Earth Sciences Commons^™

The Impact Of Small Organic Acids On Iron And Manganese Mineral Transformations And The Fate Of Trace Metals, Elaine Denise Flynn

Arts & Sciences Graduate Student Theses and Dissertations

Iron and manganese oxides are ubiquitous in soils and sediments and play a critical role in the geochemical distribution of trace elements and heavy metals through adsorption and coprecipitation. At redox interfaces, biogeochemical processes generate conditions with coexisting dissolved Fe(II) and solid-phase Fe(III). In such systems, Fe(II) induces the recrystallization of iron oxides through coupled mineral growth and dissolution due to electron transfer as oxidative adsorption of Fe(II) and reductive dissolution of Fe(III) occur. Aqueous Mn(II) adsorption onto Mn(III/IV) oxides also likely involves oxidation although likely through different mechanisms than that of the Fe system because of the potential for …

Full Issue 47(1)

International Journal of Speleology

No abstract provided.

Table Of Contents

International Journal of Speleology

No abstract provided.

Investigating Trace Metal Sequestration Of Reducing Environments In Modern And Ancient Settings, Adam Charles Turner

LSU Doctoral Dissertations

The incorporation of trace metals into a variety of reducing sediments are important proxies for the oxic state of the water mass in which the sediments form. While much work has been done interpreting these proxies, questions remain on the exact processes and products in which trace metal proxies form. This work employs bulk geochemical techniques to investigate circulation in the Late Pennsylvanian North American Midcontinent Sea (NAMS), and then uses sequential extractions to further understand the chemical phases in which trace metals are incorporated. Sequential extractions are then used to further investigate how trace metals are sequestered in modern …

Speleogenetic Evolution And Geological Remote Sensing Of The Gypsum Plain, Eddy County, New Mexico, Jessica Shields

Electronic Theses and Dissertations

Permian evaporites of the Gypsum Plain region of the Delaware Basin host extensive karst phenomena, as well as unique diagenetic alterations of host strata. Because of the complex, poorly understood hydrogeologic system, little has been established concerning the relation and evolution of the overprinted, modern and ancient karst manifestations within the Gypsum Plain, as a whole. Through a combination of traditional field studies and the development of improved remote sensing methodologies, this study established the speleogenetic evolution of the Gypsum Plain in relation to the greater tectonic, stratigraphic, hydrogeologic and climatic history of the Delaware Basin. Emphasis was focused on …

A Geophysical Delineation Of A Normal Fault Within The Gulf Coastal Plain, Montgomery County, Texas, Danielle Minteer

Electronic Theses and Dissertations

The Gulf Coast of Texas has been a known hydrocarbon basin for many years with various structural trapping mechanisms such as anticlines, faults and salt domes. While most large salt domes have been extensively studied in the Gulf Coastal Plain, many smaller normal faults have not been studied in detail. This research study employs an integrated geophysical approach to mapping the Big Barn fault in Montgomery County, Texas. This fault is located on the Gulf Coastal Plain and is approximately 20 miles north of Houston, Texas. Most normal faults in the Gulf Coastal Plain formed as a result of the …

Is The Paris Agreement Already Poised For Failure? - Discerning How Impactful The Clean Power Plan's Fate Is On The Latest Global Climate Initiative, Shawn Eric Mckenzie

Georgia Journal of International & Comparative Law

No abstract provided.

Morphometric Change Detection Of Lake Hawassa In The Ethiopian Rift Valley, Yonas Abebe, Menberu Bitew, Tenalem Ayenew, Clement Alo, Assegid Cherinet, Mulugeta Dadi

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Ethiopian Rift Valley lakes have been subjected to environmental and ecological changes due to recent development endeavors and natural phenomena, which are visible in the alterations to the quality and quantity of the water resources. Monitoring lakes for temporal and spatial alterations has become a valuable indicator of environmental change. In this regard, hydrographic information has a paramount importance. The first extensive hydrographic survey of Lake Hawassa was conducted in 1999. In this study, a bathymetric map was prepared using advances in global positioning systems, portable sonar sounder technology, geostatistics, remote sensing and geographic information system(GIS) software analysis toolswith …

Patterns Of The Past: Mountain Hemlock And Pacific Northwest Climate, Aaron Snow, Dr. Matthew Bekker

Journal of Undergraduate Research

In July, 2016, I had the opportunity to attend the North American Dendroecological Fieldweek (NADEF) at Mount Rainier National Park, Washington. NADEF organizes the attendees into five different groups to undergo specific research projects all having to do with tree rings. My group, the intro group, hiked to the southern side of the park, assembled a chronology of mountain hemlock trees (Tsuga mertensiana), and observed notable attributes of the collected data. Because the fieldweek lasted only seven days, our research was minimal, which was why I applied for an ORCA grant in order to take the research to …

Birth And Evolution Of The Virgin River: ~1 Km Of Post-5 Ma Uplift Of The Western Colorado Plateau, Cory J. Walk

Earth and Planetary Sciences ETDs

The uplift history of the Colorado Plateau has been debated for over a century with still no unified hypotheses for the cause, timing, and rate of uplift. 40Ar/39Ar dating of semi-continuous basaltic volcanism over the past ~6 Ma within the Virgin River drainage system, southwest Utah and southern Nevada, provides a way to calibrate differential river incision and compare patterns of basaltic migration, mantle velocity structure, channel steepness, lithology, incision history and the birth and evolution of the Virgin River. New detrital sanidine ages constrain the arrival of the Virgin River across the Virgin Mountains to a maximum depositional age …

Lava, Ash Flows, Mudslides And Nasty Gases: Good Reasons To Respect Volcanoes, Brittany Brand

Geosciences Faculty Publications and Presentations

Volcanoes are beautiful and awe-inspiring, but the ongoing eruption of Kilauea on Hawaii’s Big Island is showing how dangerous these events can be. So far this event has destroyed dozens of homes and displaced hundreds of people, but no deaths or serious injuries have been reported. Other volcanic eruptions have had deadlier impacts.

Physical Processes Dictate Early Biogeochemical Dynamics Of Soil Pyrogenic Organic Matter In A Subtropical Forest Ecosystem, Jason Stuart, Russell Anderson, Patrick Lazzarino, Kevin A. Kuehn, Omar R. Harvey

Faculty Publications

Quantifying links between pyOM dynamics, environmental factors and processes is central to predicting ecosystem function and response to future perturbations. In this study, changes in carbon (TC), nitrogen (TN), pH, and relative recalcitrance (R50) for pineand cordgrass-derived pyOM were measured at 3–6 weeks intervals throughout the first year of burial in the soil. Objectives were to (1) identify key environmental factors and processes driving early-stage pyOM dynamics, and (2) develop quantitative relationships between environmental factors and observed changes in pyOM properties. The study was conducted in sandy soils of a forested ecosystem within the Longleaf pine range of the United …

Predicting Spatial Patterns In Precipitation Isotope (Δ2h And Δ18o) Seasonality Using Sinusoidal Isoscapes, Scott T. Allen, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding how precipitation isotopes vary spatially and temporally is important for tracer applications. We tested how well month‐to‐month variations in precipitation δ18O and δ2H were captured by sinusoidal cycles, and how well spatial variations in these seasonal cycles could be predicted, across Switzerland. Sine functions representing seasonal cycles in precipitation isotopes explained between 47% and 94% of the variance in monthly δ18O and δ2H values at each monitoring site. A significant sinusoidal cycle was also observed in line‐conditioned excess. We interpolated the amplitudes, phases, and offsets of these sine functions across the landscape, using multiple linear …

Transient Reactivation Of A Deep-Seated Landslide By Undrained Loading Captured With Repeat Airborne And Terrestrial Lidar, Adam M. Booth, Justin Mccarley, Jason Hinkle, Jean-Paul Ampuero, Michael P. Lamb

Geology Faculty Publications and Presentations

Landslides reactivate due to external environmental forcing or internal mass redistribution, but the process is rarely documented quantitatively. We capture the three-dimensional, 1-m resolution surface deformation field of a transiently reactivated landslide with image correlation of repeat airborne lidar. Undrained loading by two debris flows in the landslide’s head, rather than external forcing, triggered reactivation. After that loading, the lower 2 km of the landslide advanced by up to 14 m in 2 years before completely stopping. The displacement field over those 2 years implies that the slip surface gained 1 kPa of shear strength, which was likely accomplished by …

A Speleothem Record Of Climate Variability In Southwestern North America During Marine Isotope Stage 3, Justin G. Peinado

Earth and Planetary Sciences ETDs

During Marine Isotope Stage 3 (MIS-3) of the last glacial period, there were rapid transitions between warm and cold climates referred to as Dansgaard-Oeschgerr (DO) events. In Southwestern North America (SWNA), two speleothem paleoclimate records document changes in moisture source delivery in response to DO-events during MIS-3, but do not address potential changes in effective moisture for the region. In this study, we introduce a new high-resolution speleothem paleoclimate record from Carlsbad Cavern in the Guadalupe Mountains. The speleothem, sample BC-5, grew continuously from 46-31 kya during the latter half of MIS-3, based on U-Th dating. We also tied stable …

Gwas For Fusarium Head Blight Related Traits In Winter Wheat (Triticum Aestivum L.) In An Artificially Warmed Treatment, Elisane W. Tessmann, David A. Van Sanford

Plant and Soil Sciences Faculty Publications

Global temperature increases will affect Fusarium head blight (FHB) levels in wheat (Triticum aestivum L.). A pressing question is whether current sources of resistance will be effective in a warmer environment. We evaluated phenotypic response to disease in 238 soft winter wheat breeding lines and cultivars grown in 2015–2016 and 2016–2017 under control and warmed (+3 °C) conditions. Warming was achieved with heating cables buried 3 cm in the rhizosphere. We measured heading date, plant height, yield, FHB rating, Fusarium damaged kernels (FDK), deoxynivalenol (DON), leaf blotch rating, powdery mildew rating and leaf rust rating. There were significant ( …

Preliminary Sedimentology And Stratigraphy Of The Enigmatic Middle Lake Beds Succession (Pleistocene?) In The Rukwa Rift Basin, Tanzania, Cassy Mtelela

Tanzania Journal of Science

This paper presents sedimentology and stratigraphic overview of a series of previously unrecognized lithostratigraphic unit in the Rukwa Rift Basin, Tanzania. Based on the cross-cutting relationship and pilot detrital zircon geochronology, these isolated, enigmatic strata are herein informally termed the middle Lake Beds (mLB). Facies analysis reveals that the mLB units were deposited within a complex array of depositional environments, ranging from alluvial to fluvial channels, floodplains and shallow lakes.  The mLB are characterised herein as isolated outcrop exposures with uncertain age relationships, but which can be divided into five distinctive lithostratigraphic units herein identified as informal members (A-E). These …

Indoor Radon Concentration Levels And Annual Effective Doses For Residence Of Houses Near Uranium Deposit In Bahi District, Dodoma, Tanzania, Najat K. Mohammed, Erasto Focus

Tanzania Journal of Science

The objective of this study was to determine the levels of indoor radon concentration in houses in Bahi District situated in the neighbourhood of uranium deposit. The study aimed also to assess the annual effective dose due to indoor radon exposure to individuals residing in the houses as a step to control the radon exposure in Tanzania. Two villages were involved in this study; Bahi Makulu, which is within the proximity of Uranium deposit and Bahi Sokoni, which is about 7 km from the deposit. The Indoor radon concentration levels were detected using Alpha Guard radon monitor and the obtained …

Assessment Of Indoor Radon-222 Concentrations In The Vicinity Of Manyoni Uranium Deposit, Singida, Germana W Mlay, Ismael N Makundi

Tanzania Journal of Science

This study aimed to assess indoor radon concentrations in the vicinity of the Manyoni Uranium Deposit in Singida. The concentrations were measured for two months in 32 houses in the vicinity of Manyoni Uranium Deposit and 9 houses at Manyoni town using a portable radon gas monitor (Alpha –GUARDTM). The radon concentrations ranged from 27±3 to 518±28 Bq/m3with the overall mean of 166±12 Bq/m3 which is above recommended values of 100 Bq/m3 and 148 Bq/m3 set by WHO (World Health Organization) and EPA (Environmental Protection Agency's), respectively. The overall mean of indoor radon concentrations from each village were Kipondoda (169±13 …

Geochemical Fingerprints Of Glacially Eroded Bedrock From West Antarctica: Detrital Thermochronology, Radiogenic Isotope Systematics And Trace Element Geochemistry In Late Holocene Glacial-Marine Sediments, Patric Simões Pereira, Tina Van De Flierdt, Sidney R. Hemming, Samantha J. Hammond, Gerhard Kuhn, Stefanie A. Brachfeld, Cathleen Doherty, Claus-Dieter Hillenbrand

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Geochemical provenance studies of glacial-marine sediments provide a powerful approach to describe subglacial geology, sediment transport pathways, and past ice sheet dynamics. The marine-based West Antarctic Ice Sheet (WAIS) is considered highly vulnerable to ocean warming and sea level rise that is likely to cause its rapid and irreversible retreat. Studies of its past response to climate change are hence essential for projecting its future behaviour. The application of radiogenic and trace element provenance studies for past ice sheet reconstructions requires surveying the geographic variability of geochemical compositions of glaciomarine sediments. In this study, we characterize the provenance of the …

Comparing Strip Trials Of Chicken Litter, Compost, Hog Manure, And Wet Cattle Manure On Soil Fertility, Tanner Douma, Emily Hummel, Wendi Jo Vande Voort

Student Work

Utilizing agriculture animal and biodegradable waste can reduce the input costs of fertilizers while enhancing the soil. This comparative study focuses on the nutrient values soil receives from agricultural waste. The central objective was, “Due to the historical over-application of manure leading to environmental concerns, a comparative study of soil fertility and economic viability of manures and compost are analyzed in a one-year study”. On an 18.7 acre corn plot, 11 strips were applied with four different manure types, which were randomized, during the 2017 growing season. Chicken litter, compost, hog manure, wet cattle manure, and control strips were replicated …

Petrographic And Stratigraphic Analysis Along The Lower Cretaceous Strata, In Kimble County Texas, Austin C. Wilkerson

Student Publications

The upper Trinity Group is predominantly a carbonate system with minor clastic couplets that were deposited during the Middle Cretaceous in the south Llano Uplift region. The upper Trinity Group was deposited on a southward dipping platform in the Kimble County area. Stratigraphic units of the upper Trinity Group are the Hensel Formation, determined to be supratidal claystones, the Glen Rose Formation, which are mudstones that were deposited in a carbonate lagoon, and the Walnut and Fort Terrett formations, which are wackestones to packstones interpreted to have been deposited on a shallow carbonate shelf.

Nine stratigraphic sections were measured along …

Cyanobacteria Reduce Quagga Mussel (Dreissena Rostriformis Bugensis) Spawning And Fertilization Success, Anna G. Boegehold, Nicholas S. Johnson, Jeffrey L. Ram, Donna R. Kashian

Environmental Science and Geology Faculty Research Publications

Quagga mussels (Dreissena rostriformis bugensis) are highly fecund broadcast spawners invasive to freshwaters of North America and western Europe. We hypothesized that environmental cues from phytoplankton can trigger gamete release in quagga mussels. Nutritious algae may stimulate dreissenid spawning, but less palatable food, such as bloom-forming cyanobacteria, could be a hindrance. The objective of our study was to test whether exposure to cyanobacteria can inhibit quagga mussel spawning and fertilization. We assessed spawning in the presence of serotonin, a known spawning inducer, where adult quagga mussels placed in individual vials were exposed to 13 cyanobacteria cultures and purified algal toxin …

Heat/Mortality Sensitivities In Los Angeles During Winter: A Unique Phenomenon In The United States, Adam J. Kalkstein, Laurence S. Kalkstein, Jennifer K. Vanos, David P. Eisenman, Paul Grady Dixon Ph.D.

Geosciences Faculty Publications

Background: Extreme heat is often associated with elevated levels of human mortality, particularly across the mid-latitudes. Los Angeles, CA exhibits a unique, highly variable winter climate, with brief periods of intense heat caused by downsloping winds commonly known as Santa Ana winds. The goal is to determine if Los Angeles County is susceptible to heat-related mortality during the winter season. This is the first study to specifically evaluate heat-related mortality during the winter for a U.S. city. Methods: Utilizing the Spatial Synoptic Classification system in Los Angeles County from 1979 through 2010, we first relate daily human mortality to synoptic …

Quantifying Factors That Influence Road Deicer Retention And Export In A Multi-Landuse Upstate New York Watershed, David Joseph Saba

Graduate Dissertations and Theses

Chloride contamination of streams and groundwater has become a prevalent issue throughout urbanizing areas in the last half century, particularly in northern latitudes where deicing salts are applied to roadways. This study determined how deicer impacted runoff disperses through sub-urban and urban areas on seasonal and multi-year scales. Chloride concentration changes were then modelled under varying pollutant loading scenarios through an integrated catchment model (INCA-Cl).

Six in-stream conductivity/stage/temperature sondes, recording at 15-minute intervals, were installed within the small (~9.6 km2) Fuler Hollow Creek multi-landuse watershed in Broome County NY and monitored over a 1-year period. Weekly grab samples were taken …

Estimating Sand Loss: Using Eolian Sand Ramps As A Proxy For Estimating Past Erosion Within The Lincoln City Dune Sheet; Lincoln City, Oregon, Kara E. P. Kingen, John Bershaw, Curt D. Peterson

Student Research Symposium

Eolian sand ramps are features that are sculpted from beach sand blowing up against sea cliffs or bluffs. In some coastal areas, sand ramp deposits only appear as the erosional remnants of pre-existing ramps that have been truncated at eroded shorelines, separating them from their previous sediment supply. Although sand ramp features have been observed in other areas on the western coast of the United States , they had not been studied or documented within the Lincoln City Dune Sheet (LINC) prior to this study – which documents the existence of truncated eolian sand ramps in LINC and uses them …

Assessment Of Observed Increases In Extreme Warm Exceedances In Locations With Short Warm Side Tails, Jacob S. Hunter, Paul C. Loikith, J. David Neelin

Student Research Symposium

Regions of shorter-than-Gaussian temperature distribution tails have been shown to occur in spatially coherent patterns in the current climate using reanalysis. Under such conditions, future changes in extremes due to global warming may manifest in more complex ways than if the underlying distribution were closer to Gaussian. For instance, under a uniform warm shift, the simplest prototype for future warming, a location with a short warm side tail would experience a greater increase in exceedances than if the distribution were Gaussian. This carries meaningful societal and environmental implications including but not limited to negative impacts on human and ecosystem health, …

Petrographic And Stratigraphic Analysis Along The Lower Cretaceous Strata, In Kimble County Texas, Austin C. Wilkerson

Electronic Theses and Dissertations

The upper Trinity Group is predominantly a carbonate system with minor clastic couplets that were deposited during the Middle Cretaceous in the south Llano Uplift region. The upper Trinity Group was deposited on a southward dipping platform in the Kimble County area. Stratigraphic units of the upper Trinity Group are the Hensel Formation, determined to be supratidal claystones, the Glen Rose Formation, which are mudstones that were deposited in a carbonate lagoon, and the Walnut and Fort Terrett formations, which are wackestones to packstones interpreted to have been deposited on a shallow carbonate shelf.

Nine stratigraphic sections were measured along …

Changing Snow Seasonality In The Highlands Of Kyrgyzstan, Monika Tomaszewska, Geoffrey Henebry

NASA Land-Cover Land-Use Change Data Sets

Few studies have examined changing snow seasonality in Central Asia. Here, we analyzed changes in the seasonality of snow cover across Kyrgyzstan (KGZ) over 14 years from 2002/03–2015/16 using the most recent version (v006) of MODIS Terra and Aqua 8 day snow cover composites (MOD10A2/MYD10A2).We focused on three metrics of snow seasonality—first date of snow, last date of snow, and duration of snow season—and used nonparametric trends tests to assess the significance and direction of trends. We evaluated trends at three administration scales and across elevation. We used two techniques to assure that our identification of significant trends was not …

Analysis Of Surface Soil Lead Contamination In Urban Neighborhoods Of Davenport, Ia, Joseph Teresi

Geology: Student Scholarship & Creative Works

Davenport, IA, is a typical Midwestern city with a population of ~102,600 residents and is characterized by aging infrastructure and housing stock. Consequently, alarmingly high rates of child lead poisoning—as a result of deteriorating lead paint—constitute a major public health concern in some urban neighborhoods. Augustana College’s Upper Mississippi Center is an organization that helps urban and rural communities solve sustainability challenges by mobilizing the college’s resources. In conjunction with their Sustainable Working Landscapes Initiative (SWLI), a research team conducted free home lead screenings in vulnerable Davenport neighborhoods to better understand the severity of the problem. Via appointment, 27 homes …