Geochemistry Commons^™

Strontium Isotopic Signatures Of The Streams And Lakes Of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering In A Polar Climate, W. B. Lyons, Carmen A. Nezat, Larry V. Benson, Thomas D. Bullen, Elizabeth Y. Graham, Jesicca Kidd, Kathleen A. Welch, James M. Thomas

United States Geological Survey: Staff Publications

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different ⁸⁷Sr/⁸⁶Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system …

The Distribution Of Airborne Coal Dust In Soil Profiles Of Norfolk, Va And Its Implication For Arsenic Loading To These Soils, William Joseph Bounds

OES Theses and Dissertations

Norfolk, Virginia is home to the Northern Hemisphere's largest coal terminal the Lamberts Point Docks. The coal loading process of this terminal creates large amounts of coal dust, which subsequently is distributed throughout the local region by atmospheric transport and deposition. While the coal dust itself poses only minor health hazards, certain trace elements within the coal, particularly arsenic, may pose environmental as well as significant health hazards. Within coal, arsenic occurs primarily in the mineral pyrite. As pyrite in the coal dust is subsequently oxidized via exposure to the atmosphere and/or meteoric water, arsenic may be released to the …

Carbon Dynamics In Peat Bogs: Insights From Substrate Macromolecular Chemistry, Kuder Tomasz, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The macromolecular compositions of subfossil plants from boreal Sphagnum bogs and restiad bogs (New Zealand) have been studied by pyrolysis-gas chromatography/mass spectrometry to evaluate the extent of degradation in the anoxic zone (catotelm) of a peat bog. Degradation of vascular plant polysaccharides was apparent only into the upper catotelm. Sphagnum was degraded more slowly than vascular plants, but no cessation of degradation was observed. The inferred rate of degradation varied depending on type of plant, extent of aerobic, precatotelmic degradation, and mode of litter deposition (rooting versus at the surface). Environmental forcing on anaerobic carbon dynamics would potentially be largest …

An Environmental Geochemical Study Of Connecticut Marsh Sediments, Nicole A. Heller, Michael A. Kruge, Johan C. Varekamp, Tabitha Zierzow

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Core material from Spartina-dominated Housatonic and Connecticut River estuarine sites (ranging from low to high marsh) were investigated in order to test the hypothesis that organic and inorganic pollutants preferentially accumulate in the low marsh environment. Radiometric data indicate that the low marsh setting experienced sedimentation rates an order of magnitude greater than that of the mid to high marsh. The low marsh sediments from the Housatonic tend to have significantly higher concentrations of trace metals (e.g., Cu and Zn, likely contributed by brass mills formerly active upstream). Petrographic examination of the samples under reflected white and blue light …

Biogeochemistry And Contaminant Geochemistry Of Marine And Estuarine Sediments, New Haven, Connecticut (Usa), Michael A. Kruge, Gaboury Benoit

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The urbanized shore areas of Long Island Sound in the vicinity of New Haven, Connecticut (USA) have a long history of exposure to point and non-point sources of pollution, New Haven having been one of the birthplaces of the industrial revolution. As an unintended consequence of such activities, the region's sedimentary systems have incorporated a complex mixture of organic and inorganic contaminants. With its long and varied pollution history and the multiplicity of sedimentary environments (fluvial, estuarine, intertidal, marsh, etc.) present in a compact geographical area, the region is ideal natural laboratory for field testing new contamination assessment techniques. The …

Multibeam Sonar Backscatter Lineaments And Anthropogenic Organic Components In Lacustrine Silty Clay, Evidence Of Shipping In Western Lake Ontario, C F Michael Lewis, L A. Mayer, Prasanta K. Mukhopadhyay, Michael A. Kruge, John P. Coakley, M D. Smith

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A multibeam sonar survey (95 kHz) covering more than 500 km² of western Lake Ontario revealed anomalous lineaments of relatively high backscatter. The lineaments did not align with or parallel the most prominent structural zones beneath the lake as expected. Instead, the principal lineaments lay on lines between ports on opposite sides of the lake, especially between Toronto and Welland Canal, and Toronto and Niagara River mouth. As the lineaments underlie current and historical shipping routes used during the steamship era, they are interpreted as an acoustic response to shipping debris cumulated in the near-surface bottom sediment. An exploratory …

Molecular Organic Geochemistry Of New York Bight Sediments. Sources Of Biogenic Organic Matter And Polycyclic Aromatic Hydrocarbons, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

As part of a multidisciplinary evaluation of the environmental impact of waste disposal in the New York Bight, a preliminary effort was undertaken to assess the molecular geochemistry of its sedimentary organic matter (OM). For this initial phase of the study, samples were taken from two New York Bight cores collected outside the area of known dumping [in Sandy Hook Bay, NJ], to establish the environmental context for future work on sediments from within dumpsite zones. The method employed was flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), which is an organic microanalysis technique suitable for solid samples, in this case dried, raw …

Environmental And Botanical Controls On Peatification - A Comparative Study Of Two New Zealand Restiad Bogs Using Py-Gc/Ms, Petrography And Fungal Analysis, Tomasz K. Kuder, Michael A. Kruge, J C. Shearer, S L. Miller

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study shows that chemical properties of two restiad species, Empodisma minus and Sporadanthus traversii, may contribute to their success as peat-formers in a climate of the North Island of New Zealand which is not conducive to raised mire development. Unlike Sphagnum, the equivalent northern hemisphere peat-former, restiads possess lignin in their tissues. In addition, the presence of non-lignin polyphenols (including tannins and phenolic acids) in restiads may be an important factor in peat formation due to the allelopathic decay retardation. Patterns of degradation of plant biopolymers have been examined and the pathway of degradation of monocotyledons (loss …

A Molecular Evaluation Of Contaminants And Natural Organic Matter In Surface Sediments From Western Lake Ontario, Michael A. Kruge, Prasanta K. Mukhopadhyay, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) analysis of bottom sediment from Lake Ontario was shown to be effective in assessing organic contaminants, especially attractive as it is a rapid technique requiring little sample preparation. Pyrolyzates of samples richer in organic matter (OM) were relatively enriched in aliphatic hydrocarbons and pyrrolic nitrogen compounds, while leaner samples were more aromatic and pyridinic. Alkylbenzene and alkylphenol distributions in the pyrolyzates were most compatible with derivation from aquatic (algal, bacterial) OM. The organonitrogen compounds indicated the presence of degraded proteinaceous material from aquatic sources and/or sewage. Normal and polycyclic aromatic hydrocarbon distributions indicate, at least in …

Estimation Of Groundwater Velocities From Yucca Flat To The Amargosa Desert Using Geochemistry And Environmental Isotopes, Ronald L. Hershey, Steve Y. Acheampong

Publications (WR)

Geochemical modeling techniques were applied to groundwater flowpaths from Yucca Flat on the Nevada Test Site (NTS) to the Amargosa Desert, south of the NTS to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The groundwater flowpaths examined considered flow in the carbonate aquifer beneath Yucca and Frenchman flats mixing with flow from carbonate aquifers east and southeast of the NTS and discharging at wells south of the NTS border. The approach used the computer codes WATEQ4F and NETPATH to calculate chemical speciation, determine the saturation state of mineral phases, and simulate mixing and the …

Application Of Environmental Organic Petrology And Geochemistry To Fingerprint Organic Pollutants In The Recent Sediments Of Lake Ontario, Prasanta K. Mukhopadhyay, Michael A. Kruge, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Selected surface sediment samples (sediment depth 0-10 cm) collected in the Niagara basin (western Lake Ontario) were chosen for organic matter characterization using organic petrological and geochemical techniques normally reserved for the study of coal, petroleum source rock and crude oil. The study was performed to assess the effectiveness of these techniques in discriminating between natural and anthropogenic organic matter and to determine the extent of organic pollution of the lake sediments. The organic carbon contents of the samples vary from 1.5 to 3.5%, with upper layer (0-5 cm) samples have higher TOC values than those from the lower layer …

Flash Pyrolysis Of Anthropogenic And Natural Organic Matter In Polluted Sediments, Sami T. Abdel Bagi, Michael A. Kruge, Gary L. Salmon

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

INTRODUCTION - Combustion products along with spilled petroleum and industrial chemicals contribute to environmental degradation by contaminating soils and sediments. Such anthropogenic organic matter (OM), if preserved in sediments, can serve an archival function, documenting the local, history of industrial pollution. Christensen and Zhang (1993) determined the sources of polycyclic aromatic hydrocarbons (P AH) to Lake Michigan from sedimentary records, finding that coal combustion was a major source for PAHs in these sediments. Bodzek and Luks-Betlej (1993) reported that atmospheric deposition is the main source of PAH in soils of the heavily industrialized Upper Silesia region of Poland. Smith and …

The Speciation Of Dissolved Uranium In Marine Waters, Darrin Kent Mann

OES Theses and Dissertations

Uranium has been used extensively for quantifying geochemical processes in the marine environment. Due to its low concentration, about 3.3 μg/1, some form of preconcentration is required for analysis. The two most widely used pre-concentration schemes are co-precipitation with iron hydroxide, and chelating ion exchange chromatography. These methods were developed by following the behavior of inorganic uranium isotopes and seemed to give identical results. However, when used for trace metal analysis, these methods have been shown to extract different fractions from the same sample. Chelex-100 resin removes only inorganic or weakly bound trace metals from a solution, while the precipitates …

Speciation Of Heteroatoms In Coal By Sulfur- And Nitrogen-Selective Techniquestrogen-Selective Techniques, Stephen R. Palmer, Michael A. Kruge, Edwin J. Hippo, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The peroxyacetic acid oxidation products from a series of coals of organic sulfur content 0.5-9.8 wt% were examined. The distributions of organic S and N compounds were determined by gas chromatography with sulfur-selective flame photometric and nitrogen-selective thermionic specific detection respectively. A selected sample was also examined in greater detail using low-voltage high-resolution mass spectrometry. The distribution of organic sulfur compounds in the oxidation products was remarkably similar for all the coals. The number of sulfur compounds detected was small compared with that of organic nitrogen compounds detected. This suggests that the sulfur chemistry of coal is considerably simpler than …

Epa's Map Of Radon Zones, Nebraska, Sharon W. White, Lisa Ratcliff, Kirk Maconaughey, R. Thomas Peake, Dave Rowson, Steve Page, Linda C. S. Gundersen, R. Randall Schumann, James K. Otton, Doug Owen, Russell Dubiel, Kendell Dickinson, Sandra L. Szarzi

United States Environmental Protection Agency: Publications

Sections 307 and 309 of the 1988 Indoor Radon Abatement Act (IRAA) direct EPA to identify areas of the United States that have the potential to produce elevated levels of radon. EPA, the U.S. Geological Survey (USGS), and the Association of, American State Geologists (AASG) have worked closely over the past several years to produce a series of maps and documents which address these directives. The EPA Map of Radon Zones is a compilation of that work and fulfills the requirements of sections 307 and 309 of IRAA. The Map of Radon Zones identifies, on a county-by-county basis, areas of …

Precipitation Dynamics In Kalamazoo, Sw Michigan: A Stable Isotope Perspective, Madhav V. Machavaram

Masters Theses

No abstract provided.

Considerations Of Variations In Ionospheric Field Effects In Mapping Equatorial Lithospheric Magsat Magnetic Anomalies, Dhananjay Ravat, W. J. Hinze

Earth and Environmental Sciences Faculty Publications

Longitudinal, seasonal, and altitude‐dependent variability of magnetic fields is investigated in equatorial latitudes to determine their effect on the isolation of lithospheric Magsat magnetic anomalies. An estimate of ‘ionospheric effect’ was compiled by averaging the total intensity Magsat anomalies as a function of dip latitudes (called ‘dip‐latitude averages’) from dawn and dusk data sets grouped according to longitudes, time (months), and altitudes. Unanticipated seasonal variations were observed in dusk Magsat data over the Indian sector that may contribute to an improved understanding of the equatorial electrojet. The amplitudes of the dawn dip‐latitude averages are small in comparison to the dusk …

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Characterization Of Organic Sulfur Compounds In Coals And Coal Macerals, Stephen R. Palmer, Edwin J. Hippo, Michael A. Kruge, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Peroxyacetic acid oxidation has been used to investigate the type and distribution of organic sulfur species in samples of vitrinite, sporinite and inertinite, separated from the Herrin No.6 and an Indiana No.5 coal seam. It was established that organic sulfur species were selectively preserved during oxidation and their analysis led to some of the first sulfur-33 NMR spectra obtained for coal. The effects of maceral separation processes on model compounds were also studied. Results from our studies support the following conclusions: 1). Different macerals have different distributions and types of organic sulfur species. 2). Organic sulfur compounds in coal occur …

Mining In Maine : Past, Present, And Future, Carolyn A. Lepage

Maine Collection

Mining in Maine : Past, Present, and Future

by Carolyn A. Lepage, Michael E. Foley, and Woodrow B. Thompson

Maine Geological Survey, Department of Conservation, Augusta, Me., 1990.

Contents: Introduction / The Early Years: Pre-Civil War / The Civil War to World War II / The War Years of the 1940's / The Postwar Years: 1940's to 1960 / The 1960's / The 1970's / Maine Mineral Resources Association / The 1980's / Current Mining and Exploration / Future Potential / Acknowledgments / References

Leachate Monitoring In Naturally Saline Groundwater Chesapeake Landfill Chesapeake Virginia, T. Britt Mcmillan

OES Theses and Dissertations

Groundwater chemistry around the Chesapeake municipal landfill was monitored over a one year period. Ten sample sites as well as two surface water sites were used to monitor water quality. Two wells, one at 3 m and the other at 10 m were located at each site. Surface water samples were taken from the Elizabeth River, north of the landfill, and a tidal channel, west of the landfill. Seven groundwater sites were downgradient of the landfill and three sites were upgradient (control sites).

The landfill overlies a tidal marsh, approximately 100 m south of the intracoastal waterway (Elizabeth River). Dredge …

A Bacteriological And Chemical Analysis Of Nonpoint Source Pollution In A Karst Aquifer Bowling Green, Kentucky, Wayne Green

Masters Theses & Specialist Projects

Monthly water samples collected from four sites in the Lost River Groundwater Basin, a shallow karst aquifer in the Bowling Green-Warren County area of Kentucky, represented samples from sites receiving conduit and diffuse flow. All sites were severely contaminated with bacteria, and on some occasions the surface water criteria for some heavy metals were exceeded.

Of the total 334 bacterial colonies identified 92.1% were verified as Escherichia coli by the API20E system. Acinetobacter calcoaceticus var. anitratum accounted for 2.10% of colonies; Citrobacter freundii for 0.30% Klebsiella pneumoniae for 0.90%; Klebsiella oxytoca, 0.90%; Citrobacter amalonaticus 0.30%; Enterobacter cloacae, 1.20%; …

Peat Resources Of Maine - Volume 4: Southern And Western Maine, Cornelia C. Cameron, Michael K. Mullen, Carolyn A. Lepage

Maine Collection

Peat Resources of Maine - Volume 4: Southern and Western Maine

by Cornelia C. Cameron, Michael K. Mullen, Carolyn A. Lepage & Walter A. Anderson

Bulletin 31 - Maine Geological Survey, Department of Conservation, Augusta, Maine (1984).

Preparation of this report was supported by funds furnished by the U.S. Department of Energy, Grant No. DE-FG18-79ET14690, the Maine Office of Energy Resources, the Maine Geological Survey, and the U.S. Geological Survey.

Contents: Introduction / The Maine Peat Resource Evaluation Program / Geologic Setting of Maine Peat Deposits / Formation of Peat Deposits in Maine / Methods of Investigation / Identification of …

Hydrochemical Data For The Truckee River Drainage System, California And Nevada, Larry V. Benson

United States Geological Survey: Staff Publications

Abstract

Surface-water samples were collected from the Truckee River drainage system during 1975, 1976, and 1981. Data resulting from chemical analyses of these samples, as well as certain other previously unpublished data, are tabulated in this report. The report contains the following hydrochemical data:

1. Chemical composition of 21 tributaries to Lake Tahoe and the Truckee River upstream from Farad, California (May and October 1971, and June 1972).

2. Chemical composition of the Truckee River at Tahoe City (January 1968-January 1975) and at Farad, California (January 1968-June 1980), and of the Little Truckee River upstream from Stampede Reservoir, California (January …

Input And Distribution Of Sewage Derived Sedimentary Material Adjacent To Chesapeake-Elizabeth Sewage Outfall, Virginia Beach, Virginia, Robert Carroll Brown

OES Theses and Dissertations

The concentrations of coprostanol and hydrocarbons were measured in the effluent from the Chesapeake-Elizabeth sewage treatment plant and surface sediments from the area surrounding the effluent discharge site. Most of the coprostanol (>84%) and hydrocarbons (>91%) were associated with particulates in the effluent. Some of these particles were incorporated into the sedimentary column within the study area, while some may have escaped from the area.

The study area is found to be a dynamic area where changes in the percentage and distribution of fine-grained sediments occur over periods of months. The movement of fine-grained sediments is an important …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …

An Ecological Analysis Of Relic Diatoms In Sediments Of Las Vegas Bay, Lake Mead, David Ross Hetzel

Publications (WR)

Relic diatoms in sediments of the inner Las Vegas Bay, near the Las Vegas Wash sewage inflow, were examined in order to assess historic trophic conditions in this area of Lake Mead. Diatom sedimentation rates and ratios of Araphidineae/Centrales (A/C) diatom groups were determined from sediment cores collected in the old wash channel 1.5 km from the sewage inflow (station 2), in a small cove 1.5 km further downstream (station 3) and in an adjacent embayment off Gypsum Wash (station 4). Diatom sedimentation rates generally increased from the bottom to the top of each core, but pronounced minima existed at …

Lithologic And Structural Controls On Karst Landforms Of The Mitchell Plain, Indiana, And Pennyroyal Plateau, Kentucky, Frederick Jennings Woodson

All-Inclusive List of Electronic Theses and Dissertations

Karst features in Harrison County, Indiana, and the Mammoth Cave region, Kentucky, are profoundly influenced by lithology and structure. In the Sinkhole Plain two classes of sinkholes, shallow solutional and deeper subsidence, differ in morphology, origin, age, distribution, and density. Distributions of the two kinds of sinkholes reflect the outcrop pattern of specific lithostratigraphic units. Broad shallow dolines (Ste. Genevieve-type sinks) develop on the Horse Cave Member of the St. Louis Limestone and on the Ste. Genevieve, Girkin, and Paoli Limestones. Innumerable steeper-sided subsidence and collapse depressions (St. Louis-type sinkholes) form on the Corydon Chert Member, lower St. Louis Limestone, …

Influence Of Las Vegas Wash Density Current On Nutrient Availability And Phytoplankton Growth In Lake Mead, John R. Baker, Larry J. Paulson

Publications (WR)

Density currents are commonly formed in reservoirs because of temperature or salinity induced density differences between inflowing and receiving waters. Anderson and Pritchard (1951) were among the first to demonstrate this in their investigations of density currents in Lake Mead. They found that the Colorado River formed an underflow in Lake Mead during the winter, an overflow in the spring and an interflow in the summer and fall. Wunderlich and Elder (1973) have since described the hydromechanics of these types of flow patterns, and density currents have been reported for several other large reservoirs (Carmack et al. 1979, Johnson and …

Chemistry Of The Spring Waters Of The Ouachita Mountains Excluding Hot Springs, Arkansas, George H. Wagner, Kenneth F. Steele

Arkansas Water Resources Center Technical Reports

This report is based on the chemical analysis of the waters from 93 springs and 9 wells. Springs, when free from metal plumbing, provide an uncontaminated source of the ground water and it was desired to obtain water uncontaminated with metals. A few wells were added to the list, usually because of their unique location in the sampling grid.