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Full-Text Articles in Inorganic Chemistry
Studying Metal-Organic Frameworks Via Solid-State Nmr: Gas Dynamics, Structure Determination, And Phase Transition, Yue Zhang
Electronic Thesis and Dissertation Repository
Metal-organic frameworks (MOFs) are a class of microporous materials constructed from virtually endless combinations of metal centres and organic linkers. MOFs have attracted intense research interest in recent decades, since MOFs have outstanding properties such as extremely high surface area, tuneable pore topology, good stability, and many others. MOFs are also promising candidates for gas storage. In this work, solid-state NMR (SSNMR) spectroscopy has been investigated to study MOFs and their guest molecules, since SSNMR can provide information on the short-range environment about target nuclei and can also reveal the dynamics of guest molecules.
An introduction to MOFs and SSNMR …
Dynamic Studies Of Guest Molecules In Metal-Organic Frameworks And Zeolites Via Solid-State Nuclear Magnetic Resonance, Bowei Wu
Electronic Thesis and Dissertation Repository
Metal-organic frameworks (MOFs) are synthetic compounds with crystalline microporous structures, consisting of metal centres joined by organic linkers. Zeolites are a class of crystalline porous materials featuring negatively charged aluminosilicate frameworks and charge-balancing cations.
In this work, solid-state nuclear magnetic resonance (SSNMR) is used to probe guest molecule locations and dynamics in MOFs and zeolites, yielding detailed informations of guest motion within these porous materials
Chapter 2 describes SSNMR dynamic studies of 13CO2, 13CO and C2D4 adsorption behaviour in the α - zinc formate MOF, [Zn3(HCOO)6], which were performed …