Geochemistry Commons^™

Predicting Spatial Patterns In Precipitation Isotope (Δ2h And Δ18o) Seasonality Using Sinusoidal Isoscapes, Scott T. Allen, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding how precipitation isotopes vary spatially and temporally is important for tracer applications. We tested how well month‐to‐month variations in precipitation δ18O and δ2H were captured by sinusoidal cycles, and how well spatial variations in these seasonal cycles could be predicted, across Switzerland. Sine functions representing seasonal cycles in precipitation isotopes explained between 47% and 94% of the variance in monthly δ18O and δ2H values at each monitoring site. A significant sinusoidal cycle was also observed in line‐conditioned excess. We interpolated the amplitudes, phases, and offsets of these sine functions across the landscape, using multiple linear …

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

Graduate Theses/Dissertations

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …

An Assessment Of Atmospheric And Meteorological Factors Regulating Red Sea Phytoplankton Growth, Wenzhao Li, Hesham El-Askary, Mohamed A. Qurban, Emmanouil Proestakis, Michael J. Garay, Olga V. Kalishnikova, Vassilis Amiridis, Antonis Gkikas, Eleni Marinou, Thomas Piechota, K. P. Manikandan

Mathematics, Physics, and Computer Science Faculty Articles and Research

This study considers the various factors that regulate nutrients supply in the Red Sea. Multi-sensor observation and reanalysis datasets are used to examine the relationships among dust deposition, sea surface temperature (SST), and wind speed, as they may contribute to anomalous phytoplankton blooms, through time-series and correlation analyses. A positive correlation was found at 0–3 months lag between chlorophyll-a (Chl-a) anomalies and dust anomalies over the Red Sea regions. Dust deposition process was further examined with dust aerosols’ vertical distribution using satellite lidar data. Conversely, a negative correlation was found at 0–3 months lag between SST anomalies …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Stable Bromine Isotope Signature Of Bromoform From Enzymatic And Abiotic Formation Pathways And Its Application In Identifying Sources Of Environmental Bromoform In The Damariscotta River, Chengyang Wang

Honors Theses

Bromoform is a major source of atmospheric bromine. Most bromoform is produced by marine organisms including macroalgae and phytoplankton, using the enzyme bromoperoxidase (BPO). Bromoform can also be a byproduct of industrial processes such as water disinfection. Identifying sources of environmental bromoform is still a challenge. A novel technique of using quadrupole mass spectrometry coupled to a gas chromatography (GCqMS) was developed and optimized for Br isotope analyses. The study shows that GCqMS in single ion monitoring (SIM) mode can measure 81Br with precision of around ±0.7‰ (60pmol bromoform injected). This study aims to investigate stable Br isotopes of bromoform …

Resolving Chronological And Temperature Constraints On Antarctic Deglacial Evolution Through Improved Dating Methodology, Cristina Subt

USF Tampa Graduate Theses and Dissertations

In order to determine the timing of Antarctic ice sheet retreat and advance during the Late Quaternary, various tools are used to measure the age of marginal marine sediments. Carbonate 14C dating is a well-established approach, but requires foraminiferal microfossils, shells or other carbonate materials that are rare in most Antarctic regions, and may also suffer from vital effects, which can result in variability of up to 500 years in living organisms. Bulk acid insoluble organic (AIO) 14C dates are frequently as an alternative, but this approach works best where high productivity and sedimentation rates reign, and not too well …

Paleoenvironmental Reconstruction Using Coral Microatolls (Sp. Siderastrea Siderea) From The Gulf Of Gonâve, Haiti, Gilman Reno Ouellette Jr.

LSU Doctoral Dissertations

Natural and anthropogenic climate changes present unique and serious risks to society. In order to plan and implement adaptation and mitigation strategies successfully, regional manifestations of broad-scale climate changes must be understood robustly. The Caribbean region contains part of the Western Hemisphere Warm Pool (WHWP), a major sea surface temperature (SST) feature that plays a key role in North Atlantic climate. Climate variability in the Caribbean is captured poorly by climate models, due in part to a lack of continuous, multidecadal instrumental climate records from the region. I explored three research questions in this dissertation: Does non-systematic bias exist in …

Bonneville Basin Data, Larry V. Benson

United States Geological Survey: Datasets

In the Bonneville Basin folder, all data were reported in: Benson, L.V., Lund, S.P., Smoot, J.P., Rhode, D.E., Spencer, R.J., Verosub, K.L., Louderback, L.A., Johnson, C.A., Rye, R.O., Negrini, R., 2011. The rise and fall of Lake Bonneville between 45 and 10.5 ka. Quaternary International 235: 57-69.

http://digitalcommons.unl.edu/usgsstaffpub/726

General Comment: in most cases an age model based on ¹⁴C analyses is not included with the data sets although ones were created for the original publications. Given the general problems with ¹⁴C ages in the lakes of the Great Basin, age models based on paleomagnetic secular variation (PSV) are …

A Near-Global Atmospheric Distribution Of N2o Isotopologues, Peter F. Bernath, Mahdi Yousefi, Eric Buzan, Chris D. Boone

Chemistry & Biochemistry Faculty Publications

The distributions of the four most abundant isotopologues and isotopomers (N₂O, ¹⁵NNO, N¹⁵NO, and NN¹⁸O of nitrous oxide have been measured in the Earth's stratosphere by infrared remote sensing with the Atmospheric Chemistry Experiment (ACE) Fourier transform spectrometer. These satellite observations have provided a near-global picture of N₂O isotopic fractionation. The relative abundances of the heavier species increase with altitude and with latitude in the stratosphere as the air becomes older. The heavy isotopologues are enriched by 20-30% in the upper stratosphere and even more over the poles. These observations are …

Selenium Distribution And Cycling In The Eastern Equatorial Pacific Ocean, Zoe Wambaugh

OES Theses and Dissertations

Oxygen minimum zones in oceanic waters have become increasingly important to the marine environment and society. Low oxygen waters affect not only the distribution and abundance of marine organisms, but also impact the solubility and transport of trace elements that are of biological importance, with the chemical speciation and solubility depending on the actual redox poise of the waters. One redox sensitive trace element of interest is selenium, which can be both toxic and essential for organisms, depending on its chemical speciation. In 2013, the US GEOTRACES program completed the GP16 transect from Peru to Tahiti, going through the oxygen …

Nuclear Weapons In A Changing Climate: Probability, Increasing Risks, And Perception, Adam Liska, Tyler R. White, Eric Holley, Robert J. Oglesby

Adam Liska Papers

Many people tend to think that the outcome of any nuclear weapons use today will result in an escalatory situation with apocalyptic outcomes for the countries involved. Yet many factors are increasing the probability of the limited use of nuclear weapons (e.g., 1 to 20 warheads) in a range of conflict scenarios. Previous atmospheric model simulations of regional nuclear conflicts employing many relatively small bombs have been estimated to cause a global “nuclear autumn,” with great reductions in agricultural productivity, stratospheric ozone loss, and spread of hazardous radioactive fallout. The totality of these effects would result in widespread damage …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Actively Forming Kuroko-Type Volcanic-Hosted Massive Sulfide (Vhms) Mineralization At Iheya North, Okinawa Trough, Japan, Christopher J. Yeats, Steven P. Hollis, Angela Halfpenny, Juan-Carlos Corona, Crystal Laflamme, Gordon Southam, Marco Fiorentini, Richard J. Herrington, John Spratt

All Faculty Scholarship for the College of the Sciences

Modern seafloor hydrothermal systems provide important insights into the formation and discovery of ancient volcanic-hosted massive sulfide (VHMS) deposits. In 2010, Integrated Ocean Drilling Program (IODP) Expedition 331 drilled five sites in the Iheya North hydrothermal field in the middle Okinawa Trough back-arc basin, Japan. Hydrothermal alteration and sulfide mineralization is hosted in a geologically complex, mixed sequence of coarse pumiceous volcaniclastic and fine hemipelagic sediments, overlying a dacitic to rhyolitic volcanic substrate. At site C0016, located adjacent to the foot of the actively venting North Big Chimney massive sulfide mound, massive sphalerite-(pyrite-chalcopyrite ± galena)-rich sulfides were intersected (to 30.2% …

Quantity Trumps Quality: Bayesian Statistical Accumulation Modeling Guides Radiocarbon Measurements To Construct A Chronology In Real-Time, Devon Robert Firesinger

USF Tampa Graduate Theses and Dissertations

The development of an accurate and precise geochronology is imperative to understanding archives containing information about Earth’s past. Unable to date all intervals of an archive, researchers use methods of interpolation to approximate age between dates. Sections of the radiocarbon calibration curve can induce larger chronological uncertainty independent of instrumental precision, meaning even a precise date may carry inflated error in its calibration to a calendar age. Methods of interpolation range from step-wise linear regression to, most recently, Bayesian statistical models. These employ prior knowledge of accumulation rate to provide a more informed interpolation between neighboring dates. This study uses …

Mono Lake Data, Larry V. Benson

United States Geological Survey: Datasets

Mono Lake Basin Data\ Depth CalAge TIC TOTC TOC 13C 18O

Mono Lake short cores.xlsx 03.03.2014 19:59:44 0.06 xlsx

Depth PSV age 18O 13C

TIC for Wilson Crk Fm.xlsx 02.03.2014 16:07:10 0.03 xlsx

Ostracode 18O and TE data Wilson Crk Fm.xlsx 10.11.2017 17:43:18 0.12 xlsx

Depth, calendar age, TIC, TOTC, TOC, ¹³C, and ¹⁸O of Mono Lake short cores were reported in:

Benson, L., Linsley, B., Smoot, J., Mensing, S., Lund, S., Stine, S., and Sarna-Wojcicki, A., 2003, Influence of the Pacific Decadal Oscillation on the climate of the Sierra Nevada, California and Nevada: Quaternary Research. Quaternary Research …

Summer Lake Basin Data, Larry V. Benson

United States Geological Survey: Datasets

Summer Lake Basin

Name Date modified Time modified Size MB Extension

Summer Lake Basin\

Depth PSV Age 13C 18O Summer Lake B&B core.xlsx 03.03.2014 16:51:12 0.03 xlsx

In the Summer Lake Basin folder:

Depth, PSV age, ¹⁸O, ¹³C data for Summer Lake core B&B are reported in:

Benson, L., Lund, S., Negrini, R., Linsley, B., and Zic, M. 2003. Response of North American Great Basin lakes to Dansgaard-Oeschger oscillations. Quaternary Science Reviews 22: 2,239-2,251.

General Comment: In most cases an age model based on ¹⁴C analyses is not included with the datasets although ones were created for …

Great Basin Surface Water And Precipitation Isotope Data, Larry V. Benson

United States Geological Survey: Datasets

In the Great Basin Surface Water and Precipitation Isotope Data folder:

Farad, Nixon, and Pyramid Lake 18O data were reported in:

Benson, L.V., 1994, Stable isotopes of oxygen and hydrogen in the Truckee River-Pyramid Lake surface-water system. 1. Data analysis and extraction of paleoclimatic information: Limnology and Oceanography, vol. 39, p. 344-355. https://digitalcommons.unl.edu/usgsstaffpub/1015

Spring chemistry around Pyramid Lake data were reported in:

Benson, L.V., 1994, Carbonate deposition, Pyramid Lake subbasin, Nevada: 1. Sequence of formation and elevational distribution of carbonate deposits (tufas): Palaeogeography, Palaeoclimatology, Palaeoecology, vol. 109, p. 55-87.

Benson, L.V., Kashgarian M., and Rubin, M., 1995, Carbonate deposition, …

Owens Lake Core Data, Larry V. Benson

United States Geological Survey: Datasets

In the Owens Lake core data folder:

¹⁴C ages for cores OL84 and OL90 were reported in:

Benson, L.V., Burdett, J.W., Kashgarian, M., Lund, S.P., Phillips, F.M., and Rye, R.O., 1996, Climatic and hydrologic Oscillations in the Owens Lake basin and adjacent Sierra Nevada, California: Science, vol. 274, p. 746-749.

Benson, L.V., 1999, Records of millennial-scale climate change from the Great Basin of the Western United States: In Clark, P., Webb, R., Keigwin, L., eds., Mechanisms of Global Climate Change at Millennial Time Scales, American Geophysical Union Monograph 112, p. 203-225.

Benson, L., 2003, Western Lakes: Chapter 9 in …

Paleomagnetic Secular Variation (Psv) Ages Of Wilson Crk, Plc08-1, Bl04-4, Ol90-1 And 2, Larry V. Benson

United States Geological Survey: Datasets

In the paleomagnetic secular variation (PSV) ages folder:

The data for OL90-1 and 2 have not been published

The data for PLC08-1 are reported in:

Benson, L.V., Smoot, J.P., Lund, S.P., Mensing, S.A., Rye, R.O., 2013. Insights from a synthesis of old and new climate-proxy data from the western Lahontan Basin for the period 48 to 11.5 ka. Quaternary International310, 62-82.

Lund, S., Benson, L., Negrini, R., Liddicoat, J., Mensing, S., 2016. A full-vector paleomagnetic secular variation record (PSV) from Pyramid Lake (Nevada) from 47-17 ka: Evidence for the successive Mono Lake and Laschamp Excursions. Earth and Planetary Sciences …

Pyramid And Winnemucca Lake Basin Carbonate Data, Larry V. Benson

United States Geological Survey: Datasets

In the Pyramid and Winnemucca lake basin carbonate data folder:

New unpublished and previously published ¹⁴C and calibrated ages for materials in the Winnemucca Caves are reported in the table and in the references listed below the table

¹⁴C and calibrated ages for Winnemucca Lake Basin carbonates are reported in:

Benson, L.V., Hattori, E.M., Southon, J., Aleck, B., 2013. Dating North America’s oldest petroglyphs, Winnemucca Lake subbasin, Nevada. Journal of Archaeological Science 40, 4466-4476.

Tufa ⁸⁷Sr, ¹⁸O, and ¹³C data are reported in:

Benson, L.V., Smoot, J.P., Lund, S.P., Mensing, S.A., Rye, R.O., 2013. Insights …

Reconstructed Discharge For Truckee River, Larry V. Benson

United States Geological Survey: Datasets

Reconstructed Discharge for Truckee River

Name Date modified Time modified Size MB Extension

Reconstructed Discharge Truckee R\ Reconstructed Discharge for Truckee River.xlsx 11.11.2017 22:40:52 0.02 xlsx

Reconstructed discharge of the Truckee River was made considering losses to evaporation in all upstream reservoirs and corrected for diversion from the Derby Dam to the Newlands area. These data were never previously published.

General Comment: In most cases an age model based on ¹⁴C analyses is not included with the datasets although ones were created for the original publications. Given the general problems with ¹⁴C ages in the lakes of the …

Walker Lake Basin Data, Larry V. Benson, Steve P. Lund

United States Geological Survey: Datasets

Walker Lake Basin Data

Name Date modified Time modified Size MB Extension

Walker Lake Core 84-8 isotope and age data.xls 27.01.2018 15:25:52 0.03 xls

Walker Lake core WL002 PSV age and chemical data.xlsx 09.02.2018 20:04:50 0.03 xlsx

In the Walker Lake Basin folder:

Depth, ¹⁴C age (not corrected for reservoir effect), ¹⁸O, ¹³C data for core 84-8 are reported in:

Benson, L. V., 1988, Preliminary paleolimnologic data for the Walker Lake subbasin, California and Nevada: United States Geological Survey Water-Resources Investigations Report 87-4258, 50 p. Palaeogeography, Palaeoclimatology, Palaeoecology 240: 497-507.

Depth, PSV age, TIC , ¹⁸O, …

Pyramid Lake Core Data, Larry V. Benson

United States Geological Survey: Datasets

Pyramid Lake Core Data

14C and calibrated ages for core PLC08-1.xlsx 01.03.2014 19:45:30 0.01 xlsx

14C and calibrated ages for core PLC92B.xlsx 04.03.2014 16:41:30 0.01 xlsx

14C and calibrated ages for core PLC97-3.xlsx 01.03.2014 19:50:48 0.01 xlsx

CalKa Depth TOC TIC 18O 13C for PLC97-1.xlsx 09.11.2017 20:51:22 0.04 xlsx

Depth 14CAge Corrected 14C AGE CAL Age PLC98-4.xlsx 15.11.2017 18:26:12 0.01 xlsx

Depth 180 13C TOTC TOC TIC porosity CYBP Box Core PLB98-2.xlsx 01.03.2014 20:00:46 0.01 xlsx

Depth CalAge TIC TOTC TOC 13C 18O PLC98-4.xlsx 02.03.2014 00:32:20 0.05 xlsx

Depth Equivalent Depth in PLC08-1 PSV age 180 13C TIC TOC for …

Comparison Of The Scavenging Intensity, Remineralization And Residence Time Of 210po And 210pb At Key Interfaces (Biotic, Sediment-Water And Hydrothermal) Along The Geotraces East Pacific Zonal Transect, John Niedermiller

Wayne State University Theses

The contrasting geochemical behavior of two long-lived progeny of 222Rn, namely 210Po and 210Pb, provide valuable insights on the extent of recycling of biogenic particulate matter and their preferential removal from the water column. A total of 135 water samples were collected and analyzed from six vertical profiles for 210Po and 210Pb along the US GEOTRACES East Pacific Zonal Transect. This study shows decreasing atmospheric 210Pb flux from the measured 210Pb activity in aerosols indicating an overall decrease from east to west along the cruise transect. Differences in scavenging intensities, inventories, and residence times of 210Po and 210Pb at key …

New And Improved Infra-Red Absorption Cross Sections And Ace-Fts Retrievals Of Carbon Tetrachloride (Ccl4), Jeremy J. Harrison, Christopher D. Boone, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

Carbon tetrachloride (CCl₄) is one of the species regulated by the Montreal Protocol on account of its ability to deplete stratospheric ozone. As such, the inconsistency between observations of its abundance and estimated sources and sinks is an important problem requiring urgent attention (Carpenter et al., 2014) [5]. Satellite remote-sensing has a role to play, particularly limb sounders which can provide vertical profiles into the stratosphere and therefore validate stratospheric loss rates in atmospheric models. This work is in two parts. The first describes new and improved high-resolution infra-red absorption cross sections of carbon tetrachloride/dry synthetic air over …

Community Production Modulates Coral Reef Ph And The Sensitivity Of Ecosystem Calcification To Ocean Acidification, Thomas M. Decarlo, Anne L. Cohen, George T. F. Wong, Fuh-Kwo Shiah, Steven J. Lentz, Kristen A. Davis, Kathryn E. F. Shamberger, Pat Lohmann

OES Faculty Publications

Coral reefs are built of calcium carbonate (CaCO₃) produced biogenically by a diversity of calcifying plants, animals, and microbes. As the ocean warms and acidifies, there is mounting concern that declining calcification rates could shift coral reef CaCO3 budgets from net accretion to net dissolution. We quantified net ecosystem calcification (NEC) and production (NEP) on Dongsha Atoll, northern South China Sea, over a 2 week period that included a transient bleaching event. Peak daytime pH on the wide, shallow reef flat during the nonbleaching period was ~8.5, significantly elevated above that of the surrounding open ocean (~8.0-8.1) as …

Spatial Patterns Of Sea Level Variability Associated With Natural Internal Climate Modes, Weiqing Han, Gerald A. Meehl, Detlef Stammer, Aixue Hu, Benjamin Hamlington, Jessica Kenigson, Hindumathi Palanisamy, Philip Thompson

OES Faculty Publications

Sea level rise (SLR) can exert significant stress on highly populated coastal societies and low-lying island countries around the world. Because of this, there is huge societal demand for improved decadal predictions and future projections of SLR, particularly on a local scale along coastlines. Regionally, sea level variations can deviate considerably from the global mean due to various geophysical processes. These include changes of ocean circulations, which partially can be attributed to natural, internal modes of variability in the complex Earth's climate system. Anthropogenic influence may also contribute to regional sea level variations. Separating the effects of natural climate modes …

Abundance Of Archaias Angulatus On The West Florida Coast Indicates The Influence Of Carbonate Alkalinity Over Salinity, Sean Thomas Beckwith

USF Tampa Graduate Theses and Dissertations

Archaias angulatus, a large symbiont-bearing foraminifer (Order Miliolida) that produces a Mg-calcite shell, is common throughout the Caribbean and warm western Atlantic region. This species lives abundantly in seagrass beds along the Springs Coast of northwest Florida (up to 4 adults per gram of sediment) where spring-fed rivers emerge from a limestone aquifer, and in Florida Bay to the southeast (25 adults/g) where the sediment is primarily biogenic carbonate. In contrast, live specimens are seldom found in the seagrass beds along the central-west coast of Florida, where barrier islands are dominated by quartz sand. My working hypothesis is that substratum …

Chlorine Demand Shows Thresholds And Hierarchy With Source Water Quality At Beaver Lake, Arkansas, Jaime M. Gile

Graduate Theses and Dissertations

This study investigated the effects of source water quality in Beaver Lake on the amount of chlorine (Cl) needed to develop decision support system to help guide chlorination practices in pre-treatment of source water. Chlorine demand assays were performed on water samples from Beaver Lake collected from the intake structure at Beaver Water District from March 2014 through August 2015, and using data from these assays, the two points of interest in this study were the Cl dose at which Cl residuals began to accumulate and the mean Cl demand occurring after that dose. Three methods of analysis were used …

A Tribute To Thomas M. Church: Exploring Chemical Oceanography In The Coastal Zone-The History And Future, Gregory A. Cutter, David J. Burdige

OES Faculty Publications

(First paragraph) One can find different historical perspectives on the development of studying the chemistry of oceans as well as names for this study—marine chemistry, chemistry of the sea, marine aquatic chemistry, marine biogeochemistry, or chemical oceanography. It could be argued that chemical oceanography is the most inclusive for an earth science since oceanography itself is an integrated discipline that links the biology, chemistry, geology, and physics together. Regardless of the name, perhaps the first intensive, modern/post-nineteenth century study of the ocean’s chemistry was the GEOSECS Program from ca. 1970–1978. The significance of GEOSECS was that it examined the chemistry …