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Full-Text Articles in Inorganic Chemistry
Investigating The Structure Of Metal-Organic Frameworks And The Behaviors Of Adsorbed Guest Molecules In Mofs Via Solid-State Nmr Spectroscopy, Yihao Shen
Electronic Thesis and Dissertation Repository
Metal-organic frameworks (MOFs) are a class of hybrid organic-inorganic microporous materials with lots of significant applications including gas capture and storage, gas separation, batteries, catalysis, ion exchange and drug delivery. MOFs based on s-block metals are important due to their many practical applications. These MOFs are also very interesting because the s-block MOFs often exhibit unpredictable behavior of coordination. In this thesis, the structures of six s-block metal (Li, Na, Cs, Mg, Ca, Sr) based MOFs involving V-shaped link, 4, 4′- sulfonyldibenzoate (SDB) are characterized by various techniques including, powder X-ray diffraction, TGA and solid-state NMR spectroscopy. 13C CPMAS …
Solid State Nmr Spectroscopic Studies Of Metal-Organic Frameworks, Peng He
Solid State Nmr Spectroscopic Studies Of Metal-Organic Frameworks, Peng He
Electronic Thesis and Dissertation Repository
Metal−organic frameworks (MOFs) are a class of novel porous materials with a wide range of chemical applications. Structural characterization is important because understanding the relationship between the properties of these industrially relevant materials and their structures allows one to develop new applications and improve current performance. In this thesis 17O solid state NMR (SSNMR) spectroscopy is used to differentiate chemically and, under favorite circumstances, crystallographically nonequivalent oxygens and to follow the phase transitions in MOF-based materials. Several cost-effective approaches were used to prepare 17O-labelled MOFs. The metal centers of MOFs, including 47/49Ti, 67Zn, 91Zr, 115 …
Solid-State Nuclear Magnetic Resonance Spectroscopy Of Unreceptive Quadrupolar Nuclei In Inorganic Materials, Andre Sutrisno
Solid-State Nuclear Magnetic Resonance Spectroscopy Of Unreceptive Quadrupolar Nuclei In Inorganic Materials, Andre Sutrisno
Electronic Thesis and Dissertation Repository
Preparation and characterization of inorganic materials is a crucial practice because understanding the relationship between structure and property is important for improving current performance and developing novel materials. Many metal centers in technologically and industrially important materials are unreceptive low-γ quadrupolar nuclei (i.e., possessing low natural abundance, low NMR frequencies and large quadrupole moments) and they usually give rise to very broad NMR resonances and low signal-to-noise ratios, making it difficult to acquire their solid-state NMR spectra. This thesis focuses on the characterization of inorganic materials using solid-state NMR (SSNMR) spectroscopy at very high magnetic field of …