Biogeochemistry Commons^™

Characterizing Cdom Spectral Variability From Seas To Space, Brice Grunert

Dissertations, Master's Theses and Master's Reports

Colored dissolved organic matter (CDOM) absorption varies significantly across the global oceans, presumably due to differences in source and degradation pathways. Tracking this variability on a global, or even regional, scale requires broad temporal and spatial sampling at high frequency. Satellite remote sensing provides this platform; however, current and near future sensors are/will be limited to measurements within the UV and visible wavelengths (> 350 nm) while most optical proxies estimating CDOM composition, and relevant for understanding largescale biogeochemical processes, use wavelengths less than 350 nm. This dissertation examines global variability in CDOM spectral variability utilizing a variety of optical …

Assessing The Periodic Groundwater Flow Conditions Of A Perched Aquifer System In The Daniel Boone National Forest, Ethan Sweet

Posters-at-the-Capitol

Assessing the Periodic Groundwater Flow Conditions of a Perched Aquifer System in the Daniel Boone National Forest

Ethan Sweet and Jonathan Malzone

Eastern Kentucky University, Department of Geosciences

Natural ephemeral wetlands situated among the ridge-tops in the Daniel Boone National Forest serve as reservoirs that recharge a shallow groundwater system. Unique interactions between surface and groundwater in these isolated systems provide substantial support for the native ecosystem, serving as a breeding ground for amphibians and as source water for vegetation—especially in periods of drought. Currently it is not understood how groundwater could provide regional biodiversity, a drought buffer, or a …

Mediation Of Eutrophication Of Surface And Subsurface Water From Non-Point Sources: Nutrient Monitoring At Meadowbrook Farm (Madison County, Kentucky), Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Non-point sources from various human activities such as farming have replaced industrial point sources as contributors of many contaminants in surface and subsurface waters of the United States. Eastern Kentucky University’s Meadowbrook Farm (720 acres, ~2.9 km²; Madison County, Kentucky) is a teaching facility dedicated to improving farming techniques and discovering best practices for farm operations that include minimizing environmental impacts. Agricultural activities on the Farm contribute nutrients to the Muddy Creek (Kentucky River) watershed that promote eutrophication and degrade water quality. Farm management already uses protocols to mediate drainage of dissolved nitrogen off the Farm, but also …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Nutrient Contamination From Non-Point Sources: Dissolved Phosphate In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Hunter R. Evans, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Farms are non-point sources for nutrient contaminants that drain into watersheds and contribute to eutrophication and other environmental problems. Eastern Kentucky University’s Meadowbrook Farm raises both crops and livestock, causing dissolved phosphorus in the form of orthophosphate (PO₄^3-) from fertilizer and animal manure to enter surface and subsurface waters, eventually flowing into Muddy Creek, a tributary of the Kentucky River.

We sampled surface water, springs, and water from French drains that emanate from the farm, and also sampled Muddy Creek waters from May through August 2016. Typically, 1 to 2 days after sampling, we colorimetrically measured dissolved …

Patterns Of Nutrient Export For A Typical Non-Point Source, Meadowbrook Farm, Madison County, Kentucky, James Scott Winter, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Excess nutrients are found in watersheds originating from active farmland often causing poor water quality and eutrophication in natural waters. Use of fertilizer and animal husbandry can contaminate both surface water and groundwater. Eastern Kentucky University’s Meadowbrook Farm raises crops and livestock and is typical of farms that contribute excess nutrient contaminants to watersheds as non-point sources. An instrumented weir is positioned within a key sub-watershed of the Farm that empties into Muddy Creek, a tributary of the Kentucky River. This drainage is the largest outlet from the Farm that is representative of the Farm’s collective activities.

We measured flow …

Nutrient Contamination From Non-Point Sources: Dissolved Phosphate In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Hunter R. Evans, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Farms are non-point sources for nutrient contaminants that drain into watersheds and contribute to eutrophication and other environmental problems. Eastern Kentucky University’s Meadowbrook Farm raises both crops and livestock, causing dissolved phosphorus in the form of orthophosphate (PO₄^3-) from fertilizer and animal manure to enter surface and subsurface waters, eventually flowing into Muddy Creek, a tributary of the Kentucky River.

We sampled surface water, springs, and water from French drains that emanate from the farm, and also sampled Muddy Creek waters from May through August 2016. Typically, 1 to 2 days after sampling, we colorimetrically measured dissolved …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Limiting Nutrient Contaminants From Agricultural Non-Point Sources: Nutrient Monitoring At Eku’S Meadowbrook Farm, Madison County, Kentucky, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Sources of contamination to U.S. waterways have largely shifted from industrial, point sources to agricultural and other non-point sources associated with common human activities. EKU’s Meadowbrook Farm explores best-practices in agriculture and animal husbandry that not only act to increase the efficiency of farm operations, but also to limit environmental effects such as the eutrophification of its neighboring watershed.

We recently started a collaboration with the Farm and the EKU Department of Agriculture, which are developing methods to sequester phosphorus and thus limit nutrient export to the adjacent Muddy Creek watershed. Our task is to quantify the amount of phosphorus …

Compost Land Management And Soil Carbon Sequestration, Kylene A. Hohman

Senior Honors Projects, 2010-2019

Extensive fossil fuel burning has released carbon dioxide into the atmosphere. Under proper ecological conditions plants convert atmospheric carbon dioxide into stable soil organic matter, a natural and efficient means of mitigating climate change. In the symbiotic relationship between mycorrhizae and plants, mycorrhizae provide plants with essential nutrients in exchange for carbon sugars leaked from the plants. Mycorrhizae convert carbon sugars to an exudate called glomalin, a protein that assists in developing soil aggregates composed of sand, silt, and clay. These aggregates, called humus, store carbon for hundreds of years under healthy ecological conditions. Compost prompts soil microbes to aerobically …

Patterns And Sources Of Anthropogenic Contaminants In The Otter Creek Watershed, Madison County, Kentucky, Elijah J. Wolfe

EKU Faculty and Staff Scholarship

Stream systems are often affected by anthropogenic activities that affect water quality and stream ecosystems. Land use typically determines the type and quantity of anthropogenic contaminants entering natural waters. The Otter Creek watershed (170 km²; Madison County, Kentucky) consists predominantly of pasture and rural housing, with some cropland. The basin also receives runoff from the town of Richmond and a sewage treatment plant operates within the watershed. We measured concentrations of nutrients (phosphate, ammonium, nitrate) and fecal microbes to discover levels of anthropogenic contaminants affecting water quality and to identify contaminant sources.

We sampled 4 times in the …

Patterns And Sources Of Anthropogenic Contaminants In The Otter Creek Watershed, Madison County, Kentucky, Elijah D. Wolfe, Walter S. Borowski, Jacob L. Robin

EKU Faculty and Staff Scholarship

Stream systems are often affected by anthropogenic contaminants that affect water quality and stream ecosystems. Land use determines the type and quantity of contaminants present in natural waters. The Otter Creek watershed (170 km²; Madison County, Kentucky) consists predominantly of pasture and rural housing, with some cropland. The basin also receives runoff from the town of Richmond and a sewage treatment plant operates within the watershed. We measured concentrations of nutrients (phosphate, ammonium, nitrate) and fecal microbes to discover levels of anthropogenic contaminants affecting water quality and to identify contaminant sources.

We sampled 4 times in the summer …

Patterns Of Anthropogenic Nutrient Contaminants In The Otter Creek Watershed, Madison County, Kentucky, Elijah D. Wolfe, Walter S. Borowski, Jacob L. Robin

EKU Faculty and Staff Scholarship

We measured nutrient concentrations within the Otter Creek watershed (Madison County, Kentucky) to: (1) discover levels of anthropogenic contaminants affecting the water quality; (2) compare these measurements to a national data set; and (3) identify nutrient sources. The watershed mainly drains rural land characterized by cattle grazing, but also drains the town of Richmond. We sampled throughout the watershed to gain a representative perspective of nutrient levels and specifically targeted localities of suspected anthropogenic nutrient sources. Water samples were passed through a 0.45 mm filter, placed in pre-acidified vials, and measured one to two days after collection. Nutrients – ammonium, …

Soil Chemistry On Watershed 1: 1998 - 2014, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

No abstract provided.

Nutrient Addition Effects On Tropical Dry Forests: A Mini-Review From Microbial To Ecosystem Scales, Jennifer S. Powers, Kristen K. Becklund, Maria G. Gei, Siddharth B. Iyengar, Rebecca Meyer, Christine S. O'Connell, Erik M. Schilling, Christina M. Smith, Bonnie G. Waring, Leland K. Werden

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Humans have more than doubled inputs of reactive nitrogen globally and greatly accelerated the biogeochemical cycles of phosphorus and metals. However, the impacts of increased element mobility on tropical ecosystems remain poorly quantified, particularly for the vast tropical dry forest biome. Tropical dry forests are characterized by marked seasonality, relatively little precipitation, and high heterogeneity in plant functional diversity and soil chemistry. For these reasons, increased nutrient deposition may affect tropical dry forests differently than wet tropical or temperate forests. Here, we review studies that investigated how nutrient availability affects ecosystem and community processes from the microsite to ecosystem scales …

Sources Of Nutrient And Escherichia Coli Contamination Within The Otter Creek Watershed, Madison County, Kentucky, Nathaniel C. Crockett, Walter S. Borowski

EKU Faculty and Staff Scholarship

The Otter Creek watershed exhibits dissolved nutrient (ammonium, NH₄; nitrate, NO₃; phosphate, PO₄) and Escherichia coli contamination that compromises its water quality. The watershed covers a substantial portion of Madison County and consists of Lake Reba, Dreaming Creek, and east and west forks, all of which enter the trunk of Otter Creek before flowing into the Kentucky River. Suspected contaminate sources include leaky sewage system pipes, runoff from pasture land, and septic system leachate. We collected 330 water samples on three occasions during summer 2014 to determine the extent and sources of contamination. Nutrients …

A Remote Sensing Based Early Warning System For Algal Blooms In Kuwait Bay And Coastal Waters, Cameron Manche

Masters Theses

The Kuwait Bay and its coastal waters are being threatened by a perpetual hazard, the proliferation of harmful algal blooms (HABS). The frequency of HAB occurrences is a growing problem that is only reported subsequent to the onset of a HAB event. Little effort has been invested in investigating the spatial and temporal distribution of these events in Kuwait Bay and even less is known about their controlling factors. All previous studies within the Kuwait Bay have focused either on measuring nutrient availability and the biodiversity of algal species.

The overall study objective is four-fold: (1) to monitor the spatial …

Estimating Nitrogen Fixation Rates, Importance, And Short-Term Efficiency In Small, Temperate Reservoirs Using Delta15n Techniques, Bryant Christopher Baker

Graduate Theses and Dissertations

Nitrogen (N2) fixation can give certain species of cyanobacteria a competitive advantage in lake and reservoir phytoplankton. These species of cyanobacteria, along with others that cannot fix N2, can form toxic compounds that impair water quality when present in high concentrations. N2 fixation rates may be substantial in small (< 1.0 km2), temperate reservoirs since these systems experience thermal stratification and often nitrogen (N) limitation throughout a substantial proportion of the year. However, the effects of N2 fixation on N cycling, alleviation of short-term N limitation, and water quality are not well-understood. A mesocosm experiment and ecosystem-scale observational study were conducted to 1) determine the efficiency of N2 fixation under varying N relative to phosphorus (P) supply, 2) examine the effects of N2 fixation on autotrophic biomass accumulation and microcystin production, and 3) measure N2 fixation rates and importance to autotrophic N demand and zooplankton N assimilation. Results of the mesocosm experiment indicated that N2 fixation was increased at low N:P supply under high P. However, N2 fixation was inefficient at alleviating N limitation when fixed N was the primary source of N. Additionally, microcystin production occurred only at high N:P supply when N2 fixation was low, indicating that reducing external N inputs may have a positive effect on water quality. Results of whole-reservoir determination of N2 fixation using seston δ15N natural abundances indicated that N2 fixation rates throughout the warm season were substantial and influenced by water temperature. Annual N2 fixation rates ranged from 2.2 - 6.6 g N m-2 yr-1, and contributed up to 19% of the annual autotrophic N demand. Zooplankton were assimilating fixed N in most of the study reservoirs, representing a possible mechanism of ecosystem fixed N retention. Collectively, these results suggest that N2 fixation plays a substantial role in N cycling in small, temperate reservoirs, but likely cannot alleviate short-term N limitation.

A Review Of The Hyporheic Zone, Stream Restoration, And Means To Enhance Denitrification, Leanne Merill, David J. Tonjes

Technology & Society Faculty Publications

The hyporheic zone is the subsurface area below and adjacent to a stream where groundwater mixes with stream water, through vertical, lateral, and longitudinal flows. The hyporheic zone connects the stream to uplands and other terrestrial environments. It is a zone of distinct faunal communities, high biological diversity and ecological complexity, and is the site of chemical processing and transformations of ground- and stream waters. The hyporheic zone is important to the overall ecosystem ecology of the stream, and it can influence stream water chemistry. Flows, reactions, and biota in the hyporheic zone are heterogeneous and patchy, making it difficult …

Sources Of Nutrient And Fecal Microbe Pollution In Otter Creek, Madison County, Kentucky, Kandice L. Smith, Walter S. Borowski

EKU Faculty and Staff Scholarship

We measured nutrient (nitrate, ammonium, phosphate) and fecal microbe concentrations in surface waters of the Otter Creek watershed, Madison County, Kentucky to access sources of these contaminants. The watershed is approximately 12.5 miles long covering ~169 km² (41,832 acres). The watershed includes East Fork, West Fork, and Dreaming Creek, all tributaries to the main trunk of Otter Creek. The upper portion of the main trunk and Dreaming Creek drain urban areas of Richmond, but 85% of total watershed area is agricultural land, used mainly for grazing cattle. Rural residential areas and woodlands also occur.

The principle contaminants are nutrients …

Spectroscopic Study Of Uranium (Vi) Reduction By Plant Biomass, Margaret C. Murphy, John Bargar, Noémie Janot

STAR Program Research Presentations

Uranium is a common and problematic groundwater contaminant at Department of Energy legacy sites. At the former uranium ore processing plant at Rifle, Colorado, sediments rich in decayed plant biomass contain large concentrations of uranium that are slowly being released back to the aquifer. To simulate the reaction that occurs in organic rich sediments of the Rifle aquifer, biomass was incubated in U (VI) bearing groundwater. Carbon X-ray absorption spectroscopy (XAS) was then used to measure if uranium was bound to the biomass. When uranium binds to biomass the peaks in the C XAS spectra will change shape. Uranium L …

Will Hubbard Brook Soils Be A Source Or Sink Of Carbon In A Changing Climate?, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

No abstract provided.

Inter- And Intra-Annual Variability Of Vegetation In The Northern Hemisphere And Its Association With Precursory Meteorological Factors, Boksoon Myoung, Yong-Sang Choi, Seungbum Hong, Seon Ki Park

Mathematics, Physics, and Computer Science Faculty Articles and Research

Determination of phenological variation is one of the most critical challenges in dynamic vegetation modeling, given the lack of a strong theoretical framework. Previous studies generally focused on the timing of a phenological event (e.g., bud-burst or onset of growing season) and its atmospheric prompts, but not on the interactive variations across phenological stages. This study, therefore, investigated the inter- and intra-annual variability existing in all the phenological stages and the relations of the variability with four meteorological variables (surface temperature (Ts), shortwave radiation (SW ), vapor pressure deficit (VPD), and precipitation (PRCP)) using a 25-year (1982-2006) dataset of leaf …

Interactions Of Zooplankton And Phytoplankton With Cyanobacteria, Rebecca Alexander

School of Natural Resources: Dissertations, Theses, and Student Research

Cyanobacteria are a major concern in Nebraska reservoirs and are capable of producing toxins that can cause skin irritations and gastrointestinal problems, as well as affect the nervous system. It is important to determine the mechanisms that can cause cyanobacteria blooms due to the effect they can have on human health. The interaction of zooplankton and other phytoplankton groups with cyanobacteria is important because there is a biological component in surface waters that should be taken into consideration along with the physical and chemical parameters that have been noted to promote cyanobacteria. For example, zooplankton have the ability to alter …

Point Source And Non-Point Source Pollution In A Secondary Stream: Nutrient Concentration And Fecal Microbe Counts In Tates Creek, Madison County, Kentucky, Walter S. Borowski, Krisopher H. Carroll, Bethany Gabbard

EKU Faculty and Staff Scholarship

Nutrient concentration and fecal microbe counts are elevated in Tates Creek, a stream that emanates from the town of Richmond, KY, passes by a conventional sewage treatment plant that discharges into the stream, and winds for 13 miles through pastureland and a series of small communities on septic systems before entering the Kentucky River. The sewage treatment plant shut-down operations during our study and we monitored dissolved nutrients (ammonium, nitrate, and phosphate), fecal microbes (total coliform and Escherichia coli), and stream biota before and after treatment operations ceased. Sampling occurred 4 times in both 2011 and 2012 between May …

An Individual-Based Process Model To Simulate Landscape-Scale Forest Ecosystem Dynamics, Rupert Seidi, Werner Rammer, Robert M. Scheller, Thomas A. Spies

Environmental Science and Management Faculty Publications and Presentations

Forest ecosystem dynamics emerges from nonlinear interactions between adaptive biotic agents (i.e., individual trees) and their relationship with a spatially and temporally heterogeneous abiotic environment. Understanding and predicting the dynamics resulting from these complex interactions is crucial for the sustainable stewardship of ecosystems, particularly in the context of rapidly changing environmental conditions. Here we present iLand (the individual-based forest landscape and disturbance model), a novel approach to simulating forest dynamics as an emergent property of environmental drivers, ecosystem processes and dynamic interactions across scales. Our specific objectives were (i) to describe the model, in particular its novel approach to simulate …

Nutrient And Fecal Microbe Assessment Of The Water Quality Of Tates Creek, Madison County, Kentucky, Walter S. Borowski, Kristopher H. Carroll

EKU Faculty and Staff Scholarship

Tates Creek is a significant tributary to the Kentucky River that has shown high levels of microbial and nutrient pollution in the past (Kentucky River Watershed Watch). We sampled the waters of Tates Creek more comprehensively by collecting stream water at 25 stations along its 13-mile length from its headwaters to the Kentucky River. Most samples were collected at the confluence of major tributaries to also access the water quality of tributary streams. Samples were collected four times between May and August 2011 during dry periods as well as immediately after a rainfall event. We measured ammonium (NH₄^{+ …}

Nutrient And Fecal Microbe Assessment Of The Water Quality Of Tates Creek, Madison County, Kentucky, Krisopher H. Carroll, Walter S. Borowski

EKU Faculty and Staff Scholarship

Tates Creek is a significant tributary to the Kentucky River that has shown high levels of microbial and nutrient pollution. We sampled the waters of Tates Creek comprehensively by occupying 25 stations along its 13-mile length, collecting stream water at the confluence of major tributaries from its headwaters to the Kentucky River. Samples were collected four times between May and August 2011 during dry periods as well as immediately after rainfall events.

We measured ammonium (NH₄⁺), nitrate (NO₃^-) and phosphate (PO₄^-) concentrations using colorimetry. Microbial samples were measured for total coliform …

Quantification Of Nitrate Sources And Sinks Using A Water Quality Network In Morro Bay Estuary, California, Johanna Nadia Jean Weston

Master's Theses

Using an instrumented water quality network in Morro Bay Estuary, California from 2007 to 2010 (15 min sampling frequency), this study addressed the two objectives of constructing a nitrate budget and assessing the influence of sampling frequency on water quality parameters. These two objectives led to the submission of an original report of research (Appendix A) and a note (Appendix B) to peer-reviewed journals.

The first objective was to characterize the high spatial and temporal variation in physical parameters and nitrate concentrations and to construct a nitrate budget quantifying sources and sinks of nitrate from the ocean, streams, and groundwater, …

Spatial Patterns Of Drought Triggers And Indicators, Joseph P. Robine

Department of Environmental Studies: Undergraduate Student Theses

Drought is a reoccurring phenomenon with widespread economic, social, and environmental impacts. Unlike other disasters, a drought cannot be easily detected. In addition, droughts are widespread and develop slowly over time making it difficult to detect its onset and monitor its severity and impacts. To assist in monitoring the severity and spatial extent of droughts, drought managers frequently use indicators and triggers. Drought indicators are meteorological or hydrological variables or indices that quantify or describe the level of drought severity. A drought trigger is a value of an indicator that initiates management and response actions. Despite the clear importance of …