Other Astrophysics and Astronomy Commons^™

Vibrational And Electronic Spectroscopy Of 2-Cyanoindene Cations, Thomas E. Douglas-Walker, Eleanor K. Ashworth, Mark H. Stockett, Francis C. Daly, Isabelle Chambrier, Vincent J. Esposito, Marius Gerlach, Angel Zheng, Julianna Palotás, Andrew N. Cammidge, Ewen K. Campbell, Sandra BrüNken, James N. Bull

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

2-Cyanoindene is one of the few specific aromatic or polycyclic aromatic hydrocarbon (PAH) molecules positively identified in Taurus molecular cloud-1 (TMC-1), a cold, dense molecular cloud that is considered the nearest star-forming region to Earth. We report cryogenic mid-infrared (550–3200 cm^–1) and visible (16,500–20,000 cm^–1, over the D2 ← D0 electronic transition) spectra of 2-cyanoindene radical cations (2CNI⁺), measured using messenger tagging (He and Ne) photodissociation spectroscopy. The infrared spectra reveal the prominence of anharmonic couplings, particularly over the fingerprint region. There is a strong CN-stretching mode at 2177 ± 1 cm^–1 (4.593 …

A Spectrum Of Light: Speculative Poetry Of Celestial Bodies And Astrophysics, Shannon Sosebee

Electronic Theses and Dissertations

This is a collection of speculative poetry with a focus on celestial objects within our solar system and larger bodies outside of our solar system, some of which are only theorized to exist. The author finishes the collection with introspective works, laying bare vulnerabilities and insecurities.

An Investigation Into The Use Of Amateur Astronomy Equipment For Optical Orbit Determination Using A Mobile Telescope Platform, Johan C. Govaars

Master's Theses

The process of optical orbit determination has long been in the domain of large organizations and stationary observatories with highly specialized scientific equipment. This thesis seeks to determine not only if satellites can be captured regularly using purely commercial-off-the-shelf (COTS) equipment, but also if initial orbit determinations can be made using that data. Moreover, the use of a mobile telescope platform allows users to circumvent the restrictions of fixed observatories such as low horizon viewing restrictions or existing light pollution.

A completely COTS setup was utilized that included an 8-inch Celestron NextStar 8SE telescope with an f/6.3 focal reducer and …

Legal And Ethical Considerations For Balancing Space Innovation And Dark Sky Preservation, Sara M. Langston, Kayla D. Taylor

Publications

The proliferation of satellites in Earth’s orbit has significantly enhanced capabilities in communication, Earth observation, and scientific research. However, this rapid expansion presents considerable legal and ethical challenges, particularly regarding the preservation of dark and quiet skies. As low Earth orbit becomes increasingly congested, the implications for astronomical observation, environmental integrity, and cultural heritage require critical examination.

This presentation provides an interdisciplinary perspective on the legal, practical and ethical considerations essential for preserving dark and quiet skies. It begins by exploring the legal frameworks governing the use of space, highlighting relevant international treaties, national responsibilities, and emerging issues aimed at …

Statistical Methods For Interpreting Spatial And Temporal Heterogeneity Of Martian Tropical Water Ice Informed By Properties Of Crater Ejecta Types, Jamie D. Riggs, Michelle R. Kirchoff

College of Population Health Faculty Papers

The martian tropical water ice spatial and temporal distribution was characterized using impact crater ejecta type, location, size, and age in one of two epochs, (Formula presented.) Ga and (Formula presented.) Ga, using statistical models designed for spatial and temporal correlation structures. The indicator thought to identify the presence of ice is craters with layered ejecta, while the indicator thought to identify no ice is craters with radial ejecta. These indicators imply the location (longitude and latitude) and, potentially, depth (crater diameter as a proxy) of ice, and when the ice was present. The spatial and temporal distribution of layered …

Battle Of The Ch Motions: Aliphatic Vs Aromatic Contributions To Astronomical Pah Emission And Exploration Of The Aliphatic, Aromatic, And Ethynyl Ch Stretches, Vincent J. Esposito, Salma Bejaoui, Brant E. Billinghurst, Christiaan Boersma, Ryan C. Fortenberry, Farid Salama

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Strong anharmonic coupling between vibrational states in polycyclic aromatic hydrocarbons (PAH) produces highly mixed vibrational transitions that challenge the current understanding of the nature of the astronomical mid-infrared PAH emission bands. Traditionally, PAH emission bands have been characterized as either aromatic or aliphatic, and this assignment is used to determine the fraction of aliphatic carbon in astronomical sources. In reality, each of the transitions previously utilized for such an attribution is highly mixed with contributions from both aliphatic and aromatic CH motions as well as non-CH motions such as CC stretches. High-resolution gas-phase IR absorption measurements of the spectra of …

From Stars To Moons: Investigating Stellar Rotations, Planetary Interactions, And Exoplanetary Prospects, Rosario Cecilio-Flores-Elie

Dissertations, Theses, and Capstone Projects

The thesis is divided into two key sections. The first chapter presents the results of analyzing TESS light curves for 99 targets within the Carina-Near moving group. By deriving rotational periods, this analysis supports stellar age estimation, contributing to the broader efforts of the Backyard Worlds: Planet 9 citizen project in determining age parameters for 89 newly identified systems, including ultracool dwarf companions. These findings enhance our understanding of stellar rotation and evolution, offering new insights into the development of secondary co-moving objects like brown dwarfs.

The second chapter investigates planet-moon interactions within our solar system by examining mass ratios, …

On The Formation And Detectability Of H2Cncn And Its Progenitors, Ryan C. Fortenberry, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

New highly exothermic formation pathways incorporating both thermodynamic and kinetic control for the newly astronomically detected H₂CNCN molecule are paired with extremely accurate quantum chemical rovibrational spectroscopic computations. The reactions between astronomically known CH₂CN/CH₂CCH + HNCN follow effectively identical pathways and proceed through stable intermediates and over deeply submerged transition states to form H₂CNCN and HCN/HCCH coproducts. Similarly, the reaction between CHM₂CN and NCN⁻ can also form H₂CNCN, although this pathway first requires the initial formation of NCN⁻, which is currently undetected in space, via …

Experimental Determination Of The Unusual Ch Stretch Frequency Of Protonated Fullerenes, Laura Finazzi, Vincent J. Esposito, Julianna Palotás, Jonathan Martens, Els Peeters, Jan Cami, Giel Berden, Jos Oomens

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We report experimental values for the CH stretch frequencies of the protonated fullerenes C₆₀H⁺ and C₇₀H⁺. Anharmonic frequency calculations at the B3LYP/6-31G level of theory, which are independent of empirical scaling factors, reproduce the experimental values to within approximately 5 cm⁻¹. Scaling theoretical harmonic frequencies by applying factors derived for polycyclic aromatic hydrocarbons deviate significantly from the experimentally measured frequency. We attribute this deviation to the unusual hydrocarbon structure that affects the degree of anharmonicity of the CH stretch. This result allows us to propose an original, specific scaling factor of …

Archaeology In Space: The Sampling Quadrangle Assemblages Research Experiment (Square) On The International Space Station. Report 1: Squares 03 And 05, Justin St. P. Walsh, Shawn Graham, Alice C. Gorman, Chantal Brousseau, Salma Abdullah

Art Faculty Articles and Research

Between January and March 2022, crew aboard the International Space Station (ISS) performed the first archaeological fieldwork in space, the Sampling Quadrangle Assemblages Research Experiment (SQuARE). The experiment aimed to: (1) develop a new understanding of how humans adapt to life in an environmental context for which we are not evolutionarily adapted, using evidence from the observation of material culture; (2) identify disjunctions between planned and actual usage of facilities on a space station; (3) develop and test techniques that enable archaeological research at a distance; and (4) demonstrate the relevance of social science methods and perspectives for improving life …

Constraining Giant Planet Occurrence Rates With The Multi-Band Imaging Survey For High-Alpha Planets (Mishaps) Observations Of 47 Tucanae, Alison Crisp

LSU Doctoral Dissertations

Though the confirmed exoplanet population has now reached over 5,500 planets, we still have a plethora of unanswered questions, e.g., regarding their formation mechanisms, true demographics, occurrence rates, and habitability. One remaining question is whether hot Jupiters formed in situ or migrated to their current orbits, so close to their host stars that their periods are 10 days or less. This question can potentially be answered by probing the effects of elemental abundances on hot Jupiter occurrence rates. These rates have been found to correlate with metallicity, but the specific elements responsible for the correlation have largely been unresolved. The …

Assigning The Ch Stretch Overtone Spectrum Of Benzene And Naphthalene With Extension To Anthracene And Tetracene Using 2- And 3-Quanta Anharmonic Quantum Chemical Computations, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The CH stretch overtone region (5750–6300 cm⁻¹) of benzene and naphthalene is assigned herein using anharmonic quantum chemical computations, and the trend of how this extends to larger polycyclic aromatic hydrocarbons (PAHs) is established. The assignment of all experimental bands to specific vibrational states is performed for the first time. Resonance polyads and the inclusion of 3-quanta vibrational states are both needed to compute accurate vibrational frequencies with the proper density-of-states to match the experimental band shape. Hundreds of 3-quanta states produce the observed band structure in naphthalene, anthracene, and tetracene, and this number is expected to increase …

Comparison Between Galfit And Lenstronomy To Analyze The Host Galaxies Of Reverberation Mapped Active Galactic Nuclei, Samantha Kay Allen

Physics

Active Galactic Nuclei (AGN) are some of the brightest objects within our Universe. Most galaxies contain a supermassive black hole (SMBH) at their center, but not all are powered by active accretion which can form an AGN. Due to the conservation of angular momentum, dust and gas rotate around the SMBH to form a disk. The large gravitational potential energy from the SMBH is converted into heat through friction, which produces a hot and luminous source of light. As a result, the SMBH is unresolved. Through a technique known as reverberation mapping (RM), the mass of the SMBH has been …

Theoretical Spectroscopic Predictions Of Electronically Excited States, Noah R. Garrett

Honors Theses

The quest for faster computation of anharmonic vibrational frequencies of both ground and excited electronic states has led to combining coupled cluster theory harmonic force constants with density functional theory (DFT) cubic and quartic force constants for defining a quartic force field (QFF) utilized in conjunction with vibrational perturbation theory at second order (VPT2). This work shows that explicitly correlated coupled cluster theory at the singles, doubles, and perturbative triples level [CCSD(T)-F12] provides accurate anharmonic vibrational frequencies and rotational constants when conjoined with any of B3LYP, CAM-B3LYP, BHandHLYP, PBE0, and ωB97XD for roughly one-quarter of the computational time of the …

Cn Stretches Around 4.4 Microns Dominate The Ir Absorption Spectra Of Cyanopolycyclic Aromatic Hydrocarbons, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Alexandros Maragkoudakis, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonic quantum chemical computations reveal a strong, narrow (width = 0.075 μm) band in the 4.3–4.5 μm region of the absorption spectra of the cyano-substituted polycyclic aromatic hydrocarbons (CN-PAHs) cyanonaphthalene, cyanoanthracene, c yanophenanthrene, and c yanopyrene. This narro w windo w with intense IR lines implies that CN-PAHs of various shapes and sizes offer little variation in both wavelength and intensity in this region. Subsequently, this band can be used as a tracer for CN-PAHs. The distinct features making up the band are assigned to mixed vibrational states consisting of the CN stretch fundamental and various combination bands, including in-plane …

The Gravitational Wave Peep: Improved Modeling Of Highly Eccentric Emris For Lisa Signal Confusion Noise, Daniel Joseph Oliver

Graduate Theses and Dissertations

Scattering events around a massive black hole will occasionally toss a stellar-mass compact object into an orbit around the massive black hole, beginning an extreme mass ratio inspiral. The early stages of such a highly eccentric orbit will not produce detectable gravitational waves as the source will only be in a suitable frequency band briefly when it is close to periapsis during each long-period orbit. This burst of emission, firmly in the millihertz band, is the gravitational wave peep. While a single peep is not likely to be detectable, if we consider an ensemble of such subthreshold sources, spread across …

Significance And Reflection Of Lunar Exploration, Jiaqi Liu

Bulletin of Chinese Academy of Sciences (Chinese Version)

Although China's lunar exploration project started later than the Soviet Union and the United States, it is the first country to land probes and retrieve samples on both the right side and the reverse side of the Moon. There have been many major breakthroughs in space technology, and many important achievements in scientific research as well. It has extended the life of the Moon for about 1 billion years.

Modeling An Extra Planet's Effects On Earth, Emily Simpson

Aerospace, Physics, and Space Science Student Publications

Orbital dynamics play a crucial role in determining the habitability of exoplanets, and many models have been developed to study the dynamical evolution of broader planetary system structure. To further investigate the implications this has regarding planetary habitability, this project simulated the evolution of the Solar System with an additional planet orbiting in place of the Asteroid Belt using the Gravitational Rigid-body InTegrator (GRIT) package. 21 total simulations were run for 100,000 years with varying values for the extra planet’s mass (from 0.01 to 10 Earth masses) and orbital parameters (based on the 4 most massive asteroids in the Asteroid …

Factors Predicting Public’S Willingness To Support National Aeronautics And Space Administration’S Artemis Mission, Sean Crouse

Doctoral Dissertations and Master's Theses

NASA's Artemis program aspires to return astronauts to the moon and aims to land the first woman and person of color on the lunar surface. The endeavor symbolizes the next evolution in space exploration and serves as a testament to the human spirit of discovery. In the face of this significant undertaking, gauging public sentiment and understanding the factors driving public support becomes necessary. The current study aimed to address a critical gap in the literature by examining public support for NASA’s Artemis mission, which is essential for sustaining the program’s momentum and cultivating a culture of innovation and exploration. …

The Infrared Absorption Spectrum Of Phenylacetylene And Its Deuterated Isotopologue In The Mid- To Far-Ir, Vincent J. Esposito, Pierro Ferrari, Wybren Jan Buma, Ryan C. Fortenberry, Christiaan Boersma, Alessandra Candian, Alexander G. G. M. Tielens

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonicity strongly influences the absorption and emission spectra of polycyclic aromatic hydrocarbon (PAH) molecules. Here, IR–UV ion-dip spectroscopy experiments together with detailed anharmonic computations reveal the presence of fundamental, overtone, as well as 2- and 3-quanta combination band transitions in the far- and mid-infrared absorption spectra of phenylacetylene and its singly deuterated isotopologue. Strong absorption features in the 400–900 cm⁻¹ range originate from CH(D) in-plane and out-of-plane wags and bends, as well as bending motions including the C≡C and CH bonds of the acetylene substituent and the aromatic ring. For phenylacetylene, every absorption feature is assigned either directly or …

Toward The Ir Detection Of Carbon Acid: Absorption And Emission Spectrum, Ryan C. Fortenberry, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

With the recent radioastronomical detection of cis-trans-carbonic acid (H₂CO₃) in a molecular cloud toward the Galactic center, the more stable but currently unobserved cis-cis conformer is shown here to have strong IR features. While the higher-energy cis-trans-carbonic acid was detected at millimeter and centimeter wavelengths, owing to its larger dipole moment, the vibrational structure of cis-cis-carbonic acid is more amenable to its observation at micron wavelengths. Even so, both conformers have relatively large IR intensities, and some of these fall in regions not dominated by polycyclic aromatic hydrocarbons. Water features may inhibit observation …

Refracting Ufos: Solutions For Fermi Questions, May 2024, John Adam

Mathematics & Statistics Faculty Publications

This article, titled "Refracting UFOs: Solutions for Fermi Questions, May 2024," recounts the author's personal experience as a teenager observing a UFO sighting near their home in England. The author used their telescope to observe the object, which turned out to be lights from a distant airplane flying in a circular holding pattern. The article then presents two questions related to the observed phenomenon, including estimating the diameter of the aircraft's path and the banking angle of the aircraft at its speed. The article concludes with a solution to estimating the distance to the aircraft. The information is presented objectively …

Refracting Ufos, John Adam

Mathematics & Statistics Faculty Publications

Question 2: Assuming θ ≈ 2° = π/90 rad, estimate the distance R to the aircraft. Assume that R ≫ d. Question 1: Suppose that the observed “period of oscillation” is 1 min, and the speed of the aircraft is 200 km/h. Estimate the diameter d of the aircraft path (assuming that it is circular). Estimate the banking angle of the aircraft at this speed. While still a teenager (and aspiring astronomer), I became interested in the subject of UFOs (more appropriately named UAPs—see Ref. 1). The region in which I lived (50 km west of London) was in the …

Possible Evidences For Existence Of An Aether Medium (Or Virtual Inertia/Spin Superfluid Medium), Victor Christianto, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

The presentation explores the possibility of an aether medium, also referred to as a virtual inertia/spin superfluid medium, existing to explain certain physical phenomena. While the concept of an aether has been historically rejected by mainstream physics, recent findings and interpretations offer potential justifications for its reconsideration. After discussions with several physicists, notably Robert N. Boyd, PhD and others, we are convinced that aether medium does exist, or may be called virtual inertia/spin superfluid medium.

Study Of Particle Accelerators In The Universe With The Hawc Observatory, Rishi Babu

Dissertations, Master's Theses and Master's Reports

HESS J1809-193 is an unidentified TeV source discovered in 2007 by the High Energy Stereoscopic System(H.E.S.S.) Collaboration. The emission originates in a region that is rich in cosmic-ray accelerators, including several supernova remnants and pulsars, including SNR G11.1+0.1, SNR G11.0-0.0, and the young radio pulsar PSR J1809-1917. Originally classified as a pulsar wind nebula candidate, recent studies show the peak of the TeV region overlapping with a system of molecular clouds and revising the original classification for other scenarios, including a pure hadronic scenario. This dissertation presents the morphological and spectral study of HESS J1809-193 using 2139 days of data …

Young Atmospheres Spiriting Away, Keighley Elizabeth Rockcliffe

Dartmouth College Ph.D Dissertations

The astronomy community has spectacularly achieved the first step in characterizing exoplanets: discovery. Over three decades of exoplanet detection have populated the Milky Way's exoplanet mosaic with thousands of planets, and more are on the way. Key trends within this mosaic reveal atmospheric escape as an underlying evolutionary process that has significantly shaped the population. While we are aware that atmospheric escape plays some role in exoplanet evolution, we do not know the extent of its influence, how it compares to other processes, and its specific physical mechanisms. Detailed studies of individual systems at known, young ages are direct tests …