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Inorganic Chemistry Commons

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Full-Text Articles in Inorganic Chemistry

The Synthesis And Characterization Of Novel Microporous Hybrid Organic/Inorganic Materials, Kelly Whitenack May 2009

The Synthesis And Characterization Of Novel Microporous Hybrid Organic/Inorganic Materials, Kelly Whitenack

Honors Capstone Projects - All

Inorganic chemistry is essential to the formulation and improvement of modern materials such as catalysts, semiconductors, optical devices, super conductors, and advanced ceramic materials.1 New areas of inorganic chemistry are constantly being explored and new and often unusual inorganic compounds are constantly being synthesized and identified.1 Recently the field of inorganic chemistry has witnessed the synthesis and characterization of microporous metal organic framework compounds (MOFs). Microporous organic/inorganic materials have a wide range of physical properties as well as applications. The physical properties and applications drive the investigation into the synthesis and discovery of new and useful hybrid MOF …


Preparation And Characterization Of Some Substituted Benzyl N-Nitrosocarbamates Containing An N-2-(Methylthio)Ethyl Or A Bis(2-Aminoethyl)Sulfide Functionality, Satya Venkata, Eric Shamo, Vladimir Benin Jan 2009

Preparation And Characterization Of Some Substituted Benzyl N-Nitrosocarbamates Containing An N-2-(Methylthio)Ethyl Or A Bis(2-Aminoethyl)Sulfide Functionality, Satya Venkata, Eric Shamo, Vladimir Benin

Chemistry Faculty Publications

The synthesis and characterization of some substituted benzyl N-nitrosocarbamates with an N-2-(methylthio)ethyl or a bis(2-aminoethyl)sulfide functionality is reported, as a part of a long-term goal to design and prepare novel photolabile structures that could be used as substances for controlled release of alkylating and/or crosslinking agents. The synthesis was accomplished by reaction of benzyl chloroformates with the corresponding amines, resulting in the preparation of carbamates. The latter were subsequently nitrosated, utilizing two different N-nitrosation methods, to yield the target structures.


Bowl-Shaped Polyaromatic Hydrocarbons (Buckybowls) : Crystal Packing And Metal Binding Reactions, Alexander S. Filatov Jan 2009

Bowl-Shaped Polyaromatic Hydrocarbons (Buckybowls) : Crystal Packing And Metal Binding Reactions, Alexander S. Filatov

Legacy Theses & Dissertations (2009 - 2024)

This work is a part of a broad program in our laboratory dedicated to the investigation of a new class of non-planar polyaromatic hydrocarbons that map onto the surfaces of fullerenes (and referred to as buckybowls). It focuses on the preparation of buckybowls, their molecular and solid state structures, and reactivity in metal binding reactions. For the first time, the structures of all available buckybowls have been analyzed using X-ray diffraction data collected in the course of this work, as well as data previously obtained in our group or reported by others (and dearchived from the Cambridge Structural Database). Forces …