Geochemistry Commons^™

Investigation Of The Mechanisms For Mobilization Of Arsenic In Two Asr Systems In Southwest Central Florida, Gregg William Jones

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery (ASR) is a strategy in which water is injected into an aquifer when it is plentiful and pumped from the aquifer when water is scarce. An impediment to ASR in Florida is leaching of naturally-occurring arsenic from limestone of the Upper Floridan Aquifer System (UFAS) into stored water. The concentration of arsenic in surface water, which serves as the recharge water for many ASR systems, and native groundwater is usually much less than 3.0 µ/L. However, data from ASR wells in Florida show that arsenic in recovered water frequently exceeded the 10 µg/L maximum contaminant level …

Phosphorus Sorption Dynamics In Shallow Groundwater, Coastal Everglades, Florida, Usa, Hilary Flower

USF Tampa Graduate Theses and Dissertations

For this dissertation I studied phosphorus (P) sorption dynamics in the shallow groundwater of the southern Everglades. In particular, I examined how the ambient water type governs soluble reactive P (SRP) availability through adsorption/desorption reactions with the aquifer matrix. Chapter 2 investigated how P sorption dynamics of the mangrove root zone sediment are affected by high bicarbonate brackish groundwater compared to both fresh groundwater and saltwater. The results from chapter 2 show that the sediment exhibited exceptionally low sorption efficiency in the high bicarbonate brackish water, which would allow ambient water SRP concentration to be maintained at a higher level. …

Ocean Forcing Of Quaternary East Antarctic Ice Sheet Evolution: An Ice-Proximal Sedimentary Perspective, Michelle E. Guitard

USF Tampa Graduate Theses and Dissertations

Antarctica and the Southern Ocean play a critical role in Earth’s climate system. Antarctica’s ice sheets contain enough ice to raise global sea level by ~58 m, and the Southern Ocean distributes climate signals and nutrients to the major ocean basins and the deep ocean. Antarctica’s largest ice sheet, the East Antarctic Ice Sheet (EAIS), was considered stable compared to those in West Antarctica and the Antarctic Peninsula because it was thought to be grounded above sea level. However, subglacial topography now reveals vast submarine basins and measurements of ice velocity in the Pacific sector indicate marine-terminating outlet glacier thinning …

Hydrochemical Characteristics And Formation Mechanism Of Groundwater In The Liulin Karst System, Min Yang, Feng'e Zhang, Sheng Zhang, Miying Yin, Guoqing Wu

Sinkhole Conference 2015

The Liulin karst system is typical of hydrogeological systems in northwestern China, with a group of springs as the dominant mechanism for regional groundwater discharge. To reveal the hydrochemical formation mechanism of the Liulin karst groundwater system, we studied the hydrogeochemical processes of karst groundwater in aquifers at the base of the hydrogeological investigation. Then starting from the chemical composition of karst groundwater together with the recharge-runoff - discharge process of groundwater systems, we analyzed the solutes origin and the dissolved mineral facies of the groundwater chemical composition. The results showed that the anionic and cationic compositions of karst water …

Hydrologic And Geochemical Dynamics Of Vadose Zone Recharge In A Mantled Karst Aquifer: Results Of Monitoring Drip Waters In Mystery Cave, Minnesota, Daniel H. Doctor, E. Calvin Alexander Jr., Roy Jameson, Scott C. Alexander

Sinkhole Conference 2015

Caves provide direct access to flows through the vadose zone that recharge karst aquifers. Although many recent studies have documented the highly dynamic processes associated with vadose zone flows in karst settings, few have been conducted in mantled karst settings, such as that of southeastern Minnesota. Here we present some results of a long-term program of cave drip monitoring conducted within Mystery Cave, Minnesota. In this study, two perennial ceiling drip sites were monitored between 1997 and 2001. The sites were located about 90 m (300 ft) apart along the same cave passage approximately 18 m (60 ft) below the …

Tracer Studies Conducted Nearly Two Decades Apart Elucidate Groundwater Movement Through A Karst Aquifer In The Frederick Valley Of Maryland, Keith A. White, Michael K. Cobb, Thomas Aley, Ethan Weikel

Sinkhole Conference 2015

A pair of groundwater tracer studies at a single karst test site were completed 18 years apart. The results of these studies have provided evidence of both relatively rapid advective transport via conduits and an extreme capacity for dye storage and retardation. The tracer results, coupled with other subsurface investigation data, are used to develop a conceptual model for groundwater movement through this karst aquifer in the Frederick Valley of Maryland, as well as identify implications for remediation. Three fluorescent tracer dyes used in the initial study were detected in several background monitoring locations established for the second study conducted …

An Investigation Into Transitions In Clay Mineral Chemistry On Mars, Seth Gainey

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three studies investigating clay mineralogy on, or near the martian surface, with an introductory chapter, introducing and linking the three studies. Chapter two is on the subject of clay mineral synthesis, including Fe/Mg clay minerals which have been detected at multiple locations across the southern highlands. These Fe/Mg clay minerals have been previously interpreted as forming in anoxic/reducing environments, conducive to the preservation of organic matter. The results of this study suggest that the previous interpretation of Fe/Mg-rich clay as requiring anoxic/reducing conditions may not be accurate, as the minor presence of Mg (below what …

Biogeochemical Alteration Of Particulate Pyrogenic Organic Carbon (Pyc), Jason Matthew Stuart

Master's Theses

The resistance of plant derived pyrogenic organic carbon (pyC) to abiotic and biotic means of degradation has led to increased interest in the role of pyC as a potential carbon sink, as well as a strategy for sequestering atmospheric CO2 to mitigate excess carbon emissions. Though much research pertaining to the fundamental properties of pyC degradation have been performed in a controlled lab setting, there has been very little work regarding pyC degradation in a field setting where factors such as precipitation and temperature fluctuate seasonally. This work focuses on various degradation characteristics of two …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Quantitative Hermeneutics: Counting Forestructures On A Path From W.M. Davis To The Concept Of Multiple-Permeability Karst Aquifers, H. L. Vacher, Lee J. Florea

International Journal of Speleology

Hermeneutics is the theory of interpretation. One of its major components is recognizing prejudgments, or forestructures, that we bring to our objects of study. In this paper, we construct a historical narrative of the evolution of thinking about the role of caves in relation to groundwater flow in limestone, and we tabulate forestructures as they appear in the story. This account consists of three overlapping time periods: the before and after of an incident that repelled hydrogeologists and students of karst from each other in the middle of the 20^th century; a period, up to around the turn of …

Nanodiamond Extraction At A Potential Impact Location, Joel Kathan

DePaul Discoveries

Meteoritic or cometary impacts create the temperature and pressure conditions necessary to form nanodiamonds (NDs). The presence of extracted NDs from rocks of the time and locations of extinctions, fires, or known environmental changes are commonly used to confirm that a theorized cosmic impact occurred to trigger those events. Samples were obtained from an archeological site described in the Old Testament of the Bible as having been destroyed by the God of the Old Testament.† To see if the historical description of Biblical events might have been triggered by a cometary impact or explosion, an attempt was made to …

The State Of The Oligocene Icehouse World: Sedimentology, Provenance, And Stable Isotopes Of Marine Sediments From The Antarctic Continental Margin, Daniel William Hauptvogel

Dissertations, Theses, and Capstone Projects

The Oligocene Epoch (34-23 Ma) was a dynamic time in Antarctica, with previous ice volume estimates suggesting fluctuations from below 50 % up to 140 % of modern all while atmospheric CO₂ decreased from above 1,000 ppm in the Early Oligocene to near modern levels by the Late Oligocene. Most of what is known about the Oligocene Antarctic cryosphere however, is derived from distal sedimentary records that can only provide a generalized view of the cryospheric dynamics in Antarctica. To better understand regional differences in Antarctic glacial dynamics, proximal records are needed. This dissertation advances our understanding of these …

Geochemical Analysis Of Surface Materials Surrounding The Bautsch-Gray Mine Superfund Site Near Galena, Illinois, Ryan Plath

Geology: Student Scholarship & Creative Works

The Bautsch-Gray zinc and lead mine, near Galena, IL, was in operation from the early 1900s until closing in 1975. The mine’s tailings pile has documented elevated lead and zinc concentrations in the surface materials surrounding the site. Numerous floods have caused contaminated sediment to migrate off the mine tailings pile, across Blackjack Road and into an outwash basin, and towards Smallpox Creek. Since this site was designated an EPA priority list Superfund site in 2010, the EPA has conducted numerous remediation efforts. This study attempts to develop a better understanding of the contamination within the soils of the outwash …

Source Constraints Of Ore Metals In Mississippi Valley-Type Deposits In Central And Eastern Tennessee Using Pb Isotopes, Austin Moyers

Graduate Theses and Dissertations

The Mississippi Valley-Type (MVT) Central and East Tennessee (TN) Districts contain economically significant lead-zinc deposits that occur in the Early Ordovician carbonates of the Knox Group. Although both districts share similar host rock, have similar temperatures of formation, and typically fill open spaces of collapse breccias or replace their host carbonates, previous studies may suggest that these ores did not form from the same mineralizing fluids and may have different Pb sources. Nu Plasma MC-ICP-MS Pb isotopic analyses on sulfides from Central and East TN were conducted and the metal sources evaluated. Results were plotted on covariation diagrams with respect …

Using Kriging, Cokriging, And Gis To Visualize Fe And Mn In Groundwater, Crystal Johnson

Electronic Theses and Dissertations

For aesthetic, economic, and health-related reasons, allowable concentrations of iron (Fe) and manganese (Mn) found present in drinking water are 0.3 mg/L and 0.05 mg/L, respectively. Water samples taken from private drinking wells in the rural communities within Buncombe County, North Carolina contain amounts of these metals in concentrations higher than the suggested limits. This study focused on bedrock geology, elevation, saprolite thickness, and well depth to determine factors affecting Fe and Mn. Using ArcGIS 10.2, spatial trends in Fe and Mn concentrations ranges were visualized, and estimates of the metal concentrations were interpolated to unmonitored areas. Results from this …

Terrestrial Impacts Of The Central Atlantic Magmatic Province On Western Pangea, Todd Kenneth Knobbe

Graduate Theses and Dissertations

Earth's climate is predominantly controlled by the fluctuation of greenhouse gases, specifically CO2 and CH4, over geologic time. The late Triassic is a period of abrupt climate change that has been associated with a disruption to the global carbon cycle due the emplacement of the Central Atlantic Magmatic Province (CAMP). Evidence has shown that this global carbon cycle perturbation may be the culprit for the end-Triassic extinction. The Whitmore Point Member of the Moenave Formation is a lacustrine deposit with a disputed age of either late Triassic or early Jurassic and currently no absolute dating techniques can be applied to …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

On The Influence Of Ionic Strength On Radium And Strontium Sorption To Sandy Loam Soils, Brian A. Powell, Todd Miller, Daniel I. Kaplan

Journal of the South Carolina Academy of Science

Models which can estimate environmental transport of radioactive contaminants in natural and engineered systems are required to 1) deploy effective remediation strategies for contaminated sites, 2) design waste repositories for future waste streams, and 3) ensure protection of human and environmental health in all cases. These models require accurate transport parameters in order to correctly predict how these contaminants will move in the subsurface. This work aimed to determine more accurately the distribution coefficients for radium and strontium sorption to Savannah River Site (SRS) soils. Radium and strontium sorption to the soils was found to be highly dependent upon ionic …

Geochemical Assessment And Separation Of Source Waters In The Upper Boulder River Watershed Near Boulder, Mt, John Anderson

Graduate Theses & Non-Theses

Environmental samples were collected at three surface water sites between 5/21/2011 and 11/21/2014 along the Upper Boulder River near Boulder Montana. The sites were located at Bernice (within the mountain block), near the High Ore drainage (near the mountain block/basin transition), and at the USGS Gauging Station near Boulder, Montana (within the basin). The parameters measured in the field were SC, temperature, and alkalinity with occasional pH measurements. We collected samples for anions, cations, and stable isotopes in the catchment. We identified endmembers by sampling snow and groundwater and determined from available data an approximate endmember for rain, snow, and …

Origin And Quantification Of Diffuse Co2 And H2s Emission At Crater Hills, Yellowstone National Park, Peipei Lin

Dissertations, Master's Theses and Master's Reports - Open

At Crater Hills, a thermally-altered area adjoining the Sour Creek resurgent dome that is located within the Yellowstone Caldera, we characterized volatile emissions based upon our soil degassing measurements and soil gas chemistry in 2014 and fumarole gas chemistry in 2007 (Bergfeld et al., 2011). The investigation at Crater Hills on its diffuse gases isotopes and CO2, H2S emission improve our understanding on its gas emission mode – including total emission and spatial distribution, and contribute to a more accurate estimation of total CO2 emission at Yellowstone volcanic system. The total emission of CO2 interpolated by sequential Gaussian simulation method …

Morphological, Structural, And Spectral Characteristics Of Amorphous Iron Sulfates, Elizabeth Sklute, Heidi Jensen, Deanne Rogers, Richard Reeder

Department of Geosciences Faculty Publications

Current or past brine hydrologic activity on Mars may provide suitable conditions for the formation of amorphous ferric sulfates. Once formed, these phases would likely be stable under current Martian conditions, particularly at low- to mid-latitudes. Therefore, we consider amorphous iron sulfates (AIS) as possible components of Martian surface materials. Laboratory AIS were created through multiple synthesis routes and characterized with total X-ray scattering, thermogravimetric analysis, scanning electron microscopy, visible/near-infrared (VNIR), thermal infrared (TIR), and Mössbauer techniques. We synthesized amorphous ferric sulfates (Fe(III)2(SO4)3 · ~ 6–8H2O) from sulfate-saturated fluids via vacuum dehydration or exposure to low relative humidity (

The Effects Of Clay On Glycerol/Carboxylic Acid Polymerization: Implications Of Mineral Controls In Prebiotic Chemistry, Joseph T. Romero

Geology: Student Scholarship & Creative Works

Proto-enzymatic catalysis on early Earth is an important consideration in prebiotic chemistry research as it leads to the understanding of the emergence of the metabolic reaction networks. Contemporary enzymes are comprised of either organic or inorganic factors scaffolded by globular protein structure whereas we consider hyperbranched polyesters as a possible extant scaffold that is easier assembled than the peptide one. The goals of this project are to consider prebiotically plausible starting materials for such structure formation utilizing a subset of conditions for polymer synthesis involving the presence of mineral surfaces as well as temperature and hydration differential. As likely candidates …

Identification And Quantification Of Diffuse Fresh Submarine Groundwater Discharge Via Airborne Thermal Infrared Remote Sensing, Joseph T. Tamborski, A Deanne Rogers, Henry J. Bokuniewicz, J Kirk Cochran, Caitlin R. Young

Department of Geosciences Faculty Publications

Airborne thermal infrared (TIR) overflights were combined with shoreline radionuclide surveys to investigate submarine groundwater discharge (SGD) along the north shore of Long Island, NY between June 2013 and September 2014. Regression equations developed for three distinct geomorphological environments suggest a positive linear relationship between the rate of diffuse SGD and the spatial extent of the observed coastal TIR anomalies; such a relationship provides quantitative evidence of the ability to use TIR remote sensing as a tool to remotely identify and measure SGD. Landsat TIR scenes were unable to resolve any of the 18 TIR anomalies identified during the various …

Feldspathic Rocks On Mars: Compositional Constraints From Infrared Spectroscopy And Possible Formation Mechanisms, Deanne Rogers, Hanna Nekvasil

Department of Geosciences Faculty Publications

Rare feldspar-dominated surfaces on Mars were previously reported based on near-infrared (NIR) spectral data and were interpreted to consist of anorthosite or felsic rocks. Using thermal infrared (TIR) data over the feldspar detections with the largest areal extent in Nili Patera and Noachis Terra, we rule out felsic interpretations. Basaltic or anorthositic compositions are consistent with TIR measurements, but the geologic contexts for these regions do not support a plutonic origin. Laboratory NIR spectral measurements demonstrate that large plagioclase crystals (>~840 μm) can be detected in mixtures with as much as 50 vol % mafics, which is higher than …

Driftless Area Karst Of Northwestern Illinois And Its Effects On Groundwater Quality, Samuel V. Panno, Walton R. Kelly

Sinkhole Conference 2015

The bedrock aquifer of the Driftless Area of northwestern Illinois is Ordovician-age Galena Dolomite. Previous work by the authors and others showed that the geology and hydrogeology of this area fall well within the definition of karst. Bedrock in the study area has been shown to be extensively fractured and creviced; karst features in the county are dominated by solution-enlarged crevices from 0.4 inches to 3 feet wide within most road cuts and quarries examined. Other karst features include cover-collapse sinkholes ranging from 3 to 25 feet in diameter overlying Galena Dolomite, karst springs and crevice caves. A preliminary evaluation …

Trace Element Behavior During Coal Combustion: Insights From Cadmium And Zinc Isotope Analysis, Fotios Fouskas

Open Access Theses & Dissertations

Due to its low cost and abundance, coal has been pervasively used in recent decades to meet large energy demands worldwide. Coal combustion provides the dominant electrical source in the U.S and produces over 100 million tons of coal combustion products (CCPs) per year domestically. The disposal/beneficial use of CCPs has the potential to release toxic trace elements, including cadmium (Cd) and zinc (Zn), into the environment. High temperature combustion of coal changes both physical states and chemical properties of Cd and Zn compounds in CCPs. Related processes such as evaporation and condensation, can lead to mass-dependent fractionation of Cd …

The Environmental Effects Of Coal Fires, Trent Garrison

Theses and Dissertations--Earth and Environmental Sciences

There are thousands of subterranean coal fires in the world that, because of incomplete combustion, emit a wide variety of volatile and semivolatile organic compounds to the atmosphere, water, and soil at concentrations that could pose health risks to humans and wildlife. The main goals of this study were to (1) review methods that are used to characterize physical and chemical characteristics of coal-fire sites, (2) determine relationships between gas emissions and physical and chemical characteristics of coal-fire sites, using a combination of regression and multivariate statistical methods, and (3) determine the concentrations of volatile and semivolatile organic compounds in …

Fluvial Responses To Growth Faulting In The West Pearl River, Louisiana, Stephen A. Prosser

Theses and Dissertations--Earth and Environmental Sciences

The Pearl River Delta (PRD) in southeastern Louisiana is an actively deforming deltaic complex displaying surface and near-surface evidence of growth faulting. Active growth faults in these environments are rarely identified at the surface, in part because the downthrown blocks often experience increased rates of sediment deposition leading to an obscured and low-relief, or entirely absent, surface expression. Faulting can be expressed in fluvial systems as changes in channel gradient, which often result in coincident changes in channel sinuosity, migration rates, planform deflections, and/or ponding features within the deformed zone. The study area is focused on a meander bend of …

A Geochemical Investigation Of Co₂ Sequestration And Site Characterization At Two Missouri Locations, Robert Allen Swain

Masters Theses

"The feasibility of sequestering CO₂ in saline aquifers of Lamotte Formation sandstone was investigated at wells located near Thomas Hill power plant, Moberly, MO and Sioux City Power Plant in Florissant, MO. Governing factors of using aquifers for CO₂ disposal include water salinity, potential for carbonic acid buffering, rate of precipitation of carbonate minerals following CO₂ introduction into the host aquifer, and the integrity of the Davis and Derby-DoeRun shale as a trap rock to prevent migration of the CO₂ phase and carbonic acid into the overlying potable Ozark Aquifer.

Both in situ and laboratory methods …