Biogeochemistry Commons^™

Biostratigraphic Analysis Of Southern Florida's Plio-Pleistocene Shell Beds, Dalton L. Rasmussen

OES Theses and Dissertations

Four molluscan assemblage zones in southern Florida corresponding to the Pinecrest Sand Member of the Tamiami Formation, and the Caloosahatchee, Bermont and Fort Thompson shell beds were identified following quantitative and qualitative analyses of the fossil molluscan fauna. Twenty-eight bulk sediment samples collected from 16 localities across southern Florida were processed for fossil material, and yielded nearly 60,000 specimens belonging to 311 species. A Q-mode cluster analysis compared sediment samples on the basis of 188 species whose abundances had been converted to binary presence-absence form. The cluster analysis was run four times using the Jaccard and Dice similarity coefficients as …

The Dinoflagellate Flora Of The Late Oligocene - Early Miocene Old Church Formation Mid-Atlantic Coastal Plain, Alan P. Hoffmeister

OES Theses and Dissertations

The Old Church Formation contains the only presently known exposed Oligocene sediments in the North American mid-Atlantic Coastal Plain. Some ambiguity concerning the exact age of the Old Church Formation exists because it may include both Oligocene and Miocene sediments. Two outcrops and four cores containing the Old Church Formation were examined for dinoflagellates to determine the composition of the dinoflagellate flora in the Old Church Formation, the age of the Old Church Formation as indicated by this flora, general depositional environment of the Old Church Formation and correlative relationships of the Old Church Formation with other Coastal Plain units. …

The Biogeochemistry Of Iodine In Seawater, Lingsu Zhang

OES Theses and Dissertations

Iodate and iodide are the two major species of iodine in seawater. In comparison to iodate, iodide is thermodynamically unstable in oxic seawater. The conversion (or reduction) of iodate to iodide may be mediated via biological activities. Since biological activities vary with the season, the conversion of iodate to iodide may also vary seasonally. The conversion (or oxidation) of iodide to iodate is thermodynamically feasible, but the mechanism is poorly known. Hydrogen peroxide, which is ubiquitous in surface seawater, may oxidize iodide to iodate.

Water samples were collected in the middle and lower Chesapeake Bay in different seasons between 1990 …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

A Comparison Of Metals In Several Ahermatypic Corals And Surficial Sediments: Mobile Pinnacles And Hoffa Reef, Northcentral Gulf Of Mexico, Kathryn M. Conko

OES Theses and Dissertations

Metal concentrations in marine sediment and carbonate secreting invertebrates are representative of surrounding environmental chemistry. Aluminum, Ba Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, and Zn were measured in carbonate and terrigenous phases of the $<$63 um fraction of sediment samples from two locations in the northcentral Gulf of Mexico. Enrichment factors indicate that Al, Ba, Cu, Cr, Mg, Mn, and Ni are all slightly depleted in these sediments relative to crustal abundances. Discriminant function analyses shows that the concentrations of five elements differ between locations.

Ahermatypic coral (106 specimens) from five genera collected from the study sites were analyzed for Cd, Cu, Cr, Pb, Zn, Mn, Sr, Ba, Fe, Ca and Mg. Eight elements vary between some genera, Al and Ba also vary in concentration in corals between either location. All elements except Sr are significantly depleted in the coral with respect to Ca in the …

Nutrient Cycling In Bordenstake Bay Sediments: A Backbarrier Lagoon, Mark J. Herrenkohl

OES Theses and Dissertations

Six sets of sediment cores were collected over a one year period (June 1986 to July 1987) to examine nutrient cycling in Bordenstake Bay, a back barrier lagoon on Virginia's Eastern Shore Peninsula. The sampling times were chosen to examine any seasonal effects (e.g., temperature changes) which may affect the rates of metabolism in these sediments.

The sedimentation rate in Bordenstake Bay is 0.76 ± 0.21 cm/yr, leading to the annual deposition of 7. 05 moles of carbon, 0.46 moles of nitrogen, and 0.15 moles of phosphorus, per square meter of the sediment surface. The remineralization of organic matter in …

The Geochemistry Of Selenium And Sulfur In A Coastal Salt Marsh, David Jay Velinsky

OES Theses and Dissertations

Investigation of the various chemical forms of selenium and sulfur in sediments and pore waters can provide information about various oxidation/reduction processes. Five cores were obtained from the Great Marsh, from April 1985 to June 1986. Sampling times coincided with the seasonal redox cycle known to occur within the marsh system. Sediments were analyzed for various selenium and sulfur phases.

Iron monosulfides and elemental sulfur both display large seasonal changes in concentration and distribution with depth, indicating a coupling with redox conditions. In contrast, the depth distribution of greigite did not show appreciable changes with season. Pyrite underwent large concentration …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …

The Marine Geochemistry Of Selenium, Kazufumi Takayanagi

OES Theses and Dissertations

A fluorometric method for the determination of Se (IV) and total selenium in natural waters has been developed and optimized. The detection limit is about 20 pM for both analyses using a one liter sample. The precisions were about 2 % at 338 pM for Se (IV) and at 234 pM for total selenium.

The concentrations of both total selenium and Se (IV) decreased with increasing salinity in the surface waters of the James River and southern Chesapeake Bay. While total selenium seemed to exhibit conservative behavior at salinities above 0.36 ('o)/oo, Se (IV) was apparently removed during estuarine mixing. …

The Effects Of Elevated Calcium Chloride And Magnesium Chloride Levels On Larval Growth And Survival Of Macrobrachium Rosenbergii (De Man) (Decapoda Palaemonidae) Reared In The Laboratory, James Thomas Michaels Ii

OES Theses and Dissertations

The effects of elevated CaCl₂ , MgCl₂ , combination CaCl₂ and MgCl₂ concentrations and their associated ionic strengths on larval growth and survival of the freshwater prawn, Macrobrachium rosenbergii were investigated in the laboratory. Larvae were reared in diluted seawater of 15 parts per thousand salinity with elevated calcium concentrations of 330 parts per million and elevated magnesium concentrations of 1275 parts per million. Control larvae were also reared with elevated NaCl concentrations to duplicate the ionic strength increases of the combination CaCl₂ - MgCl₂ test solution which had the highest ionic strength. A …

Suspended Matter And Light Attenuation In A Turbid Estuary, Daniel E. Campbell

OES Theses and Dissertations

A study was made in Hampton Roads, Virginia, to characterize the suspended matter and to investigate its relationship to the light attenuation coefficient. The study gives a detailed description of the seston and its variations with time and space. An evaluation of the light attenuation coefficient as an indicator of seston distributional parameters was made.

The distribution of the suspended matter is obtained through gravimetric, Coulter counter and microscopic analyses. Microscopic analysis is employed to determine the composition of the seston and ATP determinations give the amount of living biomass. The suspended matter is characterized in terms of weight, numbers, …