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Medicinal-Pharmaceutical Chemistry Commons

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University of Nebraska - Lincoln

Series

1995

Articles 1 - 2 of 2

Full-Text Articles in Medicinal-Pharmaceutical Chemistry

Preparation Of Doped Polycarbynes, Reuben D. Rieke Jan 1995

Preparation Of Doped Polycarbynes, Reuben D. Rieke

Chemistry Department: Faculty Publications

Polycarbynes, such as doped polycarbynes, prepared from a soluble source of electrons and an organic monomer or co-monomer containing at least one carbyne group and, optionally, containing a doping agent, in an ethereal, poly ethereal, or hydrocarbon solvent are presented. A wide variety of arylcarbyne and/or alkylcarbyne monomers and co-monomers can be combined with a source of electrons soluble in an ethereal, polyethereal, or hydrocarbon solvent to form novel polycarbyne polymers. These polycarbyne polymers can be used to form synthetic diamond materials, fibers, and other materials that can withstand extreme con ditions.


Preparations Of Polycarbynes, Reuben D. Rieke Jan 1995

Preparations Of Polycarbynes, Reuben D. Rieke

Chemistry Department: Faculty Publications

Polycarbynes prepared from a soluble source of electrons and an organic monomer or co-monomer containing at least one carbyne group in an ethereal, polyethereal, or hydrocarbon solvent are presented. A wide variety of arylcarbyne and/or alkylcarbyne monomers and co-monomers can be combined with a source of electrons soluble in an ethereal, polyethereal, or hydro-carbon solvent to form novel polycarbyne polymers. These polycarbyne polymers can be used to form synthetic diamond materials, fibers, and other materials that can withstand extreme conditions.