Chemistry Commons^™

Silver(I) Complexation Of (Poly)Aromatic Ligands. Structural Criteria For Depth Penetration Into Cis-Stilbenoid Cavities, Sergey V. Lindeman, Rajendra Rathore, Jay K. Kochi

Chemistry Faculty Research and Publications

Silver(I) complexes with aromatic donors are thoroughly analyzed (with aid of the Cambridge Crystallographic Database) to identify the basic structural factors inherent to the bonding of an arene ligand. Most strikingly, the distance parameter d (which simply measures the normal separation of Ag from the mean aromatic plane) is singularly invariant at d = 2.41 ± 0.05 Å for all silver/arene complexes, independent of the hapticity (η¹ or η²), hybridization, or multiple coordination. As such, a systematic series of stilbenoid ligands has been successfully designed to precisely modulate the penetration of silver(I) into the ligand cleft, and …

The Effects Of Computer Animations On Secondary Students’ Understanding Of The Crushing Can Chemical Demonstration, Resa Marie Kelly

Dissertations and Theses @ UNI

Understanding chemistry requires the ability to think at three different levels: submicrochemistry, macrochemistry, and representational chemistry. Students often have difficulty making connections among these three areas due to the abstract nature of many chemistry concepts. The purpose of this paper is to investigate how computer animations affected secondary students' understanding of the Crushing Can Demonstration. This investigation compared two groups of chemistry students at a large, suburban high school. The treatment group viewed the animation after seeing and discussing the crushing can demonstration, while the control group received the same instruction as the treatment group but did not see the …

Photodecomposition Of Crystal Violet Dye In Water Solution And Suspensions Of Metal Oxides, Tatiana Yurievna Zakharian

Dissertations and Theses @ UNI

Photodecomposition and photodecolorization of crystal violet dye were studied in water solution, hydrogen peroxide solution and suspensions of metal oxides. Spectroscopic evidence for the formation of methylated pararosanilines and demethylated derivatives of Michler's ketone as the reaction intermediates was obtained for the photodecomposition of crystal violet in water solution. The mechanism of formation of the intermediates was discussed in terms of charges of individual atoms calculated using Spartan software.

Photooxidation of crystal violet was shown to occur faster in hydrogen peroxide solution due to the higher oxidation potential of hydrogen peroxide and hydroxyl radicals. A mechanism similar to photooxidation in …