Earth Sciences Commons^™

Enrichment Of Volcanogenic Trace Elements In A Continuous Subsurface Eagle Ford Core In South Texas And The Origin Of The Oceanic Anoxic Event Ii At The Cenomanian-Turonian (C/T) Boundary, Daniel Valencia

Earth & Environmental Sciences Theses - Archive

The Upper Cretaceous Eagle Ford Shale of South Texas is a dark grey to black, sporadically laminated, organic rich carbonaceous mud rock located in the subsurface (~13,000), of the hydrocarbon producing shale-oil formation. This black shale formation was deposited contemporaneously worldwide across the Cenomanian-Turonian (C/T) boundary and records the Oceanic Anoxic Event (OAE-II). Geochronological and geochemical analysis of a ~300ft long continuous South Texas Eagle Ford Shale core was conducted to further constrain the sub-surface nature of the formation. Major, minor and trace element concentrations were analyzed by ED-XRF to characterize the local geochemical heterogeneity in the formation. Total Organic …

Geology And Geochemistry Of The Uvas Volcanic Field And Rubio Peak Formation Of South-Central New Mexico, Usa, Max Logan Hoffman

Graduate Theses/Dissertations

South-central New Mexico is characterized by many Cenozoic volcanic and tectonic events that produced a complex system of magma sources. These mechanisms are responsible for the diverse volcanic activity and magmatic evolution in New Mexico. To understand the growth and development of the mantle sources associated with these events, geochemical, petrographic, structural and spatial distribution data were collected from the Uvas volcanic field (UVF) and the Rubio Peak Formation of the Mogollon-Datil volcanic field (MDVF). Volcanic rocks from these volcanic fields were chosen based on their importance to relative timing of magmatic and tectonic transitioning events. The structural and spatial …

Urban Detention Basin Contamination With Polycyclic Aromatic Hydrocarbons (Pahs) And Metals, Holly Marie Duff

Graduate Theses/Dissertations

Polycyclic aromatic hydrocarbons (PAHs) are organic compounds that can be toxic to wildlife and humans when released to the environment. Coal-tar sealants, which are applied to parking lots or driveways, contribute up to 1,000 times more PAHs than alternative sealants. Over time, these sealants abrade and are transported into drainage networks. Coal-tar sealants are currently used in Springfield, Missouri, however the extent of PAH contamination throughout urban drainage systems is unclear. This study focused on PAH contamination within an urban detention basin on the Missouri State University campus which receives runoff from several coal-tar sealed parking lots. Sediment samples collected …

Foundations For A Geobiochemical Characterization Of Mudpots In Yellowstone National Park, Georgia Dahlquist

Graduate Theses & Non-Theses

Mudpots are acidic, turbid thermal features formed by the argillic or sericitic alteration of rock with enough fluid to create a viscous feature. Prior to this research, the combination of interdisciplinary sampling for geochemistry, mineralogy, and microbiology of rhyolite hosted mudpots, particularly in chemically distinct subregions of an area, remained largely unavailable. This work discusses mudpots and nearby hot springs sampled in Yellowstone National Park (YNP) in July 2016 and the measured in situ pH, temperature, and conductivity values, and dissolved oxygen concentrations. Water, filtered via gravity pre-filtration and 1.2 μm and 0.8/0.2μm syringe filtration, yielded δD and δ18O values …

Changes In Mineralogy And Geochemistry Of Quartz And Feldspars In Response To Impact Cratering, Steven Jaret

Geosciences Research Data

Impact cratering is an important geologic process that has affected all objects in the Solar System. The goal of this work is to understand how this process affects the mineralogy and geochemistry of planetary surfaces. Studies of extraterrestrial materials (e.g., laboratory studies of meteorites) and studies of planetary surfaces via orbiter or lander missions encounter impacted and shocked materials. Therefore, knowing how this secondary process of cratering has altered the rocks and minerals is critical to our ability to deconvolve the secondary effects of shock from the original primary geology. Specifically, I seek to understand impact metamorphism in three ways: …

Magmatic Hydrothermal Alteration And Secondary Post-Shock Features In Martian Olivine-Phyric Basalt Northwest Africa 10416; Petrology And Geochemistry Of Primitive Achondrite Northwest Africa 11042, Zoltan Vaci

Earth and Planetary Sciences ETDs

The Martian olivine-phyric basalt Northwest Africa (NWA) 10416 contains large olivine xenocrysts whose cores have been stained brown by hydrothermal alteration and whose rims are composed of pristine olivine overgrowths. Microanalysis of these olivine cores reveals various degrees of amorphization, some of which have been overprinted by terrestrial weathering, evident as part of a weathering rind along the exposed surface of the meteorite. Studies of a completely unweathered terrestrial analogue basalt from southern Colorado reveal similar features and indicate that both basalts were altered in a supersolidus magma chamber setting. The alteration features in NWA 10416 thus imply the presence …

Investigations On The Mesozoic Geologic And Tectonic History Of The Jackson Mountains, Northwest Nevada, Thomas Anthony Colby

Boise State University Theses and Dissertations

New geologic mapping, high-precision U-Pb zircon geochronology, and isotope geochemistry provide insight into the early Mesozoic paleogeography and magmatic, stratigraphic, and structural evolution of the Jackson Mountains in the Black Rock Desert region of northwest Nevada. The magmatic history of the Jackson Mountains records Late Triassic to Early Jurassic (~215-195 Ma) marine deposition of the Boulder Creek Beds adjacent to the arc followed by the Early Jurassic (~193-189 Ma) eruption and emplacement of the Happy Creek Igneous Complex and associated plutons of the Early Mesozoic Intrusive Suite. Pb, Sr, and Nd isotopic data from Early Jurassic intrusive rocks of the …

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence …

Mineralogy And Geochemistry Of The Heddleston Porphyry Cu-Mo Deposit, Montana, Ben Schubert

Graduate Theses & Non-Theses

The Heddleston porphyry Cu-Mo deposit is located in Lewis and Clark County, Montana, near the headwaters of the Blackfoot River. It is immediately west of the historic Mike Horse mine, an important producer of Pb-Zn from polymetallic veins and lodes. The Heddleston property was explored extensively by the Anaconda Company in the 1960s and 1970s, but was never mined. Specimens of polished drill core from the deposit are archived in the Anaconda Research Collection at Montana Tech campus. The purpose of this research project was to use the archived samples to examine the geochemistry and mineralogy of the Heddleston and …

Naturally Occurring Acid Rock Drainage In The Anaconda-Pintler Mountain Range, Montana: A Case Study Of Geochemistry In Two Streams Flowing From Mount Evans, Margaret Doolittle

Graduate Theses & Non-Theses

Mount Evans is located in the Anaconda-Pintler mountain range of southwest Montana approximately 22 km southwest of Anaconda, Montana. Mount Evans appears reddish orange on Google Earth amongst the rest of the mountain range which is a grey white color, indicating the presence of limonite staining and probable sulfide mineralization. In addition, two streams draining opposite sides of the mountain, and either side of the continental divide have conspicuous white coatings on boulders that are clearly visible with Google Earth. During a mineral resource assessment in the 1980s, the USGS suggested that the Mount Evans area could be the top …

An Antarctic Stratigraphic Record Of Stepwise Ice Growth Through The Eocene-Oligocene Transition, Sandra Passchier, Daniel J. Ciarletta, Triantafilo E. Miriagos, Peter K. Bijl, Steven M. Bohaty

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Earth’s current icehouse phase began ∼34 m.y. ago with the onset of major Antarctic glaciation at the Eocene-Oligocene transition. Changes in ocean circulation and a decline in atmospheric greenhouse gas levels were associated with stepwise cooling and ice growth at southern high latitudes. The Antarctic cryosphere plays a critical role in the ocean-atmosphere system, but its early evolution is still poorly known. With a near-field record from Prydz Bay, Antarctica, we demonstrate that Antarctic ice growth was stepwise and had an earlier onset than previously suggested. Prydz Bay lies downstream of a major East Antarctic Ice Sheet drainage system, and …

Removal Of Select Chlorinated Hydrocarbons By Nanoscale Zero-Valent Iron Supported On Powdered Activated Charcoal, Md Abu Raihan Chowdhury

Browse all Theses and Dissertations

Nanoscale Zero Valent Iron (NZVI) has shown limited effectiveness in degrading chlorinated hydrocarbons (CHCs), like 1,1,1-Trichloroethane (1,1,1-TCA) and Trichloroethene (TCE), in aqueous solution. A rapid agglomeration behavior of NZVI particles due to van der waals and magnetic forces can negatively impact its overall effectiveness due to increase in particle size, and decline in CHC degradation kinetics. Different support materials, such as clays and activated carbon, have been used to stabilize NZVI particle and reduce agglomeration in aqueous solution. In this bench-scale study, NZVI supported on Powdered Activated Charcoal (PAC) was selected to prepare a composite, called PAC/NZVI, for a more …

Geochemical, Microthermometric, And Isotopic Constraints On The Origin Of Fluorite Deposits In Central Anatolia, Turkey, Peli̇n Coşanay, Ece Kirat, Ni̇hal Çevi̇k, Ceyda Kizilkanat, Hali̇m Mutlu, Şükrü Koç

Turkish Journal of Earth Sciences

We investigate rare earth element geochemistry, microthermometric characteristics, and radiogenic isotope systematics of fluorites and stable isotope compositions of gangue minerals from several fluorite deposits in central Turkey. In the deposits, fluorite is the main ore mineral and it is accompanied by quartz, calcite, and minor pyrite and barite. Veins are represented by three different fluorite types based on their color. Total REY contents of fluorites are highly variable, ranging from 24 to 693 ppm. LREE concentrations of fluorites of all colors are similar but medium and heavy REE abundances of green fluorites are nearly an order of magnitude greater …

Petrogenesis Of Plio-Quaternary Basanites In The Gandom Beryan Area, Kerman,Iran: Geochemical Evidence For The Low-Degree Partial Melting Of Enriched Mantle, Seyed Javad Yousefi, Abbas Moradian, Hamid Ahmadipour

Turkish Journal of Earth Sciences

In the Gandom Beryan area, basanitic lava flows erupted from fractures in the Nayband fault zone and formed an area of about 300 km2 of basanitic rocks in the western part of the Lut Block. Olivine and clinopyroxene are the major phenocrysts in a microlitic groundmass for these basanitic rocks. The geochemical data show that Gandom Beryan rocks are basanite in composition and belong to intercontinental rifts related to alkali basanites. These rocks have low Fe/Mg ratios (Fe2O3t/MgO = 1.07-1.43) with low silica content (SiO2 = 44.89-48.26 wt.%) and are high-Ti basanites. The investigated rocks are characterized by a significant …

Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis

All Master's Theses

The complex bedrock lithologies in the Upper Kittitas County provide an ideal setting for developing isotopic methodology to identify groundwater sources and track flow paths through water-rock interaction. A wide range of 87Sr/86Sr (0.7040 to 0.7068) in surface waters, springs, and groundwater from wells was found, allowing for identification of the individual signatures of lithologic units. Rock leachates from different lithology were compared to water samples to determine a general 87Sr/86Sr signature of the water-rock interaction for that lithology. The signatures identified were systematically lower than their associated waters, but similar enough to identify the expected 87Sr/86Sr of water-rock interaction …

Modelling And Observational Evidence For The Igneous Evolution Of The Elysium Volcanic Province On Mars, David Andrew Susko

LSU Master's Theses

A major knowledge gap exists on how eruptive compositions of a single martian volcanic province change over time. The Elysium Volcanic Province is a location of great geologic interest on Mars. Its predominantly Amazonian surface age (beginning 3.3 Ga), and its isolation in the northern hemisphere of Mars away from other volcano-tectonic regions, make it an ideal locale to investigate igneous compositions erupted during the most recent geologic period on Mars. Here, this work seeks to fill that gap by assessing the compositional evolution of Elysium as a major martian volcanic province in two related projects. The first project seeks …

Mercury Increases In Lake Tanganyika Since ~1850, Troy A. Bole

Williams Honors College, Honors Research Projects

A series of three sediment cores were collected in Lake Tanganyika, Africa, and were analyzed for mercury concentrations. For all three cores, a decrease in mercury (Hg) levels was observed from the 1600’s (appx. 20 ng/g) until concentrations reached a minimum during the mid-1800’s (appx. 10 ng/g). The mid-1800’s marked a change from decreasing mercury levels to an increase over the following century. The core tops (circa 2006) have concentrations greater than 70 ng/g. The onset of the rise in mercury concentrations coincides with the beginning of the Industrial Revolution in the mid to late 18^th century. Relationships between …

Cycling Of Gypsiferous White Sands Aerosols In The Shallow Critical Zone At White Mountain, New Mexico, Patrick Richard Rea

Open Access Theses & Dissertations

Dry deposition significantly affects evolution of the critical zone by nutrient supply and contributing to soil genesis. Dust influx and cycling in soils are difficult to quantify because dust sources can be chemically similar to local soils. White Sands, New Mexico, emits gypsum dust with a unique chemical and isotopic signature, providing an opportunity to investigate dust deposition and its movement in soils. This study evaluated the mobility of White Sands dust particles in the critical zone at White Mountain, New Mexico, a highland 100 km downwind. Four soil profiles were collected over limestone, igneous, mixed limestone and dolostone, and …

Geologic And Geochemical Characterization Of Cross-Communication Potential Within The Northern Edwards Aquifer System, Texas, Ingrid J. Eckhoff

Electronic Theses and Dissertations

The Edwards Aquifer is a large, complex groundwater system located throughout Central Texas in association with the Balcones Fault Zone. The San Antonio and Barton Spring segments of the Edwards Aquifer have been extensively studied in the past because they provide groundwater resources to the largely urbanized areas of San Antonio and Austin, respectively, and smaller communities along the Interstate 35 corridor. Previous research has been conducted on these southern and central portions of the Edwards Aquifer system, which have characterized the structural, hydrogeological and geochemical variations within the highly karsted region. However, the Northern Segment of the Edwards Aquifer …

Ironstone Gravel Types In Western Australia: Re-Purposing A Geological Survey To Improve Soil Management, Edward A. Griffin, Karen Holmes, Tim Overheu

Conference papers and presentations

The deeply laterised landscapes of Western Australia’s wheatbelt contain large amounts of ferruginous concretions or pisoliths, referred to locally as ironstone gravel. Soil surveys over the years have described ironstone gravel presence and abundance, and the state soil classification system recognises their importance in agriculture by designating ‘ironstone gravel soils’ at the highest level of the classification hierarchy. These gravels have generally been assumed inert in agricultural soils; however, farm trials and anecdotal experience suggest they may play a more active role in nutrient and water retention than previously recognised. Gravelly soil performance under dryland agriculture varies dramatically across the …

Geothermometry Of Two Cascade Geothermal Systems, Donnel Alexander Malkemus

Dissertations and Theses

For this thesis I applied classical and multi-component geothermometry techniques to new water chemistry data from Breitenbush Hot Springs, Oregon and the Wind River Valley, Washington. A total of 20 well, spring, and stream samples from Breitenbush Hot Springs and 4 spring samples from the Wind River Valley were collected and analyzed for major, minor, and select trace anions and cations, as well as stable oxygen and hydrogen isotopes. I used two computer programs, GeoT and RTEst, to conduct multi-component geothermometry reservoir condition estimation on each water sample. Water chemistry data from Breitenbush Hot Springs indicates a range of thermal, …

Using Geochemistry And Strontium Isotopic Ratios (87sr/86sr) To Determining Water Mixing And Sources In The Picher Mining District, William Daniel Ketcheside

Theses and Dissertations

The mining of lead and zinc ores in the Tri-State Mining District of Kansas, Missouri, and Oklahoma resulted in some of the most severe environmental degradation in the country. Large amounts of waste rock, known as ‘chat’, were produced during mining and left in surface piles in the surrounding area. These chat piles, located mostly near the town of Picher, Oklahoma contain potentially harmful elements that can be leached from the rock into local streams and sediment. The mines also filled with water after mining ceased and have discharged contaminated water to nearby waterways, as well as resulted in groundwater …

Record Of Massive Upwellings From The Pacific Large Low Shear Velocity Province, Pilar Madrigal, Esteban Gazel, Kennet E. Flores, Michael Bizimis, Brian Jicha

Faculty Publications

Large igneous provinces, as the surface expression of deep mantle processes, play a key role in the evolution of the planet. Here we analyse the geochemical record and timing of the Pacific Ocean Large Igneous Provinces and preserved accreted terranes to reconstruct the history of pulses of mantle plume upwellings and their relation with a deep-rooted source like the Pacific large low-shear velocity Province during the Mid-Jurassic to Upper Cretaceous. Petrological modelling and geochemical data suggest the need of interaction between these deep-rooted upwellings and mid-ocean ridges in pulses separated by ∼10–20 Ma, to generate the massive volumes of melt …

Geochemical Comparison Of Ancient And Modern Eolian Dune Foresets Using Principal Components Analysis, David A. Little

Theses and Dissertations

Geochemistry has been used to determine the provenance and diagenetic history of eolian sandstone deposits. However, the grain size, sorting, cementation, and detrital composition of eolian units can change along dune foreset laminae. The purpose of this study was to test for consistent trends of compositional change along dune foresets. Such trends could increase the quality of geochemical sampling of eolian sandstones and possibly aid in estimating the original height of ancient sand dunes. XRF data was gathered for both major and trace elements from the Pennsylvanian to Permian Weber Sandstone, Early Jurassic Navajo Sandstone, and modern Coral Pink Sand …

A Complex Origin For The Kelso Dunes, Mojave National Preserve, California, Usa: A Case Study Using A Simple Geochemical Method With Global Applications, Daniel R. Muhs, Nicholas Lancaster, Gary L. Skipp

United States Geological Survey: Staff Publications

The Kelso Dune field in southern California is intriguing because although it is of limited areal extent (~100 km2), it has a wide variety of dune forms and contains many active dunes (~40 km2), which is unusual in the Mojave Desert. Studies over the past eight decades have concluded that the dunes are derived primarily from a single source, Mojave River alluvium, under a dominant, westerly-to-northwesterly wind regime. The majority of these studies did not, however, present data to support the Mojave River as the only source.We conducted mineralogical and geochemical studies ofmost of the 14 geomorphically defined dune groups …

Variations In Geochemistry And Mineralogy Of Aeolian Dust Deposition To Mountains In Utah And Nevada, Usa, Dylan Binder Dastrup

Theses and Dissertations

Major and trace metal loading to mountains in the western US depends on dust sources, intensity of storms and their availability for transport during snowmelt and runoff. Previous work has been conducted on dust production, composition, and its affect on solar radiation and timing of snow melt. This study was conducted to 1) examine temporal and spatial variability in dust chemistry; 2) evaluate form and availability of major and trace elements in dust; and 3) identify potential dust sources affecting mountains in Utah and Nevada. Spring and summertime dust was collected across northern Utah over the course of three years …

Development And Curation Of The Sample Data Library For The Astrobiogeochemistry Laboratory, Meika R. Nwaomah, Lorenia Jimenez, Michael Tuite

STAR Program Research Presentations

In 2011, the National Science Foundation (NSF) initiated EarthCube, an integrated cyber infrastructure initiative, to tackle challenges within geoscience research. EarthCube’s goal is to improve public access and collaboration within the geoscience community. During the summer of 2015, the Astrobiogeochemistry Laboratory (abcLab) joined the collective efforts of EarthCube by developing the Sample Data Library (SDL) for the Jet Propulsion Laboratory (JPL). The main focus of the SDL concentrates on effectively curating the samples collected by researchers within the Planetary Chemistry and Astrobiology section at JPL. The goal of this summer internship was to assimilate field notes, images, and from data …

Determining Groundwater Sources And Ages Via Isotope Geochemistry In Big Sky, Montana, Thomson Connie

Graduate Theses & Non-Theses

The Big Sky ski resort area in southwestern Montana is experiencing exponential growth in both development and population. Concerns have arisen over the quantity of good-quality groundwater in the region, and whether there is a large enough reserve to support the growing demand. In light of already-documented water-level decreases, and domestic wells needing to be deepened or replaced, the Montana Department of Natural Resources and Conservation (DNRC) enlisted the Montana Bureau of Mines and Geology's Ground Water Investigation Program to perform an assessment of groundwater availability and quality in the region, and define groundwater supply sources.

The geology in the …

Reexamination Of Ore-Forming Processes In The Emery Mining District, Powell Co., Montana, Jarred Zimmerman

Graduate Theses & Non-Theses

The present investigation was undertaken in collaboration with the Montana Bureau of Mines and Geology to re-evaluate the Emery district using modern methods of ore deposit study including fluid inclusions, stable isotopes, and mineral geochemistry. Results from this thesis will be an aid in reassessing the potential of the Boulder Batholith and surrounding geologic units to host large, undiscovered precious and/or base metal deposits. The Emery (aka Zosell) district was mined from the late 1800s until the early 1950s. Mineralized quartz veins are hosted by basaltic andesite flows of the late Cretaceous Elkhorn Mountain Volcanics (EMV). Two sets of veins …

An Investigation Of Hydrogeologic, Stratigraphic, And Structural Controls On Acer Grandidentatum Communities In A Karst Landscape, Owl Mountain Province, Fort Hood Military Installation, Texas, Melinda S. Faulkner

Electronic Theses and Dissertations

The Owl Mountain Province is located within the Fort Hood Military Installation, an approximately 880 km2 installation established in the 1940s in Bell and Coryell counties, Texas, which has undergone extensive land use changes associated with military training, maintaining much of the vegetation in early succession. This study investigates thelithologic, stratigraphic, and structural controls on the hydrologic, hydrogeologic, and geomorphologic evolution of the Owl Mountain Province as expressed by mesic vegetation communities, including Pleistocene relicts Acer grandidentatum, within karst terrains. These systems exhibit complexly overprinted speleogenetic evolutions within a dynamic groundwater regime resulting from regional climate shifts throughout the …