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OES Faculty Publications

Articles 91 - 120 of 120

Full-Text Articles in Biogeochemistry

Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey Jan 2004

Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey

OES Faculty Publications

We measured black carbon (BC) in ultrafiltered, high-molecular weight dissolved organic matter (UDOM) in surface waters of Delaware Bay, Chesapeake Bay, and the adjacent Atlantic Ocean (U.S.A.) to investigate the importance of riverine and estuarine dissolved organic matter (DOM) as a source of BC to the ocean. BC was 5-72% of UDOM-C (27 ± 17%), which corresponds to 8.9 ± 6.5% of dissolved organic carbon (DOC), with higher values in the heavily urbanized midbay region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of …

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New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu Jan 2003

New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu

OES Faculty Publications

[1] New evidence based on recent satellite data is presented to provide a rare opportunity in quantifying the long-speculated contribution of tropical cyclones to enhance ocean primary production. In July 2000, moderate cyclone Kai-Tak passed over the South China Sea (SCS). During its short 3-day stay, Kai-Tak triggered an average 30-fold increase in surface chlorophyll-a concentration. The estimated carbon fixation resulting from this event alone is 0.8 Mt, or 2-4% of SCS's annual new production. Given an average of 14 cyclones passing over the SCS annually, we suggest the long-neglected contribution of tropical cyclones to SCS's annual new production may …

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Nitrate Anomaly In The Upper Nutricline In The Northern South China Sea - Evidence For Nitrogen Fixation, George T. F. Wong, Shi-Wei Chung, Fuh-Kwo Shiah, Chung-Chi Chen, Liang-Saw Wen, Kon-Kee Liu Jan 2002

Nitrate Anomaly In The Upper Nutricline In The Northern South China Sea - Evidence For Nitrogen Fixation, George T. F. Wong, Shi-Wei Chung, Fuh-Kwo Shiah, Chung-Chi Chen, Liang-Saw Wen, Kon-Kee Liu

OES Faculty Publications

[1] Up to 2 μM of nitrate anomaly, N*, were found in the upper nutricline at the South East Asia Time-series Study (SEATS) site in the northern South China Sea (SCS). These concentrations were among the higher values reported in the Pacific and indicate the significant contribution of the remineralization of nitrogen-rich organic matter formed by nitrogen fixation to the nutrient dynamics of the area. The concentrations were systematically higher, by up to 2.5 μM, in the Fall through the early Spring, during the northeast monsoon, than in the Summer, suggesting that the impact of nitrogen fixation was higher during …

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Dark Production: A Significant Source Of Oceanic Cos, M. Von Hobe, Gregory A. Cutter, A. J. Kettle, M. O. Andreae Dec 2001

Dark Production: A Significant Source Of Oceanic Cos, M. Von Hobe, Gregory A. Cutter, A. J. Kettle, M. O. Andreae

OES Faculty Publications

Carbonyl sulfide (COS) in air and dissolved in seawater was determined during a cruise in August 1999 in the Sargasso Sea in the northwest Atlantic Ocean. Dissolved concentrations at the sea surface displayed only a weak diel cycle with a mean of 8.6 ± 2.8 pmol dm−3 owing to low abundance of photochemical precursors and high temperatures causing rapid hydrolysis. Depth profiles measured over the oceanic mixed layer revealed significant vertical gradients of COS concentration with higher values at the surface, suggesting that the rate of photochemical production at the surface exceeds the rate of vertical mixing. The mean …

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Uptake Of Dissolved Organic Selenides By Marine Phytoplankton, Stephen B. Baines, Nicholas S. Fisher, Martina A. Doblin, Gregory A. Cutter Jan 2001

Uptake Of Dissolved Organic Selenides By Marine Phytoplankton, Stephen B. Baines, Nicholas S. Fisher, Martina A. Doblin, Gregory A. Cutter

OES Faculty Publications

Se is present in multiple oxidation states in nature, each of which has unique chemical and biological reactivities. As a consequence, the rate of Se incorporation into food webs or its role as either a limiting nutrient or a toxic substance is a function of complex biogeochemistry. In particular, little is understood about the accumulation of dissolved organic selenides by phyto- or bacterioplankton. We assessed the bioavailability of dissolved organic selenides to marine and estuarine phytoplankton by presenting various algal species with filtered lysates of the diatom, Thalassiosira pseudonana, grown on media amended with radiolabeled selenite (75Se[IV]). …

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Control Of Phytoplankton Growth By Iron Supply And Irradiance In The Subantarctic Southern Ocean: Experimental Results From The Saz Project, P. W. Boyd, A. C. Crossley, G. R. Ditullio, F. B. Griffiths, D. A. Hutchins, B. Queguiner, Peter N. Sedwick, T. W. Trull Jan 2001

Control Of Phytoplankton Growth By Iron Supply And Irradiance In The Subantarctic Southern Ocean: Experimental Results From The Saz Project, P. W. Boyd, A. C. Crossley, G. R. Ditullio, F. B. Griffiths, D. A. Hutchins, B. Queguiner, Peter N. Sedwick, T. W. Trull

OES Faculty Publications

The influence of irradiance and Fe supply on phytoplankton processes was studied, north (47°S, 142°E) and south (54°S, 142°E) of the Subantarctic Front in austral autumn (March 1998). At both sites, resident cells exhibited nutrient stress (Fv/Fm 0 at 47°S and 9% I0 at 54°S because of MLDs of 40 (47°S) and 90 m (54°S), when these stations were occupied. The greater MLD at 54°S is reflected by tenfold higher cellular chlorophyll a levels in the resident phytoplankton. In the 47°S experiment, chlorophyll a levels increased to >1 μg/L-1 only in the high-Fe treatments, regardless …

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Control Of Phytoplankton Growth By Iron And Silicic Acid Availability In The Subantarctic Ocean: Experimental Results From The Saz Project, D. A. Hutchins, Peter N. Sedwick, G. R. Ditullio, P. W. Boyd, B. Queguiner, F. B. Griffiths, C. Crossley Jan 2001

Control Of Phytoplankton Growth By Iron And Silicic Acid Availability In The Subantarctic Ocean: Experimental Results From The Saz Project, D. A. Hutchins, Peter N. Sedwick, G. R. Ditullio, P. W. Boyd, B. Queguiner, F. B. Griffiths, C. Crossley

OES Faculty Publications

Subantarctic Southern Ocean surface waters in the austral summer and autumn are characterized by high concentrations of nitrate and phosphate but low concentrations of dissolved iron (Fe, similar to0.05 nM) and silicic acid (Si, <1 muM). During the Subantarctic Zone AU9706 cruise in March 1998 we investigated the relative importance of Fe and Si in controlling phytoplankton growth and species composition at a station within the subantarctic water mass (46.8degreesS, 142degreesE) using shipboard bottle incubation experiments. Treatments included unamended controls; 1.9 nM added iron (+Fe); 9 muM added silicic acid (+Si); and 1.9 nM addediron plus 9 muM added silicic acid (+Fe+Si). We followed a detailed set of biological and biogeochemical parameters over 8 days. Fe added alone clearly increased community growth rates and nitrate drawdown and altered algal community composition relative to control treatments. Surprisingly, small, lightly silicified pennate diatoms grew when Fe was added either with or without Si, despite the extremely low ambient silicic acid concentrations. Pigment analyses suggest that lightly silicified chrysophytes (type 4 haptophytes) may have preferentially responded to Si added either with or without Fe. However, for many of the parameters measured the +Fe+Si treatments showed large increases relative to both the +Fe and +Si treatments. Our results suggest that iron is the proximate limiting nutrient for chlorophyll production, photosynthetic efficiency, nitrate drawdown, and diatom growth, but that Si also exerts considerable control over algal growth and species composition. Both nutrients together are needed to elicit a maximum growth response, suggesting that both Fe and Si play important roles in structuring the subantarctic phytoplankton community.

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Holocene Sediment Records From The Continental Shelf Of Mac. Robertson Land, East Antarctica, Peter N. Sedwick, Peter T. Harris, Lisette G. Robertson, Gary M. Mcmurtry, Maximilian D. Cremer, Philip Robinson Jan 2001

Holocene Sediment Records From The Continental Shelf Of Mac. Robertson Land, East Antarctica, Peter N. Sedwick, Peter T. Harris, Lisette G. Robertson, Gary M. Mcmurtry, Maximilian D. Cremer, Philip Robinson

OES Faculty Publications

Geochemical records are presented for five sediment cores from basins on the continental shelf of Mac. Robertson Land, East Antarctica. The cores contain 2-4 m thick sequences of hemipelagic, siliceous mud and ooze (SMO) deposited under seasonally open marine conditions. The inner and middle shelf SMO sequences are massive dark olive green material, whereas the outer shelf SMO sequences are dark olive material interspersed with light olive green layers similar to1-10 cm thick. The biogenic material is dominated by marine diatoms including Fragilariopsis curta, Fragilariopsis cylindrus, and Chaetoceros spp. in the dark-colored SMO and Corethron criophilum in the …

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Introduction To Special Section: Saz Project, T. W. Trull, Peter N. Sedwick, F. B. Griffiths, S. R. Rintoul Jan 2001

Introduction To Special Section: Saz Project, T. W. Trull, Peter N. Sedwick, F. B. Griffiths, S. R. Rintoul

OES Faculty Publications

Oceanographic processes in the subantarctic region contribute crucially to the phys. and biogeochemical aspects of the global climate system. To explore and quantify these contributions, the Antarctic Cooperative Research Center organized the SAZ Project, a multidisciplinary, multiship study carried out south of Australia in the austral summer of 1997-1998. We present an overview of the SAZ Project and some of its major results.

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Effects Of Iron, Silicate, And Light On Dimethylsulfoniopropionate Production In The Australian Subantarctic Zone, G. R. Ditullio, P. N. Sedwick, D. R. Jones, P. W. Boyd, A. C. Crossley, D. A. Hutchins Jan 2001

Effects Of Iron, Silicate, And Light On Dimethylsulfoniopropionate Production In The Australian Subantarctic Zone, G. R. Ditullio, P. N. Sedwick, D. R. Jones, P. W. Boyd, A. C. Crossley, D. A. Hutchins

OES Faculty Publications

Shipboard bottle incubation experiments were performed to investigate the effects of iron, light, and silicate on algal production of particulate dimethylsulfoniopropionate (DMSPp) in the Subantarctic Zone (SAZ) south of Tasmania during March 1998. Iron enrichment resulted in threefold to ninefold increases in DMSPp concentrations relative to control treatments, following 7 and 8-day incubation experiments. Additions of Fe and Si preferentially stimulated the growth of lightly-silicified pennate diatoms and siliceous haptophytes, respectively, to which we attribute the increased DMSPp production in the incubation bottles. Both of these algal groups were previously believed to be low DMSPp …

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Iron In East Antarctic Snow: Implications For Atmospheric Iron Deposition And Algal Production In Antarctic Waters, Ross Edwards, Peter N. Sedwick Jan 2001

Iron In East Antarctic Snow: Implications For Atmospheric Iron Deposition And Algal Production In Antarctic Waters, Ross Edwards, Peter N. Sedwick

OES Faculty Publications

To evaluate the deposition and solubility of aerosol iron in the Antarctic seasonal sea ice zone (SSIZ), iron was measured in snow samples collected from three areas in the SSIZ (Prydz Bay, Dumont d'Urville Sea and Ross Sea) and one continental area (Princess Elizabeth Land) of East Antarctica. Concentrations of total-dissolvable iron (that soluble at pH ~2) ranged from 20-2950 pg g-1, with the lowest concentrations measured in snow from the Dumont d'Urville Sea. Using estimates of snow accumulation rates, we calculate atmospheric iron deposition fluxes of 0.017-0.11 mg m-2 yr-1(0.30-2.0 μmol m-2 yr …

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Modifications Of The C37 Alkenone And Alkenoate Composition In The Water Column And Sediment: Possible Implications For Sea Surface Temperature Estimates In Paleoceanography, Joan O. Grimalt, Jürgen Rullkötter, Marie-Alexandrine Sicre, Roger Summons, John Farrington, H. Rodger Harvey, Miguel Goñi, Ken Sawada Nov 2000

Modifications Of The C37 Alkenone And Alkenoate Composition In The Water Column And Sediment: Possible Implications For Sea Surface Temperature Estimates In Paleoceanography, Joan O. Grimalt, Jürgen Rullkötter, Marie-Alexandrine Sicre, Roger Summons, John Farrington, H. Rodger Harvey, Miguel Goñi, Ken Sawada

OES Faculty Publications

The literature pertaining to C37 alkenone and C37 and C38 alkenoate production and diagenesis has been reviewed and evaluated for issues that might jeopardize their usefulness in paleotemperature estimation. We also examined the use of the C37 alkenones as paleoproductivity indicators, the stability of their δ13C isotopic compositions, and their incorporation into the nonsolvent extractable organic matter fraction. Biological transformation of organic matter by bacteria and zooplankton does not appear to cause significant changes to the ratio of C37:2 and C37:3 alkenones, but there are major alterations in the relative composition of alkenoates. Studies of water column processes and postdepositional …

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Alteration Processes Of Alkenones And Related Lipids In Water Columns And Sediments, H. Rodger Harvey Aug 2000

Alteration Processes Of Alkenones And Related Lipids In Water Columns And Sediments, H. Rodger Harvey

OES Faculty Publications

Alkenones produced by the haptophyte algae are currently being used as indices of sea surface temperature in recent and past ocean environments, but limited information is available concerning the impact of biotic and abiotic processes on the integrity of these long chain lipids. This synthesis provides selected background information on major alteration processes that must be considered before such indices can be used with confidence. A number of processes in the water column and surface sediments have the potential to impact the structural integrity of alkenones and compromise their ability as temperature markers. Processes discussed include the alteration of alkenone …

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Iron And Manganese In The Ross Sea, Antarctica: Seasonal Iron Limitation In Antarctic Shelf Waters, Peter N. Sedwick, Giacomo R. Ditullio, Denis J. Mackey Jan 2000

Iron And Manganese In The Ross Sea, Antarctica: Seasonal Iron Limitation In Antarctic Shelf Waters, Peter N. Sedwick, Giacomo R. Ditullio, Denis J. Mackey

OES Faculty Publications

Dissolved iron and manganese and total dissolvable iron were measured in water column samples from the Polynya Region of the southern Ross Sea in cruises in Nov.-Dec. 1994 (spring 1994) and Dec. 1995 to Jan. 1996 (summer 1995). Iron and manganese addition bottle incubation experiments were also performed on these cruises to assess the nutritional sufficiency of ambient iron and manganese concentrations for phytoplankton growth. Generally high dissolved iron concentrations (>0.5 nM) and relatively complex iron and manganese vertical profiles were obtained in spring 1994 vs. summer 1995. Dissolved iron concentrations in the upper water column averaged 1.0 nM …

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Limitation Of Algal Growth By Iron Deficiency In The Australian Subantarctic Region, Peter N. Sedwick, Giacomo R. Ditullio, David A. Hutchins, Philip W. Boyd, F. Brian Griffiths, A. Clive Crossley, Thomas W. Trull, Bernard Queguiner Jan 1999

Limitation Of Algal Growth By Iron Deficiency In The Australian Subantarctic Region, Peter N. Sedwick, Giacomo R. Ditullio, David A. Hutchins, Philip W. Boyd, F. Brian Griffiths, A. Clive Crossley, Thomas W. Trull, Bernard Queguiner

OES Faculty Publications

In March 1998 we measured iron in the upper water column and conducted iron- and nutrient-enrichment bottle-incubation experiments in the open-ocean Subantarctic region southwest of Tasmania, Australia. In the Subtropical Convergence Zone (∼42°S, 142°E), silicic acid concentrations were low (< 1.5μM) in the upper water column, whereas pronounced vertical gradients in dissolved iron concentration (0.12-0.84 nM) were observed., presumably reflecting the interleaving of Subtropical and Subantarctic waters, and mineral aerosol input. Results of a bottle-incubation experiment performed at this location indicate that phytoplankton growth rates were limited by iron deficiency within the iron-poor layer of the euphotic zone. In the Subantarctic water mass (∼46.8°S, 142°E), low concentrations of dissolved iron (0.05-0.11nM) and silicic acid (< 1μM) were measured throughout the upper water column, and our experimental results indicate that algal growth was limited by iron deficiency. These observations suggest that availability of dissolved iron is a primary factor limiting phytoplankton growth over much of the Subantarctic Southern Ocean in the late summer and autumn.

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Iron In Ice Cores From Law Dome, East Antarctica: Implications For Past Deposition Of Aerosol Iron, R. Edwards, Peter N. Sedwick, Vin Morgan, C. F. Boutron, S. Hong Jan 1998

Iron In Ice Cores From Law Dome, East Antarctica: Implications For Past Deposition Of Aerosol Iron, R. Edwards, Peter N. Sedwick, Vin Morgan, C. F. Boutron, S. Hong

OES Faculty Publications

Total-dissolvable iron has been measured in sections of three ice cores from Law Dome, East Antarctica, and the results used to calculate atmospheric iron deposition over this region during the late Holocene and to provide a preliminary est. of aerosol iron deposition during the Last Glacial Maximum (LGM). Ice-core sections dating from 56-2730 BP (late Holocene) and ∼18 000 BP (LGM) were decontaminated using trace-metal clean techniques, and total-dissolvable iron was determined in the acidified meltwaters by flow-injection analysis. Our results suggest that the atmospheric iron flux onto the Law Dome region has varied significantly over time-scales ranging from seasonal …

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Lead Isotopes And Selected Metals In Ice From Law Dome, Antarctica, K. J. R. Rosman, W. Chisholm, C. F. Boutron, S. Hong, R. Edwards, Vin Morgan, Peter N. Sedwick Jan 1998

Lead Isotopes And Selected Metals In Ice From Law Dome, Antarctica, K. J. R. Rosman, W. Chisholm, C. F. Boutron, S. Hong, R. Edwards, Vin Morgan, Peter N. Sedwick

OES Faculty Publications

The isotopic composition. of Pb and the concentrations of Pb, Ba and Bi were measured in selected ice-core samples from Law Dome, East Antarctica, to a depth of 1196 m. The range of concentrations found in decontaminated ice was 0.03-1.5 pg g-1 for Pb, 0.9-6.1 pg g-1 for Ba and 0.4-17 fg g-1 for Bi, excluding the deepest sample which contained ∼1 ppm of rock dust. The abundances of all four stable lead isotopes were measured and gave 206Pb/207Pb ratios ≤ ∼1.23. A value of 208Pb/207Pb = 2.78 was measured in …

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Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige Jan 1997

Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige

OES Faculty Publications

Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m-2 d-1, exceeding fluxes of total dissolved Cu by 3->40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. …

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Regulation Of Algal Blooms In Antarctic Shelf Waters By The Release Of Iron From Melting Sea Ice, Peter N. Sedwick, Giacomo R. Ditullio Jan 1997

Regulation Of Algal Blooms In Antarctic Shelf Waters By The Release Of Iron From Melting Sea Ice, Peter N. Sedwick, Giacomo R. Ditullio

OES Faculty Publications

During summer 1995-96, we measured iron in the water column and conducted iron-enrichment bottle-incubation experiments at a station in the central Ross Sea (76°30'S, 170°40'W), first, in the presence of melting sea ice, and 17 days later, in ice-free conditions. We observed a striking temporal change in mixed-layer dissolved iron concentrations at this station, from 0.72-2.3 nM with sea ice present, to 0.16-0.17 nM in ice-free conditions. These changes were accompanied doubling of algal (diatom) biomass. Our incubation experiments suggest that conditions were iron-replete in the presence of sea ice, and iron-deficient in the absence of sea ice. We surmise …

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A Coupled, Non-Linear, Steady State Model For Early Diagenetic Processes In Pelagic Sediments, Surya P. Dhakar, David J. Burdige Jan 1996

A Coupled, Non-Linear, Steady State Model For Early Diagenetic Processes In Pelagic Sediments, Surya P. Dhakar, David J. Burdige

OES Faculty Publications

A steady state, coupled, non-linear model has been developed for early diagenetic processes in pelagic and hemi-pelagic marine sediments. Model results show that the occurrence of oxic and sub-oxic diagenetic processes is significantly affected by variations in parameters such as the sedimentation rate, bioturbation coefficient, sediment porosity, and organic matter flux to the sediments. Increases in the sedimentation rate or the bioturbation coefficient increase organic matter oxidation by sub-oxic processes, whereas an increase in sediment porosity decreases organic matter oxidation by sub-oxic processes. Sediment data from three contrasting MANOP sites are fit reasonably well with the model. The resulting best-fit …

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Biogenic Matter Diagenesis On The Sea Floor: A Comparison Between Two Continental Margin Transects, William M. Berelson, Jim Mcmanus, Kenneth H. Coale, Kenneth S. Johnson, Tammy Kilgore, David J. Burdige, Cynthia Pilskaln Jan 1996

Biogenic Matter Diagenesis On The Sea Floor: A Comparison Between Two Continental Margin Transects, William M. Berelson, Jim Mcmanus, Kenneth H. Coale, Kenneth S. Johnson, Tammy Kilgore, David J. Burdige, Cynthia Pilskaln

OES Faculty Publications

Benthic chamber measurements of the reactants and products involved with biogenic matter diagenesis (oxygen, ammonium, nitrate, silicate, phosphate, TCO2, alkalinity) were used to define fluxes of these solutes into and out of the sediments off southern and central California. Onshore to offshore transects indicate many similarities in benthic fluxes between these regions. The pattern of benthic organic carbon oxidation as a function of water depth, combined with published sediment trap records, suggest that the supply of organic carbon from vertical rain can just meet the sedimentary carbon oxidation + burial demand for the central California region between the …

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Elimination Of Dissolved Sulfide Interference In The Flow-Injection Determination Of Sigma-Co2 By Addition Of Molybdate, Rigel L. Lustwerk, David J. Burdige Jan 1995

Elimination Of Dissolved Sulfide Interference In The Flow-Injection Determination Of Sigma-Co2 By Addition Of Molybdate, Rigel L. Lustwerk, David J. Burdige

OES Faculty Publications

A previously described flow injection method for the analysis of ΣCO2 included the addition of ZnCl2 to some samples before analysis in order to precipitate dissolved sulfide (which interferes with the method) as ZnS. However, the use of Zn2+ in samples with high concentrations of dissolved sulfide causes the coprecipitation of ZnCO3, and in our experience with this technique, ZnCO3 also precipitates even in the absence of dissolved sulfide. The addition of molybdate effectively complexes dissolved sulfide without interfering with the determination of ΣCO2 by this technique.

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The Biogeochemistry Of Hydrogen Sulfide: Phytoplankton Production In The Surface Ocean, Russell S. Walsh, Gregory A. Cutter, William M. Dunstan, Joel Radford-Knoery, Jennifer T. Elder Jan 1994

The Biogeochemistry Of Hydrogen Sulfide: Phytoplankton Production In The Surface Ocean, Russell S. Walsh, Gregory A. Cutter, William M. Dunstan, Joel Radford-Knoery, Jennifer T. Elder

OES Faculty Publications

Hydrogen sulfide can exist in oxic waters in the form of a dissolved gas, dissociated ions, dissolved metal sulfide complexes, and particulate metal sulfides. The sum of the dissolved species is termed total dissolved sulfide (TDS). In addition to the hydrolysis of carbonyl sulfide, it has been speculated that phytoplankton may produce TDS. We present results from preliminary culture studies which demonstrate that phytoplankton produce TDS and particulate acid-volatile sulfide (pAVS). The phylogenetic order of TDS + pAVS production (per unit cell volume) for the oceanic species examined is Synechococcus sp. > Emiliania huxleyi ≈ Pyramimonas obovata > Thalassiosira oceanica. Moreover, …

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Biogeochemical Control Of Phosphorus Cycling And Primary Production In Lake Michigan, R. S. Walsh, Gregory A. Cutter, W. M. Dunstan, J. Radford-Knoery, J. T. Elder Jan 1994

Biogeochemical Control Of Phosphorus Cycling And Primary Production In Lake Michigan, R. S. Walsh, Gregory A. Cutter, W. M. Dunstan, J. Radford-Knoery, J. T. Elder

OES Faculty Publications

A 3-yr study in Lake Michigan has shown a 27 mmol P m-2 increase in the mass of total P (TP) in the water during spring when the lake is mixed from surface to sediment. This value is an order of magnitude greater than the annual P input from external sources. TP changed in concert with increases in chlorophyll a and organic N and decreases in nitrate and soluble Si. The concentration of soluble reactive PO4-3 (SRP) remained relatively constant throughout the study. We hypothesize that the SRP concentration is maintained by a chemical equilibrium with calcium-phosphate …

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The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens Jan 1992

The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens

OES Faculty Publications

Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …

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Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon Sep 1991

Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon

OES Faculty Publications

Hydrothermal plumes associated with nearshore lava flows from Kilauea Volcano, Hawaii were studied on five occasions during 1989-1990 to address the current lack of data on direct lava-seawater interactions. The following enrichments were found in the sea-surface hydrothermal plumes above the active underwater lava flows: H2, 15,000x ambient seawater concentrations; Mn, 250x; and Si, 20x. Water temperatures reached 46°C. Lower concentrations and temperatures were observed in the plumes with increasing distance from shore, with H2, Si, and Mn concentrations linearly related to seawater temperature. Unlike deep sea spreading center hydrothermal plumes, no CH4 enrichment was …

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The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige Jan 1991

The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige

OES Faculty Publications

The kinetics of sulfate reduction and inorganic nutrient production (ΣCO2, ammonium, and phosphate) were examined in the sediments at five sites in the southern Chesapeake Bay, using long term (> 200 d) sediment decomposition experiments. Average first order rate constants for these processes (at 25oC) decreased from 8.2 to 3.7 yr-1 in the surface sediments (0-2 cm), to 2.1 to 0.2 yr-1 at 12-14 cm. The C/N and C/P ratios of the organic matter undergoing decomposition also increased with depth at these sites. Taken together, these results indicate that the reactivity of the organic matter …

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Microbial Manganese Reduction By Enrichment Cultures From Coastal Marine Sediments, David J. Burdige, Kenneth H. Nealson Jan 1985

Microbial Manganese Reduction By Enrichment Cultures From Coastal Marine Sediments, David J. Burdige, Kenneth H. Nealson

OES Faculty Publications

Manganese reduction was catalyzed by enrichment cultures of anaerobic bacteria obtained from coastal marine sediments. In the absence of oxygen, these enrichment cultures reduced manganates when grown on either lactate, succinate, or acetate in both sulfate-free and sulfate-containing artificial seawaters. Sodium azide as well as oxygen completely inhibited microbial manganese reduction by these enrichment cultures, whereas molybdate had no effect on them. The addition of nitrate to the medium slightly decreased the rate of Mn2+ production by these enrichment cultures. These findings are consistent with the hypothesis that the manganese-reducing organisms in these enrichment cultures use manganates as terminal …

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The Marine Biogeochemistry Of Selenium: A Re-Evaluation, Gregory A. Cutter, Kenneth W. Bruland Jan 1984

The Marine Biogeochemistry Of Selenium: A Re-Evaluation, Gregory A. Cutter, Kenneth W. Bruland

OES Faculty Publications

Vertical and horizontal profiles from the North and South Pacific Oceans demonstrate the existence of three species of dissolved selenium: selenite, selenate, and organic selenide (operationally defined). In surface waters, organic selenide makes up about 80% of the total dissolved selenium, selenite concentrations are uniformly low, and selenate concentrations rise with increased vertical mixing. The organic selenide maximum (thought to consist of seleno-amino acids in peptides) coincides with the maxima of primary productivity, pigments, bioluminescence, and dissolved free amino acids. Deep ocean waters are enriched in selenite and selenate, while organic selenide is nondetectable. In suboxic waters of the tropical …

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A Pore Water/Solid Phase Diagenetic Model For Manganese In Marine Sediments, David J. Burdige, Joris M. Gieskes Jan 1983

A Pore Water/Solid Phase Diagenetic Model For Manganese In Marine Sediments, David J. Burdige, Joris M. Gieskes

OES Faculty Publications

A steady state diagenetic model is developed which accounts for changes in both the pore water and solid phase manganese profiles in marine sediments as a result of advection, diffusion, and redox reactions. The model is applied to observations on two cores in the E equatorial Atlantic in which pore water and solid phase manganese data are available. In situ reaction rates for manganese oxidation and reduction are estimated. The oxidation rates calculated here are in good agreement with rates measured in laboratory studies. In addition, the calculated manganese oxidation and reduction rates are compared with other estimated rates for …

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