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Inorganic Chemistry Commons

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Full-Text Articles in Inorganic Chemistry

Synthesis Of Supported Metal Nanoparticles On High Surface Area Supports For Application In Energy Conversion And Heterogeneous Catalysis, Nazgol Norouzi Jan 2020

Synthesis Of Supported Metal Nanoparticles On High Surface Area Supports For Application In Energy Conversion And Heterogeneous Catalysis, Nazgol Norouzi

Theses and Dissertations

Precise control of metal nanoparticles’ size, composition, and dispersity over high surface area supports are highly desirable to address current challenges in energy storage and conversion as well as catalytic processes involving precious metals. Therefore, developing viable synthetic routes that enable new catalytic systems derived from inexpensive transition metals or limited use of precious metals is vital for clean energy applications such as fuel cells and rechargeable batteries or affordable drugs in the pharmaceuticals arena. In addition to metal components of heterogeneous catalysts, the catalyst support is an integral part of catalyst design as it can impart both physical stability …


Investigations Of Graphene-Supported Single-Atom Catalyst Model Ions In The Gas Phase, Michael Borrome Jan 2020

Investigations Of Graphene-Supported Single-Atom Catalyst Model Ions In The Gas Phase, Michael Borrome

Theses and Dissertations

Recent developments in heterogeneous catalysis has led to the conception of single-atom catalysts (SACs), a class of catalysts based on isolated metal atoms anchored to a support scaffold. SACs are often much more reactive and can offer better selectivity when compared to nano-scale catalysts. In order to realize the full potential of SACs, a sound understanding of the underlying catalytic mechanisms is required. However, surface analysis tools can become less effective in studying catalytic mechanisms at the atomic scale. Mass spectrometry has proven to be a robust technique for studying organometallic catalytic mechanisms at the single-molecule level. Using mass spectrometry, …