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Full-Text Articles in Inorganic Chemistry
Synthesis And Characterization Of Heteronuclear Inorganic Complexes For The Photodegradation Of Persistant Organic Pollutants, Matthew A. Moyet
Synthesis And Characterization Of Heteronuclear Inorganic Complexes For The Photodegradation Of Persistant Organic Pollutants, Matthew A. Moyet
Electronic Theses and Dissertations
The focus of this thesis is to investigate the structural modification and characterization potential of common photocatalysts that have various uses for environmental remediation purposes. Pollution involving organic chemicals is one of the most common scenarios found in communities throughout the country. Efforts to rid contaminated drinking water supplies of these chemicals include physical and chemical filters, which have limited ability and efficacy. This lack of efficient filtration services has led to an increased demand for more effective treatment methods. Chemical species that react in the presence of light are known as photocatalysts and have been used in previous studies …
Development Of Bismuth Oxyhalide Photocatalysts For Environmental And Industrial Applications, Robert Arthur
Development Of Bismuth Oxyhalide Photocatalysts For Environmental And Industrial Applications, Robert Arthur
Electronic Theses and Dissertations
Heterogeneous semiconductor photocatalysis, of interest for water splitting and environmental remediation applications, uses light to drive reactions. Metal oxide and sulfide semiconductors have been previously studied but have limitations that include large band gap energies and high rates of recombination. Bismuth oxyhalides (BiOX) are an emerging class of photocatalysts with tunable band gaps and low rates of recombination due to their unique crystal structures. Studies of BiOX photocatalytic activity have largely focused on removal of azo dyes from aqueous solutions, with little attention paid to degradation byproducts. Furthermore, these catalysts have not been explored as a means to conduct organic …
Optical Memory Behavior, Metallophilic Luminescence, And Chemical Sensing Ability Of Inorganic And Organometallic Complexes: Development Of Optoelectronic Materials, Aaron D. Nicholas
Optical Memory Behavior, Metallophilic Luminescence, And Chemical Sensing Ability Of Inorganic And Organometallic Complexes: Development Of Optoelectronic Materials, Aaron D. Nicholas
Electronic Theses and Dissertations
This dissertation is divided into three sections: (1) optical memory, (2) metallophilic-based luminescence, and (3) chemical sensors. (1) Optical memory behavior of d10metal Cu(I) thiocyanate salts are investigated to explore their potential use in the development of digital data storage devices. From this study we have discovered a new class of CuSCN(3-BrPy)2optical memory material which undergo a reduction in emission intensity upon laser irradiation. This loss of emission intensity can be reversed simply by heating the sample to room temperature. The mechanism by which this emission loss occurs has been studied, revealing a migrating Br atom …
Luminescence Antenna Behavior In Lanthanide Complexes And Luminescence Sensing In Group 11 Iodides, Francis Barnes
Luminescence Antenna Behavior In Lanthanide Complexes And Luminescence Sensing In Group 11 Iodides, Francis Barnes
Electronic Theses and Dissertations
In this thesis luminescent materials are studied. The luminescent materials studied are lanthanide complexes and group 11 iodide sensing abilities. Emission intensity of the lanthanide complexes through direct excitation of the lanthanide ion are relatively weak. To overcome this, three unique organic ligands were utilized to synthesize lanthanide nitrate complexes in which higher emission intensity can be observed via the antenna effect. Increased emission intensity resulted for EuIII and TbIII complexes for each ligand except triphenylphosphane oxide (only the TbIII complex demonstrated increased emission intensity). Latva’s empirical rule allows for the antenna effect to occur, in which …