Other Astrophysics and Astronomy Commons^™

Emergent De Sitter Expansion And Closed Topology From The Cosmic Fabric Model As An Open Thermodynamic System: Resolving The Negative Bulk Modulus Paradox, T G. Tenev, C B. Ward, T F. Tenev, M F. Horstemeyer

Faculty Publications and Presentations

The Cosmic Fabric Model establishes a continuum-mechanics isomorphism to General Relativity by representing physical space as an elastic three-dimensional hyperplate embedded in a four-dimensional spatial bulk. Reproducing vacuum kinematics requires a vanishing P-wave modulus, which in turn implies a negative bulk modulus—an apparent thermodynamic instability in a closed system. This paradox is resolved by recasting the framework as an open system: the instability is not pathological but instead drives cosmic expansion. In this interpretation, the observable universe is a lower-energy solid formed through continuous solidification from a higher-dimensional precursor fluid. Using multiplicative kinematics from finite-growth mechanics, the model shows that …

Detection Of C60 Combination Bands In The Near-Ir Spectrum Of Tc 1, Morgan M. Giese, Vincent J. Esposito, Simon Van Schuylenbergh, Jan Cami, Els Peeters, Charmi Bhatt, Dries Van De Putte, A. G. G. M. Tielens, Michael J. Barlow, Jeronimo Bernard-Salas, Alessandra Candian, Bryan Changala, Nick L. J. Cox, Harriet L. Dinerstein, D. A. García-Hernández, Marco A. Gómez-Muñoz, Kay Justtanont, Kathleen E. Kraemer, Eric Lagadec, Arturo Manchado, Ana Monreal Ibero, Raghvendra Sahai, Ameek Sidhu, G. C. Sloan, N. C. Sterling, Jeremy R. Walsh, Roger Wesson, Joshua Cole Whitman, Albert Zijlstra

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We report the detection of a set of new near-infrared emission features between 3.5 and 5.2 μm in JWST/NIRSpec observations of Tc 1, the planetary nebula known for displaying the cleanest and most prominent mid-infrared cosmic fullerene spectrum. These broad features share the same spatial distribution as the well-known C₆₀ and C₇₀ mid-infrared emission bands, peaking in an asymmetric ring approximately 5″–6″ from the central star. Through comparison with new anharmonic quantum chemical calculations, we demonstrate that these features arise from C₆₀ combination bands, marking their first detection in an astrophysical environment. The total energy radiated …

What Do Black Holes Teach Us About Wigner’S Friend?, Emily Adlam

Mathematics, Physics, and Computer Science Faculty Articles and Research

Recently, Hausmann and Renner have pointed out that several famous paradoxes relating to black holes have a similar character to various Extended Wigner’s Friend paradoxes. In this paper I consider what the connection between these things could teach us about the Wigner’s Friend scenarios. I argue that if we take the analogy between these cases seriously, the black hole paradoxes appear to favour a certain class of response to the Wigner’s Friend scenario - specifically, those which posit intrinsic relationality, rather than effective and emergent relationality, and also those which posit some kind of retrocausality.

Coordinates, Time, And The Sky, John R. Thorstensen

Other Faculty Materials

This monograph explains celestial coordinates and their basis in the motion and orientation of the earth.  It was written for use in undergraduate classes in basic astronomy and observational techniques.

Discovery Of Dynamical Structures Mapping Chaotic Transport Pathways In The Earth–Moon Cr3bp, Tyler J. Kapolka, Christina E. Paljug, Robert A. Bettinger, Rachel Oliver, Bruce A. Cox, Jeremiah A. Specht

Faculty Publications

Chaos; Deterministic chaos; Earth–Moon system; Poincaré map; Quasi-chaotic; Surface of section /// For the Circular Restricted 3-Body Problem (CR3BP), the topologies present within a Poincaré map enable the extraction of useful information regarding periodic, quasi-periodic, and chaotic trajectory behavior. Aside from the prominent topologies that follow distinct concentric patterns around fixed points, indicative of the periodic and quasi-periodic motion that is often the central focus of CR3BP research, there are also many “dusty” regions on the Poincaré map that appear random without an apparent structure and are indicative of chaotic motion. This paper, for the first time in literature, identifies …

Facility Usage On The International Space Station, Justin St. P. Walsh, Rao Hamza Ali, Ryan Shihabi, Erik Linstead

Art Faculty Articles and Research

Science experiments on the International Space Station (ISS) and in future space habitats require “facilities,” as they are known to space agencies, as the core building blocks of the research capabilities they provide. Facilities are experimental apparatus that enable research, often (but not always) used for more than one experiment, such as centrifuges, furnaces, gloveboxes, freezers, and more. The US Orbital Segment of the ISS has been home to 191 such facilities, belonging to four of the five ISS international partner agencies as well as private companies, in its 25 years of continuous operation. Until now, there has been no …

Experimental And Anharmonic Theoretical Spectroscopic Benchmarks Of Nitrogenated And Doubly-Nitrogenated Polycyclic Heterocycles, Selma Bejaoui, Brant E. Billinghurst, Christiaan Boersma, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

In this study, we report the first high-resolution gas-phase infrared absorption spectra and anharmonic vibrational simulations for three nitrogenated aromatic molecules, namely indole (C₈H₇N), 1,5-diazabicyclo[4.3.0]non-5-ene (DBN; C₇H₁₂N₂), and 1,8- diazabicyclo[5.4.0]undec-7-ene (DBU; C₉H₁₆N₂) with excellent agreement between measurement and computation. Anharmonic cascade emission spectra (2–8 eV) of the three systems show that nitrogen substitution strongly modifies the emission spectra: indole reproduces the unidentified 3.3 μm emission in Titan’s atmosphere, while DBN and DBU exhibit redshifted aliphatic C–H stretches. In the 5–10 μm region, …

Integrating Universal Generative Ai Platforms In Educational Labs To Foster Critical Thinking And Digital Literacy, Vasiliy S. Znamenskiy, Joel Hernandez, Rafael Niyazov

Publications and Research

This study investigates the educational potential of generative artificial intelligence (GenAI) platforms based on large language models (LLMs), such as ChatGPT, Claude, and Gemini, as tools for studentcentred learning. Recognizing the current limitations of GenAI, particularly its propensity for generating inaccurate or misleading information—the paper proposes a novel instructional strategy: an interdisciplinary laboratory designed to foster critical evaluation of GenAI-generated outputs. In this pedagogical model, students engage with GenAI systems by posing questions or solving problems drawn from topics they have already studied and understand. Equipped with correct answers, students are positioned to assess the accuracy and relevance of AI-generated …

Enhanced Nuclear Binding Near The Proton Drip Line Opens Possible Bypass Of The 64Ge Rapid Proton Capture Process Waiting Point, Zachary Meisel, W.-J Ong, J. S. Ranhawa

Faculty Publications

We performed astrophysics model calculations with updated nuclear data to identify a possible bypass of the ⁶⁴Ge waiting point, a defining feature of the rapid proton capture (rp) process that powers type I X-ray bursts on accreting neutron stars. We find that the rp-process flow through the 64Ge bypass could be up to 36% for astrophysically relevant conditions. Our results call for new studies of ⁶⁵Se, including the nuclear mass, β-delayed proton emission branching, and nuclear structure as it pertains to the 64As(p, γ) reaction rate at X-ray burst temperatures.

A Catalytic Pathway For The Formation Of Cyanobenzene In Nitrogen-Rich Environments And The Spectroscopy Of The Reactive Intermediates, Vincent J. Esposito, Silvia Alessandrini, David Dubois, Ryan Fortenberry

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The catalytic reaction of isocyanobenzene (C₆H₅NC) with NCN⁻ produces cyanobenzene (C₆H₅NC) through various highly stable reactive intermediate species. Nitrogen-rich environments such as Titan’s atmosphere serve as favorable locations to study reaction pathways involving nitrogenated species contributing to organic growth. Formation pathways of cyanobenzene have been characterized, but none with the contribution of anions or phenyl groups. In regions with a high abundance of nitrogen anions, such as Titan’s atmosphere, reactions with species such as NCN⁻ may play a role in the formation of cyanobenzene. Highly accurate computational methods are used …

Computational Modeling Of Astrophysical Systems, Leleya Iris Stallard

Spring Showcase for Research and Creative Inquiry

This research project focuses on the computational modeling of astrophysical systems using Femap with NX Nastran. The goal was to simulate and analyze the vibrational behavior and structural deformation of celestial bodies under different material compositions and collision conditions. Materials such as iron, granite, titanium, and models for white dwarf stars were used to investigate how varying physical properties affect the systems' dynamic responses. Both isotropic and anisotropic models were created to represent realistic astrophysical materials. Through static and modal analyses, the study explored how internal structure and material stiffness influence the reaction of celestial objects to applied forces and …

Infrared Cooling In An Anharmonic Cascade Framework: 2-Cyanoindene, The Smallest Cyano-Pah Identified In Tmc-1, Mark H. Stockett, Vincent J. Esposito, Eleanor K. Ashworth, Ugo Jacovella, James N. Bull

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Infrared (IR) cooling of polycyclic aromatic hydrocarbon (PAH) molecules is a major radiative stabilization mechanism of PAHs present in space and is the origin of the aromatic infrared bands (AIBs). Here, we report an anharmonic cascade model in a master equation framework to model IR emission rates and emission spectra of energized PAHs as a function of internal energy. The underlying (simple harmonic cascade) framework for fundamental vibrations has been developed through the modeling of cooling rates of PAH cations and other carboneaous ions measured in electrostatic ion storage ring experiments performed under “molecular cloud in a box” conditions. The …

A Sensitivity Analysis Of The Modeling Of Polycyclic Aromatic Hydrocarbon Emission In Galaxies, A. Maragkoudakis, C. Boersma, P. Temi, J. D. Bregman, L. J. Allamandola, Vincent J. Esposito, A. Ricca, E. Peeters

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We have conducted a sensitivity analysis on the mid-infrared spectral decomposition of galaxies and the modeling of the polycyclic aromatic hydrocarbon (PAH) emission spectrum with the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) to assess the variance on the average galaxy PAH population properties under a grid of different modeling parameters. We find that the short-low and short-low+long-low Spitzer-IRS decomposition with PAHFIT provides consistent modeling and recovery of the 5–15 μm PAH emission spectrum. For PAHdb modeling, application of a redshift to the calculated spectra to account for anharmonic effects introduces a 15%–20% variance on the derived parameters, while its …

Photolysis And Sublimation Chemistry Of Ammonium Cyanide With Relevance To Cometary Environments, O. H. Wilkins, K. M. Yocum, Vincent J. Esposito, E. Harel, S. N. Milam, P. A. Gerakines

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Bulk nitrogen is depleted in solar system objects, including the terrestrial planets, chondritic meteorites, and comets. Recently, it was suggested that cometary nitrogen may be locked up in ammonium salts—ionic solids comprising ammonia (NH₃) and an acid such as hydrogen cyanide (HCN)—based on Rosetta/ROSINA data from comet 67P/Churyumov–Gerasimanko. Among the proposed salts to have been found in 67P were ammonium cyanide (NH₄CN) and ammonium cyanate (NH₄OCN), which were inferred from identifying HCN, cyanamide (NH₂CN), and isocyanic acid (HNCO) in the mass spectrometry data collected in the coma of 67P. However, the relationship …

Suntan (And Other Solar Trigonometric Functions): Solutions For Fermi Questions: February 2025, John Adam

Mathematics & Statistics Faculty Publications

The article discusses the intensity of sunlight on the side of the author's face as they walk to and from their office, focusing on the solar zenith angle θ. It presents a formula for solar irradiance and explores how the intensity changes based on the angle and elevation. The solutions to the questions posed in the article provide insights into the maximum irradiance levels at different angles and elevations.

From Poetry To Policy: How H-Stem Has Guided My Research Path, Kayla D. Taylor

Student Works

Embry-Riddle PhD student Kayla Taylor was invited to share how Humanistic STEM has shaped her educational journey at the third annual Humanistic STEM symposium.

Vibrational And Electronic Spectroscopy Of 2-Cyanoindene Cations, Thomas E. Douglas-Walker, Eleanor K. Ashworth, Mark H. Stockett, Francis C. Daly, Isabelle Chambrier, Vincent J. Esposito, Marius Gerlach, Angel Zheng, Julianna Palotás, Andrew N. Cammidge, Ewen K. Campbell, Sandra BrüNken, James N. Bull

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

2-Cyanoindene is one of the few specific aromatic or polycyclic aromatic hydrocarbon (PAH) molecules positively identified in Taurus molecular cloud-1 (TMC-1), a cold, dense molecular cloud that is considered the nearest star-forming region to Earth. We report cryogenic mid-infrared (550–3200 cm^–1) and visible (16,500–20,000 cm^–1, over the D2 ← D0 electronic transition) spectra of 2-cyanoindene radical cations (2CNI⁺), measured using messenger tagging (He and Ne) photodissociation spectroscopy. The infrared spectra reveal the prominence of anharmonic couplings, particularly over the fingerprint region. There is a strong CN-stretching mode at 2177 ± 1 cm^–1 (4.593 …

Legal And Ethical Considerations For Balancing Space Innovation And Dark Sky Preservation, Sara M. Langston, Kayla D. Taylor

Publications

The proliferation of satellites in Earth’s orbit has significantly enhanced capabilities in communication, Earth observation, and scientific research. However, this rapid expansion presents considerable legal and ethical challenges, particularly regarding the preservation of dark and quiet skies. As low Earth orbit becomes increasingly congested, the implications for astronomical observation, environmental integrity, and cultural heritage require critical examination.

This presentation provides an interdisciplinary perspective on the legal, practical and ethical considerations essential for preserving dark and quiet skies. It begins by exploring the legal frameworks governing the use of space, highlighting relevant international treaties, national responsibilities, and emerging issues aimed at …

Statistical Methods For Interpreting Spatial And Temporal Heterogeneity Of Martian Tropical Water Ice Informed By Properties Of Crater Ejecta Types, Jamie D. Riggs, Michelle R. Kirchoff

College of Population Health Faculty Papers

The martian tropical water ice spatial and temporal distribution was characterized using impact crater ejecta type, location, size, and age in one of two epochs, (Formula presented.) Ga and (Formula presented.) Ga, using statistical models designed for spatial and temporal correlation structures. The indicator thought to identify the presence of ice is craters with layered ejecta, while the indicator thought to identify no ice is craters with radial ejecta. These indicators imply the location (longitude and latitude) and, potentially, depth (crater diameter as a proxy) of ice, and when the ice was present. The spatial and temporal distribution of layered …

Battle Of The Ch Motions: Aliphatic Vs Aromatic Contributions To Astronomical Pah Emission And Exploration Of The Aliphatic, Aromatic, And Ethynyl Ch Stretches, Vincent J. Esposito, Salma Bejaoui, Brant E. Billinghurst, Christiaan Boersma, Ryan C. Fortenberry, Farid Salama

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Strong anharmonic coupling between vibrational states in polycyclic aromatic hydrocarbons (PAH) produces highly mixed vibrational transitions that challenge the current understanding of the nature of the astronomical mid-infrared PAH emission bands. Traditionally, PAH emission bands have been characterized as either aromatic or aliphatic, and this assignment is used to determine the fraction of aliphatic carbon in astronomical sources. In reality, each of the transitions previously utilized for such an attribution is highly mixed with contributions from both aliphatic and aromatic CH motions as well as non-CH motions such as CC stretches. High-resolution gas-phase IR absorption measurements of the spectra of …

On The Formation And Detectability Of H2Cncn And Its Progenitors, Ryan C. Fortenberry, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

New highly exothermic formation pathways incorporating both thermodynamic and kinetic control for the newly astronomically detected H₂CNCN molecule are paired with extremely accurate quantum chemical rovibrational spectroscopic computations. The reactions between astronomically known CH₂CN/CH₂CCH + HNCN follow effectively identical pathways and proceed through stable intermediates and over deeply submerged transition states to form H₂CNCN and HCN/HCCH coproducts. Similarly, the reaction between CHM₂CN and NCN⁻ can also form H₂CNCN, although this pathway first requires the initial formation of NCN⁻, which is currently undetected in space, via …

Experimental Determination Of The Unusual Ch Stretch Frequency Of Protonated Fullerenes, Laura Finazzi, Vincent J. Esposito, Julianna Palotás, Jonathan Martens, Els Peeters, Jan Cami, Giel Berden, Jos Oomens

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We report experimental values for the CH stretch frequencies of the protonated fullerenes C₆₀H⁺ and C₇₀H⁺. Anharmonic frequency calculations at the B3LYP/6-31G level of theory, which are independent of empirical scaling factors, reproduce the experimental values to within approximately 5 cm⁻¹. Scaling theoretical harmonic frequencies by applying factors derived for polycyclic aromatic hydrocarbons deviate significantly from the experimentally measured frequency. We attribute this deviation to the unusual hydrocarbon structure that affects the degree of anharmonicity of the CH stretch. This result allows us to propose an original, specific scaling factor of …

Archaeology In Space: The Sampling Quadrangle Assemblages Research Experiment (Square) On The International Space Station. Report 1: Squares 03 And 05, Justin St. P. Walsh, Shawn Graham, Alice C. Gorman, Chantal Brousseau, Salma Abdullah

Art Faculty Articles and Research

Between January and March 2022, crew aboard the International Space Station (ISS) performed the first archaeological fieldwork in space, the Sampling Quadrangle Assemblages Research Experiment (SQuARE). The experiment aimed to: (1) develop a new understanding of how humans adapt to life in an environmental context for which we are not evolutionarily adapted, using evidence from the observation of material culture; (2) identify disjunctions between planned and actual usage of facilities on a space station; (3) develop and test techniques that enable archaeological research at a distance; and (4) demonstrate the relevance of social science methods and perspectives for improving life …

Assigning The Ch Stretch Overtone Spectrum Of Benzene And Naphthalene With Extension To Anthracene And Tetracene Using 2- And 3-Quanta Anharmonic Quantum Chemical Computations, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The CH stretch overtone region (5750–6300 cm⁻¹) of benzene and naphthalene is assigned herein using anharmonic quantum chemical computations, and the trend of how this extends to larger polycyclic aromatic hydrocarbons (PAHs) is established. The assignment of all experimental bands to specific vibrational states is performed for the first time. Resonance polyads and the inclusion of 3-quanta vibrational states are both needed to compute accurate vibrational frequencies with the proper density-of-states to match the experimental band shape. Hundreds of 3-quanta states produce the observed band structure in naphthalene, anthracene, and tetracene, and this number is expected to increase …

Cn Stretches Around 4.4 Microns Dominate The Ir Absorption Spectra Of Cyanopolycyclic Aromatic Hydrocarbons, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Alexandros Maragkoudakis, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonic quantum chemical computations reveal a strong, narrow (width = 0.075 μm) band in the 4.3–4.5 μm region of the absorption spectra of the cyano-substituted polycyclic aromatic hydrocarbons (CN-PAHs) cyanonaphthalene, cyanoanthracene, c yanophenanthrene, and c yanopyrene. This narro w windo w with intense IR lines implies that CN-PAHs of various shapes and sizes offer little variation in both wavelength and intensity in this region. Subsequently, this band can be used as a tracer for CN-PAHs. The distinct features making up the band are assigned to mixed vibrational states consisting of the CN stretch fundamental and various combination bands, including in-plane …

Modeling An Extra Planet's Effects On Earth, Emily Simpson

Aerospace, Physics, and Space Science Student Publications

Orbital dynamics play a crucial role in determining the habitability of exoplanets, and many models have been developed to study the dynamical evolution of broader planetary system structure. To further investigate the implications this has regarding planetary habitability, this project simulated the evolution of the Solar System with an additional planet orbiting in place of the Asteroid Belt using the Gravitational Rigid-body InTegrator (GRIT) package. 21 total simulations were run for 100,000 years with varying values for the extra planet’s mass (from 0.01 to 10 Earth masses) and orbital parameters (based on the 4 most massive asteroids in the Asteroid …

The Infrared Absorption Spectrum Of Phenylacetylene And Its Deuterated Isotopologue In The Mid- To Far-Ir, Vincent J. Esposito, Pierro Ferrari, Wybren Jan Buma, Ryan C. Fortenberry, Christiaan Boersma, Alessandra Candian, Alexander G. G. M. Tielens

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonicity strongly influences the absorption and emission spectra of polycyclic aromatic hydrocarbon (PAH) molecules. Here, IR–UV ion-dip spectroscopy experiments together with detailed anharmonic computations reveal the presence of fundamental, overtone, as well as 2- and 3-quanta combination band transitions in the far- and mid-infrared absorption spectra of phenylacetylene and its singly deuterated isotopologue. Strong absorption features in the 400–900 cm⁻¹ range originate from CH(D) in-plane and out-of-plane wags and bends, as well as bending motions including the C≡C and CH bonds of the acetylene substituent and the aromatic ring. For phenylacetylene, every absorption feature is assigned either directly or …

Toward The Ir Detection Of Carbon Acid: Absorption And Emission Spectrum, Ryan C. Fortenberry, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

With the recent radioastronomical detection of cis-trans-carbonic acid (H₂CO₃) in a molecular cloud toward the Galactic center, the more stable but currently unobserved cis-cis conformer is shown here to have strong IR features. While the higher-energy cis-trans-carbonic acid was detected at millimeter and centimeter wavelengths, owing to its larger dipole moment, the vibrational structure of cis-cis-carbonic acid is more amenable to its observation at micron wavelengths. Even so, both conformers have relatively large IR intensities, and some of these fall in regions not dominated by polycyclic aromatic hydrocarbons. Water features may inhibit observation …

Possible Evidences For Existence Of An Aether Medium (Or Virtual Inertia/Spin Superfluid Medium), Victor Christianto, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

The presentation explores the possibility of an aether medium, also referred to as a virtual inertia/spin superfluid medium, existing to explain certain physical phenomena. While the concept of an aether has been historically rejected by mainstream physics, recent findings and interpretations offer potential justifications for its reconsideration. After discussions with several physicists, notably Robert N. Boyd, PhD and others, we are convinced that aether medium does exist, or may be called virtual inertia/spin superfluid medium.

Refracting Ufos: Solutions For Fermi Questions, May 2024, John Adam

Mathematics & Statistics Faculty Publications

This article, titled "Refracting UFOs: Solutions for Fermi Questions, May 2024," recounts the author's personal experience as a teenager observing a UFO sighting near their home in England. The author used their telescope to observe the object, which turned out to be lights from a distant airplane flying in a circular holding pattern. The article then presents two questions related to the observed phenomenon, including estimating the diameter of the aircraft's path and the banking angle of the aircraft at its speed. The article concludes with a solution to estimating the distance to the aircraft. The information is presented objectively …