Earth Sciences Commons^™

Boulder Streams, Debris Fans, And Pleistocene Climate Change In The Blue Ridge Mountains Of Central Virginia, G. Richard Whittecar, Derek W. Ryter

OES Faculty Publications

The west slope of the Blue Ridge mountains in central Virginia is a polygenetic landscape containing interglacial and periglacial features. This paper proposes a general model relating the distribution and origin of hillslope and toeslope Quaternary landforms to climatically influenced geomorphic processes. Two generations of interglacial debris fans in the study area differ in their degree of soil development and clast weathering. Boulder streams, which clog debris flow chutes for the upper debris fans, are interpreted as solifluction features formed during successive periglacial episodes. Growth of the boulder streams and associated talus slopes can influence the magnitude and frequency of …

A Paleoenvironmental Analysis Based On Ostracode Assemblages From The Late Pliocene Tuapaktushak And Middle Pleistocene Karmuk Members Of The Gubik Formation Of The Arctic Coastal Plain, Western Alaska, D. E. Loehrke

OES Theses and Dissertations

This study records and analyzes ostracode assemblages recovered from sediments assigned to the Late Pliocene Tuapaktushak and Middle Pleistocene Karmuk members of the Gubik Formation in the Skull Cliff area of the Arctic Coastal Plain in western Alaska. Forty-three species were identified from 47 samples (25 from the Tuapaktushak Member and 23 from the Karmuk Member). Samples were grouped by Q-mode cluster analysis and by member assignment for the purpose of analysis.

Paleoenvironmental analyses of ostracode assemblages representative of each cluster suggest all samples, regardless of cluster membership, were deposited in similar marine environments where water depths were in the …

The Geomorphology Of Alluvial Fan Deposits On The West Flank Of The Blue Ridge, Augusta County, Virginia, Debra Lynn Duffy

OES Theses and Dissertations

Large coalescing alluvial fans mantle the carbonate and shale formations west of the Blue Ridge mountains near Stuarts Draft, Virginia. Fan sediments are predominantly boulder and cobble gravels derived from the Antietam Quartzite, The fan complex consists of three alluvial units of significantly different ages. The surface of each fan unit was mapped using relative geomorphic position, soil color, clay content and thickness of Bt horizons, clast weathering, and degree of removal of depositional surfaces by stream incision. A five-category quartzite clast weathering scale developed for this study was very effective as a measure to distinguish map units. Stratigraphic data …

Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon

OES Faculty Publications

Hydrothermal plumes associated with nearshore lava flows from Kilauea Volcano, Hawaii were studied on five occasions during 1989-1990 to address the current lack of data on direct lava-seawater interactions. The following enrichments were found in the sea-surface hydrothermal plumes above the active underwater lava flows: H₂, 15,000x ambient seawater concentrations; Mn, 250x; and Si, 20x. Water temperatures reached 46°C. Lower concentrations and temperatures were observed in the plumes with increasing distance from shore, with H₂, Si, and Mn concentrations linearly related to seawater temperature. Unlike deep sea spreading center hydrothermal plumes, no CH₄ enrichment was …

The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige

OES Faculty Publications

The kinetics of sulfate reduction and inorganic nutrient production (ΣCO_2, ammonium, and phosphate) were examined in the sediments at five sites in the southern Chesapeake Bay, using long term (> 200 d) sediment decomposition experiments. Average first order rate constants for these processes (at 25^oC) decreased from 8.2 to 3.7 yr^-1 in the surface sediments (0-2 cm), to 2.1 to 0.2 yr^-1 at 12-14 cm. The C/N and C/P ratios of the organic matter undergoing decomposition also increased with depth at these sites. Taken together, these results indicate that the reactivity of the organic matter …

A Geophysical And Geological Study Of The Farmville Triassic Basin, Charles G. James Jr.

OES Theses and Dissertations

The Farmville basin is one of many Triassic basins which are found along the eastern coast of North America, and is the largest of the central string of basins in Virginia. Meta-volcanic and metasedimentary rocks of the Chopawamsic Formation, as well as felsic intrusives are the primary lithologies surrounding the basin. A detailed gravity survey was conducted along six roads that trend approximately NW-SE, across the basin. Geologic, gravity, magnetic, and radiometric data were used to develop a kinematic model. Gravity anomalies were isolated using two-dimensional harmonic analysis methods to isolate the local, and regional anomalies. This analysis indicates that …

Hydrogeology And Water Budget Analysis Of Two Interdunal Ponds Nags Head Woods Ecological Preserve, Dare County, North Carolina, Richard A. Hisert

OES Theses and Dissertations

Ground-water-fed interdunal ponds in Nags Head Woods Ecological Preserve lose as much as 7600 m³ yr^-1 of water through evaporation. This withdrawal of groundwater is sufficient to significantly alter flow patterns through the surficial aquifer on Bodie Island, N.C. Statistical analyses of evaporation estimates derived by various methods indicate a weak correlation, (r²=0.4-0.5) between pan evaporation data from Aurora, N.C. and pond evaporation at Nags Head Woods calculated by water budget analyses.

Results of stratigraphic and pedologic analyses in and around the ponds indicate that the ponds formed after development of multiple generations of dunes. This …

Trace Metals And Pyrite In Sediments Of Chesapeake Bay, Robert S. Kluckhohn

OES Theses and Dissertations

The formation and cycling of iron sulfides within anoxic sediments can affect the cycling of trace metals. The sediments at station CB-27 (near Annapolis, Maryland) in Chesapeake Bay were rich in FeS (39% of TS), low in greigite (3.6% of TS), and has a relatively constant pyrite concentration (50 - 60% of TS) with depth. The percent composition of total metals in pyrite were 25.7% cu, 11.8% Zn, 15.8% Fe, and non-detectable to 2.1% Cd. At Station CB- 28 (near the Choptank River), the sediments were low in FeS (1.7% of TS), richer in greigite (up to 14% of TS), …

The Hydrogeology And Leachate Generation Of An Alum Sludge Lagoon Chesapeake Virginia, Charles M. Darling

OES Theses and Dissertations

In 1986 the City of Chesapeake, Virginia began to dig shallow ponds ("lagoons") to contain alum sludge, a waste generated by the City from the process of treating potable water. Borings at the disposal site reveal that the near-surface geologic units include a thin mud-rich facies which overlies a thick sandy facies, both of which are in the Lynnhaven Member of the Tabb Formation. At 7 meters depth, a clay-rich facies of the Yorktown Formation (Morgarts Beach Member?) underlies the sandy water table aquifer. Water levels from twenty observation wells and two monitoring wells installed into the water table aquifer …

The Role Of Longshore Sediment Transport In The Loss Of Fill Material From An Estuarine Groin System, R. Neville Reynolds

OES Theses and Dissertations

The influence of shoreline structures on longshore sediment transport and the evolution of a stable beach planform was investigated at Willoughby Spit, Virginia following the placement of 410,590 cubic meters of beach fill within a groin system. Shoreline changes and wave conditions in a single groin compartment, and the growth rate of a downdrift terminal spit were monitored during 1985 and 1986. Short term fluctuations in the shoreline position within the groin compartment suggested an episodic westerly movement of sediment through the groin system. Primary sediment moving events were associated with northerly winds which produced waves up to 50 cm …

Metal Mobilization From A Near-Shore Lake Sediment Under Simulated Acidic Groundwater Inputs, Raveendra V. Ika

OES Theses and Dissertations

Simulation of acidic groundwater passing through lake sediments was conducted under controlled conditions in a laboratory. Three sediment cores collected intact from the near-shore region of an acidic lake were subjected to simulated groundwater inputs of initially identical chemistry for a seven day period. Following this period water being used in the simulation for two of the sediment cores was acidified by hydrochloric acid (HC1) addition to examine the ability of these sediments to neutralize acidic groundwater with varying H⁺ concentration.

Simulated acidic water passing through the sediment cores mobilized significant amounts of metals. The sediment acted as a …

A Comparison Of Metals In Several Ahermatypic Corals And Surficial Sediments: Mobile Pinnacles And Hoffa Reef, Northcentral Gulf Of Mexico, Kathryn M. Conko

OES Theses and Dissertations

Metal concentrations in marine sediment and carbonate secreting invertebrates are representative of surrounding environmental chemistry. Aluminum, Ba Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, and Zn were measured in carbonate and terrigenous phases of the $<$63 um fraction of sediment samples from two locations in the northcentral Gulf of Mexico. Enrichment factors indicate that Al, Ba, Cu, Cr, Mg, Mn, and Ni are all slightly depleted in these sediments relative to crustal abundances. Discriminant function analyses shows that the concentrations of five elements differ between locations.

Ahermatypic coral (106 specimens) from five genera collected from the study sites were analyzed for Cd, Cu, Cr, Pb, Zn, Mn, Sr, Ba, Fe, Ca and Mg. Eight elements vary between some genera, Al and Ba also vary in concentration in corals between either location. All elements except Sr are significantly depleted in the coral with respect to Ca in the …

Middle Eocene Foraminifera From The Piney Point Formation Of The Virginia And Maryland Coastal Plain, Megan S. Jones

OES Theses and Dissertations

This study examines the foraminiferal fauna, both benthic and planktonic, of the outcropping (45 samples) and subsurface (31 samples) middle Eocene Piney Point Formation in Virginia and Maryland. The primary objective of this study is to further refine the depositional history of the Salisbury Embayment which is represented by the middle Eocene Piney Point Formation. Ninety-six species of benthic and planktonic foraminifera were identified in this study. Of these, several are characteristic of the middle Eocene: Asterigerina texana, Hanzawaia danvillensis, Ceratobulimina exima, Cibicides westi, Chiloguembelitria columbiana, C. stavensis, Testacarinata inconspicua and Pseudohastigerina wilcoxensislmicra. While these were relatively abundant, diagnostic middle …

A Geophysical Study Of The Easternmost Piedmont: Brunswick County, Virginia, Mark A. Corbin

OES Theses and Dissertations

Gravity and magnetic models indicate that a steeply dipping, mylonitic shear zone recognized by reconnaissance mapping in the easternmost Piedmont of Brunswick County, Virginia is a listric fault. A pronounced 3 to 5 mgal Bouguer anomaly high is associated with the fault zone. A band of N10° trending aeromagnetic anomalies delineate the areal extent of the fault zone. The fault zone flattens eastward over a short distance to a depth of 15 kms where it joins a near horizontal surface that cuts across the region. This surface is herein interpreted to be a decollement. The fault zone of this study …

Lithofacies Of The Pliocene Yorktown Formation In The Vicinity Of Kingsmill On The James River, Virginia, Michael David Lawless

OES Theses and Dissertations

The Yorktown Formation beds which crop out along the James River in southeastern Virginia near Kingsmill and Carter's Grove are lithologically described in order to compare them with the "typical" Yorktown beds upriver in the area of Fort Boykins, Rushmere, and Cobham Wharf. Thirty-four stratigraphic sections are constructed of the bluffs along the river. The Yorktown beds in the area of Kingsmill and Cobham Wharf are divided into ten lithofacies: the silty sand facies (B), the Chesapecten facies (C), the Glycymeris facies (D), the Chama facies (E), the glauconitic biofragmental sand facies (F), the laminated silty clay facies (G), the …

Identification And Quantitation Of Volatile Amines In Marine Sediments, Chuen Mei Huang

Chemistry & Biochemistry Theses & Dissertations

Pore waters which were taken from sediments of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A purge-and-trap technique was used to concentrate the amines. Then, following derivatization with heptaflourobutyric anhydride, the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One secondary amine, diethylamine with a concentration of 0.3-0.6 uM, was found in a total of three pore water samples from cores collected on two different dates. A primary amine, sec-butylamine with a concentration of O. 05 AIM, was also found in one of these same samples. Another primary …

The Geomorphology And Surficial Geology Of The West Flank Of The Blue Ridge, Sherando Area, Virginia, Derek Weston Ryter

OES Theses and Dissertations

The west flank of the Blue Ridge near Sherando, Virginia (Augusta County) consists of many landforms including talus slopes, bedrock cliffs, boulder streams, colluvial slopes, residual knobs, and debris fans. The purpose of this study is to describe the geomorphic history of the area by understanding the spatial and temporal relationships between landforms on the hillslopes.

Boulder streams (maximum 30 m wide, 400 m long, 6.1 m thick) exhibit a gently dipping imbricated fabric and basal shear stresses of 0.1 to 0.4 bars.

Debris fans in Group L (lower) and Group U (upper) are distinguished by topographic position, degree of …

Sulfide In Surface Waters Of The Western Atlantic Ocean, Gregory A. Cutter, Christian F. Krahforst

OES Faculty Publications

Using newly developed techniques, some preliminary data on hydrogen sulfide in surface waters of the western Atlantic have been obtained. Concentrations of total sulfide range from <0.1 to 1.1 nmol/L, and vary on a diel basis. At these concentrations, sulfide may affect the cycling of several trace metals via the formation of stable complexes. Production of sulfide in oxygenated seawater may occur through the hydrolysis of carbonyl sulfide or by sulfate reduction within macroscopic particles in the water column. Removal mechanisms can include oxidation, complexation with particulate trace metals, and metal sulfide precipitation. However, the temporal and spatial distributions suggest a complex set of processes governing the behavior of sulfide in the surface ocean.

Recent Benthic Foraminifera Of Breton And Stake Islands Northern Gulf Of Mexico, Eric S. Collins

OES Theses and Dissertations

Fifty-three species of recent benthic foraminifera and thecamoebians have been documented and described from the Breton and Stake Island area, northern Gulf of Mexico, and from a core from Barataria Basin, Mississippi delta.

Cluster analysis of benthic assemblages using presence/absence and transformed abundance data reveals the presence of a marsh and shallow water marine biofacies. Based on the results of a presence/absence cluster analysis, the shallow water marine biofacies can be subdivided into a miliolid biofacies am an Ammonia beccarii/Elphidium species biofacies. Cluster analysis of transformed abundance data, however, shows that the shallow marine biofacies can be subdivided into four …

Structural Geology Of Page Valley, Page County, Virginia, Tamera J. Warden

OES Theses and Dissertations

Page Valley contains folded and faulted Cambro-Ordovician rocks that were deformed during the Pennsylvanian-Permian Alleghanian Orogeny. Previous authors (Allen, 1967; Thornton, 1953; and King, 1950) have mapped "high-angle" faults and a klippe along the South Fork of the Shenandoah River west of Luray, Virginia. The southernmost fault offsets the New Market/Lincolnshire and Edinburg formations with the upthrown block to the west. Thornton suggested gravity sliding and strike-slip movement to explain normal displacements along the northernmost fault where the Edinburg Formation is in contact with overturned beds of the Beekmantown Formation. A klippe, as mapped by Allen and Thornton, lies on …

Trace Elements In Northern Virginia Middle Ordovician Carbonates: Implications For Diagenesis, Ruth Ann Strauss

OES Theses and Dissertations

Ninety-three carbonate rock samples collected from four of the major lithofacies types present in the Middle Ordovician limestone sequence of northwestern Virginia were analyzed to investigate whether the lithofacies bear the geochemical signature of the depositional and/or the diagenetic environment. Significant variations in Cr, Fe, Mg, Mn and Sr concentrations exist among the major lithofacies types. Low levels of Sr in both New Market lithofacies are indicative of an open system during diagenesis. Dissimilar Fe and Mn concentrations between these, however, reflect water chemistry differences in the depositional environment. Increasingly greater Cr, Fe, Mn, and Sr concentrations in the Lincolnshire …

Nutrient Cycling In Bordenstake Bay Sediments: A Backbarrier Lagoon, Mark J. Herrenkohl

OES Theses and Dissertations

Six sets of sediment cores were collected over a one year period (June 1986 to July 1987) to examine nutrient cycling in Bordenstake Bay, a back barrier lagoon on Virginia's Eastern Shore Peninsula. The sampling times were chosen to examine any seasonal effects (e.g., temperature changes) which may affect the rates of metabolism in these sediments.

The sedimentation rate in Bordenstake Bay is 0.76 ± 0.21 cm/yr, leading to the annual deposition of 7. 05 moles of carbon, 0.46 moles of nitrogen, and 0.15 moles of phosphorus, per square meter of the sediment surface. The remineralization of organic matter in …

Holocene Geology And Migration Of A Low-Profile Barrier Island System, Metompkin Island, Virginia, Mark R. Byrnes

OES Theses and Dissertations

Analysis of historical shoreline position, cross-island profile change, and stratigraphic data provided a shoreline response model for low-profile barrier island systems. Historical shoreline data illustrates continuous, shore-parallel retreat between 1852 and 1957, at which time the island narrowed to a width of approximately 200 m. Between 1957 and 1981, ephemeral inlet breaching along southern Metompkin Island disrupted longshore sediment transport, increased the rate of shoreline recession, and resulted in differential rates of retreat associated with an abrupt break in backbarrier morphology. By 1981, a 400 m offset had formed at a position midway along Metompkin Island, suggesting that ephemeral inlet …

Foraminiferal Biostratigraphy And Paleoenvironmental Analysis Of The Anahuac Formation (Late Oligocene-Early Miocene) From A Deep Well In Vermilion Parish, Louisiana, Audrey Lynne Orndorff

OES Theses and Dissertations

In the subsurface of Vermilion Parish, Louisiana, sediments from the Anahuac Formation in the #1 J. W. Steen well are assigned an Upper Oligocene-Lower Miocene age based on planktonic foraminifera. Previous age determinations for sediments from this formation elsewhere range from Middle to Late Oligocene based on the presence of larger foraminifera contained within these strata. Planktonic foraminifera in Anahuac formation sediments in the #1 J. W. Steen well permit their assignment to an established worldwide zonation scheme and indicate that the age ranges from the Globorotalia kugleri Interval Zone (Upper Oligocene) to the Catapsydrax dissimilis Zone (Lower Miocene). Benthic …

Sulfide In Shelf/Slope Waters Of The Western Atlantic, Christian F. Krahforst

OES Theses and Dissertations

Sulfide in the surface ocean has been recently considered as a source of hydrogen sulfide gas in the marine boundary layer. This "oxic" sulfide may also be important as a ligand in trace metal complexation. In the absence of actual data, the existence of sulfide in the ocean mixed layer remains speculative. The purpose of this study was to develop a sensitive technique (having picomolar detection limits) for the determination of sulfide in seawater, and to investigate the distribution of sulfide in the surface ocean.

In order to assess the abundance and distribution of sulfide in surface waters, samples were …

Discrimination Of Subparallel Beach Ridges Using Detrital Ilmenite Composition And Fourier Shape Analysis, Allen E. Evans Jr.

OES Theses and Dissertations

Elemental composition (Fe, Ti, Mn, Mg, V, Cu, Ni, Zn, and Cr) and Fourier shape analysis of magnetically separated detrital ilmenite from seven Pleistocene and modern beach sand deposits of the Southeastern Virginia Coastal Plain were used to distinguish each deposit. Geomorphic expression, crosscutting relationships and proximity to the present shoreline differentiates the relative age of the seven sampled beach deposits. Analysis of ilmenite elemental composition, independent of geomorphic expression, distinguished beach sands of

different age and was successful in determining that each beach contained ilmenite similar in composition. Of the seven beach ridges tested, subtle yet significant differences in …

The Geochemistry Of Selenium And Sulfur In A Coastal Salt Marsh, David Jay Velinsky

OES Theses and Dissertations

Investigation of the various chemical forms of selenium and sulfur in sediments and pore waters can provide information about various oxidation/reduction processes. Five cores were obtained from the Great Marsh, from April 1985 to June 1986. Sampling times coincided with the seasonal redox cycle known to occur within the marsh system. Sediments were analyzed for various selenium and sulfur phases.

Iron monosulfides and elemental sulfur both display large seasonal changes in concentration and distribution with depth, indicating a coupling with redox conditions. In contrast, the depth distribution of greigite did not show appreciable changes with season. Pyrite underwent large concentration …

The Stratigraphy Of Late Quaternary Deposits In The Payan Mining District, Narino, Colombia, South America, Richard Alan Barringer

OES Theses and Dissertations

Late Quaternary terrace deposits along the Rio Magui consist of cobble or pebble gravels with thick volcanic ash caps. These gravel terrace deposits unconformably overlie a cemented volcanic tuff (Ananias Formation), and are subdivided into two formations (Antigua and Panambi formations) based on the cobble lithology and size, depth of weathering, geomorphic relationships, and heavy mineral assemblages. Carbon-14 dates from wood suggest that the Antigua fan deposits are older (greater than 40,000 YBP) than the lower Panambi alluvium (less tahn 25,000 YBP) which is restricted to lower terraces within the modern river valleys.

Two separate ash units identified by differences …

Provenance Of Sands Within The Lower Chesapeake Bay Based On Ilmenite Composition, Edward Augustus Council Iii

OES Theses and Dissertations

Surficial sands deposited in the Chesapeake Bay are a mixture of sands derived from the bay's shorelines, from offshore, and from relict deposits. Direct fluvial input is probably minor except from the James River, which may serve as a local source of sands in the Thimble Shoals area. Sands in the western half of the bay are primarily derived from the erosion of the adjacent shoreline. In contrast, the eastern half of the bay has two major sources of sand. Shoreline erosion is the dominant source north of the town of Eastville, Virginia, while the offshore is the major source …

Depositional And Diagenetic History Of The Middle Ordovician Carbonates Of The Shenandoah Valley, Northern Virginia, Lynn Ellen Weyenberg

OES Theses and Dissertations

An examination of the Middle Ordovician carbonates in northwest Virginia has revealed a particularly sensitive record of deposition and subsidence. Two-hundred acetate peels from six measured stratigraphic sections in Shenandoah County, Virginia were examined to interpret the depositional and diagenetic history. Two major lithofacies have been recognized within the New Market Limestone and three have been recognized in the Lincolnshire Formation. These five lithofacies represent an overall transgressive sequence. This transgression was not uniform but paused several times to allow carbonate deposition to reach sea-level. These shoaling events suggest a slowly subsiding basin in this region. The carbonate rocks within …