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Articles 31 - 59 of 59
Full-Text Articles in Environmental Chemistry
Evaluation Of Chlorinated Solvent Removal Efficiency Among Three Wetland Plant Species: A Mesocom Study, Jun Yan
Theses and Dissertations
Different species of plants need to be studied individually to compare the remediation efficiency of each species. This research will study three different wetland plants species and an unplanted control, under a laboratory setting. Each plant has a different characteristic favorable for chlorinated solvent degradation. Eleocharis erythropoda (Spike Rush) are plants with thin tube like leaves and large root mass. Carex comosa (Bearded Sedge) has broad leaves and Scirpus atrovirens (Green Bulrush) are broad leafed wetland plants with a long flowering stem during reproduction. PCE will be injected into the plant mesocosm and any possible PCE degradation will be observed. …
An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney
An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney
Theses and Dissertations
In this study, application of a catalytic reactor to facilitate chemical reduction of perchlorate was investigated. Palladium-coated pellets were used as the catalyst, and formic acid was used as the reductant. Reactor performance was evaluated under a variety of operating conditions (influent pH, reductant concentration, residence time). Very little perchlorate reduction was observed under any operating condition. At best, approximately 8% perchlorate reduction was observed. This small reduction efficiency is clearly not sufficient for environmental treatment applications. Perchlorate strongly adsorbed to the catalyst at low pH (3 - 3.3). At higher pH (4 - 10), little adsorption was observed. This …
Optimal Sampling Of A Chemical Hazard Area, Jennifer R. Plourde
Optimal Sampling Of A Chemical Hazard Area, Jennifer R. Plourde
Theses and Dissertations
This thesis proposes a methodology for optimally sampling a chemical hazard area subsequent to a chemical weapons attack. The objective is to identify the maximum number of areas that no longer require protective gear for safe operations. We model the area as an undirected graph and employ network analysis techniques to provide a methodological framework for identifying an optimal sampling sequence within a fixed time limit. We propose four models that characterize the secondary vapor concentrations: i) static and deterministic, ii) static and stochastic, iii) dynamic and deterministic, and iv) dynamic and stochastic. Comparisons of the static cases and their …
Characterization Of Chlorinated Solvent Degradation Profile Due To Microbial And Chemical Processes In A Constructed Wetland, Teresa A. Sobolewski
Characterization Of Chlorinated Solvent Degradation Profile Due To Microbial And Chemical Processes In A Constructed Wetland, Teresa A. Sobolewski
Theses and Dissertations
Perchloroethene (PCE) and its degradation products are among the most common organic groundwater contaminants in the United States. Constructed wetlands are a relatively new approach to dealing with this contamination problem. With their upward flow capability it is possible to introduce an aerobic and anaerobic environment with a consortium of microorganisms available to degrade the contaminants to within acceptable levels established by the Environmental Protection Agency (EPA). This study is a follow-up to the previous two years of research on PCE degradation in cell 1 at Wright-Patterson Air Force Base. This thesis was conducted in order to study the wetland …
An Evaluation Of Formate As An Electron Donor To Facilitate Palladium (Pd) - Catalyzed Destruction Of Chlorinated Aliphatic Hydrocarbons, Matthew D. Welling
An Evaluation Of Formate As An Electron Donor To Facilitate Palladium (Pd) - Catalyzed Destruction Of Chlorinated Aliphatic Hydrocarbons, Matthew D. Welling
Theses and Dissertations
Chlorinated aliphatic hydrocarbons (CAHs) such as trichloroethylene (TCE), tetrachloroethylene (PCE), and trichloroethane (TCA) are probable human carcinogens that have been used widely within the DoD, primarily as solvents for cleaning and metal degreasing. These compounds are frequently found to be groundwater contaminants. In fact, TCE and PCE are the first and third most commonly detected groundwater contaminants nationwide. The focus of this study was to determine the effectiveness of using a palladium (Pd) catalyst with formate as a reductant to treat CAH-contaminated groundwater. TCE was used as a model CAH. Other investigators have focused on hydrogen gas (H2) …
An Evaluation Of Formic Acid As An Electron Donor For Palladium (Pd) Catalyzed Destruction Of Nitroaromatic Compounds, Mark R. Stevens
An Evaluation Of Formic Acid As An Electron Donor For Palladium (Pd) Catalyzed Destruction Of Nitroaromatic Compounds, Mark R. Stevens
Theses and Dissertations
The Department of Defense is responsible for over 2,000 hazardous waste sites containing nitroaromatic compounds (NACs) such as 2,4,6-TNT, 2,4- and 2,6-DNT that resulted from the production and use of munitions throughout the nation and world, NACs are typically persistent in natural environments, though they can be oxidized or reduced under engineered conditions, NACs and their reduction products are toxic chemicals and suspected human carcinogens, Both TNT and 2,4-DNT are listed as priority pollutants by the U,S EPA, This study investigates the effectiveness of using a palladium (Pd) catalyst in concert with formic acid as an electron donor to reduce …
Aerobic Biodegradation Of Alternative Fuel Oxygenates In Unsaturated Soil Columns, Kevin A. Mares
Aerobic Biodegradation Of Alternative Fuel Oxygenates In Unsaturated Soil Columns, Kevin A. Mares
Theses and Dissertations
Groundwater contamination problems caused by methyl-tertiary butyl ether (MTBE) in subsurface waters have prompted the search for a gasoline oxygenate replacement. In order to avoid the problems encountered with MTBE, it is prudent to evaluate the fate and transport in the subsurface of proposed replacements, such as ethanol. In this study, ethanol transport and degradation in unsaturated soil was investigated using a series of eight soil columns. This preliminary study was to see if the soil column system components functioned properly, how similarly the eight soil columns performed, and if soil oxygen concentration affected degradation of ethanol. Tracer tests, using …
Analysis Of Anion Distributions In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Joshua D. Kovacic
Analysis Of Anion Distributions In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Joshua D. Kovacic
Theses and Dissertations
Perchloroethene (PCE), Trichloroethene (TCE) and their degradation products are among the most common organic groundwater contaminants in the United States. Constructed wetlands utilizing upward flow harbor reduction-oxidation conditions that have demonstrated the potential to promote both partial and total mineralization of PCE and TCE through the process of natural attenuation. Organic acid and inorganic anion concentrations are indicative of reduction-oxidation processes that drive chlorinated ethene degradation. These analytes were investigated to assess their development within three vertically stratified regions of a constructed wetland cell at Wright-Patterson Air Force Base fed by groundwater contaminated with PCE and TCE. Data collected during …
Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Perchlorate Contaminated Groundwater, Jeffrey C. Parr
Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Perchlorate Contaminated Groundwater, Jeffrey C. Parr
Theses and Dissertations
Groundwater contamination by perchlorate has recently been recognized as a significant environmental problem across the United States, and especially at Department of Defense facilities. In this study, a model is used to evaluate the potential of a innovative in situ bioremediation technology using Horizontal Flow Treatment Wells (HFTWs) to manage perchlorate-contaminated groundwater. The technology uses HFTWs to mix an electron donor into perchlorate-contaminated groundwater in order to promote reduction of the perchlorate by indigenous microorganisms in bioactive zones within the aquifer, as well as recirculate the contaminated water between treatment well pairs to achieve multiple passes of contaminated water through …
An Anion Characterization Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Bradley M. Bugg
An Anion Characterization Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Bradley M. Bugg
Theses and Dissertations
Chlorinated ethenes physical properties as well as its ubiquitous state at DOD installations makes it a priority for innovative remediation efforts. Current techniques are expensive and time consuming to maintain. Constructed wetlands suggest an inexpensive and operational alternative to conventional technologies. Sub-surface flow wetlands provide the anaerobic zones necessary to reduce the recalcitrant chlorinated solvents prior to anaerobic or aerobic mineralization of its daughter products. A vertical flow cell to include sequential sedimentary layers of two hydric soil lifts and a mix of hydric soil and woody compost was the subject of this investigation. This study focused on the statistical …
Dissolution Of Chromium From Inhalable Primer Paint Particles Into A Simulated Lung Fluid, David A. Kauth
Dissolution Of Chromium From Inhalable Primer Paint Particles Into A Simulated Lung Fluid, David A. Kauth
Theses and Dissertations
The use of chromate as a corrosion inhibitor in primer paint is an essential component for the protection of aluminum-skinned aircraft and the primary source of hexavalent chromium (Cr (VI)) exposure to USAF aircraft painters. The objective of this research was to quantify the dissolution of chromate from freshly sprayed paint particles into a simulated lung fluid (SLF). Two primer paints were sprayed with a paint spray gun to generate overspray particles for collection into impingers filled with SLF. Particles were allowed to soak in SLF for 24 and 48 hours and then the particles were removed by centrifugation. The …
Optimization Of Palladium-Catalyzed In Situ Destruction Of Trichloroethylene-Contaminated Groundwater Using A Genetic Algorithm, Manuel Fernandez
Optimization Of Palladium-Catalyzed In Situ Destruction Of Trichloroethylene-Contaminated Groundwater Using A Genetic Algorithm, Manuel Fernandez
Theses and Dissertations
Conventional technologies for the treatment of groundwater contaminated with chlorinated solvents have limitations that have motivated development of innovative technologies. One such technology currently under development involves using palladium-on-alumina (Pd/Al) as a catalyst to promote dechlorination. Pd/Al catalyst may be used in-well as part of a re-circulating horizontal flow treatment well (HFTW) system. An HFTW system involves two or more dual-screened wells, with in-well reactors, to capture and treat contaminated groundwater without the need to pump the water to the surface. In this study, objective and fitness functions, based on system costs and TCE concentration requirements, were developed to optimize …
In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland
In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland
Theses and Dissertations
The limitations of conventional containment technologies for groundwater contaminated with chlorinated solvents have motivated development of innovative technologies to achieve national groundwater remediation objectives. One inn9vative technology that is currently under development involves metal reductants or catalysts to chemically destroy the dissolved chlorinated solvent. Models are important tools that can be used to help transition this technology to the field. Model studies can be used to gain understanding about the technology, help determine when the prospective technology might work for a given site, and design full-scale field applications.
Modeling Chlorinated Ethene Removal In Constructed Wetlands: A System Dynamics Approach, Colby D. Hoefar
Modeling Chlorinated Ethene Removal In Constructed Wetlands: A System Dynamics Approach, Colby D. Hoefar
Theses and Dissertations
The purpose of this study is to gain understanding of the dynamics of the processes that degrade Perchloroethene (PCE) to ethylene, or carbon dioxide (CO2), within the confines of a constructed wetland. A system dynamics approach will be used. This model is focused on identifying and optimizing the naturally occurring processes in stratified wetland sediment that reduce mass, toxicity, mobility, volume or concentration of contaminants in groundwater. Contaminant fate and transport within a wetland system is extremely complex and the mechanisms that drive wetland behavior are dynamic. Confidence in the model was built through verification and testing. Reasonable …
Chromate Dissociation From Primer Paint In Simulated Lung Fluid, Tiffany J. R. Morgan
Chromate Dissociation From Primer Paint In Simulated Lung Fluid, Tiffany J. R. Morgan
Theses and Dissertations
OSHA has proposed a new strontium chromate exposure standard that would potentially cause Air Force paint facilities to be in violation of the proposed standard if adopted. This proposed reduction make the continued use of chromate containing primer paints very difficult. There is currently no acceptable replacements for chromate containing primer paints on AF aircraft. This study suggests that paint particles with chromate bound in primer paint may be unavailable for bodily absorption if inhaled and a reduced standard for painting applications may be unnecessary. Primer paint overspray was collected into simulated lung fluid (SLF) and allowed 6 hr, 24 …
A Modeling Study For The Implementation Of In Situ Cometabolic Bioremediation Of Trichloroethylene-Contaminated Groundwater, John A. Christ
A Modeling Study For The Implementation Of In Situ Cometabolic Bioremediation Of Trichloroethylene-Contaminated Groundwater, John A. Christ
Theses and Dissertations
The limitations of conventional groundwater remediation technologies have led to the development of innovative technologies which may achieve national hazardous waste site remediation goals. Before an innovative technology can be implemented in the field, remedial project managers, regulators and other stakeholders require adequate modeling tools to help assess the applicability of the technology at a particular site. This modeling study investigates how an innovative technology, in situ cometabolic bioremediation, might be implemented to remediate a TCE-contaminated site, under different site conditions. A steady-state model is developed which couples an analytical expression to simulate the effect of flow between multiple pumping …
Evaluation Of The Natural Biodegradation Of Aircraft Deicing Fluid Components In Soils, Laura M. Johnson
Evaluation Of The Natural Biodegradation Of Aircraft Deicing Fluid Components In Soils, Laura M. Johnson
Theses and Dissertations
This research effort was conducted to analyze the biodegradation of propylene glycol (PG) and tolyltriazole in two different soil types; a sandy soil and a high clay soil. Both an automated respirometer and a high performance liquid chromatograph (H PLO) were used in the analysis. Two separate experiments were conducted. In the first experiment, one level of tolyltriazole was added to the soils to determine whether or not there was a difference in the biodegradation rates of tolyltriazole in the two soils. The respirometer results indicated that there was a significant difference between the respiration rates of the microorganisms in …
Modeling The Uptake And Transpiration Of Tce Using Phreatophytic Trees, Douglas P. Wise
Modeling The Uptake And Transpiration Of Tce Using Phreatophytic Trees, Douglas P. Wise
Theses and Dissertations
Phytoremediation is a recent addition to the numerous methods used today to remediate ground water contaminants. It is proving more effective and efficient compared to existing remediation techniques. The use of phreatophytes, or water seeking trees, has great potential for phytoremediation. These trees are fast growing, long lived, grow their roots down to the ground water table, transpire large amounts of water, and are proven to actively remove contaminants from the soil horizon. The purpose of this research is to develop quantitative concepts for understanding the dynamics of TCE uptake and transpiration by phreatophytic trees over a short rotation woody …
The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako
The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako
Theses and Dissertations
The biodegradation characteristics of three fuel system icing ihhibitors (FSII) were evaluated. FSII are jet fuel additives that partition into water readily and are present in the water drained from storage tank bottoms in concentrations approaching 40%. These concentrations raise concerns as to the disposal and handling of these wastes. The current FSII, DiEGME was evaluated along with two new candidates, dipropylene glycol and glycerol formal. DiEGME appeared to be moderately but not completely biodegradable. It is likely that much of it would be removed in a wastewater treatment plant. Dipropylene glycol only showed signs of degradation after more than …
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Theses and Dissertations
Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …
Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt
Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt
Theses and Dissertations
In the past, the U.S. Navy has routinely conducted SINKing EXercises (SINKEX) for training, weapon effectiveness tests, and economic disposal of aging assets. Recent concern over polychlorinated biphenyl (PCB) chemicals aboard such target vessels has resulted in a suspension of SINKEX. The U.S. Navy has approximately 200 vessels currently requiring such disposal. Environmental legislation and health concerns preclude selling such vessels to foreign governments or scrapping. This work attempted to model the fate and transport of these PCBs by examining their transport to coastal water and their accumulation in the marine food chain. The model includes biodegradation, upwelling, partitioning of …
Effects Of Ammonium Perchlorate On The Thyroid Hormone Levels Of The Sprague-Dawley Rat, James H. King Jr.
Effects Of Ammonium Perchlorate On The Thyroid Hormone Levels Of The Sprague-Dawley Rat, James H. King Jr.
Theses and Dissertations
The purpose of this research was to determine the threshold dose for ammonium perchlorate (AP) in the Sprague-Dawley rat. No dose response data exist for AP and the EPA has studied literature on the subject of perchlorates to determine a provisional reference dose. The Perchiorate Group, a consortium of DoD and industry representatives, believes this provisional reference dose is too conservative. This experiment was executed to provide dose response data on which to base a more accurate reference dose. The study consisted of eight groups of 12 Sprague-Dawley rats, six male and six female, which were exposed to incremental doses …
Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager
Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager
Theses and Dissertations
Slow desorption of contaminants from soil presents one of the greatest challenges to modeling contaminant fate and transport and implementing effective remediation technologies. The kinetics of long-term desorption of trichloroethylene (TCE) from powdered clay soils were studied to determine the desorption rates and mechanism. Infrared absorption spectroscopy was used to monitor the concentration of TCE desorbed from contaminated flint clay for 71 hours. Observed gas phase TCE concentrations as a function of time were compared to that predicted by a one-site Langmuir desorption mechanism. The Langmuir model, with a single type of bonding site, did not account for the release …
Atmospheric Transport And Diffusion Modeling Of Rocket Exhaust, Chad A. Burel
Atmospheric Transport And Diffusion Modeling Of Rocket Exhaust, Chad A. Burel
Theses and Dissertations
Space launches at Vandenberg Air Force Base (VAFB) and the Cape Canaveral Air Station (CCAS) produce exhaust from the solid rocket boosters and liquid hypergolic fuels containing several toxic substances including hydrogen chloride and hydrazine. In order to estimate the health risk that would be imposed upon the public by proposed launches, range safety officials rely on the Rocket Exhaust Effluent Diffusion Model to predict where the exhaust chemicals will go after the launch and how strong the concentrations will be. The original REEDM program averaged the meteorological parameters (wind speed, wind direction, shear, etc.) across the entire mixing level …
Model Of Chlorocarbon (Cfc-12) Chemisorption On Solid Rocket Motor Alumina Exhaust Particles, Gary E. Lund
Model Of Chlorocarbon (Cfc-12) Chemisorption On Solid Rocket Motor Alumina Exhaust Particles, Gary E. Lund
Theses and Dissertations
Solid Rocket (SRMs) that power Titan IV rockets and Space Shuttles, exhaust large quantities of potentially ozone damaging pollutants directly into the stratosphere, while in powered flight. In the past, studies on potential stratospheric impact of the exhaust products from aluminum/ammonium perchlorate based SRMs have focused on the effect of gaseous HCl from SRMs on the stratosphere. Until recently, the impact of heterogeneous chemistry on stratospheric ozone was believed to be relatively insignificant. This research investigates the potential heterogeneous process of CFC-12 dissociative chemisorption on alumina surfaces and the release of reactive halogen species known to destroy ozone. Through a …
Exposure Of A Food Crop To Trichloroethylene From A Contaminated Aquifer, Richard G. Baringer
Exposure Of A Food Crop To Trichloroethylene From A Contaminated Aquifer, Richard G. Baringer
Theses and Dissertations
This research developed a methodology for assessment of the exposure of a mature corn crop to trichloroethylene from a contaminated aquifer. The methodology was then applied to the case of Hill AFB to determine the ability of the methodology to provide information about a specific exposure. Current procedures sample for food contamination but do not attempt to predict exposure problems. A review of the potential exposure pathways from the aquifer to the crop was conducted. Based on this review, the exposures due to soil gas and irrigation were modeled. Empirical estimated were used to approximate the expected flux of soil …
Modeling Trihalomethane Formation Potential From Wastewater Chlorination, Carol A. Mccormick
Modeling Trihalomethane Formation Potential From Wastewater Chlorination, Carol A. Mccormick
Theses and Dissertations
The deletion of federally mandated fecal coliform limits has led many states to review and modify their wastewater disinfection requirements. One issue in analyzing wastewater disinfection is the discharge of potentially carcinogenic halogenated organics formed during the chlorination process. This research investigates the formation of one class of the halogenated organics, the trihalomethanes. The applicability of using drinking water trihalomethane formation models for use with wastewater effluent is examined. Three models are compared for predictive capability by using measured trihalomethane values from previous research data. The results show that a previously developed model is applicable for use based on assumptions …
Analysis Of The Potential For Plant Uptake Of Trichloroethylene And An Assessment Of The Relative Risk From Different Crop Types, Roy-Alan C. Agustin
Analysis Of The Potential For Plant Uptake Of Trichloroethylene And An Assessment Of The Relative Risk From Different Crop Types, Roy-Alan C. Agustin
Theses and Dissertations
This research expands our limited knowledge on the influence of plants on the fate and effects of trichloroethylene (TCE), providing a screening tool on which to base decisions regarding the need for actual sampling of plants. First, physicochemical properties of TCE--vapor pressure, Henry's Law constant, water solubility, octanol-water partition coefficient, molecular weight, and half-life--were screened against relationships reported in literature to evaluate TCE plant uptake potential. This screening approach indicated TCE may be transferred to plants via retention by root surfaces, root uptake and translocation, and foliar uptake. Next, the PLANTX model developed by Trapp and others was applied to …
Vadose Zone Contamination Measurement And Modeling, Thomas A. Reeder
Vadose Zone Contamination Measurement And Modeling, Thomas A. Reeder
Theses and Dissertations
This thesis investigated the effects of the slow sorption mechanism on the transport of volatile organic contaminants in the vadose zone. Recent research has shown that slow sorption may have a significant impact on the transport of volatile organic compounds in the subsurface. Specifically, this document examined the effects of slow sorption on the Vapor Extraction System (VES) and the Purge and Trap Measurement System. It was found that the slow sorption of organic molecules on soil may profoundly influence the efficiency of VES and purge and trap. In addition, this thesis investigated possible alternatives to purge and trap, including …