Environmental Chemistry Commons^™

1080 Summary Information, Department Of Agriculture, Western Australia, Department Of Conservation And Land Management, Western Australia, Department Of Health, Western Australia

Biosecurity research reports

Fluoroacetate, the active ingredient of 1080, occurs naturally in toxic plants in Australia, South Africa, and South America. Manufactured I080 underpins most vertebrate pest control programs in Australia and New Zealand. Fluoroacetate occurs naturally in about 40 plant species in Australia with most of these plants restricted to the south-west of WA.

I080 was introduced to rabbit control programs in the early 1950s and therefore has a long history of proven effectiveness and safety in Australia. There have been few repo1ted problems associated with human safety, environmental persistence, bioaccumulation or impact on populations of non-target species.

In particular, I080 baits …

Use Of Py-Gc/Ms Analysis Techniques In Animal Waste Management: A Preliminary Survey Of Dairy Manures, Daniel L. Vaughn, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The increasing practice of industrial-scale agriculture tends to concentrate large masses of animal waste in relatively compact areas, potentially leading to excessive release of polluting nutrients into waterways during major storms. Anaerobic treatment conditions are generally favored to conserve nitrate N as an agricultural commodity. However, overall N contents in waste are often in excess of crop fertilization needs: storing excess N in soluble nitrate form increases pollution potential. Thus the perceived needs of agriculture and society-at-large become at odds. Organic nitrogen forms (e.g., proteins) are more environmentally stable and are less subject to unintentional release. Although U.S. farmers tend …

Chromate Dissociation From Primer Paint In Simulated Lung Fluid, Tiffany J. R. Morgan

Theses and Dissertations

OSHA has proposed a new strontium chromate exposure standard that would potentially cause Air Force paint facilities to be in violation of the proposed standard if adopted. This proposed reduction make the continued use of chromate containing primer paints very difficult. There is currently no acceptable replacements for chromate containing primer paints on AF aircraft. This study suggests that paint particles with chromate bound in primer paint may be unavailable for bodily absorption if inhaled and a reduced standard for painting applications may be unnecessary. Primer paint overspray was collected into simulated lung fluid (SLF) and allowed 6 hr, 24 …

Interagency Lake Mead And Las Vegas Wash Monitoring Program: Standard Operating Procedures Manual, Bureau Of Reclamation, City Of Henderson Water Reclamation Facility, City Of Las Vegas Water Pollution Control Facility, Clark County Sanitation District, Nevada, Southern Nevada Water Authority

Publications (WR)

A number of agencies sample Lake Mead and the Las Vegas Wash on a routine basis at several locations. In order to share and properly interpret the data, the Bureau of Reclamation, Southern Nevada Water Authority and the three Wastewater Treatment Facilities (City of Las Vegas, Clark County Sanitation District and City of Henderson) formed a committee to examine sampling and analytical protocols and to share information with the goal of maximizing the data quality. The group first met in April 1997. It was agreed that an effort should be made to discuss and compare specific sampling and analytical techniques …

Influences Of Acid Mine Drainage On Water Chemistry Of Blackwater River Watershed, Carla C. Morato-Lara

Theses, Dissertations and Capstones

Acidic mine drainage flow from active and abandoned coal mines has been a major source of water pollution in the Appalachian Mountain region of the eastern USA. Water samples were collected and analyzed from Blackwater River watershed during 2 years (September 1996 - May 1998). The water quality measurements determined that the Beaver Creek and North Fork tributaries were affected by acid mine drainage but not Yellow Creek. Beaver Creek and North Fork stations had high sulfate and manganese markers of acid mine drainage, whereas Yellow Creek was slightly acidic with low sulfate and manganese. North Fork was the primary …

Environmental And Botanical Controls On Peatification - A Comparative Study Of Two New Zealand Restiad Bogs Using Py-Gc/Ms, Petrography And Fungal Analysis, Tomasz K. Kuder, Michael A. Kruge, J C. Shearer, S L. Miller

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study shows that chemical properties of two restiad species, Empodisma minus and Sporadanthus traversii, may contribute to their success as peat-formers in a climate of the North Island of New Zealand which is not conducive to raised mire development. Unlike Sphagnum, the equivalent northern hemisphere peat-former, restiads possess lignin in their tissues. In addition, the presence of non-lignin polyphenols (including tannins and phenolic acids) in restiads may be an important factor in peat formation due to the allelopathic decay retardation. Patterns of degradation of plant biopolymers have been examined and the pathway of degradation of monocotyledons (loss …

Isolation From Soil Microorganisms That Are Inhibitory To Wheat Seeding Pathogens, Kynita Wilson-Humphrey

McCabe Thesis Collection

Many diseases caused by bacteria, viruses, or fungi are responsible for the ruin of a great number of crops annually. At present, many of these crops are being treated for diseases by synthetic or man-made chemicals. Some of the chemicals have been proved to have adverse effects on the environment, including humans and animals. Very few non-chemical means are available to farmers at this time to control these pathogens. This is due to the fact that many of the means of control have little effect against the pathogens or diseases. This research attempts to isolate microorganisms from the soil which …

Effects Of Ammonium Perchlorate On The Thyroid Hormone Levels Of The Sprague-Dawley Rat, James H. King Jr.

Theses and Dissertations

The purpose of this research was to determine the threshold dose for ammonium perchlorate (AP) in the Sprague-Dawley rat. No dose response data exist for AP and the EPA has studied literature on the subject of perchlorates to determine a provisional reference dose. The Perchiorate Group, a consortium of DoD and industry representatives, believes this provisional reference dose is too conservative. This experiment was executed to provide dose response data on which to base a more accurate reference dose. The study consisted of eight groups of 12 Sprague-Dawley rats, six male and six female, which were exposed to incremental doses …

Bulletin 4307 - Grass Control In Pastures Using Herbicides, Alexandra Wallace

Bulletins 4000 -

This Bulletin discusses three methods for herbicide control of grasses in pastures:

• pasture manipulation, in the early stages of pasture growth;
• spray-topping late in the growing season; and
• hay freezing, late in the growing season.

Nutrient Limitation In A Southwestern Desert Reservoir: Eutrophication Of Las Vegas Bay, Lake Mead, Nevada, Davine M. Lieberman

Publications (WR)

Algal bioassay tests were conducted with Selenastrum capricornutum and natural algae on inner Las Vegas Bay, Lake Mead, Nevada, from December 1992 through September 1993, to identify any nutrient limitation in an area of the reservoir that has experienced problems associated with severe nutrient enrichment. Three areas were sampled based on a gradient of water quality conditions that existed in Las Vegas Bay (LVB). Disodium ethylenedinitrilotetraacetate (EDTA) significantly stimulated algal growth compared to non-EDTA treatment. Algal bioassays indicated that phosphorus (P) was the primary limiting nutrient at all stations for most of the test dates. Chl a response with EDTA …

Understanding Fertilisers For Table Grapes, B. H. Goldspink, I. Cameron, J. Campbell-Clause, N. Lantzke, C. Gordon

Viticulture research reports

A course run by the Department of Agriculture, Western Australia, August 1995.

The purpose of this publication is to clarify the role fertilisers play in commercial table grape production and to detail methods of selecting fertilisers. This selection process however is not easy as there are over 600 registered fertilisers in Western Australia.

In deciding which is the best fertiliser for a particular property many factors have to be considered. These include:

* Age of vine

* Rootstock

* Variety of table grape

* Soil type

* Soil chemistry

* Irrigation methods

* Previous fertiliser history Previous yield, vigour and …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume Ii Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume I Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Thermal Decomposition Studies Of Selected Transition Metal Polysulfide Complexes. Ii. Effect Of Atmosphere On Decomposition, Benjamin Rougeau, Mark Draganjac

Journal of the Arkansas Academy of Science

Initial studies involved the thermal decomposition profile of five polysulfide complexes in air up to 550 °C. Since our first report to the Academy in 1990, we have obtained the capability to run samples up to 1500°C under various gases. Thermal Gravimetric Analysis (TGA) and Differential Thermal Analysis (DTA)of a series of transition metal polysulfide complexes are presented. Compounds analyzed included Cp2TiS5 ,MoS9 2",MoOS8 2", Zn(S x ) 2", Cd(S x ) 2-, Fe2S122 - and NiS82.

How Arsenic Residues Get In Wool, Tony Martin, Robin Jacob, Marion Davies, Peter Rutherford

Journal of the Department of Agriculture, Western Australia, Series 4

Wool can become contaminated with arsenic in various ways, and several different sources may each contribute to any individual arsenic residue problem.

• dipping sheep in an arsenical dip ( now illegal),

• dipping sheep in a non-arsenical dip in a contaminated dipping facility

• penning sheep on soil with high levels of arsenic before shearing.

Other possible sources include running sheep on land contaminated by gold mine tailings or exploration sites, and allowing sheep access to sites on the farm where arsenical compounds have been dumped, for example, rubbish dumps or sites where dip/sump sludge has been dumped.

Farmers …

A Proposal For United States/Polish Collaboration On Energy And The Environment, Carole B. Szpunar

Chemistry: Faculty Publications and Other Works

Argonne National Laboratory, a U.S. Department of Energy facility that is operated by the University of Chicago and located southwest of Chicago, Illinois, has proposed a collaborative effort by the United States and Poland to conduct applied research on energy and environmental topics of common interest. Through this collaboration, evaluative studies on energy and environmental assessment issues could be developed and implemented by Argonne and one or more sister institutions in Poland, which could lead to active research, development, and demonstration joint activities. The objective of this initiative is to produce strategies and options for review by Poland's decision makers …

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

The Nitrogen Response Of Wheat Crops Following Lupins, I C. Rowland, Mel Mason, John Hamblin

Journal of the Department of Agriculture, Western Australia, Series 4

One of the many benefitsof growing narrow-leaved lupins in a crop rotation (Rowland et al 1988) in the increased yield of the following cereal crop as a result of the improved nitrogen level of the soil.

This article reports the results from 41 wheat/lupin rotation trials involving a range of nitrogen rates throughout the Western Australian agricultural area between 1978 and 1987. These trials allowed scientists to assess the interaction of nitrogen fertilization with previous cropping history and to estimate some of the contribution of the nitrogen and other effects of lupins within the crop rotations. The results provide some …

Intensive Animal Industries In The Peel-Harvey Catchment, R W. Payne

Journal of the Department of Agriculture, Western Australia, Series 4

The Swan coastal plain to the north and south of Perth is attractive for the intensive production of pigs and poultry for several reasons. It is close to markets, feed manufacturers and labour; has a less extreme climate than inland areas; and is underlain by a large reserve of high quality groundwater.

Because these are all intensive operations, large quantaties of nutrient-rich waste are produced over a very small area. They can severely damage ground and surface waters unless steps are taken to control the wastes which they produce.

This article oulines both the nature of intensive aniamal industries in …

Limnological Monitoring Data For Lake Mead During 1987: Technical Report No. 20, Larry J. Paulson

Publications (WR)

Limnological monitoring was conducted in Las Vegas Bay and Boulder Basin from April to December of 1987. The purpose of the monitoring was to (i) document possible changes in water quality resulting from decreased phosphorus loading in Las Vegas Wash, and (ii) establish a data base for evaluating the adequacy of water quality standards.

Lake Mead Cover Enhancement Project, Jennifer Stevens Haley, Suzanne Leavitt, Larry Paulson, Donald H. Baepler

Publications (WR)

Ninety-three wildlife agencies were surveyed for information on their attempts to improve fish habitat. In addition, an annotated bibliography including over 100 summaries was completed on: 1. largemouth bass cover requirements and preferences, 2. use and effectiveness of artificial cover, 3. aquatic plant introduction and species requirements for germination and establishment, 4. terrestrial plant introduction and species requirements for germination and establishment, and 5. nutrient exchange between sediment, aquatic plants, and water. A reconnaissance of existing terrestrial and aquatic vegetation was completed in June 1986 including the production of a video tape of the Nevada shoreline of Lake Mead. Cover …

Las Vegas Wash And Lake Mead Proposed Water Quality Standards: Revisions And Rationale, State Of Nevada: Division Of Environmental Protection

Publications (WR)

Rationale of review and for proposed changes to the Nevada Pollution Control Regulations (NAC 445.1354, 445.1355, 445.1356, 455.1367, 445.1352, 445.1353, 445.1350, 445.1351) before the State Environmental Commission on June 23 and 24, 1987.

Raw Nutrient Data, Leanna Gail

Publications (WR)

Data collected at various stations around Lake Mead. Includes information about substances present in various water samples.

Maine Acid Rain Study : Reports, Maine Department Of Environmental Protection

Maine Collection

Maine Acid Rain Study : Reports

Maine Department of Environmental Protection, Augusta, Maine (February, 1987).

Contents: Acid Rain Precursor Inventory and Evaluation / Modeled Sulfur Deposition in Maine / High Elevation Lake Monitoring in Maine

A Proposal To Fertilize The Overton Arm And Gregg Basin Areas Of Lake Mead, Larry J. Paulson

Publications (WR)

Several limnological studies have been conducted in Lake Mead during the past decade. The recent studies clearly show that most of Lake Mead is deficient in nutrients, especially phosphorus, and very low in productivity. The reservoir-wide average total phosphorus concentration for 1981 - 1982 was only 9 mg/m³. This is below levels found In most oligotrophic lakes and reservoirs. Algal biomass, as measured by chlorophyll-a, averaged only 1.5 mg/m³. That also places Lake Mead in the oligotrophic range. Transparency, as measured by a Secchi disc, averaged 9-5 m in Lake Mead during 1981-1982. That far exceeds …

Las Vegas Wash Multispectral Scanner Survey, T. H. Mace, M. V. Olsen, Environmental Protection Agency

Publications (WR)

At the request of the U.S. Bureau of Reclamation, Boulder City, Nevada, the U.S. Environmental Protection Agency's Environmental Monitoring Systems Laboratory at Las Vegas collected multispectral scanner imagery of Las Vegas Wash on October 1, 1982. A combined maximum likelihood classification and editing procedure was used to classify the multispectral scanner imagery into 12 categories of land cover. The classification identified four categories of marsh vegetation, one category of riparian, two categories of mixed scrub, and two desert categories. Turbid water and cultivated land formed an "other" category. Area tabulations were formed by georeferencing the classification to the Universal Transverse …

Soil Acidity On High Rainfall Pastures, J S. Yeates, D. A. Mcghie, I. R. Wilson

Journal of the Department of Agriculture, Western Australia, Series 4

Most soils of the high rainfall area of south-western Western Australia are naturally acis.

The most acid group of soils, the peaty sands. have been routinely limed before subterranean clover pastures were established since research in the 1950s showed that poor Rhizobium nodulation could be overcome with the application of about 2 tonnes per hectare of coastal limesand.

Soil Acidity In The Eastern Wheatbelt, W M. Porter, I. R. Wilson

Journal of the Department of Agriculture, Western Australia, Series 4

In Western Australia parts of the sandplain of the eastern wheatbelt are very acid and produce poor crops, It was not until the late 1970s that the effect of soil acidity on the productivity of the sandplain soils was examined in any detail.

Since then researchers have learnt a great deal about the nature of soil acidity in the eastern wheatbelt sandplain soils and can suggest management options for farmers.

This article discisses the problem of the very acid soils. It does not deal with the moderately acid, medium textured soils of the eastern wheatbelt. Although the acidity of these …

Soil Acidity And Liming In The Lower Great Southern, R N. Glencross, M. G. Clarke

Journal of the Department of Agriculture, Western Australia, Series 4

In the 375 to 750 millimetre rainfall area of the Lower Great Southern, reports of loss of subterranean clover from established pastures, reduced carrying capacity for sheep and increasing soil acidity lead to the establishment in 1981 of a research programme into the effects of soil acidity on pasture productivity in that region.

Sulphur Needs Of Crops And Pastures, J S. Yeates

Journal of the Department of Agriculture, Western Australia, Series 4

Sulphur deficiency has long been recognised as a potential problem of legume pastures in the higher rainfall areas (over 750 mm a year) of south-west Western Australia. Before the introduction of granulated superphosphate (about 1970), sulfer deficiencies commonly developed in spring on susceptible soils despite autumn applications of superphosphate (containing about 10.5 per cent sulphur).

In loww and medium rainfall areas sulphur deficiency is rarely reported, at least partly because of annual superphosphate applications. However large areas of the sandy-surfaced soils of Western Australia would become sulphur deficient for pastures and crops if sulphur inputsd in fertilisers were substantially reduced. …