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- 2-arylprop-1-en-3-yltrimethylammonium iodides (2)
- 1 (1)
- 1-difluoro-1 (1)
- 2 (1)
- 2-aryl-3-fluoroalkoxy-1-propenes (1)
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- 2-mercapto-1-methylimidazole thioethers (1)
- 2-trifluoroethoxide (1)
- 3-(difluoromethylene)cyclohexene (1)
- 3-heptadiene (1)
- AIBN) (1)
- Ammonium salts (1)
- Benzenethiol adducts (1)
- Chemical reactions (1)
- Double dehydrohalogenation (1)
- Ester hydrolysis (1)
- Free radical addition (1)
- Hydration (1)
- Isopropyl acetate intermediate (1)
- Lemieux–von Rudloff oxidation (1)
- Liquid-phase direct hydration (1)
- Mechanism of fluoroalkoxylation (1)
- Organic compounds -- Synthesis (1)
- P-toluenesulfonic acid (1)
- Radical initiator comparison (benzoyl peroxide (1)
- Sodium 2 (1)
- Sodium benzenesulfinate reactions (1)
- Sodium perborate oxidation to 2-aryl-3-phenylsulfonyl-1-propenes (1)
- Sulfuric acid catalysis (1)
Articles 1 - 4 of 4
Full-Text Articles in Other Chemistry
The Synthesis Of 2-Aryl-3-Fluoroalkoxy-1-Propenes And Some Potentially Useful Reaction Of These Systems, Joan E. Brown
The Synthesis Of 2-Aryl-3-Fluoroalkoxy-1-Propenes And Some Potentially Useful Reaction Of These Systems, Joan E. Brown
Retrospective Theses and Dissertations
This report discusses research involving the fluoroalkoxylation of 2-arylprop-1-en-3-yltrimethylammonium iodides and the useful synthetic application of the adducts formed. The present work includes: 1) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with the sodium salt of 2,2,2-trifluoroethanol; 2) reactions of several fluoroalkoxy alcohols with 2-(4-bromophenyl)prop-1-en-3-yltrimethylammonium iodide; and 3) the oxidation of 2-(4-chlorophenyl)-3-(2,2,2-trifluoroethyoxy)-1-propene using the Lemieux/von Rudloff reagent. This report reveals the experimental conditions and procedures used as well as spectral and physical data of all new compounds synthesized. Explanation is offered for a possible mechanism for the formation of these compounds and recommendations for future research are given.
Preparation Of Geminal Diflourodienes, Antonio Landavazo
Preparation Of Geminal Diflourodienes, Antonio Landavazo
Retrospective Theses and Dissertations
This report discusses research involving the preparation of germinal difluorodienes. Free radical addition of dibromodifluoromethane to 1-hexene and cyclohexene was performed, followed by a double dehydrohalogenation to yield 1,1-difluoro-1,3-heptadiene and 3-(difluoromethylene)cyclohexene, respectively. NMR, IR, and mass spectral data were obtained and presented as groundwork for further research. A study comparing the free radical initiators, benzoyl peroxide and 2,2’-azobis-(2-methyl)proprionitrile (AIBN) was included, showing neither as ideal initiators for the free radical additions performed. The relative stabilities of the bromodifluoromethyl and the difluoroiodomethyl radicals were approximated. A Diels-Alder reaction of 1,1-difluoro-1,3-heptadiene with 4-phenyl-1,2,4-triazoline-3,5-dione produced the expected [4 + 2] cycloadduct in good …
Hydration Of Propylene To Isopropanol, Nehemiah Diala
Hydration Of Propylene To Isopropanol, Nehemiah Diala
Retrospective Theses and Dissertations
The hydration of propylene to isopropanol was investigated. The first part of this study concerned the direct hydration reaction in various liquid phase systems in the presence of sulfuric acid or p-toluenesulfonic acid. The second part in a two-stage process in which propylene was contacted with excess acetic acid to form isopropyl acetate; the ester was then hydrolyzed to isopropyl alcohol and acetic acid.
The Reaction Of 2-Arylprop-1-En-3-Yltrimethylammonium Iodides With Sulfur Nucleophiles And Useful Synthetic Applications Of These Adducts, Steven J. Duranceau
The Reaction Of 2-Arylprop-1-En-3-Yltrimethylammonium Iodides With Sulfur Nucleophiles And Useful Synthetic Applications Of These Adducts, Steven J. Duranceau
Retrospective Theses and Dissertations
This report discusses research involving the reactions of 2-arylprop-1-en-3-yltrimethyl ammonium iodides with sulfur nucleophiles and the useful synthetic applications of the adducts formed. The present work may be subdivided into four sections: 1) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with benzenethiol; 2) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with the sodium salt of benzenesulfinic acid; 3) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with 2-mercapto-1-methyl imidazole; and 4) oxidation of 2-aryl-3-phenylthio-1-propenes and 2-aryl-3-phenylsulfonyl-1-propenes using sodium perborate. This report outlines the experimental conditions and procedures responsible for the synthesis of these products; in addition, this report describes the physical properties, NMR and IR spectra of …