Geochemistry Commons^™

Thermochronological Evolution Of Calcite Formation At The Proposed Yucca Mountain Repository Site, Nevada: Part 1, Secondary Mineral Paragenesis And Geochemistry, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

In the near future a decision will be made as to whether or not Yucca Mountain, 90 miles northwest of Las Vegas, Nevada is a suitable site for a permanent, underground, high level nuclear waste repository. A major factor in determining the suitability of Yucca Mountain as a repository is the potential for the site to be flooded by water during the regulatory lifetime. The current study was undertaken to examine the past fluid history at the site, to gain a better understanding of the possibility of flooding in the near geologic future. To estimate the past fluid flux into …

Chemical, Isotopic, And Hydrogeologic Investigations Of An Agriculturally Impacted Area, Nottawa Creek Watershed, Calhoun County, Michigan, Gerald A. Unterreiner

Dissertations

A 4 km2 agricultural area within the somewhat poorly drained Nottawa Creek Watershed, south central Michigan, was investigated to help understand transport and transformation processes of nutrients and herbicides to surface water. Geology o f the study area is comprised of a thin glacial drift cover overlying shale bedrock. A one layer, two-dimensional numerical triangular finite element groundwater flow model was developed to evaluate regional groundwater flow. Selected horizontal hydraulic conductivities ranged from 3 x 10‘3 m/day to 107 m/day. Field-scale infiltration modeling with the computer program GLEAMS, substantiated with water level measurements, suggest significant recharge events occur during summer, …

Development Of A Circa 2000 Landcover Database For The United States, Collin Homer, Chengquan Huang, Limin Yang, Bruce K. Wylie

United States Geological Survey: Publications

Multi-Resolution Land Characterization 2000 (MRLC 2000) is a second-generation federal consortium to create an updated pool of nation-wide Landsat 7 imagery, and derive a second-generation National Land Cover Database (NLCD 2000). This multi-layer, multisource database will include a suite of 30-meter resolution data that will serve as standardized ingredients for the production of land cover – both nationally and locally. This database will also provide the framework to allow flexibility in developing and applying suites of independent data layers. These nationally standardized independent data layers or components, will be useful not only within the land-cover classification but as data themes …

Derivation Of A Tasseled Cap Transformation Based On Landsat 7 At-Satellite Reflectance, C. Huang, Bruce K. Wylie, Limin Yang, Collin Homer, Gregory Zylstra

United States Geological Survey: Publications

A new tasseled cap transformation based on Landsat 7 at-satellite reflectance was developed. This transformation is most appropriate for regional applications where atmospheric correction is not feasible. The brightness, greenness and wetness of the derived transformation collectively explained over 97% of the spectral variance of the individual scenes used in this study.

Assessment Of Elemental Concentrations In Streams Of The New Lead Belt In Southeastern Missouri, 2002–05, William G. Brumbaugh, Thomas W. May, John M. Besser, Ann L. Allert, Christopher J. Schmitt

United States Geological Survey: Publications

Concerns about possible effects of lead-mining activities on the water quality of federally protected streams located in southeastern Missouri prompted a suite of multidisciplinary studies to be conducted by the U.S. Geological Survey. As part of this investigation, a series of biological studies were initiated in 2001 for streams in the current mining region and the prospecting area. In this report, results are examined for trace elements and other selected chemical measurements in sediment, surface water, and sediment interstitial (pore) water sampled between 2002 and 2005 in association with these biological studies. Compared to reference sites, fine sediments collected downstream …

Strontium Isotopic Signatures Of The Streams And Lakes Of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering In A Polar Climate, W. B. Lyons, Carmen A. Nezat, Larry V. Benson, Thomas D. Bullen, Elizabeth Y. Graham, Jesicca Kidd, Kathleen A. Welch, James M. Thomas

United States Geological Survey: Staff Publications

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different ⁸⁷Sr/⁸⁶Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system …

At-Satellite Reflectance: A First Order Normalization Of Landsat 7 Etm+ Images, Chengquan Huang, Limin Yang, Collin Homer, Bruce K. Wylie, James E. Vogelmann, Thomas Defelice

United States Geological Survey: Publications

Regional Landsat applications often rely on clear and near cloud-free images. With the spectral value being represented by digital number (DN), however, such images contain substantial noises. A significant proportion of such noises can be normalized by converting the DN to at-satellite reflectance value. Being physically based and ready to automate, the conversion method can serve as a first order normalization of Landsat 7 images, making it possible to derive land surface information from such images more consistently.

A Strategy For Estimating Tree Canopy Density Using Landsat 7 Etm+ And High Resolution Images Over Large Areas, C. Huang, Limin Yang, Bruce K. Wylie, Collin Homer

United States Geological Survey: Publications

INTRODUCTION

The Multi-Resolution Land Characteristics (MRLC) consortium was initiated in early 1990s to address the need for consistently developed national and regional land cover data (Loveland and Shaw, 1996). Through this consortium, a 1992-vintage National Land Cover Dataset (NLCD) was developed for the conterminous United States (Vogelmann et al., 2001), and a second generation National Land Cover Dataset (NLCD 2000) will be developed using 2000-vintage Landsat 7 Enhanced Thematic Mapper Plus (ETM+) images and ancillary data. The 2000 NLCD will consist of a suite of data layers relevant to many applications, including a tree canopy density layer describing percentage of …

Land Cover Trends Dataset, 1973–2000, Christopher E. Soulard, William Acevedo, Roger F. Auch, Terry L. Sohl, Mark A. Drummond, Benjamin M. Sleeter, Daniel G. Sorenson, Steve Kambly, Tamara S. Wilson, Janis L. Taylor, Kristi L. Sayler, Michael P. Stier, Christopher A. Barnes, Steve C. Methven, Thomas R. Loveland, Rachel Headley, Mark S. Brooks

United States Geological Survey: Publications

The U.S. Geological Survey Land Cover Trends Project is releasing a 1973–2000 time-series land-use/land-cover dataset for the conterminous United States. The dataset contains 5 dates of land-use/land-cover data for 2,688 sample blocks randomly selected within 84 ecological regions. The nominal dates of the land-use/land-cover maps are 1973, 1980, 1986, 1992, and 2000. The land-use/land-cover maps were classified manually from Landsat Multispectral Scanner, Thematic Mapper, and Enhanced Thematic Mapper Plus imagery using a modified Anderson Level I classification scheme. The resulting land-use/land-cover data has a 60-meter resolution and the projection is set to Albers Equal-Area Conic, North American Datum of 1983. …

Water Quality In The Central Nebraska Basins, Nebraska, 1992-95, S. A. Frenzel, R. B. Swanson, T. L. Huntzinger, J. K. Stamer, P. J. Emmons, Ronald B. Zelt

United States Geological Survey: Publications

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the Central Nebraska Basins Study Unit and to relate these findings to water-quality issues of regional and national concern. The information is primarily intended for those who are involved in waterresource management. Indeed, this report addresses many of the concerns raised by regulators, water-utility managers, industry representatives, and other scientists, engineers, public officials, and members of stakeholder groups who provided advice and input to the USGS during this NAWQA Study-Unit investigation. Yet, the information contained here may also interest those who …

Hydrogeology In The Vicinity Of The Nebraska Management Systems Evaluation Area Site, Centra! Nebraska, Virginia L. Mcguire, John M. Kilpatrick

United States Geological Survey: Publications

From 1991 to 1992, the U.S. Geological Survey participated with the U.S. Department of Agriculture and the University of Nebraska-Lincoln in research activities at the Nebraska Management Systems Evaluation Area (MSEA) site near Shelton, Nebraska. The purpose of the U.S. Geological Survey study was to define the hydrogeologic system in the vicinity of the Nebraska MSEA site to aid the interpretation of ground-water sampling results by other researchers. The primary aquifer in the study area is the High Plains aquifer, which consists of an unconfined part, the shallow aquifer; a silt and clay unit that acts as a confining layer; …

Estimation Of Groundwater Velocities From Yucca Flat To The Amargosa Desert Using Geochemistry And Environmental Isotopes, Ronald L. Hershey, Steve Y. Acheampong

Publications (WR)

Geochemical modeling techniques were applied to groundwater flowpaths from Yucca Flat on the Nevada Test Site (NTS) to the Amargosa Desert, south of the NTS to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The groundwater flowpaths examined considered flow in the carbonate aquifer beneath Yucca and Frenchman flats mixing with flow from carbonate aquifers east and southeast of the NTS and discharging at wells south of the NTS border. The approach used the computer codes WATEQ4F and NETPATH to calculate chemical speciation, determine the saturation state of mineral phases, and simulate mixing and the …

Residence Time Of Groundwater Issuing From The South Rim Aquifer In The Eastern Grand Canyon, Jim Fitzgerald

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the eastern Grand Canyon, secondary porosity created by north trending faults, folds, and breccia pipes, facilitates groundwater flow through the South Rim carbonate aquifer. Springs associated with the South Rim Aquifer have low ³H concentrations, [Ca²⁺]/[Mg²⁺] rations close to unity, and variable uranium concentrations. For a geochemical comparison, springs are subcategorized on the basis of geology and discharge. Type I springs are associated with high-angle normal faults and have high discharge rates. These springs discharge Ca²⁺ - Mg²⁺, HCO₃^- waters, have ³H concentrations <2 TR, and ²³⁴U/²³⁸U activity …

Hydrogeology, Hydrogeochemistry, And Spoil Settlement At A Large Mine-Spoil Area In Eastern Kentucky: Star Fire Tract, David R. Wunsch, James S. Dinger, Page B. Taylor, Daniel I. Carey, C. Douglas R. Graham

Report of Investigations--KGS

An applied research program at the Star Fire surface mine in eastern Kentucky, owned and operated by Cypress-AMAX Coal Co., defined spoil characteristics to develop and monitor water resources, which will help identify a reliable water supply for future property development. Water stored in the mine spoil may provide a usable ground-water supply, and the spoil could also be engineered to provide base flow to surfacewater reservoirs.

Ground-water recharge enters the spoil by way of sinking streams, ground-water flow from bedrock in contact with the mine spoil, and a specially designed infiltration basin. Ground water discharges predominantly from springs and …

Hydrogeology And Hydrogeochemistry Of Government Marsh, North St. Joseph County, Michigan, Michael C. Kasenow

Dissertations

A hydrogeologic and hydrogeochemical investigation was conducted at Government Marsh located in St. Joseph County, Michigan from May, 1988, to November, 1993. Information on glacial geology, topography, drainage patterns, hydraulic conductivity, vegetation, water chemistry, and static water table elevations has been collected and analyzed. Data were collected in order to determine directions of ground water flow and areas of recharge and discharge. Bail-down tests, grain-size analysis, and permeameters were used to determine hydraulic conductivity adjacent to and within the wetland. Water table elevations and chemistry were analyzed from wells adjacent to the wetland perimeter and within the boundaries of the …

Field Test Of A Calcite Dissolution Rate Law: Fort’S Funnel Cave, Mammoth Cave National Park, J. Scott Slunder

Masters Theses & Specialist Projects

The laboratory-derived calcite dissolution rate law of Plummer et al. (1978) is the most widely used and mechanistically detailed expression currently available for predicting dissolution rates as a function of water chemistry. Such rate expressions are of great use in understanding timescales associated with limestone karst development. Little work has gone into the field testing of the rate law under natural conditions.

This work compared measured dissolution rates measured by a crystal weight loss experiment in Buffalo Creek within Fort’s Funnel Cave, which lies within a pristine, forested catchment of Mammoth Cave National Park. Continuous water chemistry sampling over the …

Precipitation Dynamics In Kalamazoo, Sw Michigan: A Stable Isotope Perspective, Madhav V. Machavaram

Masters Theses

No abstract provided.

Groundwater Chemistry Analysis Of The Saginaw Formation In Delhi Township, Michigan, Sam L. Kitchin

Masters Theses

Groundwater chemistry and well data provided by the Ingham County (Michigan) Health Department were used to evaluate the distribution of inorganic chemical constituents in the groundwater flow system of the Saginaw Formation, in Delhi Township, Michigan. The data also were used to study the distribution of chemical constituents with respect to different rock types of the Saginaw Formation. The data were analyzed to examine if variations in the concentrations of the chemical constituents and the values of other chemical parameters relate to rock-water interactions, groundwater flow systems, or groundwater contamination.

The results indicate that patterns of increasing or decreasing concentrations …

Water-Quality Assessment Of The Central Nebraska Basins: Summary Of Data For Recent Conditions Through 1990, Ronald B. Zelt, P. R. Jordan

United States Geological Survey: Publications

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning recent water-quality conditions in the study unit. The water-quality conditions of interest in addressing the objectives of the NAWQA program are those that are representative of the general water quality of a given stream reach or area of an aquifer. This report (1) identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and (2) describes, to the extent possible, recent, general water-quality conditions in the Central Nebraska Basins. The study …

Reconnaissance Data For Selected Herbicides, Two Atrazine Metabolites, And Nitrate In Surface Water Of The Midwestern United States, 1989-90, Elisabeth A. Scribner, E. Michael Thurman, Donald A. Goolsby, Michael T. Meyer, Margaret S. Mills, Michael L. Pomes

United States Geological Survey: Publications

Water-quality data were collected from 147 rivers and streams during 1989-90 to determine the temporal and geographic distribution of selected preemergent herbicides, two atrazine metabolites, and nitrate in 10 Midwestern States. This report includes a description of the sampling design, data-collection techniques, laboratory and analytical methods, and a compilation of constituent concentrations and quality-assurance data. All water samples were collected by depth-integrating techniques at three to five locations across the wetted perimeter of each stream. Sites were sampled three times in 1989~before application of herbicides, during the first major runoff after application of herbicides, and in the fall during a …

Seasonal Hydrology And Geochemistry Of Two Small High Arctic Catchments, Axel Heiberg Island, Northwest Territories, Julia Boike

Theses and Dissertations (Comprehensive)

This study examines hydrological and geochemical processes in a continuous permafrost setting in the Canadian High Arctic on Axel Heiberg Island (79°25 ' N; 90°45 ' W) with the following objective: to identify spatial and seasonal variation in hydrology and geochemistry of the East Inflow (EIF) and West Inflow (WIF) sub basins draining into Colour Lake and relate them to processes operating in the basins. Field work in the catchment was carried out between 20 May to 16 August 1991 and 23 July to 20 August 1992. Surface flow and suprapermafrost groundwater in the active layer were monitored to assess …

Chemical Analyses Of Water From Selected Wells And Springs In The Yucca Mountain Area, Nevada And Southeastern California, P. W. Mckinley, M. P. Long, Larry Benson

United States Geological Survey: Publications

Chemical analysis of water samples from 279 wells and springs in the Yucca Mountain area are presented. Where data are available, this report includes: site location expressed as Nevada Central Coordinates and latitude and longitude; source of data; name of analyzing laboratory; geologic unit from which water was obtained; lithology; water use; elevation of well or spring; well depth; depth to water; time pumped before taking the sample; yield; type of filtration; sampling method; date the sample was collected; and anion-cation balance.

Yucca Mountain, Nevada (fig. 1), is being investigated by the U.S. Geological Survey, in cooperation with the U.S. …

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Hydrogeology And Hydrogeochemistry Of The Tekonsha Moraine And Adjacent Interlobate Deposits In Charleston Township, Kalamazoo County, Michigan, Victor V. Melbardis

Masters Theses

Hydrogeochemical analyses and hydrogeologic interpretations provide the basis for an understanding of local ground-water flow, in a 12 square mile study area, transected by the Tekonsha Moraine and bound by glaciofluvial deposits. Glacial tills separate an upper and lower aquifer system throughout most of the area.

Degraded and tritiated ground water is present in the lower aquifer system. A negative correlation (-0.62) between tritium concentrations and depth is statistically significant (.04). In this local system, hydrochemical trends are characterized by decreases in sulfate percentages and increases in bicarbonate in the direction of ground-water flow. Statistical evaluation of the hydrochemical data …

Isotope Content And Temperature Of Precipitation In Southern Nevada, August 1983-August 1986, W. K. Milne, Larry Benson, P. W. Mckinley

United States Geological Survey: Publications

From August 1983 through August 1986, 429 precipitation samples of 112 precipitation events were collected at 12 stations in southern Nevada. Some of these samples were analyzed for oxygen-18, deuterium, and tritium. The results of these analyses as well as the air temperature and the precipitation measured at the collection sites are tabulated in this report. The sampling program provides a data base for future interpretive studies on the timing and origin of ground-water recharge in the Yucca Mountain region, of southern Nevada.

The stable-isotope composition of precipitation is the result of fractionation processes that occur in the atmosphere. Isotopic …

The Geology, Geochemistry, And Alteration Of Red Butte, Oregon: A Precious Metal-Bearing Paleo Hot Spring System, Carol Susan Evans

Dissertations and Theses

Red Butte is located 60 km south of Vale, Oregon, about 20 km west of the Oregon/Idaho border. The butte is within the Owyhee Upland physiographic province of eastern Oregon which lies at the intersection of the Western Snake River Plain, the High Lava Plains, and the Northern Basin and Range provinces.

The butte is composed of Miocene to Pliocene lacustrine and fluvial volcaniclastic sediments. The topography of the butte is controlled by silicification of the sandstones and mudstones which cap it. Silicification and hydrothermal alteration are both structurally and stratigraphically controlled. North-trending normal faults dominate the area, and show …

Chemical Composition Of Ground Water In The Yucca Mountain Area, Nevada, 1971-84, Larry Benson, P. W. Mckinley

United States Geological Survey: Publications

Fifteen test wells in the Yucca Mountain area of southern Nevada have been sampled for chemical analysis at least once during 1971-84. Samples were obtained by pumping water from the entire well bore (composite sample), and, in three instances, by pumping from one or more isolated intervals within a well bore. Sodium was the most abundant cation, and bicarbonate was the most abundant anion in all water samples. Samples from the deep carbonate aquifer penetrated by well UE-25p#l contained higher relative concentrations of calcium and magnesium than did samples from overlying volcanic tuffs. Concentrations of the stable isotopes of oxygen …

A Bacteriological And Chemical Analysis Of Nonpoint Source Pollution In A Karst Aquifer Bowling Green, Kentucky, Wayne Green

Masters Theses & Specialist Projects

Monthly water samples collected from four sites in the Lost River Groundwater Basin, a shallow karst aquifer in the Bowling Green-Warren County area of Kentucky, represented samples from sites receiving conduit and diffuse flow. All sites were severely contaminated with bacteria, and on some occasions the surface water criteria for some heavy metals were exceeded.

Of the total 334 bacterial colonies identified 92.1% were verified as Escherichia coli by the API20E system. Acinetobacter calcoaceticus var. anitratum accounted for 2.10% of colonies; Citrobacter freundii for 0.30% Klebsiella pneumoniae for 0.90%; Klebsiella oxytoca, 0.90%; Citrobacter amalonaticus 0.30%; Enterobacter cloacae, 1.20%; …

Hydrochemical Data For The Truckee River Drainage System, California And Nevada, Larry V. Benson

United States Geological Survey: Staff Publications

Abstract

Surface-water samples were collected from the Truckee River drainage system during 1975, 1976, and 1981. Data resulting from chemical analyses of these samples, as well as certain other previously unpublished data, are tabulated in this report. The report contains the following hydrochemical data:

1. Chemical composition of 21 tributaries to Lake Tahoe and the Truckee River upstream from Farad, California (May and October 1971, and June 1972).

2. Chemical composition of the Truckee River at Tahoe City (January 1968-January 1975) and at Farad, California (January 1968-June 1980), and of the Little Truckee River upstream from Stampede Reservoir, California (January …

Chemical Composition Of Ground Water And The Locations Of Permeable Zones In The Yucca Mountain Area, Nevada, Larry Benson, J. H. Robison, R. K. Blankennagel, A. E. Ogard

United States Geological Survey: Publications

Ten wells in the Yucca Mountain area of southern Nevada have been sampled for chemical analysis. Samples were obtained during pumping of water from the entire well bore (composite sample) and in one instance by pumping water from a single isolated interval in well UE-25b#1. Sodium is the most abundant cation and bicarbonate the most abundant anion in all water samples. Although the general chemical compositions of individual samples are similar, there are significant differences in uncorrected carbon-14 age and in inorganic and stable-isotope composition. Flow surveys of seven wells performed using iodine-131 as a tracer indicate that ground-water production …