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Articles 61 - 62 of 62
Full-Text Articles in Materials Chemistry
Photopolymerization And Characterization Of Crosslinked Thiol-Ene Networks And Poss/Thiol-Ene Nanocomposites, Tolecia Sharonda Shaunee Clark
Photopolymerization And Characterization Of Crosslinked Thiol-Ene Networks And Poss/Thiol-Ene Nanocomposites, Tolecia Sharonda Shaunee Clark
Dissertations
Interests in the area of thiol-ene photopolymerization are rapidly expanding due to the numerous advantages over the polymers produced by traditional solvent based polymerizations. Although current research of photoinitiated thiol-ene polymerization is diverse, numerous opportunities are available for investigating structure/property and structure/reactivity relationships and novel material applications. This research in this dissertation includes a fundamental study of the effect of monomelic thiol functionality on thiol-ene polymerization kinetics and formation of the thiol-ene network structure, and an investigation of the development of novel silicate based thiol-ene nanocomposites. The first fundamental study investigates the effect of thiol functionality on the kinetics and …
Investigations Of Poly[(Styrene-Co-P-Methylstyrene)-Risobutylene- R-(Styrene-Co-P-Methylstyrene)] And Poly[(Acrylic Acid)-5-Styrene-Jb-Is0butylene-5-Styrene-Jb-(Acrylic Acid)], James Grabill Kopchick
Investigations Of Poly[(Styrene-Co-P-Methylstyrene)-Risobutylene- R-(Styrene-Co-P-Methylstyrene)] And Poly[(Acrylic Acid)-5-Styrene-Jb-Is0butylene-5-Styrene-Jb-(Acrylic Acid)], James Grabill Kopchick
Dissertations
The pMe study was conducted to understand the morphological and physical property changes that occur as the ratio of pMe to styrene is increased, effectively increasing the aliphatic units. By the introduction of pMe, the interface region becomes more blended/compatible as the pMe migrates to the interface. These pMe groups are theorized in effect to create multiple ‘anchors’ to distribute the loads experienced at the interface more effectively creating a synergistic effect on the final properties of the copolymers. The primary goals of the pentablock study were the characterization of unique membranes as related to …