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Full-Text Articles in Inorganic Chemistry
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Man Lung Desmond Kwan
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Paul R. Challen
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.