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Full-Text Articles in Inorganic Chemistry
(E)-9,10-Dihydro-9-Methyl-9-Nitro-10-(TrinitroMethYl)Anthracene, Mustafa Arslan, Ronald J. Baker, John Masnovi, Erol Asker
(E)-9,10-Dihydro-9-Methyl-9-Nitro-10-(TrinitroMethYl)Anthracene, Mustafa Arslan, Ronald J. Baker, John Masnovi, Erol Asker
Chemistry Faculty Publications
The title compound, C16H12N4O8, was prepared by the photochemical reaction of 9-methylanthracene and tetranitromethane in dichloromethane. Intermolecula face-to-face π–π stacking interactions are present along the a axis.
Covalently Networked Monolayer Protected Nanoparticle Films, D. J. Tognarelli, Robert B. Miller, Rebecca R. Pompano, Andrew F. Loftus, Daniel J. Shiebley, Michael C. Leopold
Covalently Networked Monolayer Protected Nanoparticle Films, D. J. Tognarelli, Robert B. Miller, Rebecca R. Pompano, Andrew F. Loftus, Daniel J. Shiebley, Michael C. Leopold
Chemistry Faculty Publications
No abstract provided.
Synthesis, Structural Studies And Desilylation Reactions Of Some N-2-(Trimethylsilyl)Ethyl-N-Nitrosocarbamates, Arpitha Thakkalapally, Vladimir Benin
Synthesis, Structural Studies And Desilylation Reactions Of Some N-2-(Trimethylsilyl)Ethyl-N-Nitrosocarbamates, Arpitha Thakkalapally, Vladimir Benin
Chemistry Faculty Publications
The present report describes the preparation and characterization of several N-2-(trimethylsilyl)ethyl-N-nitrosocarbamates, designed as precursors to thermally unstable secondary N-nitrosocarbamate anions via fluoride-assisted cleavage. X-ray structural studies demonstrate that the core N-nitrosocarbamate moiety has a nearly planar geometry, with an s-E orientation at the N–N bond. DFT calculations (B3LYP/6-31+G(d)) reproduce accurately the structural features of the title compounds and detailed conformational analysis at the same level of theory addresses the long-standing issue of preferred geometries for three classes of related structures: N-nitrosocarbamates, N-nitrosoureas and N-nitrosoamides. Desilylation studies demonstrate that both the …