Chemistry Commons^™

Glyoxal’S Impact On Dry Ammonium Salts: Fast And Reversible Surface Aerosol Browning, David O. De Haan Phd, Lelia N. Hawkins Phd, Kevin Jansen, Hannah G. Welsh, Raunak Pednekar, Alexia De Loera, Natalie G. Jimenez, Margaret A. Tolbert Phd, Mathieu Cazaunau Phd, Aline Gratien, Antonin Bergé, Edouard Pangui, Paola Formenti, Jean-François Doussin

Chemistry and Biochemistry: Faculty Scholarship

Alpha-dicarbonyl compounds are believed to form brown carbon in the atmosphere via reactions with ammonium sulfate (AS) in cloud droplets and aqueous aerosol particles. In this work, brown carbon formation in AS and other aerosol particles was quantified as a function of relative humidity (RH) during exposure to gas-phase glyoxal (GX) in chamber experiments. Under dry conditions (RH < 5%), solid AS, AS/glycine, and methylammonium sulfate aerosol particles brown within minutes upon exposure to GX, while sodium sulfate particles do not. When GX concentrations decline, browning goes away, demonstrating that this dry browning process is reversible. Declines in aerosol albedo are found to be a function of [GX]², and are consistent between AS and AS/glycine aerosol. Dry methylammonium sulfate aerosol browns 4´ more than dry AS aerosol, but deliquesced AS aerosol browns much less than dry AS aerosol. Optical measurements at 405, 450, and 530 nm provide an …

Asp Diversity And Inclusion Committee Call To Action, Nadja Cech, Christine Salomon, Susan Mooberry, Sandra Loesgen, Katharine Watts, Josh Kellogg, Lesley Ann Giddings, Brian T. Murphy, Esther A. Guzmán

Chemistry: Faculty Publications

No abstract provided.

Soil Labile Organic Carbon Fractions And Soil Enzyme Activities After 10 Years Of Continuous Fertilization And Wheat Residue Incorporation, Ligan Zhang, Xi Chen, Yujun Xu, Mengcan Jin, Xinxin Ye, Hongjian Gao, Wenying Chu, Jingdong Mao, Michael L. Thompson

Chemistry & Biochemistry Faculty Publications

Labile organic carbon (LOC) fractions and related enzyme activities in soils are considered to be early and sensitive indicators of soil quality changes. We investigated the influences of fertilization and residue incorporation on LOC fractions, enzyme activities, and the carbon pool management index (CPMI) in a 10-year field experiment. The experiment was composed of three treatments: (1) no fertilization (control), (2) chemical fertilizer application alone (F), and (3) chemical fertilizer application combined with incorporation of wheat straw residues (F + R). Generally, the F + R treatment led to the highest concentrations of the LOC fractions. Compared to the control …

Disinfection Byproduct Drivers Of Cytotoxicity In Drinking Water And Swimming Pools, Joshua M. Allen

Theses and Dissertations

Water disinfection was cited as the greatest public health achievement of the 20th Century. By inactivating pathogens, disinfection has significantly reduced waterborne diseases in drinking water and swimming pools. However, chemical disinfection has also raised a public health issue: the potential for cancer induction, reproductive and developmental effects, and asthma-related risks associated with exposure to chemical disinfection byproducts (DBPs), which are formed by the reaction of disinfectants with organic matter (natural or anthropogenic), bromide, and iodide. In the U.S., four trihalomethanes (THMs) and five haloacetic acids (HAAs) are currently regulated in drinking water, although no DBPs are regulated in pools, …

Glyoxal’S Impact On Dry Ammonium Salts: Fast And Reversible Surface Aerosol Browning (Raw Data), David O. De Haan Phd, Lelia N. Hawkins Phd, Margaret A. Tolbert Phd, Jean-François Doussin

Chemistry and Biochemistry: Faculty Scholarship

Alpha-dicarbonyl compounds are believed to form brown carbon in the atmosphere via reactions with ammonium sulfate (AS) in cloud droplets and aqueous aerosol particles. In this work, brown carbon formation in AS and other aerosol particles was quantified as a function of relative humidity (RH) during exposure to gas-phase glyoxal (GX) in chamber experiments. Under dry conditions (RH < 5%), solid AS, AS/glycine, and methylammonium sulfate aerosol particles brown within minutes upon exposure to GX, while sodium sulfate particles do not. When GX concentrations decline, browning goes away, demonstrating that this dry browning process is reversible. Declines in aerosol albedo are found to be a function of [GX]2, and are consistent between AS and AS/glycine aerosol. Dry methylammonium sulfate aerosol browns 4´ more than dry AS aerosol, but deliquesced AS aerosol browns much less than dry AS aerosol. Optical measurements at 405, 450, and 530 nm provide an estimated Ångstrom absorbance coefficient of -16 ±4. This coefficient and the empirical relationship between GX and albedo are used to estimate an upper limit to global radiative forcing by brown carbon formed by 70 ppt GX reacting with AS (+7.6 ´10-5 W/m2). This quantity is < 1% of the total radiative forcing by secondary brown carbon, but occurs almost entirely in the ultraviolet range.

The zipped data files are in the following formats: Igor experiments (.pxp), Word documents (.docx), Excel spreadsheets (.xlsx), organized by experiment number. “Optical” files contain cavity attenuated phase shift (CAPS) extinction, scattering and albedo data; PILS/waveguide data (experiments 1,2, and 5 only); …

Elucidating Collagen Degradation Synergy Between Col G And Col H From Hathewaya (Clostridium) Histolytica And Identifying Novel Structural Features In Hpt And Rec Domains From Vars Histidine Kinase In V. Alginolyticus, Perry Caviness

Graduate Theses and Dissertations

In this research the mechanisms by which Hathewaya (Clostridia) histolytica collagenases are secreted and work together to degrade collagens are investigated. While H. histolytica collagenases Col G and Col H have similar multi-domain structures the difference in number of and orientation of the domains hint that the two target different regions in collagen. Study small angle x-ray scattering (SAXS) was used to give a low-resolution envelope of full-length Col G and Col H and Col G/Col H non-catalytic domains bound to a collagen-like peptide (mini-collagen). SAXS derived envelopes along with structural information was used to tease out the mechanisms by …

Investigation Of The Structural, Electronic, And Thermoelectric Properties Of Mono- Chalcogenides, Aida Sheibani

Graduate Theses and Dissertations

The structural, electronic, and thermoelectric properties of GeTe are studied using density functional theory and Boltzmann transport equations. This material has a rhombohedral crystal structure in ambient temperature with a ferroelectric behavior due to lack of inversion symmetry. This study suggests that the presence of asymmetry in GeTe can lead to an improvement in the thermoelectric properties of this material. In addition, studies on introducing Group III, IV, and V dopants to GeSe show that while these impurities can improve the power factor and decrease the lattice thermal conductivity, they cannot enhance the figure of merit.

The Recreation Of Wound Patterns Using Various Tissue Simulants For Crime Scene Reconstruction, Breanne Steimle

Forensic Science Master's Projects

Within the field of forensic science, there are limited reliable methods for the simulation of pattern injuries on human skin and tissue that may aid in aspects of crime scene reconstruction. The tissue simulant must be of sufficient integrity for recording blunt force trauma and bite mark impressions, electrocution, cutting, and gunshot wound related injuries for the purpose of re-enactment, court exhibition, and distance determination. For wound reenactments (such as blunt force trauma, bite mark impressions and electrocution), dead skin and tissue from human cadavers do not show wounding patterns that would occur on live tissue. This study examines different …

Investigation Of Evidence For The Internal Structure Of A Modified Science Motivation Questionnaire Ii (Msmq Ii): A Failed Attempt To Improve Instrument Functioning Across Course, Subject, And Wording Variants, Regis Komperda, Kathryn Hosbein, Michael M. Phillips, Jack Barbera

Chemistry Faculty Publications and Presentations

The Science Motivation Questionnaire II (SMQ II) was developed to measure aspects of student motivation in college-level science courses. Items on the SMQ II are structured such that the word ‘science’ can be replaced with any discipline title (e.g., chemistry) to produce a discipline-specific measure of student motivation. Since its original development as the Science Motivation Questionnaire and subsequent refinement, the SMQ II and its discipline-specific variants have been used in a number of science education studies. However, many studies have failed to produce acceptable validity evidence for their data based on the proposed internal structure of the …

Comparison Of Chemotherapeutic Activities Of Rhodamine-Based Gumbos And Nanogumbos, Nimisha Bhattarai, Mi Chen, Rocío L. Pérez, Sudhir Ravula, Robert Strongin, Karen Mcdonough, Isiah M. Warner

Chemistry Faculty Publications and Presentations

Rhodamine derivatives have been widely investigated for their mitochondrial targeting and chemotherapeutic properties that result from their lipophilic cationic structures. In previous research, we have found that conversion of Rhodamine 6G into nanoGUMBOS, i.e., nanomaterials derived from a group of uniform materials based on organic salts (GUMBOS), led to selective chemotherapeutic toxicity for cancer cells over normal cells. Herein, we investigate the chemotherapeutic activity of GUMBOS derived from four different rhodamine derivatives, two bearing an ester group, i.e., Rhodamine 123 (R123) and SNAFR-5, and two bearing a carboxylic acid group, i.e., rhodamine 110 (R110) and rhodamine B (RB). In this …

Synthesis And Evaluation Of Small Molecule Inhibitors Of Pyruvate Carboxylase, Daniel John Burkett

Master's Theses (2009 -)

Through structure-based drug design (SBDD), a series of small molecules have been synthesized and evaluated for inhibitory activity against the pyruvate carboxylase (PC) enzyme via two biological assays. The -hydroxycinnamic acid scaffold was identified as the most privileged scaffold for inhibition of PC. Analogues of phenylpyruvic acid were generated and evaluated, leading to the discovery of inhibitors with single digit micromolar (M) IC50 values. The most potent inhibitors identified were evaluated for inhibitory activity against other metalloproteins, and 2-hydroxy-3-(quinolone-2-yl)propenoic acid did not significantly inhibit human carbonic anhydrase II, matrix metalloproteinase-2, malate dehydrogenase, or lactate dehydrogenase. The small molecules presented in …

1. Dft-Guided Discovery Of Hybrid Catalysts For C-C Bond Formation; 2. Synthesis Of A Reported Pdi Inhibitor, Eric Greve

Dissertations (1934 -)

1. Dual amine/pi Lewis acid catalyst systems have been reported for intramolecular direct additions of aldehydes/ketones to unactivated alkynes and occasionally alkenes, but related intermolecular reactions are rare. We reasoned that bulky metal ligands and bulky amine catalysts could minimize catalyst poisoning and could facilitate certain examples of direct intermolecular additions of unactivated aldehydes/ketones to alkenes/alkynes. Density Functional Theory (DFT) ground state calculations on putative catalytic intermediates for alkyne versus organocatalyst complexation to the -acid, and also the key carbon-carbon bond formation were used to prioritize ligand/organocatalyst combinations. Our calculations suggested that PyBOX-Pt(II) catalysts for alkene/alkyne activation could be combined …

The Rotational Spectrum Of 1,1-Diiodoethane, Michael Joseph Carrillo

Theses and Dissertations

The first chapter of this thesis introduces the basic theory of rotational spectroscopy. This includes the theory of a rigid rotor, centrifugal distortion, and hyperfine effects. The theory behind diatomic systems is explained first, and then expanded to the asymmetric top system. The second chapter encompasses a brief overview on the development of microwave spectroscopy and discusses the instruments that were utilized during this study, namely the cavity-based and chirped-pulse Fourier transform microwave spectrometers. Chapter three describes the quantum chemical calculation methods and basis sets that were applied throughout this study. Chapter four discusses the progress of data analysis of …

Protein Co-Assembly And Its Application In Enzyme Engineering, Libo Zhang

Theses and Dissertations

Enzymes, as highly efficient biocatalysts, have been researched extensively in both academia and industry because of their distinct advantages including high substrate specificity, high regio- and stereoselectivity, environmentally benign process, etc. Though enzyme catalysis has been scaled up for commercial processes in the pharmaceutical, food and beverage and detergent industries, technical barriers associated with enzyme implementation persist, i.e., low catalytic efficiency at non-natural environment, exhausting product separations, high cost of certain enzymes, etc. Moreover, currently most industrial enzymes are used in single-step reactions; however, multistep and multienzyme catalysis with optimal efficiency could greatly expand its potential for synthetic applications to …

Exploratory Molten Flux Crystal Growth Of Complex Uranium Oxides, Christian A. Juillerat

Theses and Dissertations

While the use of nuclear technology has proven useful for energy generation and for military use, the proper disposal and storage of the resulting nuclear waste requires serious attention to ensure radioactive species are indefinitely sequestered to protect the biosphere. There are several classifications of nuclear waste such as spent nuclear fuel (from industrial power plants), low level waste (slightly contaminated trash), and high level waste (HLW) which is in the form of a sludge, precipitated salt, or liquid. Each of these requires a different approach to processing and storage. Of these, HLW requires the most attention because it is …

Thermotropic And Lyotropic Phase Behaviours Of Spontaneously Self-Assembled Amphiphilic Branched-Chain Glycosides With Various Chain Length, Abdul Hamid Hairul Amani

Student Works (2020-2029)

Lipid polymorphism is a process which illustrates the self-assembly of lipid aggregation depending on the environment. Lipids such as branched-chain glycolipids which are amphiphilic molecules also known as amphitropic tend to generate mesophases in thermotropic (dry) and lyotropic (solvation) conditions. These molecules are capable of self-aggregating into various types of glycolipid self-assemblies offering an interesting insight in relation to their functions in living cells. Hence, this study aims to investigate the mesophases of ꞵ-D-glycosides which are branched-chain synthetic glycolipids, namely, ꞵ-D-glucosides and ꞵ-D-maltosides. The study was carried out on the thermotropic phases of dry glycosides and the lyotropic phases of …

Optimisation Of Biomass And Lipid Production Of A Tropical Thraustochytrid Aurantiochytrium Sp. Umacc-T023 In Submerged-Liquid Fermentation For Large-Scale Biodiesel Production, Sohedein Mohamad Nor Azzimi

Student Works (2020-2029)

A tropical thraustochytrid, Aurantiochytrium sp. UMACC-T023, was optimised for high biomass and lipid production in submerged-liquid fermentation (SLF). Biomass and lipid production were optimised based on glucose, polypeptone, and yeast extract concentration using response surface methodology (RSM). In RSM, the applied central composite design (CCD) showed that the optimisation model was significant for all variables studied. Yeast extract and polypeptone were associated with significant effects in UMACC-T023 biomass production with p < 0.05. The model was validated by employing the optimised media composition in shake flasks and in 1.4-L stirred-tank bioreactors. The optimised media composition for both biomass and lipid production was 10 g L-1 glucose, 15.08 g L-1 polypeptone, and 13.56 g L-1 yeast extract. Biomass production in the bioreactor increased 2.12-fold compared with the shake flask culture utilising the same optimised media composition. This result demonstrated that the optimized media composition can be utilised for large-scale lipid production of UMACC-T023 for potential biodiesel feedstock as it also fulfilled the international standards for biodiesel.

Microstructural Characteristics And Mechanical Properties Of Sn-Ag-Cu Solders With Minor Additions Of Al And Zn, Yee Mei Leong

Student Works (2020-2029)

Driven by the recent trend towards miniaturization of lead free electronic products, researchers are putting immense efforts to improve the properties and reliability of Sn based solders. Recently, much interest has been shown on low silver (Ag) content solder SAC 105 (Sn-1.0Ag-0.5Cu) solder because of economic reasons and improvement of impact resistance as compared to SAC387(Sn-3.8Ag-0.7Ag). The present work investigates the effect of minor (0.1-0.5wt.%) Aluminium (Al) and Zinc (Zn) addition to SAC105 on the bulk and interfacial structure between solder and copper substrate during reflow and after thermal aging , the mechanical properties of the solder joint and the …

Synthesis Of Polyurethane Incorporated By Calcium Oxide And Magnesium Oxide For Heavy Metal Removal From Water, Fard Mohsen Vafaei

Student Works (2020-2029)

Water contaminated by heavy metals such as copper, lead, nickel, and cadmium has significant adverse impacts on receiving water. In recent years, various methods, such as adsorption, chemical precipitation, and ion exchange, have been extensively studied for the elimination of heavy metals. Adsorption is one of the numerously and diversely reported mechanisms of removing heavy metals due to its simplicity and costeffectiveness. In this study, highly permeable rigid polyurethanes (PU) incorporating calcium oxide (CaO) (PU/CaO) composite materials were prepared via a facile and economic one-pot synthesis method and characterized for remediation of heavy metal from water. To investigate the effect …

The Influence Of Carbon Nanotubes And Mn Dopant Onto Zinc Oxide For Degradation Of Organic Pollutant Model Under Visible Light Irradiation, Ab Wahab Norfarhanah

Student Works (2020-2029)

Globally untreated industrial wastewaters are contaminating soil, surface water, groundwater, and consequently, the environment. Therefore, there is a huge interest in developing efficient and effective removal methods, such as photocatalytic advanced oxidation processes (AOP) under visible light (~47% of solar irradiation). In this work, the effectiveness of Mn-doped ZnO composite decorated onto multiwall carbon nanotubes (MWCNTs) on photodegrading organic pollutants was studied. This composite was simultaneously synthesized by sol gel method. XRD was used to confirm the formation of ZnO/Mn nanocomposite and the crystalline phase changes as ZnO content decreases when other elements were added to form the nanocomposite. The …

Chemical Variability In Volatile Oils Of Bentong Ginger: A Chemometric Study, Ahmad Jahiddin Farah Syuhaidah

Student Works (2020-2029)

The volatile oil of ginger (Zingiber officinale) possesses various pharmacological properties corresponding to its chemical compositions, which in turn, depends on its source material and preparation method. In this study, preliminary experiments were carried out to investigate the variations in volatile oil of ginger prepared based on different method (dry/fresh samples), extraction duration and size reduction process (grate/slice samples). The ginger volatile oil yield can be quantitatively improved by using a fresh sample with grated form and a longer extraction cycle. Gas Chromatography-Mass Spectrometry (GC-MS) was conducted and the chromatogram profile was subjected to Principal Component Analysis (PCA). Results show …

Nitrogen-Doped Graphene-Based Metal Composites For The Non-Enzymatic Detection Of Hydrogen Peroxide, Tajabadi Poor Mohammad Taghi

Student Works (2020-2029)

Recently, much attention has been devoted to detecting hydrogen peroxide (H2O2) because of its extensive range of applications in chemical synthesis, the textile industry, food production, fuel cell devices, and even in many oxidative biological reactions. Among the various methods of detection of H2O2, electrochemical sensors has many advantages, such as simplicity, high efficiency and sensitivity, as well as good selectivity., To improve the sensitivity of non-enzymatic sensors, noble metal nanoparticles with particular electrocatalytic activities can be utilized. The present research is aimed to design a hybrid approach for the development of novel nanostructures for non-enzymatic detection of H2O2. Herein, …

Understanding The Interfacial Reactions Initiating On Lithium Metal Surfaces In Next-Generation Battery Technologies, Joshua A. Lochala

Graduate Theses and Dissertations

Li-ion batteries have started to reach the theoretical maximum energy. Next-generation batteries represent the future of portable energy sources for vehicle electrification and grid energy storage. Li metal battery is one of the most promising next-generation battery technologies that could potentially double the cell-level energy of conventional Li-ion batteries. However, Li metal has multiple drawbacks that require addressing before realization. These drawbacks include dendrite formation leading to internal short and increasing internal resistance due to the breakdown of electrolyte, leading to rapid cell death. These problems stem from the interfacial reactions occurring during the plating and stripping of Li metal. …

Ensemble And Single Particle Studies Of Cation Exchange In Cuins2/Zns Qds And Their Application In Super-Resolution Imaging, Anh Tue Nguyen

Graduate Theses and Dissertations

Colloidal quantum dots (QDs) have great potential in many applications such as bioimaging, light emitting diodes, solar cells and lasers. However, a great number of studies have been focused on Cd based (II-VI) and Pb (IV-VI) based materials which are not suitable for mass production. Therefore, alternative types of QD containing less toxic materials have been introduced, including CuInS2 QDs. This I-III-VI semiconductor nanocrystals also attract lots of attention due to their large Stock shift, long fluorescence lifetime and high defect tolerance, making them attractive emitters for applications in bioimaging, photovoltaics and light emitting diodes.

In the first project, we …

Graphene Oxide Gold Nanostructure Based Surface Enhanced Raman Scattering Dna Biosensor For The Detection Of Meat Species, Khalil Md. Ibrahim

Student Works (2020-2029)

Authentication, detection and quantification of the ingredients, and adulterant in the food, meat and meat products are of high importance in current days. However, the conventional meat species detection techniques based on lipid, protein and DNA biomarkers have been confronting challenges due to the poor selectivity, sensitivity, and unsuitability for processed food products or complex food matrices. Hence, nanoparticle based DNA biosensing strategies have attracted the most interests and considered as one of the best alternatives to conventional strategies. Among these, surface enhanced Raman scattering (SERS) has gained the substantial acceptance as an excellent, fast and ultrasensitive sensing technique due …

Synthesis And In Vitro Studies Of Polycaprolactone-Coated Superparamagnetic Iron Oxide Nanoparticles For Magnetic Hyperthermia Therapy, Nasab Ziba Hedayat

Student Works (2020-2029)

Research has garnered a great interest in utilization of superparamagnetic iron oxide nanoparticles (SPIONs) as magnetic nano-heating agents in hyperthermia cancer therapy by profiting from high apoptosis vulnerability of cancer cells at elevated temperatures. However, low oxidation resistance and high agglomeration tendency negatively affect magnetic characteristics of nanoparticles and subsequently their clinical efficiency. Particle surface modifications are potential approaches to endow SPIONs a range of desirable properties including high colloidal dispersity, low aggregation tendency, cytocompatibility, and high oxidation resistance. Currently, polymer coating has led to decrease magnetic hyperthermia efficiency through formation of intermediate layer between nanoheating agents and targeted cells. …

Syntheses, Characterisations And Electrochemical Studies Of Nickel(Ii) And Cobalt(Ii)-Ligand Assisted Cooperative Complexes, Subramaniam Jeevithra Dewi

Student Works (2020-2029)

A newly designed tetradentate ligand L1 (L1 = 3,6-bis(pyrazol-1-yl)-pyridazine) which offers multinucleation sites on its moiety structure has been prepared. The reaction of L1 with different molar ratio of nickel and cobalt salts lead to the formation of di- and tetranuclear complexes [NiII 2(L1)2(CH3CN)4](PF6)4 (1), [NiII 4(L1)4(μ-OH)4](ClO4)4 (2) and [CoII/III(L1)4(μ-CH3O)2(μ-O)2](PF6)3(NO3) (3), which served as the attempt to design of catalysts based on cheap and earth-abundant metals for carbon dioxide reduction. The presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as the base controls the nuclearity of the complex formation. In the absence of DBU, complex 1 was formed in dinuclear fashion whereas complex 2 …

Development Of Nano Carbon And Conducting Polymers Based Ternary Composites For Supercapattery, Iqbal Javed

Student Works (2020-2029)

Although significant efforts have been devoted on the development of energy storage systems such as batteries and fuel cells in the past decades, the low power density, short cyclic life and high maintenance cost have kept them away from many applications. Alternatively, supercapattery which has the characteristic features of batteries as well as supercapacitors has gained much attention because of its rapid charge/discharge mechanism, long life cycle, and high power density. However, supercapattery generally suffers from poor energy density. This research aims to develop carbon and conducting polymers based ternary nanocomposites for high performance supercapattery. Pristine metal oxide nanostructures suffer …

Identification Of Peptide Sequence To Block Dengue Virus Transmission Into Cells Via In Silico And In Vitro Assays, Arumugam Aathe Cangaree

Student Works (2020-2029)

Dengue virus (DV) infection has become main public wellbeing concerns, affecting approximately 390 million people worldwide. This fact was reported by the World Health Organization. Yet, there is no commercial antiviral treatment for DV infection. Therefore, the development of potent and non-toxic anti-DV, as a complement for the existing treatment strategies, are urgently needed. Herein, we investigate a series of low molecular weight peptides inhibitors by aiming the cellular entry process as the promising approach to block DV infection. The peptides were designed based on previously reported peptide sequence, DN58opt (TWWCFYFCRRHHPFWFFYRHN), to identify minimal effective inhibitory sequence via molecular docking …

Synthesis And Fabrication Of Self-Sustainable Triboelectric Energy Case For Powering Smart Electronic Devices, Abu Masa Abdullah, Alejandro Flores, Aminur Rashid Chowdhury, Jianzhi Li, Yuanbing Mao, M. Jasim Uddin

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

In recent times, Triboelectric Nanogenerators (TENG) have attained the focus of the scientific community due to its potential as a medium to harvest mechanical energy from the ambient environment. Human motion has been attributed as a source of mechanical energy to drive electronic devices and sensors through TENG. Based on the principles of single electrode TENG, we have developed a Triboelectricity based Stepping and Tapping Energy Case (TESTEC) which magnifies the prospect to power touch electronic devices by utilizing finger tapping and stepping motion. This novel case was constructed with two single electrode TENG operating through the triboelectric mechanism between …