Biogeochemistry Commons^™

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴ S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the effect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern United States) by extracting total sedimentary sulfide using chromium reduction. We use …

Relative Concentration Of Solid-Phase Sulfide Species In Marine Sediments Overlying Gas Hydrate Deposits: Recognition Of The Role Of Anaerobic Methane Oxidation In Authigenic Sulfide Formation, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Sulfide mineralization in marine sediments occurs when dissolved sulfide, produced by sulfate reduction processes, combines with dissolved iron to form iron sulfide minerals. Sulfide can be produced by oxidation of organic matter or by anaerobic methane oxidation (AMO), which involves the co-consumption of sulfate and methane. The latter process seems especially important within gas hydrate terrains like that of theBlakeRidge(offshore southeasternUnited States), where appreciable amounts of methane diffuse upward to the base of the sulfate reduction zone, or sulfate-methane interface (SMI).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits by sequentially extracting …

Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige

OES Faculty Publications

Calculations based on recent observations indicate that approximately one third of the organic matter presently being buried in marine sediments may be of terrestrial origin, with the majority of this terrestrial organic matter (TOM) burial occurring in muddy, deltaic sediments. These calculations further suggest that the remineralization of terrestrial organic matter in the oceans is also much less efficient than that of marine organic matter. These two underappreciated observations have important implications in terms of our understanding of the controls on the global carbon cycle. From a paleoceanographic perspective, the results presented here also suggest that changes in TOM burial …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴ S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the effect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern United States) by extracting total sedimentary sulfide using chromium reduction. We use …

Changes In Sulfur Concentration And Sulfur Isotopic Composition Within Authigenic Sulfide Minerals From Sediments Of Miocene Age To The Present, Odp Site 995, Blake Ridge, Offshore Southeastern United States, Kathryn G. Takacs, Walter S. Borowski

EKU Faculty and Staff Scholarship

The Blake Ridge area (offshore southeastern United States) consists of deep-water continental margin sediments overlying deposits of methane gas hydrate. Authigenic sulfide minerals (elemental sulfur, S˚; iron monosulfides, ~FeS; and pyrite, FeS₂) are actively deposited in these sediments due to sulfate reduction and focused anaerobic methane oxidation (AMO) at the sulfate-methane interface (SMI). Sulfide minerals at the present SMI are enriched in ³⁴S relative to those produced by sulfate reduction of organic matter higher in the sulfate reduction zone. ³⁴S enrichments preserved in the sediment column may identify relatively high amounts of AMO and thus record …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the affect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern North America) by extracting total sedimentary sulfide using chromium reduction. We use …

Enrichments Of 34s In Sulfide Minerals Of Deep-Water Marine Sediments Of The Blake Ridge, Offshore Southeastern United States, Kathryn G. Takacs, Walter S. Borowski

EKU Faculty and Staff Scholarship

Past research shows that active sulfide mineralization occurs at the base of the sulfate reduction zone (SRZ) in modern, deep-water, continental-margin sediments that overlie methane gas hydrate. These sulfide minerals (elemental sulfur, Sº; iron monosulfides, ~FeS; and pyrite, FeS₂) are enriched in ³⁴S because of sulfate reduction and anaerobic methane oxidation (AMO) processes occurring above and near the sulfate-methane interface (SMI).

The data in this study show that 5 discrete zones of sulfide minerals are preserved in a 703.8-meter sediment column associated with methane gas hydrate. These zones of sulfide minerals are also enriched in ³⁴S. …

Modifications Of The C37 Alkenone And Alkenoate Composition In The Water Column And Sediment: Possible Implications For Sea Surface Temperature Estimates In Paleoceanography, Joan O. Grimalt, Jürgen Rullkötter, Marie-Alexandrine Sicre, Roger Summons, John Farrington, H. Rodger Harvey, Miguel Goñi, Ken Sawada

OES Faculty Publications

The literature pertaining to C37 alkenone and C37 and C38 alkenoate production and diagenesis has been reviewed and evaluated for issues that might jeopardize their usefulness in paleotemperature estimation. We also examined the use of the C37 alkenones as paleoproductivity indicators, the stability of their δ13C isotopic compositions, and their incorporation into the nonsolvent extractable organic matter fraction. Biological transformation of organic matter by bacteria and zooplankton does not appear to cause significant changes to the ratio of C37:2 and C37:3 alkenones, but there are major alterations in the relative composition of alkenoates. Studies of water column processes and postdepositional …

Alteration Processes Of Alkenones And Related Lipids In Water Columns And Sediments, H. Rodger Harvey

OES Faculty Publications

Alkenones produced by the haptophyte algae are currently being used as indices of sea surface temperature in recent and past ocean environments, but limited information is available concerning the impact of biotic and abiotic processes on the integrity of these long chain lipids. This synthesis provides selected background information on major alteration processes that must be considered before such indices can be used with confidence. A number of processes in the water column and surface sediments have the potential to impact the structural integrity of alkenones and compromise their ability as temperature markers. Processes discussed include the alteration of alkenone …

Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige

OES Faculty Publications

Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m^-2 d^-1, exceeding fluxes of total dissolved Cu by 3->40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. …

The Dinoflagellate Flora Of The Late Oligocene - Early Miocene Old Church Formation Mid-Atlantic Coastal Plain, Alan P. Hoffmeister

OES Theses and Dissertations

The Old Church Formation contains the only presently known exposed Oligocene sediments in the North American mid-Atlantic Coastal Plain. Some ambiguity concerning the exact age of the Old Church Formation exists because it may include both Oligocene and Miocene sediments. Two outcrops and four cores containing the Old Church Formation were examined for dinoflagellates to determine the composition of the dinoflagellate flora in the Old Church Formation, the age of the Old Church Formation as indicated by this flora, general depositional environment of the Old Church Formation and correlative relationships of the Old Church Formation with other Coastal Plain units. …

Nutrient Cycling In Bordenstake Bay Sediments: A Backbarrier Lagoon, Mark J. Herrenkohl

OES Theses and Dissertations

Six sets of sediment cores were collected over a one year period (June 1986 to July 1987) to examine nutrient cycling in Bordenstake Bay, a back barrier lagoon on Virginia's Eastern Shore Peninsula. The sampling times were chosen to examine any seasonal effects (e.g., temperature changes) which may affect the rates of metabolism in these sediments.

The sedimentation rate in Bordenstake Bay is 0.76 ± 0.21 cm/yr, leading to the annual deposition of 7. 05 moles of carbon, 0.46 moles of nitrogen, and 0.15 moles of phosphorus, per square meter of the sediment surface. The remineralization of organic matter in …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …