Geochemistry Commons^™

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Seasonal Transport Of Dissolved Inorganic Carbon And Total Alkalinity Across The Louisiana Shelf, Michelle M. Anderson

LSU Master's Theses

Rivers and wetlands are a major source of terrestrial derived carbon for coastal ocean margins. Unfortunately, Louisiana’s wetlands are threatened by ongoing high rates of erosion, deterioration, and unprecedented rates of river water discharge that changes seasonally, leading to a net loss of terrestrial carbon into the northern Gulf of Mexico (nGOM). There exists a current lack of understanding about the distribution of dissolved inorganic carbon (DIC) and total alkalinity (TAlk) within the shallowest regions of the Louisiana shelf. Even less is known about how the transport of DIC alters seasonally with changes in river outflow and shelf currents. Quantifying …

An Estimation Of Lower Tropospheric Mixing Derived From Inverse Modeling Of Boundary Layer Water Vapor Isotopologues On Graciosa Island, Azores, Jacquelyn M. Delp

Earth and Planetary Sciences ETDs

Recent studies have shown water vapor isotopologues to be sensitive tracers of mixing processes that govern low-cloud feedback in climate models. In this study, we develop an inverse model (MBL Mix inverse model) that uses one year of isotope and humidity observations from Graciosa Island, Azores to estimate mixing for four seasons. We show the dry end-member of the model, the lower free troposphere (LFT), can be represented using Rayleigh fractionation. Isotope observations from Graciosa Island are compared to other field locations to discuss controls on isotopic variability other than mixing. Output from the MBL Mix inverse model shows the …

The Evolution Of The El Niño-Southern Oscillation And Tropical Pacific Climate Across The Last Deglaciation, Ryan Hunter Glaubke

OES Theses and Dissertations

The El Niño – Southern Oscillation (ENSO) is the largest interannual component of Earth’s climate system, capable of exerting significant influence over global climate patterns that affect communities around the globe. Nevertheless, a comprehensive understanding of the ENSO system and its relationship to tropical Pacific climate dynamics remains unclear. Although new paleoceanographic proxies have shown promise in in their ability to constrain past ENSO change, little is known about how ENSO varied in response to millennial-scale climate events over the last 25,000 years. Here, I present new records of tropical Pacific mean state and ENSO variability over the last 25,000 …

Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes

International Journal of Speleology

An important step in paleoclimate reconstructions based on vadose cave carbonate deposits or speleothems is to evaluate the sensitivity of the cave environment and speleothems to regional climate. Accordingly, we studied four caves, located at different altitudes along the western flank of Mount-Lebanon (Eastern Mediterranean). The objectives of this study are to identify the present-day variability in temperature, pCO₂, and water isotopic composition and to assess the possible influence of the altitudinal gradient on cave drip waters and cave streams. We present here an overview of the spatial variability of rainwater based on local and regional data, and …

Isolution 1.0: An Isotope Evolution Model Describing The Stable Oxygen (Δ18O) And Carbon (Δ13C) Isotope Values Of Speleothems, Michael Deininger, Denis Scholz

International Journal of Speleology

Stable oxygen and carbon isotope ratios (δ¹³C and δ¹⁸O) are the most applied climate and environmental proxies in speleothems allowing to infer past changes in cave drip water δ¹³C and δ¹⁸O related to climate and environmental variations from above the cave. However, disequilibrium isotope fractionation processes can modify δ¹³C and δ¹⁸O values in speleothems, which is in most cases difficult to estimate due to inter-dependencies on various cave specific parameter. To better understand the effect of these disequilibrium isotope fractionation processes proxy system models were developed in recent …

Biodiversity And Distribution Of Benthic Foraminifera In Harrington Sound, Bermuda: The Effects Of Physical And Geochemical Factors On Dominant Taxa, Nam Le

Honors Theses

Harrington Sound, Bermuda, is a nearly enclosed lagoon acting as a subtropical/tropical, carbonate-rich basin in which carbonate sediments, reef patches, and carbonate-producing organisms accumulate. Here, one of the most important calcareous groups is the Foraminifera. Analyses of common benthic orders, including miliolids (Quinqueloculina and Triloculina spp.) and rotaliids (Homotrema rubrum, Elphidium spp., and Ammonia beccarii), are essential in understanding past and present environmental conditions affecting the island's coastal environment. These taxa have been studied previously; however, factors explaining their individual patterns of abundance in the Sound are not well detailed. The goal of this study is …

Stable Isotope Geochemistry Of Bioapatite, Amanda E. Drewicz

Boise State University Theses and Dissertations

The Cenozoic Era was a time period where dynamic shifts in climate created for both warm-wet greenhouse environments of the mid-Miocene Climatic Optimum (MMCO), and cool-dry, glacial periods of the late Pleistocene. The Cenozoic is close to our own time period, and although past climate reconstructions cannot be used as direct analogs for future climate change, understanding previous environmental responses can help inform policy surrounding future climate change. Presented here are climate reconstructions of the interior western United States, from two different geologic time periods. Each had a different climate, that differed greatly from modern day environments. The use of …

Ice And Guano Deposits In El Malpais Lava Tubes: Potential Paleoclimate Archives For The Southwest United States, Dylan S. Parmenter

USF Tampa Graduate Theses and Dissertations

Three ice cores and one guano core were obtained from lava tubes in El Malpais National Monument, New Mexico, in the Southwest United States. A large hiatus in the Bat Cave guano record, resulting from mining activities in the early 1900's, left us with only ~50 years of data (from AD 1955-2006) to use in analysis. 13C values in guano (-18 to -11.6‰) primarily fall within the range of C4 plants, and likely indicate a tendency of Tadarida brasiliensis to feed on insects over grasslands to the North or South of the park. Variations in 13C values for this period …

Review Of Curbing Catastrophe: Natural Hazards And Risk Reduction In The Modern World, Kira H. Hamman

Numeracy

Timothy H. Dixon. 2017. Curbing Catastrophe: Natural Hazards and Risk Reduction in the Modern World. (New York, NY: Cambridge University Press) 300 pp. ISBN 978-1108113663.

In Curbing Catastrophe, Timothy H. Dixon explores commonalities among natural disasters like Hurricane Katrina, the 2010 earthquake in Haiti, and the meltdown at Fukushima. He identifies communication failure between scientists and policy makers as a major culprit in the devastation that results from such events and offers strategies for improving that communication. He includes optional in-depth scientific and quantitative examinations of the events and the resulting devastation, making the book appropriate for use …

A Novel Multiproxy Approach To Reconstructing Sea Surface Temperature In The Southwestern Gulf Of Mexico, Marissa Anne Vara

LSU Master's Theses

Coral Sr/Ca is a widely-used proxy for sea surface temperature (SST); however, discrepancies in the coral Sr/Ca-SST relationship among colonies of the same species makes uncertainty in absolute temperature reconstructions larger than the climate signal yet climate variability studies are possible. Furthermore, the riverine input of terrestrial carbonate weathering products to the coastal waters can disrupt the coral Sr/Ca-SST signal by changing local seawater chemistry. This study evaluates the fidelity and reproducibly of coral SST proxies (Sr/Ca, Li/Ca, Mg/Li, Sr-U, Mg/Ca, and U/Ca) and a riverine-upwelling proxy (Ba/Ca) in four Orbicella faveolata colonies in two reefs offshore from Veracruz, Mexico …

Resolving Chronological And Temperature Constraints On Antarctic Deglacial Evolution Through Improved Dating Methodology, Cristina Subt

USF Tampa Graduate Theses and Dissertations

In order to determine the timing of Antarctic ice sheet retreat and advance during the Late Quaternary, various tools are used to measure the age of marginal marine sediments. Carbonate 14C dating is a well-established approach, but requires foraminiferal microfossils, shells or other carbonate materials that are rare in most Antarctic regions, and may also suffer from vital effects, which can result in variability of up to 500 years in living organisms. Bulk acid insoluble organic (AIO) 14C dates are frequently as an alternative, but this approach works best where high productivity and sedimentation rates reign, and not too well …

Paleoenvironmental Reconstruction Using Coral Microatolls (Sp. Siderastrea Siderea) From The Gulf Of Gonâve, Haiti, Gilman Reno Ouellette Jr.

LSU Doctoral Dissertations

Natural and anthropogenic climate changes present unique and serious risks to society. In order to plan and implement adaptation and mitigation strategies successfully, regional manifestations of broad-scale climate changes must be understood robustly. The Caribbean region contains part of the Western Hemisphere Warm Pool (WHWP), a major sea surface temperature (SST) feature that plays a key role in North Atlantic climate. Climate variability in the Caribbean is captured poorly by climate models, due in part to a lack of continuous, multidecadal instrumental climate records from the region. I explored three research questions in this dissertation: Does non-systematic bias exist in …

Nuclear Weapons In A Changing Climate: Probability, Increasing Risks, And Perception, Adam Liska, Tyler R. White, Eric Holley, Robert J. Oglesby

Adam Liska Papers

Many people tend to think that the outcome of any nuclear weapons use today will result in an escalatory situation with apocalyptic outcomes for the countries involved. Yet many factors are increasing the probability of the limited use of nuclear weapons (e.g., 1 to 20 warheads) in a range of conflict scenarios. Previous atmospheric model simulations of regional nuclear conflicts employing many relatively small bombs have been estimated to cause a global “nuclear autumn,” with great reductions in agricultural productivity, stratospheric ozone loss, and spread of hazardous radioactive fallout. The totality of these effects would result in widespread damage …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Quantity Trumps Quality: Bayesian Statistical Accumulation Modeling Guides Radiocarbon Measurements To Construct A Chronology In Real-Time, Devon Robert Firesinger

USF Tampa Graduate Theses and Dissertations

The development of an accurate and precise geochronology is imperative to understanding archives containing information about Earth’s past. Unable to date all intervals of an archive, researchers use methods of interpolation to approximate age between dates. Sections of the radiocarbon calibration curve can induce larger chronological uncertainty independent of instrumental precision, meaning even a precise date may carry inflated error in its calibration to a calendar age. Methods of interpolation range from step-wise linear regression to, most recently, Bayesian statistical models. These employ prior knowledge of accumulation rate to provide a more informed interpolation between neighboring dates. This study uses …

Spatial Patterns Of Sea Level Variability Associated With Natural Internal Climate Modes, Weiqing Han, Gerald A. Meehl, Detlef Stammer, Aixue Hu, Benjamin Hamlington, Jessica Kenigson, Hindumathi Palanisamy, Philip Thompson

OES Faculty Publications

Sea level rise (SLR) can exert significant stress on highly populated coastal societies and low-lying island countries around the world. Because of this, there is huge societal demand for improved decadal predictions and future projections of SLR, particularly on a local scale along coastlines. Regionally, sea level variations can deviate considerably from the global mean due to various geophysical processes. These include changes of ocean circulations, which partially can be attributed to natural, internal modes of variability in the complex Earth's climate system. Anthropogenic influence may also contribute to regional sea level variations. Separating the effects of natural climate modes …

Testing Of The Late-Ordovician Pre-Gice Warm Water Carbonate Hypothesis In Alabama, Brandon Euker, Stacey Law

Senior Honors Projects, 2010-2019

The Guttenberg Carbon Isotope Excursion (GICE) (uppermost Sandbian-lower Katian, Late Ordovician) has been suggested to represent the transition from a Cambrian-Ordovician greenhouse world to Late Ordovician icehouse world. This transition is thought to coincide with a proposed shift from deposition of warm water carbonate rocks to cool water carbonate rocks in the North American midcontinent. We used oxygen isotopes (d¹⁸O) of conodonts to test the idea that the rocks below the GICE interval represent a consistently warm environment. Conodonts were isolated from samples of the Chickamauga Group collected at the Tidwell Hollow section in Blount County, AL, from …

Ocean Forcing Of Quaternary East Antarctic Ice Sheet Evolution: An Ice-Proximal Sedimentary Perspective, Michelle E. Guitard

USF Tampa Graduate Theses and Dissertations

Antarctica and the Southern Ocean play a critical role in Earth’s climate system. Antarctica’s ice sheets contain enough ice to raise global sea level by ~58 m, and the Southern Ocean distributes climate signals and nutrients to the major ocean basins and the deep ocean. Antarctica’s largest ice sheet, the East Antarctic Ice Sheet (EAIS), was considered stable compared to those in West Antarctica and the Antarctic Peninsula because it was thought to be grounded above sea level. However, subglacial topography now reveals vast submarine basins and measurements of ice velocity in the Pacific sector indicate marine-terminating outlet glacier thinning …

The Monica (Monitoring Of Ice Within Caves) Project: A Multidisciplinary Approach For The Geophysical And Paleoclimatic Characterization Of Permanent Ice Deposits In The Southeastern Alps, Renato R. Colucci, Emanuele Forte, Barbara Stenni, Marco Basso Bondini, Mauro Colle Fontana, Costanza Del Gobbo, Daniele Fontana, Doriana Belligoi, Valter Maggi, Marco Filipazzi

The International Workshop on Ice Caves

On days 30 September and 1-2 October 2013, a 7.8 m long ice core has been extracted from a permanent ice cave deposit in the Southeastern Alps (Vasto’s cave, Mt.Canin - Julian Alps). Each 20 to 100 cm long section of the ice core have been immediately stored in plastic bags and preserved thanks to dry ice. The ice samples, thanks to the helicopter, has been subsequently brought on valley and promptly stored in a refrigerated van, made available by BoFrost. Thus the ice cores has been transported intact to the EUROCOLD laboratory in Milan. These operations have been carried …

A Multi-Proxy Approach To Understanding Abrupt Climate Change And Laurentide Ice Sheet Melting History Based On Gulf Of Mexico Sediments, Clare Carlisle Williams

USF Tampa Graduate Theses and Dissertations

During the last deglaciation (ca. 24-10 ka thousand years ago (ka)), the North American Laurentide Ice Sheet (LIS) was a major source of meltwater to the Arctic Ocean, North Atlantic Ocean, and the Gulf of Mexico (GOM), and it is hypothesized that meltwater routing played an important role in regulating Late Quaternary millennial-scale climate variability, via its influence on Atlantic Meridional Overturning Circulation (AMOC). For example, the meltwater routing hypothesis predicts that a rerouting of meltwater from the GOM to the North Atlantic and/or Arctic Oceans resulted in a decrease of North Atlantic Deep Water (NADW) formation and subsequent cooling …

Modern To Late Pleistocene Stable Isotope Climatology Of Alaska, Alison Sloat

UNLV Theses, Dissertations, Professional Papers, and Capstones

Understanding modern controls on climate is necessary to interpret past climatic conditions. This project investigated the modern controls on δ18O and δD values in Alaskan surface waters to interpret the controls on Late Pleistocene climate variability. ArcGIS was used to develop an isoscape of modern δ18O and δD values of over 400 surface water samples collected across Alaska and the Yukon. It was found that winter temperature and precipitation have the greatest controls on δ18O and δD values in Alaska, resulting in high δ18O values along the coast of the Gulf of Alaska and low values inland toward Central Alaska. …

Data-Driven Diagnostics Of Terrestrial Carbon Dynamics Over North America, Jingfeng Xiao, Scott V. Ollinger, Steve Frolking, George Hurtt, David Y. Hollinger, Kenneth J. Davis, Yude Pan, Xiaoyang Zhang, Feng Deng, Jiquan Chen, Dennis D. Baldocchi, Beverly E. Law, M. Altaf Arain, Ankur R. Desai, Andrew D. Richardson, Ge Sun, Brian Amiro, Hank Margolis, Lianhong Gu, Russell L. Scott, Peter D. Blanken, Andrew E. Suyker

School of Natural Resources: Faculty Publications

The exchange of carbon dioxide is a key measure of ecosystem metabolism and a critical intersection between the terrestrial biosphere and the Earth’s climate. Despite the general agreement that the terrestrial ecosystems in North America provide a sizeable carbon sink, the size and distribution of the sink remain uncertain. We use a data-driven approach to upscale eddy covariance flux observations from towers to the continental scale by integrating flux observations, meteorology, stand age,aboveground biomass, and a proxy for canopy nitrogen concentrations from AmeriFlux and Fluxnet-Canada Research Network as well as a variety of satellite data streams from the MODIS sensors. …

Water Column Variability In A Coastal Tourist Cave In Mallorca, Spain, Liana M. Boop, Bogdan P. Onac, Jonathan G. Wynn, Joan J. Fornós, Marta Rodríguez-Homar

National Cave and Karst Management Symposium 2013

Coves del Drac is visited by more than 1 million tourists annually and has been a tourist destination in the western Mediterranean for over 100 years. All areas of the cave are developed with historic or current tour route infrastructure, including walkways, handrails, and electric lighting. This study compares one vertical water profile collected along the current tour path with two other profiles from historic tour route locations. Differences in freshwater and organic inputs, as well as direct anthropogenic impacts, are clearly observed in the aquatic parameters and stable isotopes collected in the profiles. Anthropogenically-driven undersaturation in the cave pools, …

Assessing The Reproducibility Of Coral Oxygen And Carbon Isotope Time Series From Fiji And Tonga And Their Application To The Reconstruction Of South Pacific Convergence Zone Movements Since The Mid-1800s, Emilie Pauline Dassie

Legacy Theses & Dissertations (2009 - 2024)

A major feature affecting the hydrology of the southern hemisphere is the South Pacific Convergence Zone (SPCZ); a band of high rainfall extending southeastward from the Western Pacific Warm Pool (WPWP). It is a key source of atmospheric water vapor and latent heating. While it is clear that the SPCZ plays a fundamental role in Earth's climate, little is known about the patterns and mechanisms responsible for interannual to century-scale changes in its position and how it may respond to global climate change.

Pleistocene Climate In Alaska From Stable Isotopes In An Ice Wedge, Corinne Y. Griffing

UNLV Theses, Dissertations, Professional Papers, and Capstones

The CRREL permafrost tunnel offers a unique opportunity to sample ice wedges in a climate-controlled environment, penetrating frozen silts which host massive ground ice that may record Dansgaard-Oeschger (D-O) and Heinrich Events. Ice wedges in the tunnel have been dated to approximately 36-22 ka (Hamilton et al., 1988), allowing the paleoclimate of the region to be reconstructed during MIS 3, when D-O and Heinrich events were documented in various other records. These climate cycles are rapid climate oscillations that have been recognized in records from the Arctic and subarctic, and suggest that climate can rapidly shift by 10°C over millennial …

Evaluation Of The Sensitivity Of Inventory And Monitoring National Parks To Acidification Effects From Atmospheric Sulfur And Nitrogen Deposition, Northern Great Plains Network (Ngpn), T. J. Sullivan, T. C. Mcdonnell, G. T. Mcpherson, S. D. Mackey, D. Moore

United States National Park Service: Publications

Northern Great Plains Network (NGPN)

National maps of atmospheric sulfur (S) and nitrogen (N) emissions and deposition are provided in Maps A through D as context for subsequent network data presentations. Maps A and B show county level emissions of total S and total N for the year 2002. Maps C and D show total S and total N deposition, again for the year 2002.

There are three parks in the Northern Great Plains Network that are larger than 100 square miles: Badlands (BADL), Missouri (MNRR), and Theodore Roosevelt (THRO). In addition, there are 10 smaller parks.

Total annual S …

Biogenic Tracers Through The Holocene On The Alaskan Shelf, Carie A. Curry

OES Theses and Dissertations

Dramatic environmental changes in the Arctic Ocean have been observed for the last two decades including changing the amount of sea ice thickness and extent, and increased river discharge. In order to put these and other current day observations into historical context and perhaps reveal mechanisms controlling them, a suite of paleo-proxies were used to analyze two high resolution cores collected on the 2005 HOTRAX expedition. The goals of this research were: (1) develop an analytical method for determining biogenic calcite, (2) identify the major sources of biogenic matter into the system over the Holocene, and (3) assemble the history …

Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton

United States Geological Survey: Staff Publications

Loess is one of the most extensive surficial geologic deposits in mid-continental North America, particularly in the central Great Plains region of Nebraska. Last-glacial-age loess (Peoria Loess) reaches its greatest known thickness in the world in this area. New stratigraphic, geochronologic, mineralogic, and geochemical data yield information about the age and provenance of Peoria Loess, as well as evaluation of recent climate models.

Rare-Earth Elements And Nd And Pb Isotopes As Source Indicators For Labrador Sea Clay-Size Sediments During Heinrich Event 2, Larry V. Benson, Don Barber, John T. Andrews, Howard E. Taylor, Paul Lamothe

United States Geological Survey: Staff Publications

Elemental abundances and Nd and Pb isotope ratios were determined on samples from the carbonate-free, clay-size fractions of sediments from intervals above, within, and below Heinrich event 2 (H-2) in core HU87-9 from the Northwest Labrador Sea slope. In HU87-9, rare-earth element (REE) distributions and elemental concentrations within the H-2 event are distinct from those outside this event. ɛ_Nd(0) and ²⁰⁶Pb/²⁰⁴Pb data also indicate different values for sediments deposited within and outside the H-2 event. Comparisons of REE patterns from the H-2 interval with those from bedrock units in Baffin Island, northern Quebec, and Labrador …