a series of concentric kyanite-in, staurolite-in, garnet-in, and chloritoid-in isograds. Three major deformational events, two older penetrative events and a younger doming event, are preserved. The oldest event, D1, resulted in approximately E-W trending tight to isoclinal folds of bedding with an associated moderately to steeply north dipping axial …

Multibeam Sonar Backscatter Lineaments And Anthropogenic Organic Components In Lacustrine Silty Clay, Evidence Of Shipping In Western Lake Ontario, C F Michael Lewis, L A. Mayer, Prasanta K. Mukhopadhyay, Michael A. Kruge, John P. Coakley, M D. Smith

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A multibeam sonar survey (95 kHz) covering more than 500 km² of western Lake Ontario revealed anomalous lineaments of relatively high backscatter. The lineaments did not align with or parallel the most prominent structural zones beneath the lake as expected. Instead, the principal lineaments lay on lines between ports on opposite sides of the lake, especially between Toronto and Welland Canal, and Toronto and Niagara River mouth. As the lineaments underlie current and historical shipping routes used during the steamship era, they are interpreted as an acoustic response to shipping debris cumulated in the near-surface bottom sediment. An exploratory …

Geochemistry And Petrogenesis Of The Bonanza King Mafic Intrusive Complex, Trinity Terrane Ophiolite, California, Keith R. Willse

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Bonanza King mafic intrusive complex (MIC) (>25 km^2₎ of the Trinity terrane ophiolite, northern California, consists of cogenetic plutonic and dike lithologies. Steep intrusive contacts exist between cumulate pyroxenite, isotropic gabbro, and peridotite country rock. Near vertical east-west trending, bimodal dikes intruded gabbro and are centered within the complex. Geochemical modeling indicates taht accumulation/fractionation of a gabbroic parental magma produced lithologic trends of cumulate pyroxenite and fractionated gabbro and dike lithologies. Similarities between all lithologies suggest cogenetic formation of all the elements of the Bonanza King MIC during the Late Silurian (431 +/- 3).

Parental magma …

Microanalytical Investigations Of Gold-Bearing Rocks From The An Najadi Region In Saudi Arabia, Nazrul I. Khandaker, M. Ahmed, M. M. Hariri, M. A. Garwan, K. R. Khan, M. M. Al-Ohali

Publications and Research

The Proton Induced X-ray Emission technique with a scanning microbeam (micro-PIXE) and Scanning Electron Microscopy (SEM) were employed to study gold-bearing rocks from the An Najadi and adjacent regions situated within the exposed northeastern part of the Arabian Shield. These microanalytical investigations, together with routine petrological and ore microscopic studies, demonstrated the presence of important partitioning of major minerals and trace elements in several samples. These measurements also revealed microstructural features including brecciation within quartz grains and metal concentrations within these fracture-controlled micro-conduits. Results showed promise in terms of using distinctive geochemical signatures for ore body recognition. Of particular interest …

Prolonged History Of Silicic Peralkaline Volcanism In The Eastern Pacific Ocean, Wendy A. Bohrson, Mary R. Reid, Anita L. Grunder, Matthew Heizler, T. Mark Harrison, Jeffrey Lee

All Faculty Scholarship for the College of the Sciences

Socorro Island, Mexico, is an alkaline and peralkaline volcanic island located in the eastern Pacific Ocean on a mid-ocean ridge spreading center that was abandoned at ∼3.5 Ma. Silicic peralkaline rocks comprise up to 80% of the surface of the island, rendering Socorro virtually unique in the Pacific Ocean. Precise, replicate ⁴⁰Ar/³⁹Ar ages of 21 peralkaline trachytes and rhyolites reveal a history of episodic volcanic activity from ∼540 to 370 ka that may have culminated with caldera formation; repose periods between these episodes may have had maximum duration of ∼30 kyr. After up to 200 kyr of …

Study Of Volcanic Sediments By Microbeam-Pixe Technique, Nazrul I. Khandaker, M. Ahmed, M. A. Garwan

Publications and Research

Single mineral grains in a suite of Cretaceous (85–90 Ma) volcanic sedimentary rocks were analyzed using the microbeam-PIXE technique to understand fundamental geological processes responsible for micro-scale variation in elemental composition across mineral zones, twinning, cleavage planes, fractures and grain boundaries. Distributions of major and trace elements show distinct geochemical features indicative of a specific geological setting and a subsequent diagenetic process in these volcanic sediments. Examples of mineral zoning, microstructures of variable chemistry and post-depositional fluid flow are discussed using the data on feldspar group of minerals.

Sedimentology, Structure, And Geochemistry Of The Galice Formation: Sediment Fill Of A Back-Arc Basin And Island Arc In The Western Klamath Mountains, Rosann Park-Jones

Geology Theses and Dissertations

The western Jurassic belt of the Klamath Mountains is an ideal locale for the study of ophiolite genesis, island arc development, and study of flysch deposition from a nearby eroding island arc and continental margin. Closure and imbrication of an inferred back-arc basin coincided with the Late Jurassic Nevadan orogeny (ca 150 Ma). The Galice Formation is the youngest formation involved in the Nevadan orogeny (Lanphere et al., 1968). In the type section in southwestern Oregon, the Galice structurally overlies the Rogue Formation volcaniclastics. The Rogue Formation has been previously interpreted as an island arc assemblage (Garcia, 1979). The type …

Geology, Geochemistry, And Geochronology Of The Lems Ridge Olistostrome, Klamath Mountains, California, Matthias Ohr

Geology Theses and Dissertations

The Lems Ridge olistostrome (LRO), located within the western Jurassic belt of the Klamath Mountains geologic province, is a melange unit showing a distinct block-in-matrix fabric. The conformable relationship to both an igneous basement and the overlying flysch of the Late Jurassic Galice Formation points to a sedimentary origin. The lack of pervasive deformation and the internal stratification also support a predominantly olistostromal origin of the LRO. The matrix of the LRO consists of pebbly mudstone which interfingers with tuffaceous greenstone and tuff-breccias. Subordinate beds of chert, argillite, and sandstone are also present. The matrix contains abundant ophiolitic clasts, fragments …

Fault Movements And Tectonics Of Eastern Iran: Boundaries Of The Lut Plate, Ali A. Nowroozi, A. Mohajer-Ashjai

OES Faculty Publications

Summary. From 1977 March 21 to 1981 July 28, about 15 earthquakes with M_s ≥6.0 and many earthquakes with M_s≥4.5 have occurred in Iran. The upsurge of seismic activity started following the Khorqu earthquake of 1977 March 21, M,=7.0, south-east of the Fars folded series of Zagros. This shock had a thrust focal mechanism solution indicating the general northward movement of the Arabian plate with respect to the Iranian landmass. It was followed by six major damaging earthquakes in eastern Iran. The earthquakes are associated with extensive faulting which surrounds the Lut plate. (1) The Zarand earthquake …

Lithologic And Structural Controls On Karst Landforms Of The Mitchell Plain, Indiana, And Pennyroyal Plateau, Kentucky, Frederick Jennings Woodson

All-Inclusive List of Electronic Theses and Dissertations

Karst features in Harrison County, Indiana, and the Mammoth Cave region, Kentucky, are profoundly influenced by lithology and structure. In the Sinkhole Plain two classes of sinkholes, shallow solutional and deeper subsidence, differ in morphology, origin, age, distribution, and density. Distributions of the two kinds of sinkholes reflect the outcrop pattern of specific lithostratigraphic units. Broad shallow dolines (Ste. Genevieve-type sinks) develop on the Horse Cave Member of the St. Louis Limestone and on the Ste. Genevieve, Girkin, and Paoli Limestones. Innumerable steeper-sided subsidence and collapse depressions (St. Louis-type sinkholes) form on the Corydon Chert Member, lower St. Louis Limestone, …

Tourmaline - A Prospecting Guide For Massive Base-Metal Sulfide Deposits In The Penobscot Bay Area, Maine, John F. Slack

Maine Collection

Tourmaline - A Prospecting Guide for Massive Base-Metal Sulfide Deposits in the Penobscot Bay Area, Maine

by John F. Slack, U.S. Geological Survey

Special Economic Studies Series No.8

Maine Geological Survey, Department of Conservation, Augusta, Maine (June, 1980).

Contents: Abstract / Introduction / Geologic Setting / Massive Sulfide Deposits / Tourmaline Occurrences / Tourmaline: A Guide to Ore / Acknowledgements / References Cited

Saratoga: The Bubbles Of Reputation And Their Implications For An Embryonic Rift System In The Upper Hudson River Valley, James R. Young

Geology Theses and Dissertations

Carbonated, alkaline, saline waters occur over a wide area in the upper Hudson River Valley approaching 1,000 square miles. Through the sampling (spring and fall) of 39 locations, half of which were hitherto unsampled, the waters are shown to be a complexly mixed system with at least five major components.
They are:
1) a gaseous phase consisting primarily of CO2;
2) a fluid (containing the dissolved CO2) possibly analogous to a metamorphic brine whose major chemistry is HCO3>Na>Cl;
3) formational waters of variably low salinities which may be the end products of progressive dilution of Paleozoic connate brines …

Petrology Of The Oceanographer Fracture Zone (35ºn35ºw), Tsugio Shibata

Geology Theses and Dissertations

During a geological and geophysical survey of the Oceanographer Fracture Zone (35°N, 35°W), seventeen dredge hauls containing a variety of rocks were obtained. Petrographic study shows that these rock samples can be classified into six main rock types: fresh basalt, weathered basalt, metabasalt, gabbro, metagabbro, and serpentinite. Most of the dredge hauls were positioned on the steep, southern wall of the fracture zone, and an inference from the dredging results suggests that basalt is the most abundant rock type which outcrops at the junction between the rift valley and the fracture zone; however, as we move away from the junction, …

The Geology Of The Pittsburg Landing Area, Snake River Canyon, Oregon-Idaho, David L. White

All-Inclusive List of Electronic Theses and Dissertations

The major purpose of the study was to map, describe, and correlate the pre-Tertiary rocks. Accessible and excellent exposures at Pittsburg Landing enabled the writer to make a somewhat detailed study of the stratigraphy. The thesis area also offered an opportunity to study in a reconnaissance manner, the Tertiary Columbia River Basalt as described by Waters, and more recently y Ozier.

Geology Of The Moose River And Roach River Synclinoria, Northwestern Maine, Arthur J. Boucot, Edward W. Heath

Maine Collection

Geology of the Moose River and Roach River Synclinoria, Northwestern Maine

by Arthur J. Boucot, with contributions by Edward W. Heath

Bulletin No.21, Maine Geological Survey

Department of Economic Development, Augusta, Maine (August, 1969).

Contents: Abstract / Introduction / Stratigraphy / Intrusive Rocks / Metamorphism / Structure / Large Scale Maps / Somerset Island / Lobster Island / Historical Geology / The Problem of Shell Beds / References / Appendix I /

A Detailed Economic Investigation Of Geochemical And Aeromagnetic Anomalies North Central Maine, W. F. Stickney, R. S. Young, L. A. Wing

Maine Collection

A Detailed Economic Investigation of Geochemical and Aeromagnetic Anomalies North Central Maine

W.F.Stickney, R.S.Young and L.A.Wing

Special Economic Series No.4, Maine Geological Survey, Department of Economic Development, Augusta, Maine (March 1965).

Contents: Foreword / Part I - Geology (W.F. Stickney) / Part II - Geophysics (R.S. Young) / Part III - Geochemistry (L.A. Wing) / References