Astrophysics and Astronomy Commons^™

Detailed Abundances Of The Solar Twins 16 Cygni And B Cygni: Constraining Planet Formation Models, Simon C. Schuler, Katia Cunha, Verne V. Smith, Luan Ghezzi, Jeremy R. King, Constantine P. Deliyannis, Ann Merchant Boesgaard

Publications

Results of a detailed abundance analysis of the solar twins 16 Cyg A and 16 Cyg B based on high-resolution, high signal-to-noise ratio echelle spectroscopy are presented. 16 Cyg B is known to host a giant planet while no planets have yet been detected around 16 Cyg A. Stellar parameters are derived directly from our high-quality spectra, and the stars are found to be physically similar, with ΔTeff = +43 K, Δ log g =−0.02 dex, and Δξ = +0.10 km s−1 (in the sense of A − B), consistent with previous findings. Abundances of 15 elements are derived and …

Beating The Spin-Down Limit On Gravitational Wave Emission From The Vela Pulsar, J. Abadie, B. P. Abbott, Matthew Benacquista, Teviet Creighton, Mario C. Diaz, Soumya D. Mohanty, Soma Mukherjee, Volker Quetschke, Malik Rakhmanov, Joseph D. Romano

Physics & Astronomy Faculty Publications

We present direct upper limits on continuous gravitational wave emission from the Vela pulsar using data from the Virgo detector's second science run. These upper limits have been obtained using three independent methods that assume the gravitational wave emission follows the radio timing. Two of the methods produce frequentist upper limits for an assumed known orientation of the star's spin axis and value of the wave polarization angle of, respectively, 1.9 × 10-24 and 2.2 × 10-24, with 95% confidence. The third method, under the same hypothesis, produces a Bayesian upper limit of 2.1 × 10-24, with 95% degree of …

Guiding The Experimental Discovery Of Magnesium Alloys, Richard H. Taylor, Gus L. W. Hart, Stefano Curtarolo

Faculty Publications

Magnesium alloys are among the lightest structural materials known and are of considerable technological interest. To develop superior magnesium alloys, experimentalists must have a thorough understanding of the concentration-dependent precipitates that form in a given system, and hence, the thermodynamic stability of crystal phases must be determined. This information is often lacking but can be supplied by first-principles methods. Within the high-throughput framework, AFLOW, T = 0 K ground-state predictions are made by scanning a large set of known candidate structures for thermodynamic (formation energy) minima. The following 34 systems are investigated: AlMg, AuMg, CaMg, CdMg, CuMg, FeMg , GeMg, …

Galaxy Formation In Heavily Overdense Regions At Z ~ 10: The Prevalence Of Disks In Massive Halos, Emilio Romano-Díaz, Jun-Hwan Choi, Isaac Shlosman, Michele Trenti

Physics and Astronomy Faculty Publications

Using a high-resolution cosmological numerical simulation, we have analyzed the evolution of galaxies at z ~ 10 in a highly overdense region of the universe. These objects could represent the high-redshift galaxies recently observed by the Hubble's Wide Field Camera 3 and could as well be possible precursors of QSOs at z ~ 6-7. To overcome the sampling and resolution problems in cosmological simulations of these rare regions, we have used the constrained realizations method. Our main result for z ~ 10 shows the high-resolution central region of 3.5 h^–1 Mpc radius in comoving coordinates being completely dominated by …

Structure And Feedback In 30 Doradus. Ii. Structure And Chemical Abundances, E. W. Pellegrini, J. A. Baldwin, Gary J. Ferland

Physics and Astronomy Faculty Publications

We use our new optical-imaging and spectrophotometric survey of key diagnostic emission lines in 30 Doradus, together with CLOUDY photoionization models, to study the physical conditions and ionization mechanisms along over 4000 individual lines of sight at points spread across the face of the extended nebula, out to a projected radius 75 pc from R136 at the center of the ionizing cluster NGC 2070. We focus on the physical conditions, geometry, and importance of radiation pressure on a point-by-point basis, with the aim of setting observational constraints on important feedback processes. We find that the dynamics and large-scale structure of …

Discovery Of A Bright, Extremely Low Mass White Dwarf In A Close Double Degenerate System, S. Vennes, J. R. Thorstensen, A. Kawka, P. Németh, J. N. Skinner

Dartmouth Scholarship

We report the discovery of a bright (V ~ 13.7), extremely low-mass white dwarf in a close double degenerate system. We originally selected GALEX J171708.5+675712 for spectroscopic follow-up among a group of white dwarf candidates in an ultraviolet-optical reduced proper-motion diagram. The new white dwarf has a mass of 0.18 M_solar and is the primary component of a close double degenerate system (P=0.246137 d, K_1 = 288 km/s) comprising a fainter white dwarf secondary with M_2 ~ 0.9 M_solar. Light curves phased with the orbital ephemeris show evidence of relativistic beaming and weaker ellipsoidal variations. The light curves also reveal …

On The Measurement Of Angular Dependent Sound Transmission Through Airborne Supercritical Plates, Matthew D. Shaw

Theses and Dissertations

A method of measuring angular dependence of acoustic transmission through supercritical plates in air is discussed. The coincidence effect occurs in a supercritical plate when the component of the acoustic wave number parallel to the plate matches the bending wave number in the plate. The transmission of sound is a maximum at the angle where this trace wave number matching occurs. The theory of the coincidence effect is well-defined for unbounded thin plates using plane-wave excitation. However, experimental results for finite plates are known to diverge from theory, especially near grazing angles. An experimental setup has been developed in order …

Scaling Carbon Nanotube Localization By Floating Potential Dielectrophoresis: An Enabling Geometry, Brian S. Davis

Theses and Dissertations

Dielectrophoresis has been used as a technique for the parallel localization and alignment of both semiconducting and metallic carbon nanotubes (CNTs) at junctions between electrodes. A variation of this technique known as Floating Potential Dielectrophoresis (FPD) allows for a self-limiting number of CNTs to be localized at each junction, on a massively parallel scale. However, the smallest FPD geometries to date are restricted to conductive substrates and have a lower limit on floating electrode size. We present a geometry which eliminates this lower limit and enables FPD to be performed on non-conducting substrates. We also discuss experiments clarifying the self-limiting …

N Ii Λλ5668−5712: A New Class Of Spectral Features In Eta Carinae, Andrea Mehner, Kris Davidson, Gary J. Ferland

Physics and Astronomy Faculty Publications

We report on the N II λλ5668-5712 emission and absorption lines in the spectrum of η Carinae. Spectral lines of the stellar wind regions can be classified into four physically distinct categories: (1) low-excitation emission such as H I and Fe II, (2) higher-excitation He I features, (3) the N II lines discussed in this paper, and (4) He II emission. These categories have different combinations of radial velocity behavior, excitation processes, and dependences on the secondary star. The N II lines are the only known features that originate in "normal" undisturbed zones of the primary wind but depend primarily …

The Variable Quiescent X-Ray Emission Of The Neutron Star Transient Xte J1701-462, Joel K. Fridriksson, Jeroen Homan, Rudy Wijnands, Edward M. Cackett, Diego Altamirano, Nathalie Degenaar, Edward F. Brown, Mariano Méndez, Tomaso M. Belloni

Physics and Astronomy Faculty Research Publications

We present the results of continued monitoring of the quiescent neutron star low-mass X-ray binary XTE J1701-462 with Chandra and Swift. A new Chandra observation from 2010 October extends our tracking of the neutron star surface temperature from ≃ 800 days to ≃ 1160 days since the end of an exceptionally luminous 19 month outburst. This observation indicates that the neutron star crust may still be slowly cooling toward thermal equilibrium with the core; another observation further into quiescence is needed to verify this. The shape of the overall cooling curve is consistent with that of a broken power law, …

Supernova Remnants And Cosmic Ray Acceleration Mechanisms, Ariel L. Simons, Yasunobu Uchiyama

STAR Program Research Presentations

Supernova remnants (SNRs) are considered to be the primary energy source of galactic-origin cosmic rays. Within this prediction exist two models, leptonic and hadronic, to explain the acceleration of charged particles up to a PeV in energy. Using data from the Fermi Gamma-ray Space Telescope (FGST) each model is expected to produce a distinct spectral energy distribution (SED) over a photon energy range of 100MeV to 100GeV. This analysis is focused on the methods for generating SEDs for the SNR Cassiopeia A and how they can be used to constrain the likelihood of either acceleration model.

X-Ray Monitoring Of Classical Novae In The Central Region Of M 31 Iii. Autumn And Winter 2007/2008 And 2008/2009, M. Henze, W. Pietsch, F. Haberl, M. Hernanz, G. Sala, D. Hartzidimitriou, M. Della Velle, A. Rau, Dieter H. Hartmann, V. Burwitz

Publications

Context. Classical novae (CNe) represent the major class of supersoft X-ray sources (SSSs) in the central region of the galaxy M 31. Aims. We performed a dedicated monitoring of the M 31 central region with XMM-Newton and Chandra between Nov. 2007 and Feb. 2008 and between Nov. 2008 and Feb. 2009, respectively, to find SSS counterparts of CNe, determine the duration of their SSS phase, and derive physical outburst parameters. Methods. We systematically searched our data for X-ray counterparts of CNe, determined their X-ray light curves and characterised their spectra using blackbody fits and white dwarf (WD) atmosphere models. Additionally, …

Chandra X-Ray Spectroscopy Of The Very Early O Supergiant Hd 93129a: Constraints On Wind Shocks And The Mass-Loss Rate, David H. Cohen, M. Gagné, M. A. Leutenegger, James Paton Macarthur , '11, Emma Edwina Wollman , '09, J. O. Sundqvist, A. W. Fullerton, S. P. Owocki

Physics & Astronomy Faculty Works

We present an analysis of both the resolved X-ray emission-line profiles and the broad-band X-ray spectrum of the O-2 If* star HD 93129A, measured with the Chandra High Energy Transmission Grating Spectrometer ( HETGS). This star is among the earliest and most massive stars in the Galaxy, and provides a test of the embedded wind-shock scenario in a very dense and powerful wind. A major new result is that continuum absorption by the dense wind is the primary cause of the hardness of the observed X-ray spectrum, while intrinsically hard emission from colliding wind shocks contributes less than 10 per …

The Role Of Llnl's Fast Calibration Facility In Diagnosing Nif Fusion Plasmas, Joshua G. Thompson, Carey Scott, Greg V. Brown

STAR Program Research Presentations

The Fusion and Astrophysics (FAST) Calibration and Diagnostic Facility uses the original Electron Beam Ion Trap (EBIT-I) to profile x-ray filters that are used in the Dante Soft X-Ray Diagnostic at the National Ignition Facility (NIF). FAST has an advantage over any other facility not only for its high accuracy, but also for its proximity to NIF in the Lawrence Livermore National Laboratory (LLNL). This makes for highly accurate and near-instantaneous filter calibration turnover.

EBIT-I was first constructed to create, trap, and observe static highly charged ions (HCIs) and conduct experimental astrophysics (creating an x-ray spectroscopy catalogue of ions). To …

Laboratory Astrophysics: Using Ebit Measurements To Interpret High Resolution Spectra From Celestial Sources, Carey Scott, Joshua Thompson, N. Hell, Greg V. Brown

STAR Program Research Presentations

Astrophysicists use radiation to investigate the physics controlling a variety of celestial sources, including stellar atmospheres, black holes, and binary systems. By measuring the spectrum of the emitted radiation, astrophysicists can determine a source’s temperature and composition. Accurate atomic data are needed for reliably interpreting these spectra. Here we present an overview of how LLNL’s EBIT facility is used to put the atomic data on sound footing for use by the high energy astrophysics community.

New Cross Sections For H On H2 Collisional Transitions, Qianxia Zou

UNLV Theses, Dissertations, Professional Papers, and Capstones

The cross section for H on H₂ collisions is important for astrophysics as well as our understanding of the simple chemical systems. This is the simplest atom-molecule cross section. With a new H₃ potential surface by Mielke et al., we have modified the ABC code by Skouteris, Castillo and Manolopoulos to calculate new cross sections. These cross sections are compared to previous cross section calculations.

Mass Loss History Of Evolved Stars, Kathleen M. Geise

Electronic Theses and Dissertations

We provide high-resolution maps of the circumstellar dust shells of several dozen Asymptotic Giant Branch (AGB) stars using data from the Spitzer space telescope Multiband Imaging Photometer (MIPS) imaged at 70µm. AGB stars are the major contributors of chemical elements such as carbon, oxygen and silicon, which are essential to the existence of life in the universe, through mass loss processes that take place at the surface of the star. We probe the spatial distribution of cold (~40 K) dust grains in order to trace the history of mass loss from the observed radial density variation in these shells. Our …

The Ghosts Survey. I. Hubble Space Telescope Advanced Camera For Surveys Data., D. J. Radburn-Smith, R. S. De Jong, A. C. Seth, J. Bailin, E. F. Bell, T. M. Brown, J. S. Bullock, S. Courteau, J. J. Dalcanton, H. C. Ferguson, P. Goudfrooij, S. Holfeltz, Benne W. Holwerda, C. Purcell, J. Sick, D. Streich, M. Vlajic, D. B. Zucker

Faculty and Staff Scholarship

We present an overview of the GHOSTS survey, the largest study to date of the resolved stellar populations in the outskirts of disk galaxies. The sample consists of 14 disk galaxies within 17 Mpc, whose outer disks and halos are imaged with the Hubble Space Telescope Advanced Camera for Surveys (ACS). In the first paper of this series, we describe the sample, explore the benefits of using resolved stellar populations, and discuss our ACS F606W and F814W photometry. We use artificial star tests to assess completeness and use overlapping regions to estimate photometric uncertainties. The median depth of the survey …

Star Messangers, Paul Zimet, Ellen Maddow

Kahn Institute Projects

Star Messengers is a musical theater work about two scientists, Galileo Galilei and Johannes Kepler, who changed our view of the universe. Writer Paul Zimet and composer Ellen Maddow have created a carnival of genres—opera, Com- media dell’Arte, Strindbergian Dream Play, and contemporary dance/theater—to produce a theatrical language that conveys the wonder of Galileo’s and Kepler’s discoveries.

While some aspects of Galileo’s life and discoveries are well known, hardly anything is popularly known of his scientific contemporaries. Johannes Kepler’s realization that the planets moved not in perfect circles, but in elliptical paths, was a leap of mind as extraordinary as …

Helical Antiferromagnetic Ordering In The Lowest Landau Level Of A Semiconductor Superlattice, Liqiu Zheng, D C. Marinescu

Publications

When subjected to a tilted magnetic field, the ground state of a semiconductor superlattice (SL) with two identical quantum wells per unit cell is shown to exhibit different magnetic configurations that are dependent on the strength and direction of the field and the SL characteristics. Intra- and interunit cell tunneling between the wells, assumed to be infinitely attractive, generate an energy miniband structure of the lowest Landau level that, in cooperation with the Zeeman splitting, creates, at certain points in the momentum space, an energy difference between opposite-spin single-particle states that can be overcome by the Coulomb interaction. Within the …

From The Big Bang To Table Mountain: The Cosmic Biography Of Atoms, Shane L. Larson

Public Talks

No abstract provided.

New Precision Orbits Of Bright Double-Lined Spectroscopic Binaries. Vii. 47 Andromedae, 38 Cassiopeiae, And Hr 8467, Francis C. Fekel, Jocelyn Tomkin, Michael H. Williamson, Dimitri Pourbaix

Information Systems and Engineering Management Research Publications

Improved orbital elements for three double-lined spectroscopic binaries, 47 And, 38 Cas, and HR 8467, have been determined with extensive new radial velocities. For 38 Cas lines of the secondary have been detected for the first time. Given the orbital periods for these systems of 35.3682, 134.130, and 42.3813 days, respectively, it is not surprising that all three have either moderate or relatively high eccentricities. The orbital dimensions (a1sin i and a2sin i) and minimum masses (m1sin 3i and m2sin 3i) have accuracies of 0.5% or better. An astrometric orbit for 38 Cas, which was recomputed with Hipparcos astrometry and …

Investigating Students' Mental Models And Knowledge Construction Of Microscopic Friction. I. Implications For Curriculum Design And Development, Edgar D. Corpuz, N. Sanjay Rebello

Physics & Astronomy Faculty Publications

In this paper, we discuss the first phase of a multiphase study aimed at investigating the dynamics of students' knowledge construction in the context of unfamiliar physical phenomenon-microscopic friction. The first phase of this study involved the investigation of the variations in students' mental models of microscopic friction. Clinical interviews were conducted with 11 students enrolled in conceptual modern physics to elicit their ideas and generate themes of explanations. A phenomenographic approach of data analysis was employed to establish the variations in students' explanations. Results show that students' mental models of friction at the atomic level are dominated by their …

Ejecta Knot Flickering, Mass Ablation, And Fragmentation In Cassiopeia A, Robert A. Fesen, Jordan A. Zastrow, Molly C. Hammell, J. Michael Shull, Devin W. Silvia

Dartmouth Scholarship

Ejecta knot flickering, ablation tails, and fragmentation are expected signatures associated with the gradual dissolution of high-velocity supernova (SN) ejecta caused by their passage through an inhomogeneous circumstellar medium or interstellar medium (ISM). Such phenomena mark the initial stages of the gradual merger of SN ejecta with and the enrichment of the surrounding ISM. Here we report on an investigation of this process through changes in the optical flux and morphology of several high-velocity ejecta knots located in the outskirts of the young core-collapse SN remnant Cassiopeia A using Hubble Space Telescope images. Examination of WFPC2 F675W and combined ACS …

Torus And Active Galactic Nucleus Properties Of Nearby Seyfert Galaxies: Results From Fitting Infrared Spectral Energy Distributions And Spectroscopy, Almudena Alonso-Herrero, Almeida Cristina Ramos, Rachel Mason, Ramos Andrés Asensio, Patrick F. Roche, Nancy A. Levenson, Moshe Elitzur, Christopher Packham, José Miguel Rodríguez Espinosa, Stuart Young, Tanio Díaz-Santos, Ana M. Pérez-García

Physics and Astronomy Faculty Publications

We used the CLUMPY torus models and a Bayesian approach to fit the infrared spectral energy distributions and ground-based high angular resolution mid-infrared spectroscopy of 13 nearby Seyfert galaxies. This allowed us to put tight constraints on torus model parameters such as the viewing angle i, the radial thickness of the torus Y, the angular size of the cloud distribution σ_torus, and the average number of clouds along radial equatorial rays N₀. We found that the viewing angle i is not the only parameter controlling the classification of a galaxy into type 1 or …

Photoemission By Large Electron Wave Packets Emitted Out The Side Of A Relativistic Laser Focus, Eric Flint Cunningham

Theses and Dissertations

There are at least two common models for calculating the photoemission of accelerated electrons. The 'extended-charge-distribution' method uses the quantum probability current (multiplied by the electron charge) as a source current for Maxwell's equations. The 'point-like-emitter' method treats the electron like a point particle instead of like a diffuse body of charge. Our goal is to differentiate between these two viewpoints empirically. To do this, we consider a large electron wave packet in a high-intensity laser field, in which case the two viewpoints predict measurable photoemission rates that differ by orders of magnitude. Under the treatment of the 'extended-charge-distribution' model, …

Dynamical Masses Of Early-Type Galaxies: A Comparison To Lensing Results And Implications For The Stellar Initial Mass Function And The Distribution Of Dark Matter, J. Thomas, R. P. Saglia, R. Bender, D. Thomas, K. Gebhardt, J. Magorrian, E. M. Corsini, G. Wegner, S. Seitz

Dartmouth Scholarship

This work aims to study the distribution of the luminous and dark matter in Coma early-type galaxies. Dynamical masses obtained under the assumption that mass follows light do not match with the masses of strong gravitational lens systems of similar velocity dispersions. Instead, dynamical fits with dark matter haloes are in good agreement with lensing results. We derive mass-to-light ratios of the stellar populations from Lick absorption line indices, reproducing well the observed galaxy colours. Even in dynamical models with dark matter haloes the amount of mass that follows the light increases more rapidly with the galaxy velocity dispersion than …

The Dark Side Of Qso Formation At High Redshifts, Emilio Romano-Díaz, Isaac Shlosman, Michele Trenti, Yehuda Hoffman

Physics and Astronomy Faculty Publications

Observed high-redshift QSOs, at z ~ 6, may reside in massive dark matter (DM) halos of more than 10¹² M_☉ and are thus expected to be surrounded by overdense regions. In a series of 10 constrained simulations, we have tested the environment of such QSOs. The usage of constrained realizations has enabled us to address the issue of cosmic variance and to study the statistical properties of the QSO host halos. Comparing the computed overdensities with respect to the unconstrained simulations of regions empty of QSOs, assuming there is no bias between the DM and baryon distributions, and …

The Young Exoplanet Transit Initiative (Yeti), R. Neuhäuser, R. Errmann, A. Berndt, G. Maciejewski, H. Takahashi, W. P. Chen, D. P. Dimitrov, T. Pribulla, E. H. Nikogossian, Eric L.N. Jensen, L. Marschall, Z.-Y. Wu, A. Kellerer, F. M. Walter, C. Briceño, R. Chini, M. Fernández, S. Raetz, G. Torres, D. W. Latham, S. N. Quinn, A. Niedzielski, L. Bukowiecki, G. Nowak, T. Tomov, K. Tachihara, S. C.-L. Hu, L. W. Hung, D. P. Kjurkchieva, V. S. Radeva, B. M. Mihov, L. Slavcheva-Mihova, I. N. Bozhinova, J. Budaj, M. Vanko, E. Kundra, L. Hambalek, V. Krushevska, T. Movsessian, H. Harutyunyan, J. J. Downes, J. Hernandez, V. H. Hoffmeister, David H. Cohen, Imoleayo Samson Abel , '14, Rebecca Ruby Ahmad , '14, Seth Walker Chapman , '14, Sierra Clare Eckert , '14, Jackson Goodman , '13, Adrien Charles Guerard , '14, H. M. Kim, Andrew Evan Koontharana , '11, Joshua Daniel Sokol , '11, Jennifer Trinh , '11, Yuwen Wang , '14, X. Zhou, R. Redmer, U. Kramm, N. Nettelmann, M. Mugrauer, J. Schmidt, M. Moualla, C. Ginski, C. Marka, C. Adam, M. Seeliger, S. Baar, T. Roell, T. O.B. Schmidt, L. Trepl, T. Eisenbeiss, S. Fiedler, N. Tetzlaff, E. Schmidt, M. M. Hohle, M. Kitze, N. Chakrova, C. Grafe, K. Schreyer, V. V. Hambaryan, C. H. Broeg, J. Koppenhoefer, A. K. Pandey

Physics & Astronomy Faculty Works

We present the Young Exoplanet Transit Initiative (YETI), in which we use several 0.2 to 2.6-m telescopes around the world to monitor continuously young (<= 100 Myr), nearby (<= 1 kpc) stellar clusters mainly to detect young transiting planets (and to study other variability phenomena on time-scales from minutes to years). The telescope network enables us to observe the targets continuously for several days in order not to miss any transit. The runs are typically one to two weeks long, about three runs per year per cluster in two or three subsequent years for about ten clusters. There are thousands of stars detectable in each field with several hundred known cluster members, e. g. in the first cluster observed, Tr-37, a typical cluster for the YETI survey, there are at least 469 known young stars detected in YETI data down to R = 16.5 mag with sufficient precision of 50 millimag rms (5 mmag rms down to R = 14.5 mag) to detect transits, so that we can expect at least about one young transiting object in this cluster. If we observe similar to 10 similar clusters, we can expect to detect similar to 10 young transiting planets with radius determinations. The precision given above is for a typical telescope of the YETI network, namely the 60/90-cm Jena telescope (similar brightness limit, namely within +/-1 mag, for the others) so that planetary transits can be detected. For targets with a periodic transit-like light curve, we obtain spectroscopy to ensure that the star is young and that the transiting object can be sub-stellar; then, we obtain Adaptive Optics infrared images and spectra, to exclude other bright eclipsing stars in the (larger) optical PSF; we carry out other observations as needed to rule out other false positive scenarios; finally, we also perform spectroscopy to determine the mass of the transiting companion. For planets with mass and radius determinations, we can calculate the mean density and probe the internal structure. We aim to constrain planet formation models and their time-scales by discovering planets younger than similar to 100 Myr and determining not only their orbital parameters, but also measuring their true masses and radii, which is possible so far only by the transit method. Here, we present an overview and first results. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

The Role Of Hole Localization In Sacrificial Hydrogen Production By Semiconductor-Metal Heterostructured Nanocrystals, Krishna P. Acharya, Rony S. Khnayzer, Timothy O’Connor, Geoffrey Diederich, Maria Kirsanova, Anna Klinkova, Daniel Roth, Erich Kinder, Martene Imboden, Mikhail Zamkov

Physics and Astronomy Faculty Publications

The effect of hole localization on photocatalytic activity of Pt-tipped semiconductor nanocrystals is investigated. By tuning the energy balance at the semiconductor-ligand interface, we demonstrate that hydrogen production on Pt sites is efficient only when electron-donating molecules are used for stabilizing semiconductor surfaces. These surfactants play an important role in enabling an efficient and stable reduction of water by heterostructured nanocrystals as they fill vacancies in the valence band of the semiconductor domain, preventing its degradation. In particular, we show that the energy of oxidizing holes can be efficiently transferred to a ligand moiety, leaving the semiconductor domain intact. This …