Chemistry Commons^™

Microhollow Cathode Discharges, K. H. Schoenbach, R. Verhappen, R. Tessnow, F. E. Peterkin, W. W. Byszewski

Bioelectrics Publications

The current–voltage characteristics of hollow cathode discharges and their predischarges in argon under dc and pulsed conditions were found to have a positive slope at pressures up to approximately 50 Torr, and currents up to 20 mA, at a hole diameter of 0.7 mm. In this range of pressure and current, parallel operation of hollow cathode discharges, without ballast, was demonstrated. Scaling to higher pressure is possible by reducing the hole diameter. Pulsed experiments with an array of cathode rings of 75 μm diameter allowed us to obtain parallel operation of more than 50 discharges at a pressure of 350 …

Bulletin 4307 - Grass Control In Pastures Using Herbicides, Alexandra Wallace

Bulletins 4000 -

This Bulletin discusses three methods for herbicide control of grasses in pastures:

• pasture manipulation, in the early stages of pasture growth;
• spray-topping late in the growing season; and
• hay freezing, late in the growing season.

Ua35/11 Student Honors Research Bulletin, Wku Honors Program

WKU Administration Documents

The WKU Student Honors Research Bulletin is dedicated to scholarly involvement and student research. These papers are representative of work done by students from throughout the university.

• Allen, Melody. Women in Control of Courtship in As You Like It, The Merchant of Venice and All's Well That Ends Well
• Amlani, Islamshah. Electron Stimulated Desorption of Alkali Halides
• Brillhart, Kelly. Women Without Men: Hemingway's Female Characters
• Burton, Lori. Financial Statements with Environmental Concerns: An Exploratory Study of the Impact on the Auditor's Role and Responsibilities
• Combs, Vicki. Dancing the Descent: Energy and Entrophy in William Carlos Williams
• Davis, Julie. Prelude to …

Aggregation Of Chlorophyll A Probed By Resonance Light Scattering Spectroscopy, J. C. De Paula, J. H. Robblee, Robert F. Pasternack

Chemistry & Biochemistry Faculty Works

We report the resonance light scattering (RLS) spectra of chlorophyll a aggregated in a 9:1 solution of formamide and pH 6.8 phosphate buffer. The aggregate formed after 2 h of mixing, referred to as Chl(469), shows a strong scattering feature at 469 nm (Soret band) and a much weaker feature at 699 nm (Q(y) band). A kinetic investigation confirmed that the aggregation process is cooperative, and also detected one intermediate (Chl(458)) with a strong RLS spectrum but only a weak CD spectrum. We propose that aggregation proceeds via at least three steps: 1) formation of a nucleating species, probably a …

Understanding Fertilisers For Table Grapes, B. H. Goldspink, I. Cameron, J. Campbell-Clause, N. Lantzke, C. Gordon

Viticulture research reports

A course run by the Department of Agriculture, Western Australia, August 1995.

The purpose of this publication is to clarify the role fertilisers play in commercial table grape production and to detail methods of selecting fertilisers. This selection process however is not easy as there are over 600 registered fertilisers in Western Australia.

In deciding which is the best fertiliser for a particular property many factors have to be considered. These include:

* Age of vine

* Rootstock

* Variety of table grape

* Soil type

* Soil chemistry

* Irrigation methods

* Previous fertiliser history Previous yield, vigour and …

Electron Stimulated Desorption Of Alkali Halides, Islamshah Amlani

Mahurin Honors College Capstone Experience/Thesis Projects

No abstract provided.

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

Evidence For An Unusual Kinetic Phenomenon In The Metallation Of Porphyrins, F. González-Vílchez, R. A. Vilaplana, Robert F. Pasternack

Chemistry & Biochemistry Faculty Works

Reaction of copper(II) with water soluble porphyrins (H₂porph) in the presence of ethylenediamine shows an unusual and so far unreported kinetic phenomenon that can be explained in terms of supramolecular assembly formation apparently involving all solute species as confirmed via light scattering and conductivity measurements.

Seed Phosphorus In Wheat And Lupins, Blakely Paynter, K. Adcock, R. W. Bell, Tim Pope

Experimental Summaries - Plant Research

Trial 90NO119

Seed P in wheat.

Location: Greenhills.

Design: 2 applied P x 3 seed P x 4 replicates, sowing wheat (cv. Aroona) seed from 89N33 at 70 kg/ha on May 15, 1990.

Trial 90NO120

Seed P in wheat.

Location: York

Design: 2 applied from P x 3 seed P x 4 replicates, 89N33 at 70 kg/ha on May 25, 1990.

Trial 90NO117

Seed P in lupins

Location: Greenhills.

Design: 2 applied P x 3 seed P x 4 replicates, sowing lupins (cv. Gungurru) from 85BA35 at 100 kg/ha on May 15, 1990.

Trial 90NO118

Seed P in lupins.

Location: …

Development Of Procedures To Determine The Fertilizer Requirements Of Annual Pasture Legumes Grown In Cereal Cropping Systems., Blakely H. Paynter

Experimental Summaries - Plant Research

Trials 88ME67, 88SC17, 90ME1 and 90ME2

Location: Merredin

To determine the phosphate (P) fertilizer requirements of burr medic on marginally acidic, medium textured soils and yellow serradella on acidic, light textured soils.

Trials 89ME52, 89ME55 and 86ME61

Location: Merredin

Determine the response of yellow serradella and burr medic to residual phosphate and freshly applied phosphate.

Trials 89ME50, 89ME54, 88ME67, 88SC17, 89ME60

Location: Merredin.

To measure the influence of different levels of pasture productivity (generated by different levels of P supply) and the different pasture legumes on subsequent wheat crops.

Second Coefficient Of Viscosity In Air, Robert L. Ash, Allan J. Zuckerwar, Zhonquan Zheng

Mechanical & Aerospace Engineering Faculty Publications

Acoustic attenuation measurements in air were analyzed in order to estimate the second coefficient of viscosity. Data over a temperature range of 11 C to 50 C and at relative humidities between 6 percent and 91 percent were used. This analysis showed that the second coefficient of viscosity varied between 1900 and 20,000 times larger than the dynamic or first coefficient of viscosity over the temperature and humidity range of the data. In addition, the data showed that the molecular relaxation effects, which are responsible for the magnitude of the second coefficient of viscosity, place severe limits on the use …

Hydrogen Sulfide And Radon In And Over The Western North Atlantic Ocean, T. W. Andreae, Gregory A. Cutter, N. Hussain, J. Radford-Knoery, M. O. Andreae

OES Faculty Publications

Atmospheric measurements of radon and hydrogen sulfide, and seawater measurements of total sulfide, free sulfide, and carbonyl sulfide, were made on a cruise in the western North Atlantic Ocean (October 24 to November 9, 1989). Measured values for ²²²Rn ranged from 3 to 70 pCi m⁻³, those for atmospheric hydrogen sulfide from 1 to 85 parts per trillion, and those for dissolved total and free sulfide in seawater from 33 to 930 pmol L⁻¹ and 0 to 73 pmol L⁻¹, respectively. A positive correlation between ²²²Rn and atmospheric H₂S was observed. …

Trace Elements In Estuarine And Coastal Waters: U.S. Studies From 1986-1990, Gregory A. Cutter

OES Faculty Publications

The use of specialized analytical techniques, field studies, controlled laboratory experiments, and geochemical modeling have allowed U.S. investigators to expand our understanding of trace element cycling in coastal waters and estuaries. Considerable emphasis has been placed on quantifying the flux of trace elements within and through the coastal zone. In addition, substantial progress has been made in identifying the chemical speciation of many trace elements, providing a linkage between the geochemical and biochemical behavior of these elements. Another significant advance has been the use of trace elements as tracers of geochemical processes and water masses in the coastal environment.

Pea And Faba Bean Symbiosis With Rhizobium., J. Evans, C. Wallace, N. Dobrowolski

Experimental Summaries - Plant Research

Trial 89WH55, 89KA57, 89M26, 90A12, 90A13, 90M59, 90M60

Location: Merredin, Konnongorring, Dalwallinu, Wongan Hills, Kojonup, Avondale Research Station.

To undertake relevant field studies to establish whether there are constraints to pea and bean symbiosis, arising from management, environment or genetics, and affecting crop N accumulation and productivity.

Trial 90BA60

Using Le-mat (omethoate) insecticide and legume inoculant on seed.

Location: Badgingarra Research Station,

To measure the effect of Lemat on the nodulation and growth of medics and luceme.

Rhizoctonia Bare Patch Of Cereals And Lupins. Sterile Red Fungus (Srf) And Control Of Take-All Disease In Wheat., G. C. Macnish

Experimental Summaries - Plant Research

Trial 86E31

Rhizoctonia strains and paddock history.

Location: Esperance Downs Research Station ( Paddock C5)

To determine the effects of pasture, cultivation and cropping on Rhizoctonia root rot, Rhizoctonia patch and distribution of patch and non-patch strains of R. spp

Trial 88E39

Rhizoctonia patch mini-plot establishment area.

Location: Esperance Downs Research Station ( Paddock N1B)

To examine the effects of cultivation and minimum tillage in patches in lupins and to provide sites for mini-plot experiment.

Trial 88KO15

Rhizoctonia bare patch establishment area.

Location: Kojaneerup annex.

To establish an area (with a known history) for future research.

Trial 89E12

Rhizoctonia bare …

Virus Diseases In Lupins., R. Jones, Simon Mckirdy, A. R. Baker, J. Stevenson

Experimental Summaries - Plant Research

Trial 90BA12, 90WH17, 90A6, 90MT13

Location: Badgingarra, Wongan Hills, Avondale and Mt Barker.

Cucumber Mosaic Virus - Effect of different levels of infection in seed sown.

Trials were done at Badgingarra and Wongan Hills in which plots were sown with seed of cv. Gungurru which transmitted CMV at rates of 5,, l' and O,. The plots were separated by 30 m wide cereal buffers. The intended plant density of 45 plants/sq m (seeding rate 80 kg/ha) was not achieved at either site because of non-wetting soil problems (Table 1). Establishment of CMV infected seedlings as opposed to healthy ones was …

Leaf Diseases Of Wheat, R. Loughman, Geoff Thomas, J. A. Bathgate, W. R. Smith

Experimental Summaries - Plant Research

Trial 90PE10

Strategic variety mixtures to reduce septoria diseases of wheat. Evaluation of wheat lines for suitability to mixing for septoria control.

Location: Mt. Barker Research Station

To determine components of partial resistance to both Septoria species to ensure that lines with components that are complimentary are chosen for evaluation as mixtures for Septoria control.

Trial 90MT12 and 90ME10

Assessing effects of a paired variety mixture to reduce Septoria.

Location: Borden and Mt Barker Research Station.

To assess the effects of a variety mixture on Septoria diseases.

Trial 90MT11 and 90JE9

Evaluating variety mixtures to reduce septoria, using a range …

Management Of Lupin Root Rots In The Northern Agricultural Region., W. Macleod

Experimental Summaries - Plant Research

Trial 90GE93

Field survey of lupin root diseases in the northern wheatbelt.

Location: Northern Agricultural Region - majority within Geraldton Advisory District.

To determine the extent, severity and exact nature of fungi causing root and hypocotyl rots of lupins in the northern wheatbelt.

Trial 90GE98

Effect of time of sowing on rhizoctonia infection of lupins.

Location: Woorree.

To examine the effects of sowing lupins at various intervals after the start of the season on the level of Rhizoctonia hypocotyl rot.

Trial 90EC24

Observations on stunt patch on the eradu sandplain.

Location: East Chapman Research Station.

To examine the effects of …

Pleiochaeta Diseases Of Lupins, Mark Sweetingham

Experimental Summaries - Plant Research

Trial 90WH20, 90SC5, 90LG8

Rates of dicarboximide fungicides for lupins.

Location: Wongan Hills Research Station, South Carrabin Research Station, East Hyden.

To compare the disease control and yield response of Rovral and Sumisclex seed treatments at a range of rates.

Trial 90M11, 90BA17

Rates of dicarboxide fungicides for lupins.

Location: Merredin Research Station, Badgingarra Research Station.

To compare the disease control and yield response of Rovral and Sumisclex seed treatments at a range of rates,

Weed Control On The South Coast., J. H. Moore

Experimental Summaries - Plant Research

Trial 90A141

Barley variety tolerance to herbicides.

Location: Gairdner river.

To determine the tolerance of five barley varieties to 19 herbicides and mixtures.

Trial 90AL43

Herbicides for erodium control in serradella.

Location: North Woogenilup.

To determine the efficacy and phytotoxicity of a range of herbicides at varying rates, on erodium in a first year serradella pasture.

Trial 90AL44

Silvergrass control in pasture.

Location: Cheynes Beach Road.

To determine the efficacy of simazine and gramoxone, either tankmixed or individually at varying rates, on silver grass in a clover based pasture.

Trial 90AL45

Pattersons curse control.

To determine which herbicides and at …

A Survey Using 14n:15n Natural Abundance Of The N Fixation By Pasture Legumes In The Field And Of Factors Affecting Fixation, P. Sanford

Experimental Summaries - Plant Research

Trial 89AL43, 90AL50, 90KO16

A preliminary survey using 14N:15N natural abundance to assess N2 fixation by pasture legumes in the field.

Location: Albany.

1. Develop a sampling methodology for the 1990 farm survey.
2. An initial assessment of nitrogen fixation by pasture legumes in the field.

Trial 90MT70

Using 14N:15N natural abundance to assess N2-fixation by subterranean clover.

Location Mount Barker Research Station

To examine symbiotic nitrogen fixation by subterranean clover, in detail, through one season in a productive pasture. To better assess the point in the season at which as one time sampling would most accurately determine the proportion …

Herbicide Resistance In Weeds., G. S. Gill

Experimental Summaries - Plant Research

Trial 90WH76

Alternative herbicides for diclofop-methyl resistant annual ryegrass in wheat.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in wheat.

Trial 90WH80

Alternative herbicides for diclofop-methyl resistant annual ryegrass in lupins.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in lupins

Trial 90A15

Alternative herbicides for Diclofop-methyl resistant wild oats in wheat.

Location: Avondale Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant wild oats in wheat.

Trial 90A17 …

Phosphorus Nutrition., M. D. Bolland, M. J. Baker

Experimental Summaries - Plant Research

Evaluation of soil test for phosphate on sandy soils.

Results presented for this project, commenced in 1988, which started as a joint project between the Department of Agriculture and Soil Science and Plant Nutrition, School of Agriculture, University of Western Australia.

In the field experiments, 10 levels of superphosphate (three replicates) were applied in May 1988, and 10 levels of superphosphate (also three replicates) were applied in May 1989 onto an adjacent area to the 1988 treatments. Colwell P I(soil test values) and yield data are presented for 1988 and 1989 for the 1988 treatments layed out in 1988, and …

Cranola Rapseed Variety Assessment. Cranola Agronomy. Linseed. Tillage., J. D. Warren

Experimental Summaries - Plant Research

Trial 90AB15. 90N68, 90EB39

Canola : assessment of early maturing Stage 2 lines.

Location: Katanning, Newdegate Research Station, East Beverley Annex

Production of Canola in medium rainfall zones offers the opportunity for a rapid expansion of the industry. However presently recommended varieties take too long to mature for the area's shorter growing season. The Stage 2 trials assess Canola lines selected on the basis of earliness from the remnants of Dr Roy's now defunct rapeseed breeding programme as well as selections from Eastern States breeding programmes. The trials arc conducted at three sites to account for environmental effects on cultivar …

Getting The Best Out Of Our Wheats., Brenda Shackley, L. Lambert

Experimental Summaries - Plant Research

Trials: 90KA82 (TOS1), 90KA83 (TOS 2), 90KA84 (TOS 3)
90LG4 (TOS 1), 90LG45 (TOS 2), 90LG46 (TOS 3)
90LG47 (TOS 1), 90LG48 (TOS 2), 90LG49 (TOS 3)
90N42 (TOS 1), 90N43 (TOS 2), 90N44 (TOS 3)

Variety * time of sowing (TOS)

Locations: Wagin, Tarin Rock, Newdegate Research Station and Lake Varley.

Determine the optimum sowing date for maximum yield for a range of released and unreleased wheat cultivars.

Trials: 90KA79, 90LG50, 90LG51, 90N62

Nitrogen application.

Locations: Wagin, Tarin Rock, Newdegate Station and Lake Varley.

Determine the response of released and unreleased wheat cultivars to the application of nitrogen.

Trials: …

Tactical Nitrogen For Wheat., J. W. Bowden, S. J. Burgess, Ian Fillery

Experimental Summaries - Plant Research

Trial 90NO104, 90NO111, 90NO112, 90MO53

Associated Work: 90N0105,111,112, 90M053,54, 55 and 56

Wheat responses to levels, sources and times of application of nitrogen.

Location: Southern Brook, Regan's Ford

This project characterizes the dynamics of nitrogen supply to a wheat crop at each of the sites on which various methods of making fertilizer recommendation were tested. It supposedly provides the "optimum" nitrogen fertilizer regime as well as detailed information on nitrogen supply and demand so that results can be made transferable to other situations.

Trial 90NO105, 90NO112, 90M054

Related trials: 90N0104, 105,111,112; 90M053,54,55 and 56

Tactical nitrogen application for wheat.

Location: …

Pursuit For Weed Control In Peas., S. Curtin

Experimental Summaries - Plant Research

All trials were located in Merredin.

Trial 90ME86

This trial was one of the best demonstrations of pursuits effectiveness against mustard in particular. Other weeds were rough poppy and ryegrass and a small amount of cereal and doublegee.

250 ml applied immediate before seeding (IBS) was by far the best treatment with 100% control of mustard and poppy and good ryegrass control. This is in contract to 375 ml most emergent which had good control of mustard (77%) and suppression of ryegrass. There was no yield advantage from the post emergent treatment but there was a 55% yield increase from …

Weed Control In Crops And Pasture., J. Buckley

Experimental Summaries - Plant Research

Trial 90WH74

Crop establishment trial

Location: Wongan Hills Research Station.

To assess the effect of timing of roundup and sprayseed application and cultivation on crop growth.

Trial 90AB19

Ryegrass control in wheat using slow release trifluralin.

Location: Katanning.

To compare 2 experimental formulations of controlled release trifluralin at 4 rates and 2 timings with some commonly used herbicides for the control of ryegrass in wheat.

Trial 90ME84

Early application of 2, 4-D to wheat.

Location: Corrigin.

To assess the use of 2,4-D.amine at early times of application for the control of broadleaf weeds in wheat.

Trial 90WH92

Early application of …

Deep Phosphate Banding., R. J. Jarvis

Experimental Summaries - Plant Research

Trial 90A1

Lupins sown 26/4. York gum/jam sandy loam 33 ppm bic. P. Wheat in 1989. Cultivation reduced yield (one pass banding points). Deep banding P overcame this reduction. No additional response to banding compared with TD or D. No response to P. Yield 2.0 t/ha.

Trial 90A2

Wheat sown 8/6. York gum/jam sandy loam 42 ppm bic. P. Lupins in 1989. All treatments had deep cultivation in the one pass. No response to deep band cf. drilled. 23% response to P. Top yield was 1.9 Oa.

88EB12 Wheat sown 5/6. Loamy grey sand/clay 27 ppm bic. P. Lupins in …

National Subterranean Clover Improvement Programme., P. G. H. Nichols

Experimental Summaries - Plant Research

The National Subterranean Clover Improvement Programme (NSCIP) aims to develop, by breeding and selection, better adapted and more productive low—oestrogen cultivars of subterranean clover for a range of environments in southern Australia. The programme is a collaborative one with the University of Western Australia and consists of two phases: (i) early generation selection, which involves selecting varieties satisfying primary selection criteria; and (ii) field evaluation of advanced lines, which is conducted by the Departments of Agriculture in each State and co—ordinated by the Plant Breeder.

The first phase is conducted at the University Field Station (UFS) and is continued until …