Earth Sciences Commons^™

Structural Control Of Thermal Fluid Circulation And Geochemistry In A Flat-Slab Subduction Zone, Peru, Brandt E. Scott

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Hot spring geochemistry from the Peruvian Andes provide insight on how faults, or fractures in the Earth's crust, are capable of influencing fluid circulation. Faults can either promote or inhibit fluid flow and the goal of this study is test the role of a major fault, such as the Cordillera Blanca detachment, as a channel for transporting deep fluids to the surface. Hot springs are abundant in the Cordillera Blanca and Huayhuash ranges in Peru, and several springs issue along the Cordillera Blanca detachment, making this region an ideal setting for our study. To test the role of the Cordillera …

Petrogenesis Of The El Rechuelos Rhyolite, Jemez Mountains Volcanic Field, New Mexico, Usa, Kelsy Jo Konkright

UNLV Theses, Dissertations, Professional Papers, and Capstones

The El Rechuelos Rhyolite represents volcanic activity preceding the multiple caldera collapse events of the Jemez Mountains volcanic field (JMVF) in northern New Mexico. This study focuses on seven rhyolitic units clustered north of the Valles caldera. These units have been studied in order to interpret their relationships to one another and the eruptive history of the JMVF. Additionally, this study adds to the research on the relationships between effusive and explosive rhyolitic volcanism, and understanding how caldera-forming eruptions develop from silicic systems.

Limited previous research includes K/Ar dates and a few inconsistent 40Ar/39Ar dates, in addition to whole rock …

A Multi-Proxy Approach To Refining Paleotempestology Records On The Northern Gulf Of Mexico Coast, Marianne Elizabeth Dietz

LSU Doctoral Dissertations

Reconstructing pre-historic hurricane activity is typically accomplished through the analysis of sandy overwash deposits identified in coastal lake settings. This method has been used successfully in many parts of the world and can extend the hurricane record thousands of years into the past. However, this approach also has its limitations. This dissertation addresses some of the limitations associated with geologic proxies used to reconstruct hurricane landfalls in the absence of historic data and tests new proxies for the identification of hurricane-derived overwash deposits. Modern storm deposits from two sites on the northern Gulf of Mexico coast are analyzed in detail …

Precipitation And Transformation Of Iron-Sulfide Nanoparticles In Low-Temperature Aqueous Environment: Effects Of Reactant Iron And Sulfide Sources, Ezequiel A. Moreno Flores

Open Access Theses & Dissertations

Iron sulfide nanoparticles assume an important role within a wide range of geological settings as indicators of redox environmental conditions and elemental cycling mechanisms. Initial precipitates of iron sulfide are exclusively nanoscale sized in low temperature aqueous conditions and have been reported to go through diverse morphological and phase transformations, possibly leading to the ultimate deposits of pyrite in geologic records of various times. A systematic understanding of how the early-stage nanoparticles of iron sulfide may develop into more crystalline iron sulfide forms is still lacking however. The major goal for this study was to illuminate the effects of the …

Upper Cretaceous Volcaniclastic Complexes And Calcareous Plankton Biostratigraphy Inthe Western Pontides, Nw Turkey, Katharina Boehm, Michael Wagreich, Erik Wolfgring, Okan Tüysüz, Susanne Gier, İsmai̇l Ömer Yilmaz

Turkish Journal of Earth Sciences

This study describes and interprets Upper Cretaceous volcaniclastics interbedded with hemipelagic to pelagic limestones, marls, and turbidites from the Western Pontides, northwestern Turkey. The Dereköy Formation, the Unaz Formation (red pelagic limestone unit), and the Cambu Formation can be distinguished, overlain by the turbiditic Akveren Formation. Biostratigraphic ages from the predominantly volcaniclastic Dereköy Formation indicate Turonian (Dicarinella concavata planktonic foraminifera zone, CC13/UC8-9 nannofossil zones) to middle/late Santonian ages up to CC17/UC13. The Unaz Formation, deposited during the late Santonian (UC13, Dicarinella asymetrica Zone), is overlain by the volcaniclastic Cambu Formation of latest Santonian (CC17b/UC13) to early/middle Campanian (CC20/UC15a) age. However, …

The Medicine Hat Block And The Assembly Of Laurentia: New Interpretations From Single-Grain Zircon Analyses, Blake Oswell Ladouceur

Electronic Theses and Dissertations

The Medicine Hat Block (MHB) is one of the core cratonic elements that amalgamated in the Paleoproterozoic to form Laurentia. However the role of the MHB in the formation of Laurentia is poorly constrained due to virtually all of the MHB being concealed by Proterozoic and younger supracrustal sequences limiting availability of data. The primary sources of samples from the MHB are 1) xenoliths of variable metamorphic grade including gneisses amphibolites and meta-plutonic rocks collected from Eocene volcanic rock; and 2) similar lithologies recovered from boreholes that penetrate to the MHB basement. Previous work on samples from the MHB yielded …

A Survey Of Sierra Nevada Magmatism Using Great Valley Detrital Zircon Trace-Element Geochemistry: View From The Forearc, Kathleen D. Surpless, D. Clemens-Knott, A. P. Barth, M. Gevedon

Earth and Environmental Geosciences Faculty Research

The well-characterized Sierra Nevada magmatic arc offers an unparalleled opportunity to improve our understanding of continental arc magmatism, but present bedrock exposure provides an incomplete record that is dominated by Cretaceous plutons, making it challenging to decipher details of older magmatism and the dynamic interplay between plutonism and volcanism. Moreover, the forearc detrital record includes abundant zircon formed during apparent magmatic lulls, suggesting that understanding the long-term history of arc magmatism requires integrating plutonic, volcanic, and detrital records. We present trace-element geochemistry of detrital zircon grains from the Great Valley forearc basin to survey Sierra Nevadan arc magmatism through Mesozoic …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

Mineralogy And Geochemistry Of Feed Coals And Combustion Residues Of The Kangal Power Plant (Sivas, Turkey), Ali̇ İhsan Karayi̇ği̇t, Riza Görkem Oskay, Rod A. Gayer

Turkish Journal of Earth Sciences

This study focuses on mineralogical and geochemical compositions of feed coal (FC) and combustion residues, namely fly ash (FA) and bottom ash (BA) samples, obtained from the Kangal coal-fired power plant in central Turkey. The X-ray powder diffraction data indicate that carbonate and clay minerals are dominant phases in the FC samples. In the FA samples, quartz, hematite, anhydrite, lime, and feldspar are generally dominant and abundant phases, whereas calcite, ettringite, and portlandite are generally more abundant in the BA samples. The elements Mo, Cs, and U are significantly enriched in the studied FC, FA, and BA samples. The statistical …

The Early Eocene Ekmekçi Granodiorite Porphyry In The Karacabey Region(Sakarya Zone, Nw Turkey), Gürsel Sunal, Mehmet Korhan Erturaç, Gülteki̇n Topuz, Aral Okay, Thomas Zack

Turkish Journal of Earth Sciences

The Ekmekçi granodiorite porphyry is a unit in the E-W trending, postcollisional Eocene magmatic rocks of northern Anatolia. It occurs as a relatively small stock, but represents a link between plutonic and volcanic rocks. This Early Eocene granodiorite porphyry intruded into the Upper Triassic rocks of the Karakaya complex in the Sakarya Zone. In this study we present geochemical and zircon U-Pb LA-ICP-MS age data to contribute to understanding the Early Tertiary postcollisional tectonic setting of NW Anatolia. The granodiorite porphyry includes plagioclase, quartz, hornblende, K-feldspar, biotite, and minor zircon, apatite, sphene, and opaque minerals. The stock displays medium-K calc-alkaline …

Petrography, Geochemistry, And Provenance Of Jurassic Sandstones From Thesakarya Zone, Nw Turkey, Firat Şengün, Osman Ersi̇n Koralay

Turkish Journal of Earth Sciences

The Jurassic sandstones exposed in the western part of the Sakarya Zone are yellowish to brown, moderate to well sorted, medium to coarse-grained, grain-supported, and cemented by calcareous and minor silica. Sandstones are mainly classified as litharenite, subarkose, and arkose according to the relative proportions of quartz, feldspar and rock fragments, and major element ratios. On the SiO2 variation diagram, Na2O and K2O show slight positive correlations, which could reflect abundance of sodic plagioclase and K-feldspar with quartz within high Si-content sandstones. Sandstones generally exhibit slight LREE enrichment with respect to HREEs. The REE plots are characteristic for sedimentary rocks …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Unroofing History Of The Northwestern Ethiopian Plateau: Insights From Low-Temperature Apatite Thermochronology, Shelby Bowden

Masters Theses & Specialist Projects

The geology of Ethiopia is dominated by the Ethiopian Plateau that is similar in elevation to, but aerially larger than, the Colorado Plateau. Several rivers have incised through the plateau, creating gorges that reach up to 1.5 km in depth. The plateau uplifted to its current elevation and was subsequently incised sometime after the Oligocene flood basalt event that signaled the arrival of the African Superplume below Kenya and Ethiopia. Due to its size and extent, published climate modeling has indicated that Late Cenozoic plateau formation could have been a driving force in the East African Cenozoic climate changes. Although …

Replacement Times Of A Spectrum Of Elements In The North Atlantic Based On Thorium Supply, Christopher T. Hayes, Robert F. Anderson, Hai Cheng, Tim M. Conway, R. L. Edwards, Martin Q. Fleisher, Peng Ho, Kuo-Fang Huang, Seth G. John, William M. Landing

School of Geosciences Faculty and Staff Publications

The measurable supply of ²³²Th to the ocean can be used to derive the supply of other elements, which is more difficult to quantify directly. The measured inventory of an element divided by the derived supply yields a replacement time estimate, which in special circumstances is related to a residence time. As a proof of concept, Th‐based supply rates imply a range in the replacement times of the rare earth elements in the North Atlantic that is consistent with the chemical reactivity of rare earth elements related to their ionic charge density. Similar estimates of replacement times for the …

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

Graduate Theses/Dissertations

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …

Understanding The Late Mesoproterozoic Earth System From The Oldest Strata In Grand Canyon: C-Isotope Stratigraphy And Facies Analysis Of The 1254 Ma Bass Formation, Grand Canyon Supergroup, Az., Usa, Erin C. Lathrop

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Rocks provide insight into ancient times before complex animals existed. The oldest sedimentary rocks in Grand Canyon (the Bass Formation) allow us to glimpse into what things might have been like over a billion years ago. These rocks record the time known as the Mesoproterozoic Era (1.6 to 1.0 billion years ago), otherwise known as the ‘boring billion’. These rocks are thought to be the right age to indicate the end of an oddly stable world when continents were quiet and life was calm, yet they predate younger rocks that record extreme events. The Bass Formation, some of the only …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Geochemistry And Mineralogy Of Late Quaternary Loess In The Upper Mississippi River Valley, Usa: Provenance And Correlation With Laurentide Ice Sheet History, Daniel R. Muhs, E. Arthur Bettis Iii, Gary L. Skipp

United States Geological Survey: Staff Publications

The midcontinent of North America contains some of the thickest and most extensive last-glacial loess deposits in the world, known as Peoria Loess. Peoria Loess of the upper Mississippi River valley region is thought to have had temporally varying glaciogenic sources resulting from inputs of sediment to the Mississippi River from different lobes of the Laurentide Ice Sheet. Here, we explore a new method of determining loess provenance using K/Rb and K/Ba values (in K-feldspars and micas) in loess from a number of different regions in North America. Results indicate that K/Rb and K/Ba values can distinguish loess originating from …

Characterization Of Groundwater And Surface Water Geochemistry In An Agricultural Setting At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. Eastern Kentucky University (EKU) Meadowbrook Farm raises crops and livestock, which contribute dissolved nutrients to the neighboring Muddy Creek watershed. Consequently, the Farm is developing methods to sequester phosphorous and limit nutrient contamination.

Before phosphorous sequestration methods can be tested, Farm surface water and groundwater geochemistry must be better understood to determine hydrological pathways for nutrients. We use naturally-occurring dissolved cations, pH, oxidation-reduction potential (ORP), specific conductivity (SC), dissolved oxygen (DO%), total hardness, and alkalinity as chemical tracers to parse the contribution of dissolved ions …

Petrogenesis, Geochemistry, And Tectonic Setting Of A Basaltic Body Within Thegercus Formation Of Northern Iraq: First Record For Eocene Anorogenic Volcanicactivity In The Region, Yawooz A. Kettanah, Adnan H. Bamarni

Turkish Journal of Earth Sciences

An abnormally odd and rare occurrence of a basaltic body has been discovered in the middle of the Gercus Formation within the large, double-plunging NW-SE trending Bekhair Anticline to the north of Duhok city, northern Iraq. This is the first discovery of such a volcanic body within the widely exposed Gercus Formation in northern Iraq, southeastern Turkey, and western Iran. This volcanic body, named by the authors the Gercus Basalt, has a long tabular/lenticular shape with a total length of ~4.5 km and a thickness ranging between 1 to 16 m. It is exposed on both limbs of the anticline …

Heavy Minerals And Exotic Pebbles From The Eocene Flysch Deposits Of The Magura Nappe (Outer Western Carpathians, Eastern Slovakia): Their Composition And Implications On The Provenance, Katarína Bónová, Ján Bóna, Martin Kovácik, Tomás Mikus

Turkish Journal of Earth Sciences

The study aims to reconstruct the crystalline parent rock assemblages of the Eocene Strihovce Formation (Krynica Unit) and Mrazovce Member (Raca Unit) deposits, based on the heavy mineral suites, their corrosive features, geochemistry of garnet and tourmaline, zircon cathodoluminescence (CL) images, and exotic pebble composition. Both units are an integral part of the Magura Nappe belonging to the Flysch Belt (Outer Western Carpathians). Corrosion signs observable on heavy minerals point to different burial conditions and/or diverse sources. The compositions of the detrital garnets and tourmalines as well as the CL study of zircons indicate their origin in gneisses, mica schists, …

Environmental Monitoring And Peat Assessment Using Multivariate Analysis Of Regional-Scale Geochemical Data, Jennifer M. Mckinley, Eric Grunsky, Ute Mueller

Research outputs 2014 to 2021

A compositional multivariate approach was used to analyse regional-scale soil geochemical data obtained as part of the Tellus Project generated by the Geological Survey of Northern Ireland. The multi-element total concentration data presented comprise X-ray fluorescence (XRF) analyses of 6862 rural soil samples collected at 20-cm depth on a non-aligned grid at one site per 2km2" role="presentation">2km2. Censored data were imputed using published detection limits. Each soil sample site was assigned to the regional geology map, resulting in spatial data for one categorical variable and 35 continuous variables comprised of individual and amalgamated elements. This paper examines the extent …

Abandoned Mine Land Impacts On Tributaries In The Upper Yakima River Watershed, Eastern Cascades, Washington, Scott Kugel

All Master's Theses

Effluent from abandoned mine lands (AMLs) in several drainages in Washington’s Eastern Cascades flows into the Yakima River. Similar sites in Idaho and Colorado are known producers of heavy metals and acid mine drainage. I determined the effects of nine AMLs on water quality in four tributaries to the Yakima River. Archival work was conducted to determine sites that were mined and contained a mill. Each site was characterized by physical features. Water and sediment samples were collected above, at, and below each AML. Samples were analyzed for pH and heavy metal content, and evaluated to determine if the AMLs …

Qualitative And Quantitative Analysis Of Carbonate Waters In The Peters Mountain Region Of Monroe County, Wv, Emily A. Bausher

Graduate Theses, Dissertations, and Problem Reports (ETD)

Water in Monroe County, WV is used extensively for public and private supply and requires quantification, chemical analysis, and assessment for contamination susceptibility. Over 250 springs were previously identified in the eastern side of Monroe County on or near Peters Mountain; 14 were continuously monitored in this study. Springs were grouped based on geologic and spatial distribution: interbedded clastic-rock springs on the mountain flanks, carbonate springs in the valley, and a thermal spring associated with the St. Clair thrust fault. Clastic and carbonate springs have calcium-magnesium-bicarbonate chemistries, neutral pHs and high alkalinities; the thermal spring has calcium-magnesium-sulfate-carbonate chemistry, low pH, …

Stream Water And Soil Water Chemistry After The Table Mountain Wildfire, Washington, Usa, Vincent J. Roccanova

All Master's Theses

Analyses of major and trace elements, major ions, and nutrient concentrations were made to investigate how stream water and soil water chemistry changed over 16 months following the Table Mountain wildfire. Sites with different burn severity were also compared. The fire occurred in 2012 in Kittitas County, north of Ellensburg, Washington. Samples were collected at severely burned, moderately burned, and unburned field sites from within and adjacent to the wildfire perimeter. Total nitrogen concentrations increased in the second year after the fire in both the severely and moderately burned sites. In contrast, total phosphorus was variable at all three sites …

Coupled Geochemical And Nano-Petrophysical Study Of The Utica Play, Appalachian Basin, Ohio, U.S.A., Dillon Worley

Earth & Environmental Sciences Theses - Archive

Being more extensive than the Marcellus Play, the Utica Play covers from New York state in the north to northeastern Kentucky and Tennessee in the south. The Utica Play is a stacked play consisting of organic-rich mudstones from upper Ordovician units of Utica Shale, Point Pleasant, and the Logana member of the Lexington/Trenton Limestone. This study will focus on the pore structure and rock-fluid interaction and with relation to the rocks geochemical properties to assess the Utica Play. To achieve this research purpose, 7 core samples and 16 cuttings, with different maturities were collected from various wells, to study rocks …

Provenance Analysis Of The Grover Gravel Using Detrital Zircon Geochronology, Petrology And Heavy Mineral Analysis, Grant Spoering

Graduate Theses/Dissertations

The Grover Gravel in the St. Louis, Missouri area contains a mix of chert, quartzite, jasper, and ironstone in clast sizes ranging up to 60 cm. The gravel varies in thickness from a veneer to over 30 feet and rests on upland surfaces at elevations sometimes exceeding 300 feet above the floors of major valleys. A pre-Pleistocene age generally has been proposed or assumed for the gravel, which classically has been interpreted to be a meandering-stream deposit atop an extensive flat upland surface, which was subsequently eroded and dissected by rejuvenated streams. However, large quartzite boulders in the gravel also …

Geochemical Characteristics And Storm Dynamics Of Surface Waters And Groundwater At Eastern Kentucky University’S Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. Eastern Kentucky University’s Meadowbrook Farm raises crops and livestock, contributing dissolved nutrients to the neighboring Muddy Creek watershed. Consequently, the Farm is developing methods to sequester and limit nutrient contamination.

Before phosphorous sequestration methods can be tested, the geochemistry of surface water and groundwater on the Farm need to be better understood to determine hydrological pathways. We use naturally-occurring, dissolved cations as tracers to identify the contribution of different water sources and interpret storm events.

Water samples taken from springs (groundwater), surface water, and storm …

The Geochemistry Of Loess: Asian And North American Deposits Compared, Daniel R. Muhs

United States Geological Survey: Staff Publications

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the …

Investigating Core Shale Depositional Environments Of Late Pennsylvanian Cyclothems Utilizing Geochemical Proxies To Test The Superestuarine Model, Bryce A. Mathis

LSU Master's Theses

The Late Paleozoic Midcontinent Sea (LPMS) inundated vast areas of the North American interior during glacio-eustatic transgressions, depositing widespread black shales facies within the core shale intervals of major cyclothems. These black shale deposits are unique because no modern analogs can adequately explain the depositional environments and model for organic matter preservation across such vast ancient epicontinental settings. One possible explanation is that a superestuarine circulation system developed across the LPMS during humid interglacial phases, which promoted strong water column stratification and benthic anoxia.

The goal of this research was to test the validity of the superestuarine estuarine model and …