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Full-Text Articles in Cosmochemistry

Experimental Determination Of Zinc, Potassium And Rubidium Diffusion Coefficients In Olivine, Christopher J. Willingham Jan 2023

Experimental Determination Of Zinc, Potassium And Rubidium Diffusion Coefficients In Olivine, Christopher J. Willingham

Graduate Theses/Dissertations

One of NASA’s key strategies is to learn more about the early solar system and its formation. Chondrites were formed from the most primitive materials at the collapse of the solar system and over time have been classified into different categories based on their elemental abundance. These chondrites have fallen to Earth and have even formed entities such as asteroids and planetary bodies. It has been found through studies that one of these chondrites is close to the elemental abundance of the Sun. The other types of chondrites were up to two orders of magnitude less in concentration …


Halogen And Non-Traditional Isotope Geochemistry Of Planetary And Terrestrial Materials, Anthony Gargano, Zachary Sharp, Justin Simon, Charles Shearer, Adrian Brearley, James Day Jul 2022

Halogen And Non-Traditional Isotope Geochemistry Of Planetary And Terrestrial Materials, Anthony Gargano, Zachary Sharp, Justin Simon, Charles Shearer, Adrian Brearley, James Day

Earth and Planetary Sciences ETDs

This dissertation presents the advances in non-traditional isotope geochemistry of planetary and terrestrial materials encompassing chlorine, sulfur, and zinc isotopes, as well as halogen geochemistry. A wide breadth of materials was studied throughout the completion of this work including iron meteorites, achondrites, chondrites, Apollo lunar samples, as well ancient marine chert, and carbonate sediments. Much of the focus involved the development of a method capable of simultaneously measuring the halogen contents and chlorine isotope compositions of geological materials. Here, I present these data sets to broadly characterize the process of devolatilization of planetary materials, and specifically the problem of ‘halogen-poisoning’ …


Effects Of Terrestrial Weathering On Rare Earth Element Concentrations And Sulfur Isotopic Signatures Of Carbonaceous And Ordinary Chondrites, Ruby Virginia Patterson Jul 2020

Effects Of Terrestrial Weathering On Rare Earth Element Concentrations And Sulfur Isotopic Signatures Of Carbonaceous And Ordinary Chondrites, Ruby Virginia Patterson

Graduate Theses and Dissertations

Understanding the effects of weathering of chondrites is essential to gaining accurate and useful information about the formation of our solar system, as well as a more detailed account of the mobilization of chondritic compounds when they encounter terrestrial conditions. Elemental concentrations and stable isotope analyses of chondrites, considered to be the most primordial material in the solar system, are two tools which help unlock the weathering patterns of these specimens when they enter the earth system. However, it is not currently known exactly how time spent in the field alters rare earth element (REE) concentration or δ34S signatures within …


Aluminum-26: A Canonized Cosmochemical Conundrum, John Anton Feb 2018

Aluminum-26: A Canonized Cosmochemical Conundrum, John Anton

Dissertations, Theses, and Capstone Projects

This study focuses on the challenges associated with the historical development of the interpretative role of 26Al as both a thermodynamic contributor to planetesimal formation processes and an acutely precise chronometer of protoplanetary disk events. Conventional thought asserts that 26Mg concentrations can occur as isotopic excesses in meteorites and represent the daughter product of 26Al, a radioactive form of aluminum (t½ = ~0.73 ka). The greatest 26Mg concentrations generally occur in calcium aluminum inclusions (CAIs), meteoric constituents considered among the oldest known materials in the Solar System whose formation appear to predate the less refractory …


The Formation Of Fine-Grained Chondrule Rims In Unequilibrated Ordinary Chondrites, John Bigolski Sep 2017

The Formation Of Fine-Grained Chondrule Rims In Unequilibrated Ordinary Chondrites, John Bigolski

Dissertations, Theses, and Capstone Projects

Fine-grained rims are ubiquitous, non-igneous, features that completely or partially envelope the majority of chondrules within the least equilibrated of the unequilibrated ordinary chondrites (UOCs). A detailed examination of such rims in 4 UOC samples less than petrologic type 3.2 was conducted in order to 1) characterize the relative distribution of rims within chondrite samples, 2) inspect differences between fine-grained rims and adjacent matrix material, 3) petrologically analyze the rims and their relationships with chondrule cores, 4) characterize an ungrouped UOC, Northwest Africa 5717, 5) conduct a microanalytical investigation of rim / matrix boundaries to discern relative chronologies of fine-grained …