Earth Sciences Commons^™

The Effect Of Arctic River Hydrological Cycles On Arctic Ocean Circulation, Peter Becker

OES Theses and Dissertations

Understanding Arctic Ocean circulation may be critical to fully understanding the global oceanic salt and heat cycles and their response to climate variability. This thesis examines how one important aspect of Arctic Ocean circulation, the effect of freshwater inflow, may contribute to the variability of these cycles. The multiple roles that freshwater runoff performs in the Arctic Ocean include: (1) the formation of shelf and basin scale density currents; (2) maintenance of the strong density stratification; (3) control of the thickness and strength of the ice pack; and (4) control of deep convection. Sources and sinks of freshwater in the …

Late Cretaceous Foraminifera As Indicators Of Sequence Boundaries, Book Cliffs, Utah, U.S.A., Kimberly A. Smith

OES Theses and Dissertations

Foraminiferal assemblages were described from three different depositional settings within the Upper Cretaceous (Campanian) Blackhawk Formation of Utah (known marginal marine environments, known marine environments, and along a suspected sequence boundary). Assemblages from the known marginal marine setting (as defined by sedimentologic-stratigraphic criteria) consisted of entirely agglutinated taxa dominated by Textularia sp. A. Assemblages from the known marine environment consisted of a mix of calcareous and agglutinated species, dominated by calcareous species (e.g., Gavelinella talaria). The foraminiferal assemblages from these known environments provide independent evidence that these sampled areas are characterized by marginal marine and fully marine deposits.

The foraminiferal …

Elimination Of Dissolved Sulfide Interference In The Flow-Injection Determination Of Sigma-Co2 By Addition Of Molybdate, Rigel L. Lustwerk, David J. Burdige

OES Faculty Publications

A previously described flow injection method for the analysis of ΣCO₂ included the addition of ZnCl₂ to some samples before analysis in order to precipitate dissolved sulfide (which interferes with the method) as ZnS. However, the use of Zn²⁺ in samples with high concentrations of dissolved sulfide causes the coprecipitation of ZnCO₃, and in our experience with this technique, ZnCO₃ also precipitates even in the absence of dissolved sulfide. The addition of molybdate effectively complexes dissolved sulfide without interfering with the determination of ΣCO2 by this technique.

Seismic Stratigraphic Analysis Of The Upper Indus-Fan Complex A Model For Fan Development, Syed Firasat Shah

OES Theses and Dissertations

The seismic stratigraphic analysis of the upper Indus-Fan Complex has revealed the presence of six depositional sequences. Deposition of these sequences occurred primarily during the Miocene period. The Indus River drainage system that developed as a consequence of Himalayan orogeny transported the bulk of the sediments deposited in the Indus Fan. The distribution and thickness of the sequences of the upper Indus Fan are closely related to the canyon-channel systems. Seismic facies analysis of the slope has revealed the presence of a facies relationship that shows continued deepening from the time of deposition of slope fan to the latest deposits …

Geology Of An Archean Greenstone Belt At Point Lake, Northwest Territories, Canada, Patrick Rowan Considine

OES Theses and Dissertations

Several well-preserved circa 2.6 Ga Archean granite-greenstone belts are exposed in the Slave Province of Northwest Territories, Canada. At Point Lake, a "supracrustal sequence" comprised mainly of mafic volcanic and metasedimentary rocks lies over and east of a granitoid gneissic terrane. Field and laboratory studies have helped to clarify the petrography and structural relationships of this fold-and-thrust belt. Traditional models have suggested that granite-greenstone belts in the Slave Province are relict continental rifts in which volcanic and sedimentary rocks filled troughs in older sialic crust. However, this study supports a collisional model for the Slave Province, in which oceanic crust …

The Influence Of Saprolite Composition Texture And Structure On Groundwater Flow In The Piedmont Province Henry County Virginia, John Thomas Russell

OES Theses and Dissertations

At a 500 acre site in Henry County, Virginia, differences in vertical hydraulic conductivity (K_V) and lateral hydraulic conductivity (K_H) measured in saprolites formed from the Fork Mountain biotite gneiss and the Leatherwood granite reflect the control of the fabric, texture, and structure of the parent rock preserved within the saprolite horizon. Using subsurface data collected from approximately 350 boreholes in conjunction with published information enabled various maps to be generated that identify the spatial relationships between geology and topography and their influence on the nature of the saprolite aquifer.

Measurements of K_H determined from …

The Speciation Of Dissolved Uranium In Marine Waters, Darrin Kent Mann

OES Theses and Dissertations

Uranium has been used extensively for quantifying geochemical processes in the marine environment. Due to its low concentration, about 3.3 μg/1, some form of preconcentration is required for analysis. The two most widely used pre-concentration schemes are co-precipitation with iron hydroxide, and chelating ion exchange chromatography. These methods were developed by following the behavior of inorganic uranium isotopes and seemed to give identical results. However, when used for trace metal analysis, these methods have been shown to extract different fractions from the same sample. Chelex-100 resin removes only inorganic or weakly bound trace metals from a solution, while the precipitates …

Invariant Manifolds Of A Toy Climate Model, Michael Toner

Mathematics & Statistics Theses & Dissertations

According to astronomical theory, ice ages are caused by variations in the Earth's orbit. However, ice core data shows strong fluctuations in ice volume at a low frequency not significantly present in orbital variations. To understand how this might occur, the dynamics of a two dimensional nonlinear differential equation representing glacier/temperature interaction of an idealized climate was studied. Self sustained oscillation of the autonomous equation was used to model the internal mechanisms that could produce these fluctuations. Periodic parametric modulation of a damped internal oscillation was used to model periodic climate response at double the external modulation period. Both phenomena …

The Biogeochemistry Of Hydrogen Sulfide: Phytoplankton Production In The Surface Ocean, Russell S. Walsh, Gregory A. Cutter, William M. Dunstan, Joel Radford-Knoery, Jennifer T. Elder

OES Faculty Publications

Hydrogen sulfide can exist in oxic waters in the form of a dissolved gas, dissociated ions, dissolved metal sulfide complexes, and particulate metal sulfides. The sum of the dissolved species is termed total dissolved sulfide (TDS). In addition to the hydrolysis of carbonyl sulfide, it has been speculated that phytoplankton may produce TDS. We present results from preliminary culture studies which demonstrate that phytoplankton produce TDS and particulate acid-volatile sulfide (pAVS). The phylogenetic order of TDS + pAVS production (per unit cell volume) for the oceanic species examined is Synechococcus sp. > Emiliania huxleyi ≈ Pyramimonas obovata > Thalassiosira oceanica. Moreover, …

Biogeochemical Control Of Phosphorus Cycling And Primary Production In Lake Michigan, R. S. Walsh, Gregory A. Cutter, W. M. Dunstan, J. Radford-Knoery, J. T. Elder

OES Faculty Publications

A 3-yr study in Lake Michigan has shown a 27 mmol P m^-2 increase in the mass of total P (TP) in the water during spring when the lake is mixed from surface to sediment. This value is an order of magnitude greater than the annual P input from external sources. TP changed in concert with increases in chlorophyll a and organic N and decreases in nitrate and soluble Si. The concentration of soluble reactive PO_4^-3 (SRP) remained relatively constant throughout the study. We hypothesize that the SRP concentration is maintained by a chemical equilibrium with calcium-phosphate …

Periodic And Homoclinic Orbits In A Toy Climate Model, M. Toner, A. D. Kirwan Jr.

Mathematics & Statistics Faculty Publications

A two dimensional system of autonomous nonlinear ordinary differential equations models glacier growth and temperature changes on an idealized planet. We apply standard perturbative techniques from dynamical systems theory to study small amplitude periodic orbits about a constant equilibrium. The equations are put in cononical form and the local phase space topology is examined. Maximum and minimum periods of oscillation are obtained and related to the radius of the orbit. An adjacent equilibrium is shown to have saddle character and the inflowing and outflowing manifolds of this saddle are studied using numerical integration. The inflowing manifolds show the region of …

The Dinoflagellate Flora Of The Late Oligocene - Early Miocene Old Church Formation Mid-Atlantic Coastal Plain, Alan P. Hoffmeister

OES Theses and Dissertations

The Old Church Formation contains the only presently known exposed Oligocene sediments in the North American mid-Atlantic Coastal Plain. Some ambiguity concerning the exact age of the Old Church Formation exists because it may include both Oligocene and Miocene sediments. Two outcrops and four cores containing the Old Church Formation were examined for dinoflagellates to determine the composition of the dinoflagellate flora in the Old Church Formation, the age of the Old Church Formation as indicated by this flora, general depositional environment of the Old Church Formation and correlative relationships of the Old Church Formation with other Coastal Plain units. …

Quaternary Seismic Stratigraphy Of The Inner Shelf And Coastal Zone, Southern Delmarva Peninsula, Virginia, Anthony M. Foyle

OES Theses and Dissertations

The Pleistocene stratigraphic record beneath the Virginia inner shelf is largely unknown. On the adjacent lower Atlantic Coastal Plain of southeastern Virginia, the Pleistocene record consists of seven stacked transgressive sequences, while on the southern Delmarva Peninsula, a series of three transgressive to highstand sequences are developed. Reconstruction of the mid-Atlantic basin margin response to high-frequency Quaternary glacioeustasy is limited by this sparse record of late transgressive through early regressive deposition. Knowledge of high-frequency depositional sequence architecture, developed under conditions of low subsidence (to net uplift) and low sediment input, is also incomplete. The Atlantic inner shelf and coastal zone, …

A Comparison Of No And N20 Production By The Autophic Nitrifier Nitrosomonas Europaea And The Heterotrophic Nitrifier Alcaligenes Faecalis, Iris C. Anderson, Mark Poth, Julie Homstead, David J. Burdige

OES Faculty Publications

Soil microorganisms are important sources of the nitrogen trace gases NO and N₂O for the atmosphere. Present evidence suggests that autotrophic nitrifiers such as Nitrosomonas europaea are the primary producers of NO and N₂O in aerobic soils, whereas denitrifiers such as Pseudomonas spp. or Alcaligenes spp. are responsible for most of the NO and N₂O emissions from anaerobic soils. It has been shown that Alcaligenes faecalis, a bacterium common in both soil and water, is capable of concomitant heterotrophic nitrification and denitrification. This study was undertaken to determine whether heterotrophic nitrification might be …

Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna

Chemistry & Biochemistry Theses & Dissertations

Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.

Three-Dimensional Transport Simulations Of The Dispersal Of Volcanic Aerosol From Mount Pinatubo, T. Duncan A. Fairlie

Mechanical & Aerospace Engineering Theses & Dissertations

A global finite-difference model that simulates the large-scale dynamics of the Earth's stratosphere and mesosphere is combined with a global spectral transport model to investigate aspects of the initial dispersal of the volcanic aerosol plume from the Mount Pinatubo eruption in 1991. Results of the modelling study are found to compare well with observations of the volcanic plume made from satellite instruments. Dynamical quantities, diagnosed from the simulated fields are used to provide insight into the evolution of the volcanic plume. Lagrangian trajectory analysis is used to help assess the performance of the Eulerian transport model and to highlight small-scale …

The Biogeochemistry Of Iodine In Seawater, Lingsu Zhang

OES Theses and Dissertations

Iodate and iodide are the two major species of iodine in seawater. In comparison to iodate, iodide is thermodynamically unstable in oxic seawater. The conversion (or reduction) of iodate to iodide may be mediated via biological activities. Since biological activities vary with the season, the conversion of iodate to iodide may also vary seasonally. The conversion (or oxidation) of iodide to iodate is thermodynamically feasible, but the mechanism is poorly known. Hydrogen peroxide, which is ubiquitous in surface seawater, may oxidize iodide to iodate.

Water samples were collected in the middle and lower Chesapeake Bay in different seasons between 1990 …

Lithofacies Of The Pliocene-Pleistocene Lucayan Limestone, Great Abaco Island, Little Bahama Bank, Mary K. Mullen

OES Theses and Dissertations

Petrographic and sedimentologic analyses of eleven shallow subsurface cores (3 to 19 meters in length) from the Lucayan Limestone where it occurs along northeastern Great Abaco Island (little Bahama Bank) are used to delineate five carbonate lithofacies. The most prevalent lithofacies is a mottled, nonskeletal, peloidal packstone to grainstone. Other lithofacies include a rudstone, a laminated nonskeletal grainstone, a crossbedded grainstone and a mudstone-wackestone.

Cementation varies from poor to very well cemented core intervals. Cements observed included equant granular, equant blocky, drusy, meniscus, and needle fiber "whisker" cements. These cements reflect a variety of diagenetic environments such as the vadose, …

Paleobathymetric Interpretation Of Pleistocene Sediments In The South Padre Island Area, Northwestern Gulf Of Mexico, Using Benthic Foraminiferal Morphology, Karen Ianthe Kruebbe-Belwood

OES Theses and Dissertations

This study tested the validity of using intraspecific variation in benthic foraminifera as a means for determining Pleistocene paleobathymetry. Canonical variate analysis was used as a means for determining visually undetectable but statistically significant differences in the morphology of selected species. Two species, Cassidulina subglobosa and Uvigerina peregrina, were collected from Pleistocene well cuttings from the northwest Gulf of Mexico. The canonical analysis involved comparing the intraspecific variation of these Pleistocene species to their counterparts occurring in the modern Gulf of Mexico, where intraspecific variation was previously analyzed and found to be sufficient to allow detection of bathymetric differences …

Petrology Of A Large Granophyre-Rich Mesozoic Diabase Dike Near Farmville, Virginia, Philip Thomas Rogan

OES Theses and Dissertations

Up to 37% granophyre occurs in the center of a 150m-wide Mesozoic diabase dike near Farmville, Virginia. The exceptional abundance of granophyre compared with other Mesozoic diabase dikes suggests unusual petrogenetic processes are involved in formation of the dike. Petrographic analyses show that granophyre increases from 5-10% near the flanks of the dike to a maximum of 37% in the core of the dike, and that granophyre distribution is approximately symmetrical about the center of the dike. Major and trace element concentrations parallel variations in the modal abundance of granophyre, with SiO₂ , Na₂O and K_{2 …}

Recent Benthic Foraminifera, Petrology, And Implications For Recent Transport In Wilmington And South Heyes Submarine Canyons, U.S. Atlantic Continental Margin, Jason James Lundquist

OES Theses and Dissertations

Two hundred and forty-six species of benthic foraminifera have been recognized in fourteen short cores (≤ 24cm) taken from within the Wilmington and South Heyes submarine canyons along the slope and rise of the United States Atlantic Continental Margin. Of these one hundred and forty-five species were identified to the species level, thirty were closely related to known species, sixty-six could not be assigned specific names, and five species were of uncertain generic placement. The petrologic character of the sediments was determined for each of the seventy-eight micropaleontogical samples.

Cluster analysis of benthic foraminiferal data identified twelve groups which, together …

Paleocene To Miocene Foraminifera From A Well Near Gloucester, Virginia, Nelson Stanley Ford

OES Theses and Dissertations

Lithologic analysis of twenty-one core samples from a well near Gloucester, Virginia, when compared to published descriptions of formations occurring in the study area, indicates the presence of five formations. From oldest to youngest these units are the Aquia (late Paleocene), Nanjemoy (early Eocene), Chickahominy (late Eocene), Old Church (late Oligocene and early Miocene), and Eastover (late Miocene) formations. Comparison of the stratigraphic ranges of key planktic and benthic foraminifera from each of the core samples shows chronological agreement with previously published ages for each of these formations.

Paleoenvironmental analysis of each of the formations in the well is based …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

Ground Water Investigation Of The Petersburg Granite In Chesterfield County, Virginia, Michael W. Bennett

OES Theses and Dissertations

Yields of new water wells in areas underlain by the Petersburg Granite in Chesterfield County, Virginia should improve if procedures for site selection and well construction follow the new guidelines proposed. These guidelines integrate analyses of aerial photo linears and drainage patterns, survey of bedrock joints and shallow geophysical properties and techniques using several statistical methods.

Throughout the study area, fracture traces form in nearly the same orientation as bedrock fractures. The dominant N-S and E-W trending bedrock joints also corresponded to aerial photo linears of similar orientation.

Across one large fracture zone, both gamma-ray and electrical resistivity surveys reveal …

Fluid Inclusion Studies Of The Morefield Pegmatite Amelia County, Virginia, John Richard Smerekanicz

OES Theses and Dissertations

The Morefield Pegmatite is a planar, nearly vertical body situated in Grenville age gneisses and schists in the southeast Piedmont of Virginia. It consists of a mineralogically simple albite-quartz outer zone and a texturally and mineralogically complex inner zone of microcline-topaz-quartz, with trace amounts of rare-element minerals. Fluid inclusions in samples of quartz, topaz, beryl, spessartite and albite that span the length, width and depth of both zones can be classified by chemical composition into two main groups: H₂O-rich solutions and CO₂- H₂O -rich fluids. The H₂O -rich inclusions consist of H …

Mat Movement In Coastal Louisiana Marshes: Effect Of Salinity And Inundation On Vegetation And Nutrient Levels, Christopher Martin Swarzenski

Biological Sciences Theses & Dissertations

The present research compared and contrasted the physical structure of floating and rooted marshes, their differing responses to open-water salinities and inundation, as well as the nutrient distribution in the porewaters and sediment. The effects of the physical differences in the two marsh types on the ocurrence of the dominant emergent vegetation was discussed.

The main difference in physical structure of the two marsh types was the presence of a mineral, non-buoyant layer at 25-45 cm depth in the rooted marsh, which could serve as an anchor for the overlying highly organic mat layer found in both marsh types. Porewater …

Evaluation Of Late Mesozoic And Cenozoic Tectonism: Atlantic Inner Coastal Plain Margin Near Richmond, Virginia, Andrew A. Gremos

OES Theses and Dissertations

A combined geologic, geophysical, and geomorphic analysis of the Virginia Inner Coastal Plain margin near Richmond was conducted to investigate the presence of basement structures and to evaluate their influence on the overlying sedimentary package and present-day landscape. Basement structures identified included north-northeast and northwest oriented faults that appear to bound and transect a north-northeast trending early Mesozoic basin or basins and other pre-existing zones of weakness. Observed offsets are propagated upward through the pre-Miocene strata in the form of reverse faults and flexuring. Fracture sets measured in the Petersburg Granite and overlying Coastal Plain units, stream drainage lines, and …

Relation Of Groundwater Fluoride Concentrations To Sediment Mineralogy, Potomac Formation (Cretaceous), Southeastern Virginia, Paul Anthony Maciuika

OES Theses and Dissertations

Thirty-seven Early cretaceous sediment samples of the Potomac Formation were obtained from four cores to determine if fluoride bearing minerals are responsible for elevated fluoride concentrations in Potomac Formation groundwaters of southeastern Virginia. Investigative methods included total sediment fluoride and particle size analysis, semiquantitative mineralogical analysis (achieved by X-Ray Diffraction) and statistical methods (cluster, canonical and regression analysis). The sediments showed wide variation in textures, ranging from clean sands and gravels to silty clays. Sediment mineralogies were dependent on the prevailing size fraction, with quartz and feldspar dominating the sand and silt fractions, muscovite primarily being found in the silt …

Distribution Of Foraminifera And Pollen In Coastal Depositional Environments Of The Southern Delmarva Peninsula, Virginia, U.S.A., Han Jun Woo

OES Theses and Dissertations

The coastal zone of the southern Delmarva Peninsula exhibits a wide variety of barrier island system subenvironments. This study investigates whether 20 a priori subenvironments can be distinguished from each other on the basis of abiotic environmental variables, pollen assemblages, living foraminiferal populations, and total (living plus dead) foraminiferal assemblages.

The physical data collected from the coastal zone were subjected to canonical variate analysis which discriminated 83% of the stations in 19 groups. These groups were clustered into two internally overlapping sets which represented the inside and outside of the inlet.

Twenty-two pollen types were found in low-energy marsh and …

The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens

OES Faculty Publications

Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …